Ultra-fast diffusion of hydrogen in a novel mesoporous N-doped carbon
The diffusional behaviour of H2 adsorbed in a novel mesoporous N-doped carbon material and on exfoliated graphite has been studied with quasi-elastic neutron scattering. While the activation energies for diffusion obtained for exfoliated graphite was in line with prior results, H2 in the mesoporous...
- Autores:
-
Bahn, Emanuel
Hoyos Giraldo, Leidy Astrid
Kuznetsov, Vitalii
Calvo Almazán, Irene
Zbiri, Mohamed
Koza, Michael Marek
Hansen, Thomas C.
Henry, Paul F.
Lapp, Alain
Pouget, Stéphanie
Mesa Cadavid, Mónica
Fouquet, Peter
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2020
- Institución:
- Tecnológico de Antioquia
- Repositorio:
- Repositorio Tdea
- Idioma:
- eng
- OAI Identifier:
- oai:dspace.tdea.edu.co:tdea/2902
- Acceso en línea:
- https://dspace.tdea.edu.co/handle/tdea/2902
- Palabra clave:
- Carbono
Carbon
Carbone
Carbono mesoporoso
Mesoporous carbon
N mesoporoso
N mesoporous
- Rights
- closedAccess
- License
- http://purl.org/coar/access_right/c_14cb
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Ultra-fast diffusion of hydrogen in a novel mesoporous N-doped carbon |
| title |
Ultra-fast diffusion of hydrogen in a novel mesoporous N-doped carbon |
| spellingShingle |
Ultra-fast diffusion of hydrogen in a novel mesoporous N-doped carbon Carbono Carbon Carbone Carbono mesoporoso Mesoporous carbon N mesoporoso N mesoporous |
| title_short |
Ultra-fast diffusion of hydrogen in a novel mesoporous N-doped carbon |
| title_full |
Ultra-fast diffusion of hydrogen in a novel mesoporous N-doped carbon |
| title_fullStr |
Ultra-fast diffusion of hydrogen in a novel mesoporous N-doped carbon |
| title_full_unstemmed |
Ultra-fast diffusion of hydrogen in a novel mesoporous N-doped carbon |
| title_sort |
Ultra-fast diffusion of hydrogen in a novel mesoporous N-doped carbon |
| dc.creator.fl_str_mv |
Bahn, Emanuel Hoyos Giraldo, Leidy Astrid Kuznetsov, Vitalii Calvo Almazán, Irene Zbiri, Mohamed Koza, Michael Marek Hansen, Thomas C. Henry, Paul F. Lapp, Alain Pouget, Stéphanie Mesa Cadavid, Mónica Fouquet, Peter |
| dc.contributor.author.none.fl_str_mv |
Bahn, Emanuel Hoyos Giraldo, Leidy Astrid Kuznetsov, Vitalii Calvo Almazán, Irene Zbiri, Mohamed Koza, Michael Marek Hansen, Thomas C. Henry, Paul F. Lapp, Alain Pouget, Stéphanie Mesa Cadavid, Mónica Fouquet, Peter |
| dc.subject.agrovoc.none.fl_str_mv |
Carbono Carbon Carbone |
| topic |
Carbono Carbon Carbone Carbono mesoporoso Mesoporous carbon N mesoporoso N mesoporous |
| dc.subject.proposal.none.fl_str_mv |
Carbono mesoporoso Mesoporous carbon N mesoporoso N mesoporous |
| description |
The diffusional behaviour of H2 adsorbed in a novel mesoporous N-doped carbon material and on exfoliated graphite has been studied with quasi-elastic neutron scattering. While the activation energies for diffusion obtained for exfoliated graphite was in line with prior results, H2 in the mesoporous carbon showed an exceptionally low diffusion barrier and behaved qualitatively like liquid hydrogen. Complementary results from neutron and X-ray diffraction as well as from isothermal nitrogen sorption studies provide a full characterisation of this novel mesoporous carbon. |
| publishDate |
2020 |
| dc.date.issued.none.fl_str_mv |
2020 |
| dc.date.accessioned.none.fl_str_mv |
2023-05-16T22:35:06Z |
| dc.date.available.none.fl_str_mv |
2023-05-16T22:35:06Z |
| dc.type.spa.fl_str_mv |
Artículo de revista |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.content.spa.fl_str_mv |
Text |
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info:eu-repo/semantics/article |
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http://purl.org/redcol/resource_type/ART |
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info:eu-repo/semantics/publishedVersion |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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0008-6223 |
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https://dspace.tdea.edu.co/handle/tdea/2902 |
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0008-6223 |
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https://dspace.tdea.edu.co/handle/tdea/2902 |
| dc.language.iso.spa.fl_str_mv |
eng |
| language |
eng |
| dc.relation.citationendpage.spa.fl_str_mv |
315 |
| dc.relation.citationstartpage.spa.fl_str_mv |
307 |
| dc.relation.citationvolume.spa.fl_str_mv |
166 |
| dc.relation.ispartofjournal.spa.fl_str_mv |
Carbon |
| dc.relation.references.spa.fl_str_mv |
Davis, S.J., Lewis, N.S., Shaner, M., Aggarwal, S., Arent, D., Azevedo, I.L., et al. Net-zero emissions energy systems. Science 2018;360(6396):eaas9793. Jin, H., Guo, C., Liu, X., Liu, J., Vasileff, A., Jiao, Y., et al. Emerging TwoDimensional Nanomaterials for Electrocatalysis. Chem Rev 2018;118(13):6337–6408. Z¨uttel, A., Sudan, P., Mauron, P., Kiyobayashi, T., Emmenegger, C., Schlapbach, L.. Hydrogen storage in carbon nanostructures. Int J Hydrogen Energy 2002;27(2):203–212. Z¨uttel, A.. Hydrogen storage methods. Naturwissenschaften 2004;91(4):157–172. Candelaria, S.L., Shao, Y., Li, X., Xiao, J., Zhang, J.G., Wang, Y., et al. Nanostructured carbon for energy storage and conversion. Nano Energy 2012;1(2):195–220. Zhang, Q., Uchaker, E., Candelaria, S.L., Cao, G.. Nanomaterials for energy conversion and storage. Chem Soc Rev 2013;42:3127–3171. Gadipelli, S., Guo, Z.X.. Graphene-based materials: Synthesis and gas sorption, storage and separation. Prog Mat Sci 2015;69:1–60. Chambers, A., Park, C., Baker, R.T.K., Rodriguez, N.M.. Hydrogen storage in graphite nanofibers. J Phys Chem B 1998;102(22):4253–4256. Dillon, A.C., Jones, K.M., Bekkedahl, T.A., Kiang, C.H., Bethune, D.S., Heben, M.J.. Storage of hydrogen in single-walled carbon nanotubes. Nature 1997;386(6623):377–379. Chen, P., Wu, X., Lin, J., Tan, K.L.. High H2 uptake by alkali-doped carbon nanotubes under ambient pressure and moderate temperatures. Science 1999;285(5424):91–93. Tanaka, H., Kanoh, H., El-Merraoui, M., Steele, W.A., Yudasaka, M., Iijima, S., et al. Quantum Effects on Hydrogen Adsorption in Internal Nanospaces of Single-Wall Carbon Nanohorns. J Phys Chem B 2004;108(45):17457–17465. Wang, L., Yang, R.T.. Molecular hydrogen and spiltover hydrogen storage on high surface area carbon sorbents. Carbon 2012;50(9):3134–3140. Kabbour, H., Baumann, T.F., Satcher, J.H., Saulnier, A., Ahn, C.C.. Toward New Candidates for Hydrogen Storage: High-Surface-Area Carbon Aerogels. Chem Mater 2006;18(26):6085–6087. Bahn, E., Czakkel, O., Nagy, B., L´aszl´o, K., Villar-Rodil, S., Tasc´on, J.M.D., et al. Diffusion of molecular hydrogen in carbon aerogel. Carbon 2016;98:572–581. Czakkel, O., Nagy, B., Dobos, G., Fouquet, P., Bahn, E., L´aszl´o, K.. Static and dynamic studies of hydrogen adsorption on nanoporous carbon gels. Int J Hydrogen Energy 2019;44(33):18169–18178. Nielsen, M., McTague, J.P., Ellenson, W.. Adsorbed Layers of D2, H2, O2, and 3He on Graphite Studied by Neutron Scattering. J Phys Colloq 1977;38(C4):C4–10 – C4–18. Bruch, L.W.. Physical Adsorption: Forces and Phenomena; vol. 6 of International series of monographs on chemistry. Oxford: Clarendon Press; 1997. ISBN 9780198556381. Freimuth, H., Wiechert, H., Lauter, H.J.. The commensurate-incommensurate transition of hydrogen monolayers physisorbed on graphite. Surf Sci 1987;189/190:548– 556 Freimuth, H., Wiechert, H., Schildberg, H.P., Lauter, H.J.. Neutron-diffraction study of the commensurate-incommensurate phase transition of deuterium monolayers physisorbed on graphite. Phys Rev B 1990;42(1):587–603. Wiechert, H.. Ordering phenomena and phase transitions in the physisorbed quantum systems H2, HD and D2. Physica B 1991;169(1–4):144–152. Bienfait, M., Zeppenfeld, P., Ramos Jr, R.C., Gay, J.M., Vilches, O.E., Coddens, G.. Isotopic ordering in adsorbed hydrogen monolayers. Phys Rev B 1999;60(16):11773–11782. Narehood, D., Pearce, J., Eklund, P., Sokol, P.E., Lechner, R.E., Pieper, J., et al. Diffusion of H2 adsorbed on single-walled carbon nanotubes. Phys Rev B 2003;67(20):1–5. Fernandez-Alonso, F., Bermejo, F.J., Cabrillo, C., Loutfy, R., Leon, V., Saboungi, M.. Nature of the Bound States of Molecular Hydrogen in Carbon Nanohorns. Phys Rev Lett 2007;98(21):1–4. Haas, O.E., Simon, J.M., Kjelstrup, S., Ramstad, A.L., Fouquet, P.. Quasi-elastic neutron scattering investigation of the hydrogen surface self-diffusion on polymer electrolyte membrane fuel cell catalyst support. J Phys Chem C 2008;112(8):3121– 3125. Contescu, C.I., Saha, D., Gallego, N.C., Mamontov, E., Kolesnikov, A.I., Bhat, V.V.. Restricted dynamics of molecular hydrogen confined in activated carbon nanopores. Carbon 2012;50(3):1071–1082. Haas, O.E., Simon, J.M., Kjelstrup, S.. Surface Self-Diffusion and Mean Displacement of Hydrogen on Graphite and a PEM Fuel Cell Catalyst Support. J Phys Chem C 2013;113(47):20281–20289. Bahn, E., Hedgeland, H., Jardine, A.P., Henry, P.F., Hansen, T.C., Fouquet, P.. The structure of deuterated benzene films adsorbed on the graphite (0001) basal plane: what happens below and above the monolayer coverage? Phys Chem Chem Phys 2014;16(40):22116–22121. Purewal, J., Keith, J.B., Ahn, C.C., Fultz, B., Brown, C.M., Tyagi, M.. Adsorption and melting of hydrogen in potassium-intercalated graphite. Phys Rev B 2009;79(5):1–7. Purewal, J., Keith, J.B., Ahn, C.C., Brown, C.M., Tyagi, M., Fultz, B.. Hydrogen diffusion in potassium intercalated graphite studied by quasielastic neutron scattering. J Chem Phys 2012;137(22):224704–1 – 224704–10. Yang, Y., Brown, C.M., Zhao, C., Chaffee, A.L., Nick, B., Zhao, D., et al. Microchannel development and hydrogen adsorption properties in templated microporous carbons containing platinum nanoparticles. Carbon 2011;49(4):1305–1317. Nguyen, T.X., Jobic, H., Bhatia, S.K.. Microscopic Observation of Kinetic Molecular Sieving of Hydrogen Isotopes in a Nanoporous Material. Phys Rev Lett 2010;105(8):1–4. Hoyos, L., Ramirez Velez, A., Mesa Cadavid, M.. Polymerization of aniline in different SBA-16 silica hosts. Quim Nova 2016;39(7):845–852. Hoyos Giraldo, L.A.. S´ıntesis y caracterizaci´on de materiales carbon´aceos porosos n-dopados y su evaluaci´on como soportes catal´ıticos para electrodos en celdas de hidr´ogeno s´ıntesis y caracterizaci´on de materiales carbon´aceos porosos n-dopados y su evaluaci´on como soportes catal´ıticos para electrodos en celdas de hidr´ogeno. Ph.D. thesis; University of Antioquia; 2016. Brunauer, S., Emmett, P.H., Teller, E.. Adsorption of gases in multimolecular layers. J Am Chem Soc 1938;60:309–319. Barrett, E.P., Joyner, L.G., Halenda, P.P.. The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms. J Am Chem Soc 1951;73:373–380. Iacomi, P., Llewellyn, P.L.. pyGAPS: a Python-based framework for adsorption isotherm processing and material characterisation. Adsorption 2019;25(8):1533–1542. Jagiello, J.. Stable numerical solution of the adsorption integral equation using splines. Langmuir 1994;10:2778–2785. Gilbert, E.P., Reynolds, P.A.. Characterisation of a basal-plane-oriented graphite. J Chem Soc, Faraday Trans 1 1998;94(13):1861–1868. Gilbert, E.P., Reynolds, P.A.. Characterisation of a basal-plane-oriented graphite. J Chem Soc, Faraday Trans 1 1998;94(13):1861–1868 Calvo-Almaz´an, I., Sacchi, M., Tamt¨ogl, A., Bahn, E., Koza, M.M., Miret-Art´es, S., et al. Ballistic Diffusion in Polyaromatic Hydrocarbons on Graphite. J Phys Chem Lett 2016;7(24):5285–5290. ILL, . The Yellow Book 2008. Grenoble: Institut Laue Langevin; 2008. Hansen, T., Henry, P., Fischer, H., Torregrossa, J., Convert, P.. The D20 instrument at the ILL: a versatile high-intensity 2-axis neutron diffractometer. Meas Sci Technol 2008;19:034001 Blanc, Y.. Le Spectrometre a temps de vol IN6. Grenoble: Institut Laue Langevin; 1983. Fouquet, P., Agnese, F., Bahn, E., Calvo Almazan, I., Hoyos Giraldo, L., Zbiri, M.; 2013;Hydrogen diffusion in novel porous carbon materials for fuel cells. URL: http://dx.doi.org/10.5291/ILL-DATA.7-05-415. Brochier, D.. Crysostat `a temp´erature variable pour mesures neutroniques ou optiques. Tech. Rep. 77/74; Institut Laue-Langevin; Grenoble; 1977. Bienfait, M., Zeppenfeld, P., Bovie, L.J., Vilches, O.E., Lauter, H.J.. Structure of monolayer films of hydrogen isotope mixtures. PHYSICA B-CONDENSED MATTER 1997;234-236:159–163. Richard, D., Ferrand, M., Kearley, G.J., Bradley, A.D.. The Lamp Book. Grenoble: Institut Laue Langevin; 2010. Thommes, M., Kaneko, K., Neimark, A.V., Olivier, J.P., Rodriguez-Reinoso, F., Rouquerol, J., et al. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure and Applied Chemistry 2015;87(9-10):1051–1069. Jagiello, J., Olivier, J.P.. 2D-NLDFT adsorption models for carbon slit-shaped pores with surface energetical heterogeneity and geometrical corrugation. Carbon 2013;55:70–80. Jagiello, J., Olivier, J.P.. Carbon slit pore model incorporating surface energetical heterogeneity and geometrical corrugation. Adsorption 2013;19(2-4):777–783. Silvestre-Albero, A., Silvestre-Albero, J., Mart´ınez-Escandell, M., Futamura, R., Itoh, T., Kaneko, K., et al. Non-porous reference carbon for N2 (77.4K) and Ar (87.3K) adsorption. Carbon 2014;66(C):699–704. Hammouda, B.. A new guinier-porod model. J Appl Cryst 2010;43:716–719. Sinha, S., Sirota, E., Garoff, S., Stanley, H.. X-ray and neutron scattering from rough surfaces. Phys Rev B 1988;38(4):2297–2312. Pattersson, A.L.. The scherrer formula for x-ray particle size determination. Phys Rev A 1939;56:978–982. Hammouda, B.. Analysis of the beaucage model. J Appl Cryst 2010;43:1474–1478. B´ee, M.. Quasielastic neutron scattering. Bristol: Adam Hilger; 1988. Singwi, K.S., Sj¨olander, A.. Diffusive motions in water and cold neutron scattering. Phys Rev 1960;119(3):863 Egelstaff, P.A.. An introduction to the liquid state. London: Academic Press; 1967. Hall, P.L., Ross, D.K.. Incoherent neutron scattering functions for random jump diffusion in bounded and infinite media. Mol Phys 1981;42(3):673–682. O’Reilly, D.E., Peterson, E.M.. Self-diffusion of liquid hydrogen and deuterium. J Chem Phys 1977;66:934–937. |
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Bahn, Emanuel5866134a-6a46-40a6-90fd-d5c2d00050a0Hoyos Giraldo, Leidy Astridcbfff834-4a40-4473-84b2-4ac983630978Kuznetsov, Vitaliia2811a91-24a6-4cd3-b5fd-9e5173af5bccCalvo Almazán, Irenec4bf85f4-8fd5-4105-9f87-50a1640fb5baZbiri, Mohamed40aafe63-6a9b-472b-865e-7ef3d2451f8dKoza, Michael Marek386a2bd7-1b5b-4d44-aa88-6557416d432bHansen, Thomas C.1a3a10c4-3cf3-4cc4-ae1b-d506de3ed759Henry, Paul F.54c35440-35a2-4d52-bc62-9eb08c689d9eLapp, Alain847d1720-7478-436f-a285-d404ac2a803bPouget, Stéphanie3c42c0ca-5a09-400f-994a-aee1884ec6caMesa Cadavid, Mónicacc285d24-9aa3-4a87-bec9-c6991242466cFouquet, Peterbe706fa5-5c5d-4a59-b116-2e26f13cc5232023-05-16T22:35:06Z2023-05-16T22:35:06Z20200008-6223https://dspace.tdea.edu.co/handle/tdea/2902The diffusional behaviour of H2 adsorbed in a novel mesoporous N-doped carbon material and on exfoliated graphite has been studied with quasi-elastic neutron scattering. While the activation energies for diffusion obtained for exfoliated graphite was in line with prior results, H2 in the mesoporous carbon showed an exceptionally low diffusion barrier and behaved qualitatively like liquid hydrogen. Complementary results from neutron and X-ray diffraction as well as from isothermal nitrogen sorption studies provide a full characterisation of this novel mesoporous carbon.7 páginasimage/jpegengElsevier BVReino Unidohttps://www.sciencedirect.com/science/article/abs/pii/S0008622320304413Ultra-fast diffusion of hydrogen in a novel mesoporous N-doped carbonArtículo de revistahttp://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85315307166CarbonDavis, S.J., Lewis, N.S., Shaner, M., Aggarwal, S., Arent, D., Azevedo, I.L., et al. Net-zero emissions energy systems. Science 2018;360(6396):eaas9793.Jin, H., Guo, C., Liu, X., Liu, J., Vasileff, A., Jiao, Y., et al. Emerging TwoDimensional Nanomaterials for Electrocatalysis. Chem Rev 2018;118(13):6337–6408.Z¨uttel, A., Sudan, P., Mauron, P., Kiyobayashi, T., Emmenegger, C., Schlapbach, L.. Hydrogen storage in carbon nanostructures. Int J Hydrogen Energy 2002;27(2):203–212.Z¨uttel, A.. Hydrogen storage methods. Naturwissenschaften 2004;91(4):157–172.Candelaria, S.L., Shao, Y., Li, X., Xiao, J., Zhang, J.G., Wang, Y., et al. Nanostructured carbon for energy storage and conversion. Nano Energy 2012;1(2):195–220.Zhang, Q., Uchaker, E., Candelaria, S.L., Cao, G.. Nanomaterials for energy conversion and storage. Chem Soc Rev 2013;42:3127–3171.Gadipelli, S., Guo, Z.X.. Graphene-based materials: Synthesis and gas sorption, storage and separation. Prog Mat Sci 2015;69:1–60.Chambers, A., Park, C., Baker, R.T.K., Rodriguez, N.M.. Hydrogen storage in graphite nanofibers. J Phys Chem B 1998;102(22):4253–4256.Dillon, A.C., Jones, K.M., Bekkedahl, T.A., Kiang, C.H., Bethune, D.S., Heben, M.J.. Storage of hydrogen in single-walled carbon nanotubes. Nature 1997;386(6623):377–379.Chen, P., Wu, X., Lin, J., Tan, K.L.. High H2 uptake by alkali-doped carbon nanotubes under ambient pressure and moderate temperatures. Science 1999;285(5424):91–93.Tanaka, H., Kanoh, H., El-Merraoui, M., Steele, W.A., Yudasaka, M., Iijima, S., et al. Quantum Effects on Hydrogen Adsorption in Internal Nanospaces of Single-Wall Carbon Nanohorns. J Phys Chem B 2004;108(45):17457–17465.Wang, L., Yang, R.T.. Molecular hydrogen and spiltover hydrogen storage on high surface area carbon sorbents. Carbon 2012;50(9):3134–3140.Kabbour, H., Baumann, T.F., Satcher, J.H., Saulnier, A., Ahn, C.C.. Toward New Candidates for Hydrogen Storage: High-Surface-Area Carbon Aerogels. Chem Mater 2006;18(26):6085–6087.Bahn, E., Czakkel, O., Nagy, B., L´aszl´o, K., Villar-Rodil, S., Tasc´on, J.M.D., et al. Diffusion of molecular hydrogen in carbon aerogel. Carbon 2016;98:572–581.Czakkel, O., Nagy, B., Dobos, G., Fouquet, P., Bahn, E., L´aszl´o, K.. Static and dynamic studies of hydrogen adsorption on nanoporous carbon gels. Int J Hydrogen Energy 2019;44(33):18169–18178.Nielsen, M., McTague, J.P., Ellenson, W.. Adsorbed Layers of D2, H2, O2, and 3He on Graphite Studied by Neutron Scattering. J Phys Colloq 1977;38(C4):C4–10 – C4–18.Bruch, L.W.. Physical Adsorption: Forces and Phenomena; vol. 6 of International series of monographs on chemistry. Oxford: Clarendon Press; 1997. ISBN 9780198556381.Freimuth, H., Wiechert, H., Lauter, H.J.. The commensurate-incommensurate transition of hydrogen monolayers physisorbed on graphite. Surf Sci 1987;189/190:548– 556Freimuth, H., Wiechert, H., Schildberg, H.P., Lauter, H.J.. Neutron-diffraction study of the commensurate-incommensurate phase transition of deuterium monolayers physisorbed on graphite. Phys Rev B 1990;42(1):587–603.Wiechert, H.. 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J Chem Phys 1977;66:934–937.info:eu-repo/semantics/closedAccesshttp://purl.org/coar/access_right/c_14cbCarbonoCarbonCarboneCarbono mesoporosoMesoporous carbonN mesoporosoN mesoporousORIGINALUltra-fast diffusion of hydrogen in a novel mesoporous N-doped carbon.jpgUltra-fast diffusion of hydrogen in a novel mesoporous N-doped carbon.jpgSolo datos del documentoimage/jpeg215179https://dspace.tdea.edu.co/bitstream/tdea/2902/1/Ultra-fast%20diffusion%20of%20hydrogen%20in%20a%20novel%20mesoporous%20N-doped%20carbon.jpge1fd5c41dd24c594624bbaf9f32229e6MD51open accessLICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://dspace.tdea.edu.co/bitstream/tdea/2902/2/license.txt2f9959eaf5b71fae44bbf9ec84150c7aMD52open accessTHUMBNAILUltra-fast diffusion of hydrogen in a novel mesoporous N-doped carbon.jpg.jpgUltra-fast diffusion of hydrogen in a novel mesoporous N-doped carbon.jpg.jpgGenerated Thumbnailimage/jpeg11450https://dspace.tdea.edu.co/bitstream/tdea/2902/3/Ultra-fast%20diffusion%20of%20hydrogen%20in%20a%20novel%20mesoporous%20N-doped%20carbon.jpg.jpg6a975152e9b11266d65a8fb5648d9163MD53open accesstdea/2902oai:dspace.tdea.edu.co:tdea/29022023-05-17 03:00:22.223open accessRepositorio Institucional Tecnologico de 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 incorporada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.
 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