Ultra-fast diffusion of hydrogen in a novel mesoporous N-doped carbon

The diffusional behaviour of H2 adsorbed in a novel mesoporous N-doped carbon material and on exfoliated graphite has been studied with quasi-elastic neutron scattering. While the activation energies for diffusion obtained for exfoliated graphite was in line with prior results, H2 in the mesoporous...

Full description

Autores:
Bahn, Emanuel
Hoyos Giraldo, Leidy Astrid
Kuznetsov, Vitalii
Calvo Almazán, Irene
Zbiri, Mohamed
Koza, Michael Marek
Hansen, Thomas C.
Henry, Paul F.
Lapp, Alain
Pouget, Stéphanie
Mesa Cadavid, Mónica
Fouquet, Peter
Tipo de recurso:
Article of investigation
Fecha de publicación:
2020
Institución:
Tecnológico de Antioquia
Repositorio:
Repositorio Tdea
Idioma:
eng
OAI Identifier:
oai:dspace.tdea.edu.co:tdea/2902
Acceso en línea:
https://dspace.tdea.edu.co/handle/tdea/2902
Palabra clave:
Carbono
Carbon
Carbone
Carbono mesoporoso
Mesoporous carbon
N mesoporoso
N mesoporous
Rights
closedAccess
License
http://purl.org/coar/access_right/c_14cb
Description
Summary:The diffusional behaviour of H2 adsorbed in a novel mesoporous N-doped carbon material and on exfoliated graphite has been studied with quasi-elastic neutron scattering. While the activation energies for diffusion obtained for exfoliated graphite was in line with prior results, H2 in the mesoporous carbon showed an exceptionally low diffusion barrier and behaved qualitatively like liquid hydrogen. Complementary results from neutron and X-ray diffraction as well as from isothermal nitrogen sorption studies provide a full characterisation of this novel mesoporous carbon.