Remoción de fenol en una corriente de aire mediante el proceso de biofiltración

En el proceso de biofiltración la biodegradación de una corriente de aire contaminada con fenol se realizó con una concentración sobresaturada de 100 ppm de entrada y un tiempo de retención (tr) de 92.4 segundos, con una operación continua de 30 días en los cuales se evaluaron parámetros como humeda...

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Autores:
De La Hoz, Yira Jiménez
Acosta Díaz, Viviana
Tipo de recurso:
Trabajo de grado de pregrado
Fecha de publicación:
2011
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Universidad Libre
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RIU - Repositorio Institucional UniLibre
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spa
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https://hdl.handle.net/10901/11295
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Tesis
Tesis ingeniería
Facultad de ingeniería
Ingeniería ambiental
Medio ambiente
Medio ambiente natural
Aire
Atmósfera
Medio ambiente
Vapor
Luz solar
Óxidos de nitrógeno
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http://creativecommons.org/licenses/by-nc-nd/2.5/co/
id RULIBRE2_c7aada733c6a61a671b94ff1e6731f79
oai_identifier_str oai:repository.unilibre.edu.co:10901/11295
network_acronym_str RULIBRE2
network_name_str RIU - Repositorio Institucional UniLibre
repository_id_str
dc.title.spa.fl_str_mv Remoción de fenol en una corriente de aire mediante el proceso de biofiltración
title Remoción de fenol en una corriente de aire mediante el proceso de biofiltración
spellingShingle Remoción de fenol en una corriente de aire mediante el proceso de biofiltración
Tesis
Tesis ingeniería
Facultad de ingeniería
Ingeniería ambiental
Medio ambiente
Medio ambiente natural
Aire
Atmósfera
Medio ambiente
Vapor
Luz solar
Óxidos de nitrógeno
title_short Remoción de fenol en una corriente de aire mediante el proceso de biofiltración
title_full Remoción de fenol en una corriente de aire mediante el proceso de biofiltración
title_fullStr Remoción de fenol en una corriente de aire mediante el proceso de biofiltración
title_full_unstemmed Remoción de fenol en una corriente de aire mediante el proceso de biofiltración
title_sort Remoción de fenol en una corriente de aire mediante el proceso de biofiltración
dc.creator.fl_str_mv De La Hoz, Yira Jiménez
Acosta Díaz, Viviana
dc.contributor.advisor.none.fl_str_mv Suarez Escobar, Andrés Felipe
dc.contributor.author.none.fl_str_mv De La Hoz, Yira Jiménez
Acosta Díaz, Viviana
dc.subject.lemb.spa.fl_str_mv Tesis
Tesis ingeniería
Facultad de ingeniería
Ingeniería ambiental
Medio ambiente
Medio ambiente natural
Aire
Atmósfera
topic Tesis
Tesis ingeniería
Facultad de ingeniería
Ingeniería ambiental
Medio ambiente
Medio ambiente natural
Aire
Atmósfera
Medio ambiente
Vapor
Luz solar
Óxidos de nitrógeno
dc.subject.proposal.spa.fl_str_mv Medio ambiente
Vapor
Luz solar
Óxidos de nitrógeno
description En el proceso de biofiltración la biodegradación de una corriente de aire contaminada con fenol se realizó con una concentración sobresaturada de 100 ppm de entrada y un tiempo de retención (tr) de 92.4 segundos, con una operación continua de 30 días en los cuales se evaluaron parámetros como humedad del material de relleno, temperatura, pH, con el fin de establecer la eficiencia de remoción de en el biofiltro. El biofiltro se compone se 4 etapas en las cuales se observó una remoción promedio de 97%, presentando una máxima remoción en la etapa 4 con un 100% de remoción y una minima de 92% en la etapa 2. A los 20 días de puesta en marcha se encontró que el porcentaje de humedad estaba en un 15% y había una caída de presión promedio de 1.2 mmHg, esto implica que para las variables estudiadas que determinan el desarrollo óptimo del biofiltro no se cumplieron los limitos mínimos establecidos en estudios previos. Por lo tanto, se considera que el alto porcentaje de eficiencia de remoción se debe a que en la salida de corriente en la etapa 4, no hubo un caudal suficiente de gas que permitiera medir con precisión la cantidad de fenol presente en ella. Se concluye que teniendo un control detallado de las variables que intervienen en el proceso se puede obtener una alta eficacia en el tratamiento de aire contaminado con fenol por medio de la biofiltración.
publishDate 2011
dc.date.created.none.fl_str_mv 2011-07
dc.date.accessioned.none.fl_str_mv 2018-03-16T16:32:06Z
dc.date.available.none.fl_str_mv 2018-03-16T16:32:06Z
dc.type.local.spa.fl_str_mv Tesis de Pregrado
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dc.identifier.instname.spa.fl_str_mv instname:Universidad Libre
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dc.relation.references.Spa.fl_str_mv Klapková, E., Halecký, M., Fitch, M. et al. Impact of Biocatalyst and Moisture Content on Toluene / Xylene Mixture Biofiltration. Brazilian Archives of Biology and Technology. Vol 49 p 1001-1006. 2006.
TOX FAQ. Phenol Characterization. Agency for toxic substances and disease registry. 1999
Classification NIOSH for Phenol. National institute for occupational safety and health. p 29. 1992
Classification OSHA for Phenol. Occupational safety and health guideline. Table Z-1. 1992
dc.relation.references.Eng.fl_str_mv Kyun, J., Kam, S. & Lee, M. Characteristics of benzene, toluene and xylene gas removal by a biofilter using scoria. International Journal of Environment and Pollution. Vol. 39 p 264 – 278, 2009
Yanick, M. & Ramsay. Active compost biofiltration of toluene. Journal of Biodegradation. Vol 8. p 135-145, 1997.
Lim, J., Park, S., Koo, J. & Park, H. Evaluation of Porous Ceramic as Microbial Carrier of Biofilter to Remove Toluene Vapor. Journal of Environmental Technology. Vol. 22. p. 47-56, 2001.
Moe, W. & Irvine, R. Polyurethane foam based biofilter media for toluene removal. Journal of Water Science and Technology. Vol 43. p 35–42. 2001.
Kyun, J., Kam, S. & Lee, M. Characteristics of benzene, toluene and xylene gas removal by a biofilter using scoria. International Journal of Environment and Pollution. Vol 39 p. 264 – 278. 2009.
Chang, K. & Lu, C. Biofiltration of toluene and acetone mixtures by a tricklebed air biofilter. World -Journal of Microbiology and Biotechnology. Vol 19 p. 791- 798, 2003.
Mario Zilli, 1993, 1996;. Ritchie y Hill, 1995; Nikakhtari y Hill, 2006. Laboratory- Scale experiments with a powdered compost biofilter treating benzene-polluted air. Process Biochem, Vol 40 p. 2035-2043.
Klaudia Chmiel, Agnieszka Konieczny, Michał Palica and A.B. Jarze¸bski , Devinny y col., Periodic operation of biofilters. A concise model and experimental validation, Department of Chemical Engineering, Faculty of Chemistry, Silesian University of Technology, M.
Kwang-Hee Lim† and Eun Ju Lee Ottengraff, . Biofilter Modeling for Waste Air Treatment, Comparisons of Inherent Characteristics of Biofilter Models, Department of Chemical Engineering. P 712-714. 2002
Khan y Ghoshal, 2000; y Ray Wang, 2000; Jeong et al, 2004;. Delhomenie y Heitz, 2005; Shareefdeen y Singh, 2005; Mohseni Moussavi , 2007. The treatment of waste air containing phenol vapors in biotrickling filter. Vol 72, p. 1649-1654.
Wang, L.K., Pereira, N.C. y Hung, Y.T. Air pollution control engineering. (Handbook of environmental engineering, Vol. 1. Humana Press. 2000.
Epstein E. The science of composting.Tecnomic publication. USA. 1997.
Lesson G. and Winer A.M. Biofiltration: An innovative air pollution control technologý for VOC emisions. Journal of the Air and Waste Management Association. Vol 41. p. 1045-1054. 1991.
EPA, Environmental Protection Agency. An analysis of composting as an environmental remediation technology. EPA530-R-98-008.USA. 1998.
Shareefdeen, Z. and B. C. Baltzis. Biofiltration of toluene vapor under steady state and transient conditions: Theory and experimental results. Chem. Eng. Sci. Assoc. 49 p. 4347-4360, 1994.
Delhoménie, M. ; Heitz, M. Biofiltration of Air: A review. Criticals Reviews in Biotechnology; Vol 25. p 53- 72. ISSN 0738-8551. 2005.
Kennes y Thalasso, Parameters affecting performance and modeling of biofilters treating alkylbenzene-polluted air. 1998. Kennes, C., and Assoc 113: 305-319, 2004.
Devinny J.S., Medina V.F. and Hodge D.S. Biofiltration for treatment of gasoline vapors. In Hydrocarbons Bioremediation.R.E. Hinchee, B.C. Alleman, R.E. Hoeppel and R.N. Miller. p. 12-19. 1994.
Yang, Y.; Allen, E.R. Biofiltration Control of Hydrogen Sulfide. Design and Operational Parameters; J. Air & Waste Manage. Assoc 44, p 863-868. 1994.
M Heitz. Biofiltration of methane: An experimental study. Faculty of Engineering, Chemical Engineering Department, Universite de Sherbrooke. Chemical Engineering Journal, 2005.
Yang, Y. and E. R. Allen, Biofiltration control of hydrogen sulfide, Kinetics, biofilter performance and maintenance. J. Air Waste Manage. Assoc, 44 p. 1315- 1321. 1994.
Morgan-Sagastume, F.; Sleep, B.E.; Allen, D.G. Effects of Biomass Growth on Gas Pressure Drop in Biofilters; J. Environ. Eng. Assoc 127, p 388-396. 2001.
Pinnette. Evaluation of Biofiltration of Air an Innovative Air Pollution Control Technology. University of Minnesota, Minnesota Building Research Center. 1994
Delhoménie y Heitz. A Study of the Biofiltration of High-Loads of Toluene in Air: Carbon and Water Balances, Temperature Changes and Nitrogen Effect, 2005.
Delhoménie, M.C. y Heitz, M. Biofiltration of air: a review. Crit. Rev. Biotechnol. Assoc 25, p. 53–72. 2005
Kennes C. y Thalasso F. Waste gas biotreatment technology. J. Chem. Technol. Biotechnol. Assoc 72 p. 303–319. 1998
Yang, Y. Allen, E.R. Biofiltration Control of Hydrogen Sulfide: Desgin and Operational parameters. Journal of Air and Waste Management Assoc 44, p. 863 – 868. 1994
Morgan-Sagastume, F.; Sleep, B.E.; Allen, D.G. Effects of Biomass Growth on Gas Pressure Drop in Biofilters; J. Environ. Eng. Assoc 127, p 388-396. 2001.
Pinnette, J.R., Giggey, M.D., Marcy, G.J. y O’Brien, M.A. Performance of biofilters at two agitated bin composting facilities. 1994
Cohen, Y. Biofiltration. The treatment of fluids by microorganism innobilized into the filter bedding material: A review. Biosource Technology. Assoc 77 p. 257- 274. 2001
Classification NIOSH for Phenol. National institute for occupational safety and health. p 29. 1992.
Resumen de Salud Pública ATSDR. Agency for toxic substances & disease registry.
Rippen S. Toxicity designations for phenol. 1989.
Greenlief. Determination of phenol by UV-VIS absortion spectroscopy. 2001.
Delhoménie y Heitz. A Study of the Biofiltration of High-Loads of Toluene in Air: Carbon and Water Balances, Temperature Changes and Nitrogen Effect, 2005.
Leson, G y Winter A.M. Biofiltration: An innovate air pollution control technology for VOC emissions. Air Waste Manage. Assoc 41 p. 1045-1054. 1991.
Elsgaard, L. Ethylene renoval at low temperature under biofilter and batch conditions. Enviromental Microbiology. Assoc 66 p. 3878-3822. 2000.
Auria, R. Frere, G, Morales, M. Acuña, M.E y Revah, S. Influence of mixing and water addition on the removal rate of toluene vapors in a biofilter. Biotechnology Bioengineering. Assoc 68. p. 448-455, 2000
Ottengraf, S.P.P. Exhaust gas purification, in Biotechnology, Vol. 8. 1990.
Van Lith, C., David, S.L. y Marsh, R. Design criteria for biofilters. Effluent treatment and waste disposal. ClairTech. Netherlands institution of of Chemicals engineers simposium. P 127-132. 1990.
dc.relation.references.ee.fl_str_mv Moe & Irvine. Polyurethane foam based biofilter media for toluene removal. Journal of water Science and Technology. Vol. 43. p. 35–42. 2001.
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spelling Suarez Escobar, Andrés FelipeDe La Hoz, Yira JiménezAcosta Díaz, VivianaBogotá2018-03-16T16:32:06Z2018-03-16T16:32:06Z2011-07https://hdl.handle.net/10901/11295instname:Universidad Librereponame:Repositorio Institucional Universidad LibreEn el proceso de biofiltración la biodegradación de una corriente de aire contaminada con fenol se realizó con una concentración sobresaturada de 100 ppm de entrada y un tiempo de retención (tr) de 92.4 segundos, con una operación continua de 30 días en los cuales se evaluaron parámetros como humedad del material de relleno, temperatura, pH, con el fin de establecer la eficiencia de remoción de en el biofiltro. El biofiltro se compone se 4 etapas en las cuales se observó una remoción promedio de 97%, presentando una máxima remoción en la etapa 4 con un 100% de remoción y una minima de 92% en la etapa 2. A los 20 días de puesta en marcha se encontró que el porcentaje de humedad estaba en un 15% y había una caída de presión promedio de 1.2 mmHg, esto implica que para las variables estudiadas que determinan el desarrollo óptimo del biofiltro no se cumplieron los limitos mínimos establecidos en estudios previos. Por lo tanto, se considera que el alto porcentaje de eficiencia de remoción se debe a que en la salida de corriente en la etapa 4, no hubo un caudal suficiente de gas que permitiera medir con precisión la cantidad de fenol presente en ella. Se concluye que teniendo un control detallado de las variables que intervienen en el proceso se puede obtener una alta eficacia en el tratamiento de aire contaminado con fenol por medio de la biofiltración.In the biofiltration process of biodegradation of an air stream contaminated with phenol was performed with a supersaturated entry concentration of 100 ppm and retention time (tr) of 92.4 seconds, with continuous operation of 30 days in which we evaluated parameters such as fill material humidity, temperature, pH, in order to establish the removal efficiency in the biofilter. The biofilter consists in 4 stages in which there was an average removal of 97%, with maximum removal at stage 4 with a 100% and a minimum of 92% in stage 2. The day 20th of start-up was found that the humidity content was 15% and had an average pressure drop of 1.2 mmHg, this implies that for the studied variables that determine the optimal development of the biofilter did not comply with the limits minimum standards established in previous studies. Therefore, it is considered that the high percentage of removal efficiency is due to the current output in stage 4, there was a sufficient flow of gas that would accurately measure the amount of phenol present in it. We conclude that having a detailed control of the variables involved in the process can achieve high effectiveness in the treatment of phenol contaminated air through biofiltration.PDFapplication/pdfspahttp://creativecommons.org/licenses/by-nc-nd/2.5/co/Atribución-NoComercial-SinDerivadas 2.5 Colombiainfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Remoción de fenol en una corriente de aire mediante el proceso de biofiltraciónTesisTesis ingenieríaFacultad de ingenieríaIngeniería ambientalMedio ambienteMedio ambiente naturalAireAtmósferaMedio ambienteVaporLuz solarÓxidos de nitrógenoTesis de Pregradoinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_7a1finfo:eu-repo/semantics/bachelorThesisKlapková, E., Halecký, M., Fitch, M. et al. Impact of Biocatalyst and Moisture Content on Toluene / Xylene Mixture Biofiltration. Brazilian Archives of Biology and Technology. Vol 49 p 1001-1006. 2006.TOX FAQ. Phenol Characterization. Agency for toxic substances and disease registry. 1999Classification NIOSH for Phenol. National institute for occupational safety and health. p 29. 1992Classification OSHA for Phenol. Occupational safety and health guideline. Table Z-1. 1992Kyun, J., Kam, S. & Lee, M. Characteristics of benzene, toluene and xylene gas removal by a biofilter using scoria. International Journal of Environment and Pollution. Vol. 39 p 264 – 278, 2009Yanick, M. & Ramsay. Active compost biofiltration of toluene. Journal of Biodegradation. Vol 8. p 135-145, 1997.Lim, J., Park, S., Koo, J. & Park, H. Evaluation of Porous Ceramic as Microbial Carrier of Biofilter to Remove Toluene Vapor. Journal of Environmental Technology. Vol. 22. p. 47-56, 2001.Moe, W. & Irvine, R. Polyurethane foam based biofilter media for toluene removal. Journal of Water Science and Technology. Vol 43. p 35–42. 2001.Kyun, J., Kam, S. & Lee, M. Characteristics of benzene, toluene and xylene gas removal by a biofilter using scoria. International Journal of Environment and Pollution. Vol 39 p. 264 – 278. 2009.Chang, K. & Lu, C. Biofiltration of toluene and acetone mixtures by a tricklebed air biofilter. World -Journal of Microbiology and Biotechnology. Vol 19 p. 791- 798, 2003.Mario Zilli, 1993, 1996;. Ritchie y Hill, 1995; Nikakhtari y Hill, 2006. Laboratory- Scale experiments with a powdered compost biofilter treating benzene-polluted air. Process Biochem, Vol 40 p. 2035-2043.Klaudia Chmiel, Agnieszka Konieczny, Michał Palica and A.B. Jarze¸bski , Devinny y col., Periodic operation of biofilters. A concise model and experimental validation, Department of Chemical Engineering, Faculty of Chemistry, Silesian University of Technology, M.Kwang-Hee Lim† and Eun Ju Lee Ottengraff, . Biofilter Modeling for Waste Air Treatment, Comparisons of Inherent Characteristics of Biofilter Models, Department of Chemical Engineering. P 712-714. 2002Khan y Ghoshal, 2000; y Ray Wang, 2000; Jeong et al, 2004;. Delhomenie y Heitz, 2005; Shareefdeen y Singh, 2005; Mohseni Moussavi , 2007. The treatment of waste air containing phenol vapors in biotrickling filter. Vol 72, p. 1649-1654.Wang, L.K., Pereira, N.C. y Hung, Y.T. Air pollution control engineering. (Handbook of environmental engineering, Vol. 1. Humana Press. 2000.Epstein E. The science of composting.Tecnomic publication. USA. 1997.Lesson G. and Winer A.M. Biofiltration: An innovative air pollution control technologý for VOC emisions. Journal of the Air and Waste Management Association. Vol 41. p. 1045-1054. 1991.EPA, Environmental Protection Agency. An analysis of composting as an environmental remediation technology. EPA530-R-98-008.USA. 1998.Shareefdeen, Z. and B. C. Baltzis. Biofiltration of toluene vapor under steady state and transient conditions: Theory and experimental results. Chem. Eng. Sci. Assoc. 49 p. 4347-4360, 1994.Delhoménie, M. ; Heitz, M. Biofiltration of Air: A review. Criticals Reviews in Biotechnology; Vol 25. p 53- 72. ISSN 0738-8551. 2005.Kennes y Thalasso, Parameters affecting performance and modeling of biofilters treating alkylbenzene-polluted air. 1998. Kennes, C., and Assoc 113: 305-319, 2004.Devinny J.S., Medina V.F. and Hodge D.S. Biofiltration for treatment of gasoline vapors. In Hydrocarbons Bioremediation.R.E. Hinchee, B.C. Alleman, R.E. Hoeppel and R.N. Miller. p. 12-19. 1994.Yang, Y.; Allen, E.R. Biofiltration Control of Hydrogen Sulfide. Design and Operational Parameters; J. Air & Waste Manage. Assoc 44, p 863-868. 1994.M Heitz. Biofiltration of methane: An experimental study. Faculty of Engineering, Chemical Engineering Department, Universite de Sherbrooke. Chemical Engineering Journal, 2005.Yang, Y. and E. R. Allen, Biofiltration control of hydrogen sulfide, Kinetics, biofilter performance and maintenance. J. Air Waste Manage. Assoc, 44 p. 1315- 1321. 1994.Morgan-Sagastume, F.; Sleep, B.E.; Allen, D.G. Effects of Biomass Growth on Gas Pressure Drop in Biofilters; J. Environ. Eng. Assoc 127, p 388-396. 2001.Pinnette. Evaluation of Biofiltration of Air an Innovative Air Pollution Control Technology. University of Minnesota, Minnesota Building Research Center. 1994Delhoménie y Heitz. A Study of the Biofiltration of High-Loads of Toluene in Air: Carbon and Water Balances, Temperature Changes and Nitrogen Effect, 2005.Delhoménie, M.C. y Heitz, M. Biofiltration of air: a review. Crit. Rev. Biotechnol. Assoc 25, p. 53–72. 2005Kennes C. y Thalasso F. Waste gas biotreatment technology. J. Chem. Technol. Biotechnol. Assoc 72 p. 303–319. 1998Yang, Y. Allen, E.R. Biofiltration Control of Hydrogen Sulfide: Desgin and Operational parameters. Journal of Air and Waste Management Assoc 44, p. 863 – 868. 1994Morgan-Sagastume, F.; Sleep, B.E.; Allen, D.G. Effects of Biomass Growth on Gas Pressure Drop in Biofilters; J. Environ. Eng. Assoc 127, p 388-396. 2001.Pinnette, J.R., Giggey, M.D., Marcy, G.J. y O’Brien, M.A. Performance of biofilters at two agitated bin composting facilities. 1994Cohen, Y. Biofiltration. The treatment of fluids by microorganism innobilized into the filter bedding material: A review. Biosource Technology. Assoc 77 p. 257- 274. 2001Classification NIOSH for Phenol. National institute for occupational safety and health. p 29. 1992.Resumen de Salud Pública ATSDR. Agency for toxic substances & disease registry.Rippen S. Toxicity designations for phenol. 1989.Greenlief. Determination of phenol by UV-VIS absortion spectroscopy. 2001.Delhoménie y Heitz. A Study of the Biofiltration of High-Loads of Toluene in Air: Carbon and Water Balances, Temperature Changes and Nitrogen Effect, 2005.Leson, G y Winter A.M. Biofiltration: An innovate air pollution control technology for VOC emissions. Air Waste Manage. Assoc 41 p. 1045-1054. 1991.Elsgaard, L. Ethylene renoval at low temperature under biofilter and batch conditions. Enviromental Microbiology. Assoc 66 p. 3878-3822. 2000.Auria, R. Frere, G, Morales, M. Acuña, M.E y Revah, S. Influence of mixing and water addition on the removal rate of toluene vapors in a biofilter. Biotechnology Bioengineering. Assoc 68. p. 448-455, 2000Ottengraf, S.P.P. Exhaust gas purification, in Biotechnology, Vol. 8. 1990.Van Lith, C., David, S.L. y Marsh, R. Design criteria for biofilters. Effluent treatment and waste disposal. ClairTech. Netherlands institution of of Chemicals engineers simposium. P 127-132. 1990.Moe & Irvine. Polyurethane foam based biofilter media for toluene removal. Journal of water Science and Technology. Vol. 43. p. 35–42. 2001.THUMBNAILREMOCIÓN DE FENOL EN UNA CORRIENTE DE AIRE MEDIANTE EL PROCESO DE BIOFILTRACIÓN.pdf.jpgREMOCIÓN DE FENOL EN UNA CORRIENTE DE AIRE MEDIANTE EL PROCESO DE BIOFILTRACIÓN.pdf.jpgimage/png52885http://repository.unilibre.edu.co/bitstream/10901/11295/3/REMOCI%c3%93N%20DE%20FENOL%20EN%20UNA%20CORRIENTE%20DE%20AIRE%20%20MEDIANTE%20EL%20PROCESO%20DE%20%20BIOFILTRACI%c3%93N.pdf.jpg3bc73bd5870529958665d995ce3e1279MD53ORIGINALREMOCIÓN DE FENOL EN UNA CORRIENTE DE AIRE MEDIANTE EL PROCESO DE BIOFILTRACIÓN.pdfREMOCIÓN DE FENOL EN UNA CORRIENTE DE AIRE MEDIANTE EL PROCESO DE BIOFILTRACIÓN.pdfAcostaDíazViviana2011application/pdf5010941http://repository.unilibre.edu.co/bitstream/10901/11295/1/REMOCI%c3%93N%20DE%20FENOL%20EN%20UNA%20CORRIENTE%20DE%20AIRE%20%20MEDIANTE%20EL%20PROCESO%20DE%20%20BIOFILTRACI%c3%93N.pdfbcb72d3bfba9d5bb1feeb1a4c83f921aMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://repository.unilibre.edu.co/bitstream/10901/11295/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD5210901/11295oai:repository.unilibre.edu.co:10901/112952024-09-02 12:16:55.531Repositorio Institucional Unilibrerepositorio@unilibrebog.edu.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