Characterization of the tribological properties of bismuth-titanate coatings synthesized by sol-gel on 316L stainless steel substrates
The objective of this investigation was to obtain ceramic coatings of bismuth titanate by Sol-gel synthesis on 316L stainless steel substrates using bismuth nitrate pentahydrate (III) and titanium tetrabutoxide as precursors. The characterization focused on determining wear rates, coefficients of fr...
- Autores:
-
Bautista-Ruiz, Jorge
Aperador Chaparro, Willian
Olaya, Jhon
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2019
- Institución:
- Universidad Francisco de Paula Santander
- Repositorio:
- Repositorio Digital UFPS
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.ufps.edu.co:ufps/1730
- Acceso en línea:
- http://repositorio.ufps.edu.co/handle/ufps/1730
- Palabra clave:
- Tribological
Wear
Sol-gel
Bimuth-titanate
Thin films
- Rights
- openAccess
- License
- Atribución-NoComercial 4.0 Internacional (CC BY-NC 4.0)
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Characterization of the tribological properties of bismuth-titanate coatings synthesized by sol-gel on 316L stainless steel substrates |
| title |
Characterization of the tribological properties of bismuth-titanate coatings synthesized by sol-gel on 316L stainless steel substrates |
| spellingShingle |
Characterization of the tribological properties of bismuth-titanate coatings synthesized by sol-gel on 316L stainless steel substrates Tribological Wear Sol-gel Bimuth-titanate Thin films |
| title_short |
Characterization of the tribological properties of bismuth-titanate coatings synthesized by sol-gel on 316L stainless steel substrates |
| title_full |
Characterization of the tribological properties of bismuth-titanate coatings synthesized by sol-gel on 316L stainless steel substrates |
| title_fullStr |
Characterization of the tribological properties of bismuth-titanate coatings synthesized by sol-gel on 316L stainless steel substrates |
| title_full_unstemmed |
Characterization of the tribological properties of bismuth-titanate coatings synthesized by sol-gel on 316L stainless steel substrates |
| title_sort |
Characterization of the tribological properties of bismuth-titanate coatings synthesized by sol-gel on 316L stainless steel substrates |
| dc.creator.fl_str_mv |
Bautista-Ruiz, Jorge Aperador Chaparro, Willian Olaya, Jhon |
| dc.contributor.author.none.fl_str_mv |
Bautista-Ruiz, Jorge Aperador Chaparro, Willian Olaya, Jhon |
| dc.subject.proposal.eng.fl_str_mv |
Tribological Wear Sol-gel Bimuth-titanate Thin films |
| topic |
Tribological Wear Sol-gel Bimuth-titanate Thin films |
| description |
The objective of this investigation was to obtain ceramic coatings of bismuth titanate by Sol-gel synthesis on 316L stainless steel substrates using bismuth nitrate pentahydrate (III) and titanium tetrabutoxide as precursors. The characterization focused on determining wear rates, coefficients of friction, adhesion, nano-hardness, and thickness of the coatings, depending on the concentration of the precursors, the speed of rotation and the number of layers. It is concluded that the sol presents favorable conditions for their potential application as coatings on metallic substrates |
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2019 |
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2019 |
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2021-12-07T20:46:25Z |
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2021-12-07T20:46:25Z |
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Artículo de revista |
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publishedVersion |
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http://repositorio.ufps.edu.co/handle/ufps/1730 |
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10.24874/ti.2019.41.03.15 |
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http://repositorio.ufps.edu.co/handle/ufps/1730 |
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10.24874/ti.2019.41.03.15 |
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eng |
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eng |
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Tribology in Industry |
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Vol.41 No.3.(2019) |
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462 |
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3 (2019) |
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452 |
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41 |
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Bautista-Ruiz, J., Chaparro, A., & Olaya, J. J. (2019). Characterization of the Tribological Properties of Bismuth-titanate Coatings Synthesized by Sol-gel on 316L Stainless Steel Substrates. Tribology in Industry, 41(3). |
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Tribology in Industry |
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info:eu-repo/semantics/openAccess |
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Atribución-NoComercial 4.0 Internacional (CC BY-NC 4.0) |
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openAccess |
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Atribución-NoComercial 4.0 Internacional (CC BY-NC 4.0) http://purl.org/coar/access_right/c_abf2 |
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Tribology in Industry |
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Belgrado , Serbia |
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http://www.tribology.rs/journals/2019/2019-3/2019-3-15.html |
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Bautista-Ruiz, Jorged2ad76c1874f15a36c3360ca84fbcb66600Aperador Chaparro, Willian191f4339ff5499599f465c937e31698d600Olaya, Jhonf5238af2daab5d1477b8ac92b0a22a876002021-12-07T20:46:25Z2021-12-07T20:46:25Z2019http://repositorio.ufps.edu.co/handle/ufps/173010.24874/ti.2019.41.03.15The objective of this investigation was to obtain ceramic coatings of bismuth titanate by Sol-gel synthesis on 316L stainless steel substrates using bismuth nitrate pentahydrate (III) and titanium tetrabutoxide as precursors. The characterization focused on determining wear rates, coefficients of friction, adhesion, nano-hardness, and thickness of the coatings, depending on the concentration of the precursors, the speed of rotation and the number of layers. It is concluded that the sol presents favorable conditions for their potential application as coatings on metallic substratesapplication/pdfengTribology in IndustryBelgrado , SerbiaTribology in IndustryVol.41 No.3.(2019)4623 (2019)45241Bautista-Ruiz, J., Chaparro, A., & Olaya, J. J. (2019). Characterization of the Tribological Properties of Bismuth-titanate Coatings Synthesized by Sol-gel on 316L Stainless Steel Substrates. Tribology in Industry, 41(3).Tribology in IndustryThis is an open access journal which means that all content is freely available without charge to the user or his/her institution. All papers are licensed under a Creative Commons Attribution- NonCommercial 4.0 International Licenseinfo:eu-repo/semantics/openAccessAtribución-NoComercial 4.0 Internacional (CC BY-NC 4.0)http://purl.org/coar/access_right/c_abf2http://www.tribology.rs/journals/2019/2019-3/2019-3-15.htmlCharacterization of the tribological properties of bismuth-titanate coatings synthesized by sol-gel on 316L stainless steel substratesArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85TribologicalWearSol-gelBimuth-titanateThin filmsJ. Bautista-Ruiz, W. Aperador, A. Delgado, M. Díaz-Lagos, Synthesis and Characterization of Anticorrosive Coatings of SiO2 -TiO2 - ZrO2 Obtained from Sol-Gel Suspensions, International Journal of Electrochemical Science, vol. 9, pp. 4144-4157, 2014H. Uchiyama, T. Bando, H. Kozuka, Effect of the amount of H2O and HNO3 in Ti(OC3H7 i)4 solutions on the crystallization of sol-gel-derived TiO2 films, Thin Solid Films, vol. 669, no. 1, pp. 157-161, 2019, doi: 10.1016/j.tsf.2018.10.050C. Brinker, G. Scherer, Sol–gel science: The physics and chemistry of sol–gel processing, San Diego: Academic Press, 1990B. Tlili, A. Barkaoui, M. Walock, Tribology and wear resistance of the stainless steel. The sol–gel coating impact on the friction and damage, Tribology International, vol. 102, pp. 348-354, 2016, doi: 10.1016/j.triboint.2016.06.004H. Cheraghi, M. Shahmiri, Z. Sadeghian, Corrosion behavior of TiO2–NiO nanocomposite thin films on AISI 316L stainless steel prepared by sol–gel method, Thin Solid Films, vol. 552, pp. 289-296, 2012, doi: 10.1016/j.tsf.2012.07.125G. Ruhi, O.P. Modi, A.S.K. Sinha, I.B. Singh, Effect of sintering temperatures on corrosion and wear properties of sol–gel alumina coatings on surface pre-treated mild steel, Corrosion Science, vol. 50, iss. 3, pp. 639-649, 2008, doi: 10.1016/j.corsci.2007.10.002S.A. Omar, J. Ballarre, S.M. Ceré, Protection and functionalization of AISI 316L stainless steel for orthopedic implants: hybrid coating and sol gel glasses by spray to promote bioactivity, Electrochimica Acta, vol. 203, pp. 309-315, 2016, doi: 10.1016/j.electacta.2016.01.051S.M. Hosseinalipour, A. Ershad-langroudi, A. Nemati, A.M. Nabizade-Haghighi,Characterization of sol–gel coated 316L stainless steel for biomedical applications, Progress in Organic Coatings, vol. 67, iss. 4, pp. 371-374, 2010, doi: 10.1016/j.porgcoat.2010.01.002S. Rahoui, V. Turq, J.-P. Bonino, Effect of thermal treatment on mechanical and tribological properties of hybrid coatings deposited by sol–gel route on stainless steel, Surface and Coatings Technology, vol. 235, pp. 15-23, 2013, doi: 10.1016/j.surfcoat.2013.07.008A. Alvarez-Vera,H.M. Hdz-García, R. Muñoz-Arroyo, J.C. Diaz-Guillen, A.I. Mtz-Enriquez, J.L. AcevedoDávila, Tribological study of a thin TiO2 nanolayer coating on 316L steel, Wear, vol. 376, pp. 1702- 1706, 2017, doi: 10.1016/j.wear.2017.01.029C. Belon, M. Schmitt, S. Bistac, C. Croutxé-Barghorn, A. Chemtob, Friction and wear properties of hybrid sol–gel nanocomposite coatings against steel: Influence of their intrinsic properties, Applied Surface Science, vol. 257, iss. 15, pp. 6618-6625, 2011, doi: 10.1016/j.apsusc.2011.02.088I. Piwoński, K. Soliwoda, The effect of ceramic nanoparticles on tribological properties of alumina sol–gel thin coatings, Ceramics International, vol. 36, iss. 1, pp. 47-54, 2010, doi: 10.1016/j.ceramint.2009.06.024G. Ji, Z. Shi, W. Zhang, G. Zhao, Tribological properties of titania nanofilms coated on glass surface by the sol–gel method, Ceramics International, vol. 40, iss. 3, pp. 4655-4662, 2014, doi: 10.1016/j.ceramint.2013.09.006F. Alférez, J.J. Olaya, J. Bautista-Ruiz, Síntesis y evaluación de resistencia a la corrosión de recubrimientos de SiO2-TiO2-ZrO2-BiO2 sobre acero inoxidable 316L producidos por sol-gel, Boletín, de la Sociedad Española de Cerámica y Vidrio, vol. 57, iss. 5, pp. 195-206, 2018, doi. 10.1016/j.bsecv.2018.02.001S. Omar, F. Repp, P. Desimone, R. Weinkamer, W. Wagermaier, S. Ceré, J. Ballarre, Sol–gel hybrid coatings with strontium-doped 45S5 glass particles for enhancing the performance of stainless steel implants: Electrochemical, bioactive and in vivo response, Journal of NonCrystalline Solids, vol. 425, pp. 1-10, 2015, doi: 10.1016/j.jnoncrysol.2015.05.024A. Marsal, F. Ansart, V. Turq, J.P. Bonino, J.M. Sobrino, Y.M. Chen, J. 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Lic, Growth of layered perovskite Bi4Ti3O12thin films by sol–gel process, Journal of Crystal Growth, vol. 186, iss. 3, pp. 403-408, 1998, doi: 10.1016/S0022-0248(97)00508-3W. Oliver, G. Pharr, An Improved Technique for Determining Hardness and Elastic Modulus Using Load and Displacement Sensing Indentation Experiments, Journal of Materials Research, vol. 7, iss. 6, pp. 1564–1583, 1992, doi: 10.1557/JMR.1992.1564ORIGINALCharacterization of the Tribological Properties of Bismuth-titanate Coatings Synthesized by Sol-gel on 316L Stainless Steel Substrates.pdfCharacterization of the Tribological Properties of Bismuth-titanate Coatings Synthesized by Sol-gel on 316L Stainless Steel Substrates.pdfapplication/pdf1670823https://repositorio.ufps.edu.co/bitstream/ufps/1730/1/Characterization%20of%20the%20Tribological%20Properties%20of%20Bismuth-titanate%20Coatings%20Synthesized%20by%20Sol-gel%20on%20316L%20Stainless%20Steel%20Substrates.pdf8c7436269cb644d12f171f60c969385aMD51open accessLICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.ufps.edu.co/bitstream/ufps/1730/2/license.txt2f9959eaf5b71fae44bbf9ec84150c7aMD52open accessTEXTCharacterization of the Tribological Properties of Bismuth-titanate Coatings Synthesized by Sol-gel on 316L Stainless Steel Substrates.pdf.txtCharacterization of the Tribological Properties of Bismuth-titanate Coatings Synthesized by Sol-gel on 316L Stainless Steel Substrates.pdf.txtExtracted texttext/plain32827https://repositorio.ufps.edu.co/bitstream/ufps/1730/3/Characterization%20of%20the%20Tribological%20Properties%20of%20Bismuth-titanate%20Coatings%20Synthesized%20by%20Sol-gel%20on%20316L%20Stainless%20Steel%20Substrates.pdf.txt6cc25f8e27ff72a60104ab99c58bbeb1MD53open accessTHUMBNAILCharacterization of the Tribological Properties of Bismuth-titanate Coatings Synthesized by Sol-gel on 316L Stainless Steel Substrates.pdf.jpgCharacterization of the Tribological Properties of Bismuth-titanate Coatings Synthesized by Sol-gel on 316L Stainless Steel Substrates.pdf.jpgGenerated 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 incorporada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.
0000-0003-3430-2173d2ad76c1874f15a36c3360ca84fbcb66600 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