Obtaining and characterization of nanostructured coatings of zirconiaalumina- ceria by thermal spray flame
Zirconia, alumina and ceria powders were agglomerated, by granulator disk, to be used as raw material in the manufacture of coatings on red clay substrates by flame spray. Three mixtures of different compositions were made to determine which of them produces the most homogeneous and best bonded coat...
- Autores:
-
Peña Rodriguez, Gabriel
Ferrer, Martha
Rodriguez Wilches, Luis Francisco
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2019
- Institución:
- UNIVERSIDAD FRANCISCO DE PAULA SANTANDER
- Repositorio:
- Repositorio Digital UFPS
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.ufps.edu.co:ufps/1426
- Acceso en línea:
- http://repositorio.ufps.edu.co/handle/ufps/1426
- Palabra clave:
- Rights
- openAccess
- License
- Atribución 4.0 Internacional (CC BY 4.0)
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Obtaining and characterization of nanostructured coatings of zirconiaalumina- ceria by thermal spray flame |
| title |
Obtaining and characterization of nanostructured coatings of zirconiaalumina- ceria by thermal spray flame |
| spellingShingle |
Obtaining and characterization of nanostructured coatings of zirconiaalumina- ceria by thermal spray flame |
| title_short |
Obtaining and characterization of nanostructured coatings of zirconiaalumina- ceria by thermal spray flame |
| title_full |
Obtaining and characterization of nanostructured coatings of zirconiaalumina- ceria by thermal spray flame |
| title_fullStr |
Obtaining and characterization of nanostructured coatings of zirconiaalumina- ceria by thermal spray flame |
| title_full_unstemmed |
Obtaining and characterization of nanostructured coatings of zirconiaalumina- ceria by thermal spray flame |
| title_sort |
Obtaining and characterization of nanostructured coatings of zirconiaalumina- ceria by thermal spray flame |
| dc.creator.fl_str_mv |
Peña Rodriguez, Gabriel Ferrer, Martha Rodriguez Wilches, Luis Francisco |
| dc.contributor.author.none.fl_str_mv |
Peña Rodriguez, Gabriel Ferrer, Martha Rodriguez Wilches, Luis Francisco |
| description |
Zirconia, alumina and ceria powders were agglomerated, by granulator disk, to be used as raw material in the manufacture of coatings on red clay substrates by flame spray. Three mixtures of different compositions were made to determine which of them produces the most homogeneous and best bonded coatings. Likewise, the phase transformations that occur in the thermal spraying process were evaluated. The morphology and microstructure of the powders and coatings were determined by scanning electron microscopy and X-ray diffraction, respectively. Bimodal coatings were obtained, preserving the nanometric structure of the powders, homogeneous, low porosity and good adhesion. |
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2019 |
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2019-11-19 |
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2021-11-25T17:15:22Z |
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2021-11-25T17:15:22Z |
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Artículo de revista |
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10.1088/1742-6596/1388/1/012005 |
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10.1088/1742-6596/1388/1/012005 |
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eng |
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eng |
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Journal of Physics: Conference Series |
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Vol.1388 No.1.(2019) |
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7 |
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1 (2019) |
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1 |
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1388 |
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Rodríguez, L. F., Ferrer, M., & Peña, G. (2019, November). Obtaining and characterization of nanostructured coatings of zirconia-alumina-ceria by thermal spray flame. In Journal of Physics: Conference Series (Vol. 1388, No. 1, p. 012005). IOP Publishing. |
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Atribución 4.0 Internacional (CC BY 4.0) |
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openAccess |
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Atribución 4.0 Internacional (CC BY 4.0) http://purl.org/coar/access_right/c_abf2 |
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Journal of Physics: Conference Series |
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Peña Rodriguez, Gabriel4eaba0408a3f49f82929dc957fa8eee1600Ferrer, Martha88ad545f6192acf16fe2404ee96980b2600Rodriguez Wilches, Luis Francisco58301d384343cb6e3e62ea62f87ebe042021-11-25T17:15:22Z2021-11-25T17:15:22Z2019-11-19http://repositorio.ufps.edu.co/handle/ufps/142610.1088/1742-6596/1388/1/012005Zirconia, alumina and ceria powders were agglomerated, by granulator disk, to be used as raw material in the manufacture of coatings on red clay substrates by flame spray. Three mixtures of different compositions were made to determine which of them produces the most homogeneous and best bonded coatings. Likewise, the phase transformations that occur in the thermal spraying process were evaluated. The morphology and microstructure of the powders and coatings were determined by scanning electron microscopy and X-ray diffraction, respectively. Bimodal coatings were obtained, preserving the nanometric structure of the powders, homogeneous, low porosity and good adhesion.application/pdfengJournal of Physics: Conference SeriesJournal of Physics: Conference SeriesVol.1388 No.1.(2019)71 (2019)11388Rodríguez, L. F., Ferrer, M., & Peña, G. (2019, November). Obtaining and characterization of nanostructured coatings of zirconia-alumina-ceria by thermal spray flame. In Journal of Physics: Conference Series (Vol. 1388, No. 1, p. 012005). IOP Publishing.Journal of Physics: Conference SeriesContent from this work may be used under the terms of the Creative Commons Attribution 3.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI. Published under licence by IOP Publishing Ltdinfo:eu-repo/semantics/openAccessAtribución 4.0 Internacional (CC BY 4.0)http://purl.org/coar/access_right/c_abf2https://iopscience.iop.org/article/10.1088/1742-6596/1388/1/012005/metaObtaining and characterization of nanostructured coatings of zirconiaalumina- ceria by thermal spray flameArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Cadavid Iglesias E, Parra Velásquez C and Vargas Galvis F 2016 Estudio de llamas oxiacetilénicas usadas en la proyección térmica Revista Colombiana de Materiales 9 15-26Ferrer Pacheco M Y, Moreno Téllez C M and Vargas Galvis F 2018 Recubrimientos de circona y alúmina por proyección térmica con llama: parámetros para obtener recubrimientos de alto punto de fusión (Tunja: Universidad Pedagógica y Tecnológica de Colombia)González Hernández A G 2014 Estudio del comportamiento a alta temperatura de recubrimientos nanoestructurados elaborados por proyección térmica por combustión y plasma a partir de polvos y suspensiones (Francia: Université de Limoges)Morales Torres J A, Olaya Flórez J J and Rojas Molano H F 2012 Una aproximación a la tecnología de proyección térmica AVANCES Investigación en Ingeniería 9 60-71Arias Gómez J A, Vargas Galvis F and López M E 2014 Aglomeración de partículas nanométricas de ZrO2 mediante peletización en tambor para uso en proyección térmica por llama oxiacetilénica Revista Colombiana de Materiales 5 290-295Gil López J F, Rodríguez J E, Vargas F, López E and Restrepo E 2014 Mejoramiento de la estructura de los recubrimientos de Al2O3-43% elaborados mediante la técnica de proyección térmica por llama oxiacetilénica a partir de los parámetros de proyección Revista Colombiana de Materiales 5 120-126Valle J, Anglada M, Ferrari B and Baudín C 2015 Processing, nanoindentation and scratch testing of alumina-coated YTZP Boletín de la Sociedad Española de Cerámica y Vidrio 54 133-141American Society for Testing and Materials (ASTM) 2014 Standard guide for metallographic preparation of thermal sprayed coatings, ASTM E1920-0320 (USA: American Society for Testing and Materials)American Society for Testing and Materials (ASTM) 2014 Standard test methods for determining area percentage porosity in thermal sprayed coatings, ASTM E2109-01 (USA: American Society for Testing and Materials)American Society for Testing and Materials (ASTM) 2014 Standard guide for pull-off test for FRP-concrete interfaces, ASTM D7522 (USA: American Society for Testing and Materials)Vargas F 2010 Élaboration de couches céramiques épaisses à structures micrométriques et nanométriques par projections thermiques pour des applications tribologiques (Francia: Université de Limoges)Pawlowski L 2008 The science and engineering of thermal spray coatings (Washington: John Wiley & Sons)González A G, Ageorges H, Rojas O, López E, Hurtado F M and Vargas F 2015 Efecto de la microestructura y de la microdureza sobre la resistencia al desgaste de recubrimientos elaborados por proyección térmica por plasma atmosférico a partir de circona-alúmina, circona-itria y circona-ceria Boletín de la Sociedad Española de Cerámica y Vidrio 54 124-132González A, López E, Tamayo A, Restrepo E and Hernández F 2009 Análisis de la microestructura y de las fases de elaborados por proyección térmica DYNA 77 151-160González A, Henao J, Díaz A F, López E and Vargas F 2013 Influencia de los parámetros de proyección térmica en la microestructura de los recubrimientos de circona-alúmina y circona-ceria usados como barreras térmicas Revista Latinoamericana de Metalurgia y Materiales 33 272-281ORIGINALObtaining and characterization of nanostructured coatings of zirconiaalumina- ceria by thermal spray flame.pdfObtaining and characterization of nanostructured coatings of 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 incorporada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.
 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