Analysis of the biodiesel production yield from waste frying oil
This research sought to produce biodiesel from waste frying oil (WFO) from chicken grills by using chemical transesterification to evaluate quality conditions and the yield of the biodiesel obtained. For this, acid esterification and basic transesterification were applied under the following conditi...
- Autores:
-
Urbina-Suarez, Nestor Andres
Acevedo, Astrid
Acevedo Paez, Juan Camilo
Arenas, Erika
Becerra, L. C.
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2018
- Institución:
- UNIVERSIDAD FRANCISCO DE PAULA SANTANDER
- Repositorio:
- Repositorio Digital UFPS
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.ufps.edu.co:ufps/544
- Acceso en línea:
- http://repositorio.ufps.edu.co/handle/ufps/544
- Palabra clave:
- Rights
- openAccess
- License
- Atribución 4.0 Internacional (CC BY 4.0)
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Analysis of the biodiesel production yield from waste frying oil |
| title |
Analysis of the biodiesel production yield from waste frying oil |
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Analysis of the biodiesel production yield from waste frying oil |
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Analysis of the biodiesel production yield from waste frying oil |
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Analysis of the biodiesel production yield from waste frying oil |
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Analysis of the biodiesel production yield from waste frying oil |
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Analysis of the biodiesel production yield from waste frying oil |
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Analysis of the biodiesel production yield from waste frying oil |
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Urbina-Suarez, Nestor Andres Acevedo, Astrid Acevedo Paez, Juan Camilo Arenas, Erika Becerra, L. C. |
| dc.contributor.author.none.fl_str_mv |
Urbina-Suarez, Nestor Andres Acevedo, Astrid Acevedo Paez, Juan Camilo Arenas, Erika Becerra, L. C. |
| description |
This research sought to produce biodiesel from waste frying oil (WFO) from chicken grills by using chemical transesterification to evaluate quality conditions and the yield of the biodiesel obtained. For this, acid esterification and basic transesterification were applied under the following conditions: reaction temperature 60°, catalyst concentration of 1% (m/m) KOH, oil:alcohol 1: 6 , and two reaction times (55 70) for the transesterification. The physicochemical properties of the raw material were analyzed (i.e., density, humidity, kinematic viscosity, fatty acid profile, acidity index, peroxides, and saponification) where the WFO showed high contents of oleic acid (42.45%) and palmitic acid (33.52%), which are fundamental for biodiesel production. Chemical transesterification under the conditions of 60°, 1% KOH, and 70 obtained the best yield by presenting a high conversion percentage (96.15%) and an acid number of 1.33/, according to ASTM D6751 and EN 14214 international standards. |
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2018 |
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2018-09 |
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2021-10-31T17:04:47Z |
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2021-10-31T17:04:47Z |
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10.1088/1742-6596/1126/1/012006 |
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eng |
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Journal of Physics: Conference Series ISSN: 1742-6588, 2018 vol:1126 fasc: 1 págs: 1 - 7, DOI:10.1088/1742-6596/1126/1/012006 |
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Vol. 1126, No. 012006 (2018) |
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7 |
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012006 (2018) |
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1126 |
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J C Acevedo et al 2018 J. Phys.: Conf. Ser. 1126 012006 |
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Journal of Physics: Conference Series |
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Atribución 4.0 Internacional (CC BY 4.0) |
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openAccess |
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Atribución 4.0 Internacional (CC BY 4.0) http://purl.org/coar/access_right/c_abf2 |
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7 páginas |
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Journal of Physics: Conference Series |
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Reino Unido |
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Urbina-Suarez, Nestor Andres3e8ce1897f5d9382bb88755e9ec9cb96600Acevedo, Astrid581eb70e39c40e20a146526911507aee600Acevedo Paez, Juan Camiloc75ee0f7deaf58b647b6401fef886aae600Arenas, Erika1c7734ae0e3ab8d8d00ffa6d2a2f9d00600Becerra, L. C.127c1bc895cd9b65ad7c48fbe0c0aeef2021-10-31T17:04:47Z2021-10-31T17:04:47Z2018-09http://repositorio.ufps.edu.co/handle/ufps/54410.1088/1742-6596/1126/1/012006This research sought to produce biodiesel from waste frying oil (WFO) from chicken grills by using chemical transesterification to evaluate quality conditions and the yield of the biodiesel obtained. For this, acid esterification and basic transesterification were applied under the following conditions: reaction temperature 60°, catalyst concentration of 1% (m/m) KOH, oil:alcohol 1: 6 , and two reaction times (55 70) for the transesterification. The physicochemical properties of the raw material were analyzed (i.e., density, humidity, kinematic viscosity, fatty acid profile, acidity index, peroxides, and saponification) where the WFO showed high contents of oleic acid (42.45%) and palmitic acid (33.52%), which are fundamental for biodiesel production. Chemical transesterification under the conditions of 60°, 1% KOH, and 70 obtained the best yield by presenting a high conversion percentage (96.15%) and an acid number of 1.33/, according to ASTM D6751 and EN 14214 international standards.7 páginasapplication/pdfengJournal of Physics: Conference SeriesReino UnidoJournal of Physics: Conference Series ISSN: 1742-6588, 2018 vol:1126 fasc: 1 págs: 1 - 7, DOI:10.1088/1742-6596/1126/1/012006Vol. 1126, No. 012006 (2018)7012006 (2018)11126J C Acevedo et al 2018 J. Phys.: Conf. Ser. 1126 012006Journal of Physics: Conference SeriesContent from this work may be used under the terms of theCreative Commons Attribution 3.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI. Published under licence by IOP Publishing Ltdinfo:eu-repo/semantics/openAccessAtribución 4.0 Internacional (CC BY 4.0)http://purl.org/coar/access_right/c_abf2https://iopscience.iop.org/article/10.1088/1742-6596/1126/1/012006Analysis of the biodiesel production yield from waste frying oilArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85IDEAM, PNUD, MADS, DNP 2016 Inventario nacional y departamental de gases efecto invernadero Tercera Comunicación Nacional de Cambio Climático (Bogotá: DNP-MADS)Sanabria A 2018 La economía del carbono: una adicción de difícil tratamiento Ciencia Política 13 51–65International Energy Agency 2017 World energy outlook 2017 (Paris: International Energy Agency)Ferrari L 2013 Energías fósiles: Diagnostico, perspectivas e implicaciones económicas Revista Mexicana de Física 59 36-43Robelius F 2008 Giant oil fields. The highway to oil: Giant oil fields and their importance for future oil production (Upsala: Uppsala University)Periódico El Tiempo 2015 Recicle el aceite usado de cocina y evite riesgos para su mesa Consulted on: http://www.eltiempo.com/archivo/documento/CMS-15683577Ministerio de Ambiente y Desarrollo Sostenible 2018 Ministerio de Ambiente reglamenta disposición de aceites de cocina usados en el país, Resolución 0316 (Colombia: Ministerio de Ambiente y Desarrollo Sostenible)Tareke E, Rydberg P, Karlsson P, Eriksson S and Törnqvist M 2002 Analysis of acrylamide, a carcinogen formed in heated foodstuffs J. Agric. Food Chem 50 4998-5006Murcia B, Andredy M, Rodríguez W, Alvarado E y Chaves L 2013 Caracterización de biodiesel obtenido de aceite residual de cocina Revista Colombiana de Biotecnología 15 61-70American Society for Testing and Materials (ASTM) 2015 Standard Specification for Biodiesel Fuel Blend Stock (B100) for Middle Distillate Fuels, ASTM D6751-15ce1 (USA: American Society for Testing and Materials)European Committee for Standardization (CEN) 2014 Fatty acid methyl esters (FAME) for use in diesel engines and heating applications. 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Determination of ester and linolenic acid methyl ester contents, European Standards EN 14103 (Belgium: European Committee for Standardization)Duc P, Takenaka N, Van L, Pham L, Imamura K and Maeda Y 2014 Co-solvent method produce biodiesel from waste cooking oil with small pilot plant Energy Procedia 61 2822-32Herrera J y Vélez A 2008 Caracterización y aprovechamiento del aceite residual de frituras para la obtención de un combustible (biodiesel) (Pereira: Universidad Tecnológica de Pereira)Phan A and Phan T 2008 Biodiesel production from waste cooking oils Fuel 87 3490–96Cifuentes M 2010 Obtención de biodiesel a partir de aceite usado de cocina por transesterificación en dos etapas, con dos tipos de alcoholes (Bogotá: Universidad Libre de Colombia)Galeano C y Marulanda E 2011 Aprovechamiento y caracterización de los residuos grasos del pollo para la producción de un biocombustible (biodiesel) (Pereira: Universidad Tecnológica de Pereira)Bulla E 2014 Diseño del proceso de producción de biodiesel a partir de aceites de fritura (Bogotá: Universidad Nacional de Colombia)Rojas A, Canchala M y Torres H 2009 Producción de biodiesel a partir de aceites usados de cocina utilizando catalizadores adsorbidos en matrices sólidas Memorias IV Simposio de Química Aplicada (Palmira: Universidad Nacional de Colombia)Martínez J, Castillo L, García M y Medina L 2007 Fraccionamiento y caracterización de las fracciones (oleína y estearina) del aceite crudo de palma africana producido en el estado de Tabasco IX Congreso de Ciencia de los Alimentos (Guanajuato: Universidad de Guanajuato)Acevedo J, Hernández J, Valdés C and Khanal S 2015 Analysis of operating costs for producing biodiesel from palm oil at pilot-scale in Colombia Bioresource Technology 188 117–23García E, Alfaro Y y Ruiz M 2012 Estudio de pre factibilidad para la generación de biodiesel a partir de aceite quemado en el restaurante Tip Top, Estelí, Nicaragua (Managua: Universidad Nacional de Ingeniería)Felizardo P, Joana N, Idalina R, Joao M, Rui B and Joao B 2005 Production of biodiesel from waste frying oils Waste Management 26 487–94Bulla E, Sierra F E y Guerrero C 2014 Producción de biodiésel usando aceites residuales de fritura y etanol por catálisis alcalina Ingeniería Solidaria 10 61-9Bouaid A 2016 Effect of free fatty acid contents on biodiesel quality. Pilot plant studies Fuel 174 54-62Chen G, Ying M and Li W 2006 Enzymatic conversion of waste cooking oils into alternative fuel-biodiesel Applied Biochemistry and Biotechnology 129 911-21Azócar L 2011 Proceso enzimático para la producción de metil ésteres de ácidos grasos utilizando aceites residuales de fritura en mezcla con aceite de raps como materia prima (Temuco: Universidad de la Frontera)ORIGINALAnalysis of the biodiesel production yield from waste frying oi.pdfAnalysis of the biodiesel production yield from waste frying oi.pdfapplication/pdf752785https://repositorio.ufps.edu.co/bitstream/ufps/544/1/Analysis%20of%20the%20biodiesel%20production%20yield%20from%20waste%20frying%20oi.pdf62a7d115527b01a17782d42dd7762e3cMD51open accessLICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.ufps.edu.co/bitstream/ufps/544/2/license.txt2f9959eaf5b71fae44bbf9ec84150c7aMD52open accessTEXTAnalysis of the biodiesel production yield from waste frying oi.pdf.txtAnalysis 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 incorporada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.
0000-0002-6954-508X3e8ce1897f5d9382bb88755e9ec9cb966000000-0003-1686-6872c75ee0f7deaf58b647b6401fef886aae6000000-0002-4813-883X1c7734ae0e3ab8d8d00ffa6d2a2f9d00600 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