Quicklime as an alternative in the photodegradation of contaminants

Chemical oxidation is one of the many different methods of removing contaminants that has emerged recently, is an alternative method to traditional techniques. According to this research calcium peroxide is suitable choice for contaminant biodegradation in soil and ground water, but it happens at a...

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Autores:
Bautista-Ruiz, Jorge
Rincón Joya, Miryam
Raba Paez, Angela Mercedes
Tipo de recurso:
Article of journal
Fecha de publicación:
2016
Institución:
Universidad Francisco de Paula Santander
Repositorio:
Repositorio Digital UFPS
Idioma:
eng
OAI Identifier:
oai:repositorio.ufps.edu.co:ufps/702
Acceso en línea:
http://repositorio.ufps.edu.co/handle/ufps/702
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openAccess
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Atribución 4.0 Internacional (CC BY 4.0)
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dc.title.eng.fl_str_mv Quicklime as an alternative in the photodegradation of contaminants
title Quicklime as an alternative in the photodegradation of contaminants
spellingShingle Quicklime as an alternative in the photodegradation of contaminants
title_short Quicklime as an alternative in the photodegradation of contaminants
title_full Quicklime as an alternative in the photodegradation of contaminants
title_fullStr Quicklime as an alternative in the photodegradation of contaminants
title_full_unstemmed Quicklime as an alternative in the photodegradation of contaminants
title_sort Quicklime as an alternative in the photodegradation of contaminants
dc.creator.fl_str_mv Bautista-Ruiz, Jorge
Rincón Joya, Miryam
Raba Paez, Angela Mercedes
dc.contributor.author.none.fl_str_mv Bautista-Ruiz, Jorge
Rincón Joya, Miryam
Raba Paez, Angela Mercedes
description Chemical oxidation is one of the many different methods of removing contaminants that has emerged recently, is an alternative method to traditional techniques. According to this research calcium peroxide is suitable choice for contaminant biodegradation in soil and ground water, but it happens at a very low speed. We hope that the method of synthesis of calcium peroxide in nano size by increased ratio of surface to volume can increase the speed of reaction and solve the problem. In the first synthesis of the material we obtained CaO instead of CaO2. Calcium oxide (CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound in obtaining hypochlorite and to neutralize acidic soils. In this study we characterize the material by X-ray scanning electron microscopy, and ultraviolet-visible spectroscopy.
publishDate 2016
dc.date.issued.none.fl_str_mv 2016-02-12
dc.date.accessioned.none.fl_str_mv 2021-11-06T15:35:15Z
dc.date.available.none.fl_str_mv 2021-11-06T15:35:15Z
dc.type.spa.fl_str_mv Artículo de revista
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dc.identifier.uri.none.fl_str_mv http://repositorio.ufps.edu.co/handle/ufps/702
dc.identifier.doi.none.fl_str_mv 10.1088/1742-6596/687/1/012044
url http://repositorio.ufps.edu.co/handle/ufps/702
identifier_str_mv 10.1088/1742-6596/687/1/012044
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.ispartof.none.fl_str_mv Journal of Physics: Conference Series
dc.relation.citationedition.spa.fl_str_mv Vol.687 No.1.(2016)
dc.relation.citationendpage.spa.fl_str_mv 4
dc.relation.citationissue.spa.fl_str_mv 1 (2016)
dc.relation.citationstartpage.spa.fl_str_mv 1
dc.relation.citationvolume.spa.fl_str_mv 687
dc.relation.cites.none.fl_str_mv Joya, M. R., Ruiz, J. B., & Raba, A. M. (2016, February). Quicklime as an alternative in the photodegradation of contaminants. In Journal of Physics: Conference Series (Vol. 687, No. 1, p. 012044). IOP Publishing.
dc.relation.ispartofjournal.spa.fl_str_mv Journal of Physics: Conference Series
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dc.rights.creativecommons.spa.fl_str_mv Atribución 4.0 Internacional (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv Atribución 4.0 Internacional (CC BY 4.0)
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dc.format.mimetype.spa.fl_str_mv application/pdf
dc.publisher.spa.fl_str_mv Journal of Physics: Conference Series
dc.publisher.place.spa.fl_str_mv Estados Unidos
dc.source.spa.fl_str_mv https://iopscience.iop.org/article/10.1088/1742-6596/687/1/012044/meta
institution Universidad Francisco de Paula Santander
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spelling Bautista-Ruiz, Jorged2ad76c1874f15a36c3360ca84fbcb66600Rincón Joya, Miryamc0b8ca13fba2cb3b97bde3a3b5f95b0c600Raba Paez, Angela Mercedesf198a05b6b9a044be51079a446cc029c2021-11-06T15:35:15Z2021-11-06T15:35:15Z2016-02-12http://repositorio.ufps.edu.co/handle/ufps/70210.1088/1742-6596/687/1/012044Chemical oxidation is one of the many different methods of removing contaminants that has emerged recently, is an alternative method to traditional techniques. According to this research calcium peroxide is suitable choice for contaminant biodegradation in soil and ground water, but it happens at a very low speed. We hope that the method of synthesis of calcium peroxide in nano size by increased ratio of surface to volume can increase the speed of reaction and solve the problem. In the first synthesis of the material we obtained CaO instead of CaO2. Calcium oxide (CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound in obtaining hypochlorite and to neutralize acidic soils. In this study we characterize the material by X-ray scanning electron microscopy, and ultraviolet-visible spectroscopy.application/pdfengJournal of Physics: Conference SeriesEstados UnidosJournal of Physics: Conference SeriesVol.687 No.1.(2016)41 (2016)1687Joya, M. R., Ruiz, J. B., & Raba, A. M. (2016, February). Quicklime as an alternative in the photodegradation of contaminants. In Journal of Physics: Conference Series (Vol. 687, No. 1, p. 012044). IOP Publishing.Journal of Physics: Conference SeriesContent from this work may be used under the terms of theCreative Commons Attribution 3.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI. Published under licence by IOP Publishing Ltdinfo:eu-repo/semantics/openAccessAtribución 4.0 Internacional (CC BY 4.0)http://purl.org/coar/access_right/c_abf2https://iopscience.iop.org/article/10.1088/1742-6596/687/1/012044/metaQuicklime as an alternative in the photodegradation of contaminantsArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Arpin M T and Yusup 2011 S Canad J Appl Sci 5 1391Ameta S C, Punjabi P B, Ameta R and Ameta C 2014 Microwave-assisted organic synthesis a green chemical 1st ed (New York: CRC Press)Buasri A, Chaiyut N, Loyuenyong V, Worawanitchaphong P and tronyong S 2013 Sci Worl J Hind 7Nageeb R M 2013 Adsorption Technique for the Removal of Organic Pollutants from Water and Wastewater (Croatia: InTech) 167 chapterPatnaik 2002 P Handbook of inorganic (New York: McGraw-Hill)European Commision Joint Research Centre and 2001 Integrated pollution prevention and control (Seville: European Commission)Harrison D J 1993 Indistrial minerals laboratory limestone (Nottingham: British Geological Servey)YGaceram M, Pujol M C, Aguilo M and Diaz F 2007 J Sol-Gel Sci Techn 42 79Yu C, Huang C and Tanr C 2012 Aeros Air Qual Reser 12 745Manovic V and Anthonyr E J 2010 Int J Environ Res Public 8 3129Liu H, Cai X, Wang Y and Chen J 2011 Water Research 45 3499Tangi Z X, Yu Z, Zhang Z L, Zhang X Y, Pan Q and Shi L E 2013 Quim Nova 36 933TEXTQuicklime as an alternative in the photodegradation of contaminants.pdf.txtQuicklime as an alternative in the photodegradation of contaminants.pdf.txtExtracted texttext/plain10125https://repositorio.ufps.edu.co/bitstream/ufps/702/3/Quicklime%20as%20an%20alternative%20in%20the%20photodegradation%20of%20contaminants.pdf.txt351be0b84fb3aa3d982eea473ee7d2a3MD53open accessTHUMBNAILQuicklime as an alternative in the photodegradation of contaminants.pdf.jpgQuicklime as an alternative in the photodegradation of contaminants.pdf.jpgGenerated Thumbnailimage/jpeg9049https://repositorio.ufps.edu.co/bitstream/ufps/702/4/Quicklime%20as%20an%20alternative%20in%20the%20photodegradation%20of%20contaminants.pdf.jpg01d805b7a6b1a8b4b6d703587ba53a42MD54open accessORIGINALQuicklime as an alternative in the photodegradation of contaminants.pdfQuicklime as an alternative in the photodegradation of contaminants.pdfapplication/pdf1249993https://repositorio.ufps.edu.co/bitstream/ufps/702/1/Quicklime%20as%20an%20alternative%20in%20the%20photodegradation%20of%20contaminants.pdf7d9d966ccd9468ba8e0902ecd1dd452aMD51open accessLICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.ufps.edu.co/bitstream/ufps/702/2/license.txt2f9959eaf5b71fae44bbf9ec84150c7aMD52open accessufps/702oai:repositorio.ufps.edu.co:ufps/7022022-05-23 11:01:26.237open accessRepositorio Universidad Francisco de Paula 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 incorporada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.
0000-0003-3430-2173d2ad76c1874f15a36c3360ca84fbcb66600