Characterization of physical properties of bismuth-titanium coatings on 316L stainless steel

The 316 L steel is a type of stainless steel widely used in the medical industry, which in recent years has been studied for different uses in society. Being an engineering material, it is imperative to know its performance based on its physical and mechanical properties that allow identifying the r...

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Autores:
GARZÓN AGUDELO, PEDRO
palacios alvarado, wlamyr
Medina Delgado, Byron
Tipo de recurso:
Article of journal
Fecha de publicación:
2022
Institución:
Universidad Francisco de Paula Santander
Repositorio:
Repositorio Digital UFPS
Idioma:
eng
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oai:repositorio.ufps.edu.co:ufps/6596
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openAccess
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© 2022 by the authors
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dc.title.eng.fl_str_mv Characterization of physical properties of bismuth-titanium coatings on 316L stainless steel
title Characterization of physical properties of bismuth-titanium coatings on 316L stainless steel
spellingShingle Characterization of physical properties of bismuth-titanium coatings on 316L stainless steel
title_short Characterization of physical properties of bismuth-titanium coatings on 316L stainless steel
title_full Characterization of physical properties of bismuth-titanium coatings on 316L stainless steel
title_fullStr Characterization of physical properties of bismuth-titanium coatings on 316L stainless steel
title_full_unstemmed Characterization of physical properties of bismuth-titanium coatings on 316L stainless steel
title_sort Characterization of physical properties of bismuth-titanium coatings on 316L stainless steel
dc.creator.fl_str_mv GARZÓN AGUDELO, PEDRO
palacios alvarado, wlamyr
Medina Delgado, Byron
dc.contributor.author.none.fl_str_mv GARZÓN AGUDELO, PEDRO
palacios alvarado, wlamyr
Medina Delgado, Byron
dc.contributor.corporatename.spa.fl_str_mv Journal of Physics: Conference Series
description The 316 L steel is a type of stainless steel widely used in the medical industry, which in recent years has been studied for different uses in society. Being an engineering material, it is imperative to know its performance based on its physical and mechanical properties that allow identifying the response of this steel in addition to thin films as coatings. Bismuth and titanium have been recently used to improve the properties of 316 L steel, so they were used in this study. The sol-gel technique was used as the film forming method. The response of physical and mechanical properties was evaluated from the analysis of microhardness and coefficient of friction reported for the different types of steel-coating systems. Higher microhardness values were found for films with higher proportion of titanium. The coefficient of friction values is influenced by the system used, with higher values obtained for samples with a single coating layer.
publishDate 2022
dc.date.accessioned.none.fl_str_mv 2022-11-22T22:01:58Z
dc.date.available.none.fl_str_mv 2022-11-22T22:01:58Z
dc.date.issued.none.fl_str_mv 2022-01-05
dc.type.spa.fl_str_mv Artículo de revista
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dc.identifier.uri.none.fl_str_mv https://repositorio.ufps.edu.co/handle/ufps/6596
dc.identifier.doi.none.fl_str_mv 10.1088/1742-6596/2159/1/012014
url https://repositorio.ufps.edu.co/handle/ufps/6596
identifier_str_mv 10.1088/1742-6596/2159/1/012014
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.ispartof.none.fl_str_mv Journal of Physics: Conference Series. Vol 2159 No°1[2022]
dc.relation.citationedition.spa.fl_str_mv Vol. 2159 No° 1 [2022]
dc.relation.citationendpage.spa.fl_str_mv 6
dc.relation.citationissue.spa.fl_str_mv 1[2022]
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dc.relation.citationvolume.spa.fl_str_mv 2159
dc.relation.cites.none.fl_str_mv P A Garzón-Agudelo et al 2022 J. Phys.: Conf. Ser. 2159 012014 DOI 10.1088/1742-6596/2159/1/012014
dc.relation.ispartofjournal.spa.fl_str_mv Journal of Physics: Conference Series
dc.rights.eng.fl_str_mv © 2022 by the authors
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dc.rights.creativecommons.spa.fl_str_mv Atribución 4.0 Internacional (CC BY 4.0)
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Atribución 4.0 Internacional (CC BY 4.0)
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dc.publisher.spa.fl_str_mv Journal of Physics: Conference Series
dc.publisher.place.spa.fl_str_mv Reino Unido
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institution Universidad Francisco de Paula Santander
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spelling GARZÓN AGUDELO, PEDRO047cc88eb9cac25f9f02b91f8bdb1d93600palacios alvarado, wlamyr735190501fdb6e5d51e2f4cc4e5b66ec600Medina Delgado, Byron77a81f47bf20466c22fcea2d1e82a753600Journal of Physics: Conference Series2022-11-22T22:01:58Z2022-11-22T22:01:58Z2022-01-05https://repositorio.ufps.edu.co/handle/ufps/659610.1088/1742-6596/2159/1/012014The 316 L steel is a type of stainless steel widely used in the medical industry, which in recent years has been studied for different uses in society. Being an engineering material, it is imperative to know its performance based on its physical and mechanical properties that allow identifying the response of this steel in addition to thin films as coatings. Bismuth and titanium have been recently used to improve the properties of 316 L steel, so they were used in this study. The sol-gel technique was used as the film forming method. The response of physical and mechanical properties was evaluated from the analysis of microhardness and coefficient of friction reported for the different types of steel-coating systems. Higher microhardness values were found for films with higher proportion of titanium. The coefficient of friction values is influenced by the system used, with higher values obtained for samples with a single coating layer.7application/pdfengJournal of Physics: Conference SeriesReino UnidoJournal of Physics: Conference Series. Vol 2159 No°1[2022]Vol. 2159 No° 1 [2022]61[2022]12159P A Garzón-Agudelo et al 2022 J. Phys.: Conf. Ser. 2159 012014 DOI 10.1088/1742-6596/2159/1/012014Journal of Physics: Conference Series© 2022 by the authorshttps://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessAtribución 4.0 Internacional (CC BY 4.0)http://purl.org/coar/access_right/c_abf2https://www.scopus.com/record/display.uri?eid=2-s2.0-85124302075&doi=10.1088%2f1742-6596%2f2159%2f1%2f012014&origin=inward&txGid=f1d4288fac35de5f90b0a6b6c7309c79Characterization of physical properties of bismuth-titanium coatings on 316L stainless steelArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Bull S, Jones A 1994 Multilayer coatings for improved performance Surface and Coatings Technology 78(1-3) 173Liu G, Tao N, Lu K 2010 316L austenite stainless steels strengthened by means of nanoscale twins Journal of Materials Science & Technology 26(4) 289Rojas Z 2016 Biocompatibilidad y Resistencia a la Corrosión de Recubrimientos de Titanato de Bismuto con un Abordaje desde la Perspectiva de la Bioética (Bogotá: Universidad Nacional de Colombia)Brinker C, Scherer G 1990 Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing (San Diego: Academic Press)Bautista J, Duque E 2016 Synthesis and biocompatibility properties of bismuth-titanium thin films obtained by sol-gel process International Journal of Chemical Science 14(3) 1447Bautista J, Olaya J, Aperador W 2017 Biocompatibility of bismuth silicate coatings deposited on 316L stainless steel by sol-gel process Revista Facultad de Ingeniería, Universidad de Antioquia 84 27Garzón P, Bautista J, Chaparro A 2019 Evaluation of mechanical wear in bismuth-titanium coatings synthesized by the sol-gel method and applied on 316 L stainless steel substrates Journal of Physics: Conference Series 1386(1) 012090:1Tapia J 2018 Factibilidad de Unión del Sistema Disímil: Compósito de Matriz Metálica de Aluminio Reforzado con Grafito/A380 Mediante el Proceso Brazing sin y con Deposición de Nanocapas de Bismuto (Saltillo: Corporación Mexicana de Investigación en Materiales)Li T, Li H, Pan F 2001 Microstructure and nanoindentation hardness of Ti/TiN multilayered films Surface and Coatings Technology 137(2-3) 225Meza J, Chavez C, Vélez J 2006 Técnicas de indentación: medición de propiedades mecánicas en cerámicas Dyna 73(149) 81Meza J, Franco E, Farias M, Buiochi F, Souza R, Cruz J 2008 Medición del módulo de elasticidad en materiales de ingeniería utilizando la técnica de indentación instrumentada y de ultrasonido Revista de Metalurgia 44(1) 52Pazos L, Florez M, García J 2010 Comportamiento al desgaste y a la corrosión de un acero inoxidable martensítico con recubrimientos mono y multicapa para uso en herramental quirúrgico IBEROMET CONAMET/SAM Congreso Internacional de Metalurgia y Materiales (Viña del Mar: Sociedad Chilena de Metalurgia y Materiales)Arai T 2013 Thermoreactive deposition/diffusion process for surface hardening of steels ASM Handbook: Steel Heat Treating Fundamentals and Processes ed Dossett J, Totten G (Cleveland: ASM International)Sen U 2005 Friction and wear properties of thermo-reactive diffusion coatings against titanium nitride coated steels Materials and Design 26(2) 167ORIGINALGarzón-Agudelo_2022_J._Phys.__Conf._Ser._2159_012014.pdfGarzón-Agudelo_2022_J._Phys.__Conf._Ser._2159_012014.pdfapplication/pdf3098963https://repositorio.ufps.edu.co/bitstream/ufps/6596/1/Garz%c3%b3n-Agudelo_2022_J._Phys.__Conf._Ser._2159_012014.pdf62a13fe979b171a3596449384df8f5b1MD51open accessLICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.ufps.edu.co/bitstream/ufps/6596/2/license.txt2f9959eaf5b71fae44bbf9ec84150c7aMD52open accessTEXTGarzón-Agudelo_2022_J._Phys.__Conf._Ser._2159_012014.pdf.txtGarzón-Agudelo_2022_J._Phys.__Conf._Ser._2159_012014.pdf.txtExtracted 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 incorporada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.
0000-0003-0754-862977a81f47bf20466c22fcea2d1e82a753600