Sol-Gel Synthesis of Titanium/Bismuth Oxide Coatings for Biocompatibility Applications on 316L Stainless Steel

Objectives: This study was carried out in order to establish the potential offered by the sol-gel method to obtain Titanium/ Bismuth oxide coatings on 316L Stainless Steel (SS) substrates in biocompatibility applications. Methods/Analysis: The stable sol was synthesized by using Bismuth nitrate (III...

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Autores:
Aperador Chaparro, William Arnulfo
Bautista-Ruiz, Jorge
Caicedo, J. C.
Tipo de recurso:
Article of journal
Fecha de publicación:
2018
Institución:
Universidad Francisco de Paula Santander
Repositorio:
Repositorio Digital UFPS
Idioma:
eng
OAI Identifier:
oai:repositorio.ufps.edu.co:ufps/1745
Acceso en línea:
http://repositorio.ufps.edu.co/handle/ufps/1745
Palabra clave:
Biocompatibility
Corrosion
Sol-gel
Titanium/Bismuth Oxide Coatings
316L
Rights
openAccess
License
This work is licensed under a Creative Commons Attribution 4.0 International License.
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network_acronym_str RUFPS2
network_name_str Repositorio Digital UFPS
repository_id_str
dc.title.eng.fl_str_mv Sol-Gel Synthesis of Titanium/Bismuth Oxide Coatings for Biocompatibility Applications on 316L Stainless Steel
title Sol-Gel Synthesis of Titanium/Bismuth Oxide Coatings for Biocompatibility Applications on 316L Stainless Steel
spellingShingle Sol-Gel Synthesis of Titanium/Bismuth Oxide Coatings for Biocompatibility Applications on 316L Stainless Steel
Biocompatibility
Corrosion
Sol-gel
Titanium/Bismuth Oxide Coatings
316L
title_short Sol-Gel Synthesis of Titanium/Bismuth Oxide Coatings for Biocompatibility Applications on 316L Stainless Steel
title_full Sol-Gel Synthesis of Titanium/Bismuth Oxide Coatings for Biocompatibility Applications on 316L Stainless Steel
title_fullStr Sol-Gel Synthesis of Titanium/Bismuth Oxide Coatings for Biocompatibility Applications on 316L Stainless Steel
title_full_unstemmed Sol-Gel Synthesis of Titanium/Bismuth Oxide Coatings for Biocompatibility Applications on 316L Stainless Steel
title_sort Sol-Gel Synthesis of Titanium/Bismuth Oxide Coatings for Biocompatibility Applications on 316L Stainless Steel
dc.creator.fl_str_mv Aperador Chaparro, William Arnulfo
Bautista-Ruiz, Jorge
Caicedo, J. C.
dc.contributor.author.none.fl_str_mv Aperador Chaparro, William Arnulfo
Bautista-Ruiz, Jorge
Caicedo, J. C.
dc.subject.proposal.eng.fl_str_mv Biocompatibility
Corrosion
Sol-gel
Titanium/Bismuth Oxide Coatings
316L
topic Biocompatibility
Corrosion
Sol-gel
Titanium/Bismuth Oxide Coatings
316L
description Objectives: This study was carried out in order to establish the potential offered by the sol-gel method to obtain Titanium/ Bismuth oxide coatings on 316L Stainless Steel (SS) substrates in biocompatibility applications. Methods/Analysis: The stable sol was synthesized by using Bismuth nitrate (III) pentahydrate and Titanium (IV) butoxide. The coatings were deposited by spin-coating technique at 4000 rpm and characterized topographically by Scanning Electron Microscopy SEM and structurally by X-ray diffraction XRD. Through the techniques of polarization potentiodynamic curves and Electrochemical Impedance Spectroscopy (EIS), the anticorrosive response of the �ilms was evaluated. The thickness was then measured, and biocompatibility test was developed. Findings: It was found that the coatings with high composition of the precursor titanium (IV) butoxide offer the best results as an anticorrosive application. Likewise, the growth of cells was uniform on the �ilms indicating that the medium offered by the �ilms does not present active cytotoxicity and surpasses by a large number the cellular growth level compared to stainless steel. Applications /Improvement: 316L (SS) is very useful in implantology, for its low cost compared with other materials. The implanted steel suffers corrosion by the physiological �luids of body. Titanium/Bismuth coatings establish a barrier between body �luids and SS implant.
publishDate 2018
dc.date.issued.none.fl_str_mv 2018-05
dc.date.accessioned.none.fl_str_mv 2021-12-08T16:56:37Z
dc.date.available.none.fl_str_mv 2021-12-08T16:56:37Z
dc.type.spa.fl_str_mv Artículo de revista
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dc.type.content.spa.fl_str_mv Text
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dc.identifier.uri.none.fl_str_mv http://repositorio.ufps.edu.co/handle/ufps/1745
dc.identifier.doi.none.fl_str_mv 10.17485/ijst/2018/v11i19/122820
url http://repositorio.ufps.edu.co/handle/ufps/1745
identifier_str_mv 10.17485/ijst/2018/v11i19/122820
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.ispartof.none.fl_str_mv Indian Journal of Science and Technology
dc.relation.citationedition.spa.fl_str_mv Vol.11 No.19.(2018)
dc.relation.citationendpage.spa.fl_str_mv 10
dc.relation.citationissue.spa.fl_str_mv 19 (2018)
dc.relation.citationstartpage.spa.fl_str_mv 1
dc.relation.citationvolume.spa.fl_str_mv 11
dc.relation.cites.none.fl_str_mv Bautista-Ruiz, J., Aperador, W., & Caicedo, J. C. (2018). Sol-Gel Synthesis of Titanium/Bismuth Oxide Coatings for Biocompatibility Applications on 316L Stainless Steel. Indian Journal of Science and Technology, 11(19).
dc.relation.ispartofjournal.spa.fl_str_mv Indian Journal of Science and Technology
dc.rights.eng.fl_str_mv This work is licensed under a Creative Commons Attribution 4.0 International License.
dc.rights.coar.fl_str_mv http://purl.org/coar/access_right/c_abf2
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dc.rights.creativecommons.spa.fl_str_mv Atribución 4.0 Internacional (CC BY 4.0)
rights_invalid_str_mv This work is licensed under a Creative Commons Attribution 4.0 International License.
Atribución 4.0 Internacional (CC BY 4.0)
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eu_rights_str_mv openAccess
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dc.publisher.spa.fl_str_mv Indian Journal of Science and Technology
dc.publisher.place.spa.fl_str_mv Nueva Delhi
dc.source.spa.fl_str_mv https://indjst.org/articles/sol-gel-synthesis-of-titaniumbismuth-oxide-coatings-for-biocompatibility-applications-on-316l-stainless-steel
institution Universidad Francisco de Paula Santander
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spelling Aperador Chaparro, William Arnulfod0ab25696c12a7e94a910bc7647be528600Bautista-Ruiz, Jorged2ad76c1874f15a36c3360ca84fbcb66600Caicedo, J. C.484086117144e7d3cc9ecde2024bb6222021-12-08T16:56:37Z2021-12-08T16:56:37Z2018-05http://repositorio.ufps.edu.co/handle/ufps/174510.17485/ijst/2018/v11i19/122820Objectives: This study was carried out in order to establish the potential offered by the sol-gel method to obtain Titanium/ Bismuth oxide coatings on 316L Stainless Steel (SS) substrates in biocompatibility applications. Methods/Analysis: The stable sol was synthesized by using Bismuth nitrate (III) pentahydrate and Titanium (IV) butoxide. The coatings were deposited by spin-coating technique at 4000 rpm and characterized topographically by Scanning Electron Microscopy SEM and structurally by X-ray diffraction XRD. Through the techniques of polarization potentiodynamic curves and Electrochemical Impedance Spectroscopy (EIS), the anticorrosive response of the �ilms was evaluated. The thickness was then measured, and biocompatibility test was developed. Findings: It was found that the coatings with high composition of the precursor titanium (IV) butoxide offer the best results as an anticorrosive application. Likewise, the growth of cells was uniform on the �ilms indicating that the medium offered by the �ilms does not present active cytotoxicity and surpasses by a large number the cellular growth level compared to stainless steel. Applications /Improvement: 316L (SS) is very useful in implantology, for its low cost compared with other materials. The implanted steel suffers corrosion by the physiological �luids of body. Titanium/Bismuth coatings establish a barrier between body �luids and SS implant.application/pdfengIndian Journal of Science and TechnologyNueva DelhiIndian Journal of Science and TechnologyVol.11 No.19.(2018)1019 (2018)111Bautista-Ruiz, J., Aperador, W., & Caicedo, J. C. (2018). Sol-Gel Synthesis of Titanium/Bismuth Oxide Coatings for Biocompatibility Applications on 316L Stainless Steel. Indian Journal of Science and Technology, 11(19).Indian Journal of Science and TechnologyThis work is licensed under a Creative Commons Attribution 4.0 International License.info:eu-repo/semantics/openAccessAtribución 4.0 Internacional (CC BY 4.0)http://purl.org/coar/access_right/c_abf2https://indjst.org/articles/sol-gel-synthesis-of-titaniumbismuth-oxide-coatings-for-biocompatibility-applications-on-316l-stainless-steelSol-Gel Synthesis of Titanium/Bismuth Oxide Coatings for Biocompatibility Applications on 316L Stainless SteelArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85BiocompatibilityCorrosionSol-gelTitanium/Bismuth Oxide Coatings316LBautista-Ruiz J, Aperador W, Delgado A, Díaz-Lagos M. Synthesis and characterization of anticorrosive coatings of SiO2-TiO2-ZrO2 obtained from sol-gel suspensions. International Journal of Electrochemical Science. 2014 May; 9:4144–57.Brinker C, Scherer G. Sol–gel science: The physics and chemistry of sol–gel processing. San Diego: Academic Press; 1990Amiri A. Solid-phase microextraction-based sol–gel technique. TrAC Trends in Analytical Chemistry. 2016; 75:57– 74. CrossrefWu X, Fu Q, Kumar D. Mechanically robust superhydrophobic and super-oleophobic coatings derived by sol–gel method. Materials and Design. 2016; 89:1302–9. CrossrefOubaha M, Gorin A, McDonagh C, Duffy B. Development of a multianalyte optical sol–gel biosensor for medical diagnostic. Sensors and Actuators B: Chemical. 2015; 221:96– 103. CrossrefCao X, Jiang S, Li Y. Synthesis and characterization of calcium and iron co-doped lanthanum silicate oxyapatites by sol–gel process for solid oxide fuel cells. Journal of Power Sources. 2015; 293:806–814. CrossrefSetsoafiaa D, Hinga P, Junga S. Sol–gel synthesis and characterization of Zn2+ and Mg2+ doped La10Si6O27 electrolytes for solid oxide fuel cells. Solid State Sciences. 2015; 48:163–70. CrossrefRubešová K, Jakeš V, Hlásek T. Bi-Sr-Co-O thermos-electrics prepared by sol-gel methods with modified gel decomposition. Journal of Physics and Chemistry of Solids. 2012; 73(3):448–53. CrossrefWang W, Chen Q, Cui Q. Improvement in structure and superconductivity of YBa2Cu3O6+ δ ceramics superconductors by optimizing sintering processing. Physica C: Superconductivity and its Applications. 2015; 511:1–3.Wang X, Lu M, Qiu L. Graphene/titanium carbide composites prepared by sol–gel infiltration and spark plasma sintering. Ceramics International, 2016; 42(1):122–31. CrossrefAbbasi Z, Bahrololoum M, Bagheri, R. Characterization of the bioactive and mechanical behavior of dental ceramic/ sol–gel derived bioactive glass mixtures. Journal of the Mechanical Behavior of Biomedical Materials. 2016; 54:115–22. Crossref. PMid:26454135Mackenzie J, Ulrich D. Ultrastructure Processing of Advanced Ceramics. New York: Wiley; 1988.Gua H, Dongb C, Chena P, Kuanga A, Lic X. Growth of layered perovskite Bi4Ti3O12 thin films by sol–gel proces. Journal of Crystal Growth. 1998; 186(3):403–8. CrossrefVeber A, Kunej S, Suvorov D. Synthesis and microstructural characterization of Bi12SiO20 (BSO) thin films produced by the sol–gel process. Ceramics International. 2010; 36(1):245–50. CrossrefManiscalco S, Caligari Conti M, Cassar J, Grima C, Karl A, Wismayer PS, Mallia B, Buhagiar J. Low temperature carburised austenitic stainless steel for metal-on-metal tribological contact. Thin Solid Films. 2016; 620:103–13. Crossref. Chang K, Chung SC, Lai S. The Electrochemical Behavior of Thermally Oxidized CrN Coatings Deposited on Steel by Cathodic Arc Plasma Deposition. Applied Surface Science. 2004; 236(1):406–15. CrossrefAltun H, Sen S. The effect of DC magnetron sputtering AlN coatings on the corrosion behavior of magnesium alloys. Surface and Coatings Technology. 2005; 197(2):193–200. CrossrefMoreno C, Hernández S, Santana J. Characterization of Water Uptake by Organic Coatings Used for the Corrosion Protection of Steel as Determined from Capacitance Measurements. International Journal of Electrochemical Science. 2012; 7:8444–57.Yoo Y, Le D, Kim S. Corrosion behavior of TiN, TiAlN, TiAlSiN thin films deposited on tool steel in the 3.5 wt. % NaCl solution. Thin Solid Films. 2008; 516(11):3544–8. CrossrefXin Z, Lei M, Jian-gang W, Hui-min Z. Investigation on ultrathin titanium oxide films synthesized by surface solgel method. Optik - International Journal for Light and Electron Optics. 2016; 127(5):2780–3.ORIGINALSol-Gel Synthesis of TitaniumBismuth Oxide Coatings for Biocompatibility Applications on 316L Stainless Steel.pdfSol-Gel Synthesis of TitaniumBismuth Oxide Coatings for Biocompatibility Applications on 316L Stainless Steel.pdfapplication/pdf968972https://repositorio.ufps.edu.co/bitstream/ufps/1745/1/Sol-Gel%20Synthesis%20of%20TitaniumBismuth%20Oxide%20Coatings%20for%20Biocompatibility%20Applications%20on%20316L%20Stainless%20Steel.pdfe81abf8bf12a95b11c52c04c95e1d608MD51open accessLICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.ufps.edu.co/bitstream/ufps/1745/2/license.txt2f9959eaf5b71fae44bbf9ec84150c7aMD52open accessTEXTSol-Gel Synthesis of TitaniumBismuth Oxide Coatings for Biocompatibility Applications on 316L Stainless Steel.pdf.txtSol-Gel Synthesis of TitaniumBismuth Oxide Coatings for Biocompatibility Applications on 316L Stainless Steel.pdf.txtExtracted 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 incorporada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.
0000-0003-1778-0851d0ab25696c12a7e94a910bc7647be5286000000-0003-3430-2173d2ad76c1874f15a36c3360ca84fbcb66600