Treatment of Agricultural Wastewater with Chlorpyrifos by Coupling of Heterogeneous Photocatalysis and Anaerobic Biological Process
Treatment of wastewater with Chlorpyrifos content using heterogeneous photocatalysis was evaluated, for which a compound parabolic collector (CPC) was used, under diferent combinations of pH and TiO2 concentration designed using the response surface methodology (RSM), and an anaerobic biological pro...
- Autores:
-
Becerra Moreno, Dorance
Barrientos, Ingrid
Rodriguez, Ana
Machuca-Martinez, Fiderman
Ramírez, Luisa
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2020
- Institución:
- Universidad Francisco de Paula Santander
- Repositorio:
- Repositorio Digital UFPS
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.ufps.edu.co:ufps/1507
- Acceso en línea:
- http://repositorio.ufps.edu.co/handle/ufps/1507
- Palabra clave:
- Pesticides
Compound parabolic collector
TiO2
Response surface methodology
Specifc methanogenic activity
Real wastewater
- Rights
- openAccess
- License
- Springer Science+Business Media, LLC, part of Springer Nature 2020
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Treatment of Agricultural Wastewater with Chlorpyrifos by Coupling of Heterogeneous Photocatalysis and Anaerobic Biological Process |
| title |
Treatment of Agricultural Wastewater with Chlorpyrifos by Coupling of Heterogeneous Photocatalysis and Anaerobic Biological Process |
| spellingShingle |
Treatment of Agricultural Wastewater with Chlorpyrifos by Coupling of Heterogeneous Photocatalysis and Anaerobic Biological Process Pesticides Compound parabolic collector TiO2 Response surface methodology Specifc methanogenic activity Real wastewater |
| title_short |
Treatment of Agricultural Wastewater with Chlorpyrifos by Coupling of Heterogeneous Photocatalysis and Anaerobic Biological Process |
| title_full |
Treatment of Agricultural Wastewater with Chlorpyrifos by Coupling of Heterogeneous Photocatalysis and Anaerobic Biological Process |
| title_fullStr |
Treatment of Agricultural Wastewater with Chlorpyrifos by Coupling of Heterogeneous Photocatalysis and Anaerobic Biological Process |
| title_full_unstemmed |
Treatment of Agricultural Wastewater with Chlorpyrifos by Coupling of Heterogeneous Photocatalysis and Anaerobic Biological Process |
| title_sort |
Treatment of Agricultural Wastewater with Chlorpyrifos by Coupling of Heterogeneous Photocatalysis and Anaerobic Biological Process |
| dc.creator.fl_str_mv |
Becerra Moreno, Dorance Barrientos, Ingrid Rodriguez, Ana Machuca-Martinez, Fiderman Ramírez, Luisa |
| dc.contributor.author.none.fl_str_mv |
Becerra Moreno, Dorance Barrientos, Ingrid Rodriguez, Ana Machuca-Martinez, Fiderman Ramírez, Luisa |
| dc.subject.proposal.eng.fl_str_mv |
Pesticides Compound parabolic collector TiO2 Response surface methodology Specifc methanogenic activity Real wastewater |
| topic |
Pesticides Compound parabolic collector TiO2 Response surface methodology Specifc methanogenic activity Real wastewater |
| description |
Treatment of wastewater with Chlorpyrifos content using heterogeneous photocatalysis was evaluated, for which a compound parabolic collector (CPC) was used, under diferent combinations of pH and TiO2 concentration designed using the response surface methodology (RSM), and an anaerobic biological process based on the specifc methanogenic activity test (SMA), using a focculent sludge and an initial concentration of 2.0 g VSS/L. Initially, water resulting from the triple washing of equipment for manual application of Chlorpyrifos from the El Zulia Irrigation District and the municipality of Bucarasica were characterized. In the biological process, COD and TOC removals of 46.4% and 86.6% were obtained; while by applying preliminary photocatalytic processes, under optimal conditions of TiO2 (100 mg/L), pH (3 units) and retention time (3 h), better biodegradability efciencies (72.2% and 53.0%) were achieved. The results revealed that the combined use of advanced oxidation processes with biological treatment technologies is technically viable, as it increases the efciency of removing contaminants from agricultural efuents with Chlorpyrifos. |
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2020 |
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2020-05-29 |
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2021-11-27T23:20:32Z |
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2021-11-27T23:20:32Z |
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Artículo de revista |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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http://repositorio.ufps.edu.co/handle/ufps/1507 |
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10.1007/s11244-020-01281-4 |
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http://repositorio.ufps.edu.co/handle/ufps/1507 |
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10.1007/s11244-020-01281-4 |
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eng |
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eng |
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Topics in Catalysis ISSN: 1572-9028, 2020 vol:63 fasc: N/A págs: 1 - 11, DOI:10.1007/s11244-020-01281-4 |
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Vol. 63 (2020) |
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1271 |
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1261 |
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63 |
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Becerra, D., Barrientos, I., Rodriguez, A. et al. Treatment of Agricultural Wastewater with Chlorpyrifos by Coupling of Heterogeneous Photocatalysis and Anaerobic Biological Process. Top Catal 63, 1261–1271 (2020). https://doi.org/10.1007/s11244-020-01281-4 |
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Topics in Catalysis |
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Springer Science+Business Media, LLC, part of Springer Nature 2020 |
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Springer Science+Business Media, LLC, part of Springer Nature 2020 http://purl.org/coar/access_right/c_abf2 |
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openAccess |
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11 páginas |
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Topics in Catalysis |
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Luxemburgo |
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Becerra Moreno, Dorance81ffadb12b7f7803d974959f5ecd568c600Barrientos, Ingrid1f8198a2889efa01737cbe1a7509ec0cRodriguez, Ana26403951b0b80f73422b79044cc8dadaMachuca-Martinez, Fiderman6ea4bab6365eb577b6f4afd1ee2e9f40600Ramírez, Luisa43c990029a296d5e13dc41ac78f19dae2021-11-27T23:20:32Z2021-11-27T23:20:32Z2020-05-29http://repositorio.ufps.edu.co/handle/ufps/150710.1007/s11244-020-01281-4Treatment of wastewater with Chlorpyrifos content using heterogeneous photocatalysis was evaluated, for which a compound parabolic collector (CPC) was used, under diferent combinations of pH and TiO2 concentration designed using the response surface methodology (RSM), and an anaerobic biological process based on the specifc methanogenic activity test (SMA), using a focculent sludge and an initial concentration of 2.0 g VSS/L. Initially, water resulting from the triple washing of equipment for manual application of Chlorpyrifos from the El Zulia Irrigation District and the municipality of Bucarasica were characterized. In the biological process, COD and TOC removals of 46.4% and 86.6% were obtained; while by applying preliminary photocatalytic processes, under optimal conditions of TiO2 (100 mg/L), pH (3 units) and retention time (3 h), better biodegradability efciencies (72.2% and 53.0%) were achieved. The results revealed that the combined use of advanced oxidation processes with biological treatment technologies is technically viable, as it increases the efciency of removing contaminants from agricultural efuents with Chlorpyrifos.11 páginasapplication/pdfengTopics in CatalysisLuxemburgoTopics in Catalysis ISSN: 1572-9028, 2020 vol:63 fasc: N/A págs: 1 - 11, DOI:10.1007/s11244-020-01281-4Vol. 63 (2020)1271126163Becerra, D., Barrientos, I., Rodriguez, A. et al. Treatment of Agricultural Wastewater with Chlorpyrifos by Coupling of Heterogeneous Photocatalysis and Anaerobic Biological Process. Top Catal 63, 1261–1271 (2020). https://doi.org/10.1007/s11244-020-01281-4Topics in CatalysisSpringer Science+Business Media, LLC, part of Springer Nature 2020info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2https://link.springer.com/article/10.1007%2Fs11244-020-01281-4#additional-informationTreatment of Agricultural Wastewater with Chlorpyrifos by Coupling of Heterogeneous Photocatalysis and Anaerobic Biological ProcessArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85PesticidesCompound parabolic collectorTiO2Response surface methodologySpecifc methanogenic activityReal wastewaterFood and Agriculture Organization of the United Nations (FAO) (2002) World Agriculture: towards the years 2015/2030—Summary Report. Rome, Italy. ISBN: 92-5-304761-5Corporación Autónoma Regional de la Frontera Nororiental— CORPONOR (2014) Sectional committee of pesticides developed the articulation of the action plan for Norte of Santander, Cúcuta, Colombia. http://www.corponor.gov.co/es/index.php/es/comun icaciones/historico-de-noticias/1835-comite-seccional-de-plagu icidas-desarrollo-la-articulacion-del-plan-de-accion-para-norte -de-santander. Accessed March 2018Barba-Ho L, Becerra D, Angulo V, Salazar L (2011) Transformation of agroindustry efuents with pesticides content by heterogeneous catalysis. Nat Resour Environ Eng 10:127–136García L (2013) Study of the behavior of anaerobic sludge treatment before pH modifcations. Polytechnic University of Valencia, Higher Technical School of Design Engineering, Spain. https://riunet.upv.es/handle/10251/50162Becerra D (2013) Coupling of photocatalytic and biological processes for the treatment of wastewater with pesticide residues. J Chem Inf Model 53:1689–1699Barba L, Becerra D, Gutiérrez H (2009) Biological treatment alternatives for pesticides used in sugarcane for coupling with photocatalytic systems. Nat Resour Environ Eng 8:4–12American Public Health Association—APHA, American Water Works Association—AWWA, Water Environment Federation— WEF (1999) Standard methods for the examination of water and wastewater 20th edition. Washington, United StatesTorres P, Pérez A (2010) Specific methanogenic activity: a control and optimization tool for anaerobic wastewater treatment systems. Nat Resour Environ Eng 9:5–14Torres P, Victoria J, Cajigas A, Pérez A (2002) Methanogenic activity as a tool for the optimization of the anaerobic process in the treatment of easily acidifiable wastewater. In: XXVIII Congreso Interamericano de Ingeniería Sanitaria y Ambiental. AIDIS. Cancún, MéxicoAquino S, Chernicharo C, Foresti E, Florêncio dos M, Monteggia L (2007) Methodologies for determining specific methanogenic activity (SMA) in anaerobic sludge. Sanitary and Environmental Engineering. https://doi.org/10.1590/S1413-41522007000200010Castro L, Quintero A (2001) Study of the anaerobic biodegradability of the Carbofuran pesticide. Universidad del Valle, Santiago de CaliFernández M, Abalos A, Crombet S, Caballero H (2010) Anaerobic biodegradability tests of wastewater generated in a soybean oil refining plant. Interciencia 35:600–604Moreira N, Narciso-da-Rocha C, Polo M, Pastrana L, Faria J, Manaia C, Fernández P, Nunes O, Silva A (2018) Solar treatment (H2O2, TiO2-P25 and GO-TiO2 photocatalysis, photo-Fenton) of organic micropollutants, human pathogen indicators antibiotic resistant bacteria related genes in urban wastewater. Water Res 135:195–206. https://doi.org/10.1016/j.watres.2018.01.064Prieto-Rodriguez L, Miralles L, Oller S, Agüera I, Li Puma A, Malato G (2012) Treatment of emerging contaminants in wastewater treatment plants (WWTP) effluents by solar photocatalysis using low TiO2 concentrations. J Hazard Mater 211–212:131–137. https://doi.org/10.1016/j.jhazmat.2011.09.008López A (2006) Photocatalytic oxidation of 2,4-D herbicide. Universidad del Valle, Santiago de CaliLópez B, Torres R, Peñuela G (2011) Solar photocatalitycal treatment of Carbofurán at lab and pilot scale: effect of classical parameters, evaluation of the toxicity and analysis of organic by-products. J Hazard Mater 191:196–203García J (2014) Treatment of water contaminated with pesticides used in sugarcane cultivation in Colombia. Universitat Politècnica de València, ValenciaJiménez M, Santos J (2008) Chlorpyrifos pesticide mobility and environmental impact study, on CORPOICA soils located in Villavicencio from a simulated spill. Universidad de la Salle, Bogotá D.C. https://ciencia.lasalle.edu.co/ing_ambiental_sanitaria/597/Baquero A, Lara-Borrero J, Torres A (2014) Study of treatability of wastewater in Bogotá with activated sludge: Continuous monitoring aspects, specific characterization and simulation of the process. Pontificia Universidad Javeriana, Bogotá. https://doi.org/10.13140/rg.2.1.1054.0962Jiménez E, Mojica M (2005) Study of feasibility of an anaerobic reactor of flow to piston to scale of laboratory, in the treatment of the residual maidservants’ waters of the municipality of Tunja to a temperature average of 14 oC. Tecnogestión 2:13–18. https://revistas.udistrital.edu.co/index.php/tecges/article/view/4320Díaz-Báez M, Espitia S, Molina F (2002) Chapter Five: Characterization of anaerobic sludge and wastewater. Anaerobic digestion: an approach to technology. Universidad Nacional de Colombia. http://www.bdigital.unal.edu.co/43178/11/Digestion%20anaerobia_Parte%202.pdfMosquera J, Martínez B (2012) Evaluation of anaerobic digestion as an alternative for stabilization of biosolids produced in the wastewater treatment plant of the Technological University of Pereira. Universidad Tecnológica de Pereira, PereiraSivagami K, Vikraman B, Krishna R, Swaminathan T (2016) Chlorpyrifos and Endosulfan degradation studies in an annular slurry photo reactor. Ecotoxicol Environ Saf 134:327–331. https://doi.org/10.1016/j.ecoenv.2015.08.015 (ISSN 0147–6513)Gar Alalm M, Tawfik A, Ookawara S (2015) Comparison of solar TiO2 photocatalysis and solar photo-Fenton for treatment of pesticides industry wastewater: operational conditions, kinetics, and costs. J Water Process Eng 8:55–63. https://doi.org/10.1016/j.jwpe.2015.09.007Amalraj A, Pius A (2015) Photocatalytic degradation of monocrotophos and chlorpyrifos in aqueous solution using TiO2 under UV radiation. J Water Process Eng 7:94–101González M, Saldarriaga J (2008) Biological removal of organic matter, nitrogen and phosphorus in an anaerobic-anoxic-aerobic type system. Mag EIA 5:45–53Valery K (2010) Treatment of water contained in oil pits using native mixed cultivation. 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 incorporada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.
0000-0001-8556-991481ffadb12b7f7803d974959f5ecd568c600 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