Effective thermal properties and proximate analysis of coke-coal fines mixtures

We report the effective thermal properties at room temperature and proximate analysis of three mixtures of coke and carbon fines formed by uniaxial pressing at 30 MPa. Using differential scanning calorimetry and thermogravimetry, the thermal behavior of the carbon samples was determined. The KD2 Pro...

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Autores:
Soto Rivero, M F
Quintero Garzón, A C
Peña Rodríguez, G
Miranda Molina, L A
Sepulveda Solano, G
Tipo de recurso:
Article of investigation
Fecha de publicación:
2021
Institución:
Universidad Francisco de Paula Santander
Repositorio:
Repositorio Digital UFPS
Idioma:
eng
OAI Identifier:
oai:repositorio.ufps.edu.co:ufps/6591
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https://repositorio.ufps.edu.co/handle/ufps/6591
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Published under licence by IOP Publishing Ltd
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dc.title.eng.fl_str_mv Effective thermal properties and proximate analysis of coke-coal fines mixtures
title Effective thermal properties and proximate analysis of coke-coal fines mixtures
spellingShingle Effective thermal properties and proximate analysis of coke-coal fines mixtures
title_short Effective thermal properties and proximate analysis of coke-coal fines mixtures
title_full Effective thermal properties and proximate analysis of coke-coal fines mixtures
title_fullStr Effective thermal properties and proximate analysis of coke-coal fines mixtures
title_full_unstemmed Effective thermal properties and proximate analysis of coke-coal fines mixtures
title_sort Effective thermal properties and proximate analysis of coke-coal fines mixtures
dc.creator.fl_str_mv Soto Rivero, M F
Quintero Garzón, A C
Peña Rodríguez, G
Miranda Molina, L A
Sepulveda Solano, G
dc.contributor.author.none.fl_str_mv Soto Rivero, M F
Quintero Garzón, A C
Peña Rodríguez, G
Miranda Molina, L A
Sepulveda Solano, G
dc.contributor.corporatename.spa.fl_str_mv Journal of Physics: Conference Series
description We report the effective thermal properties at room temperature and proximate analysis of three mixtures of coke and carbon fines formed by uniaxial pressing at 30 MPa. Using differential scanning calorimetry and thermogravimetry, the thermal behavior of the carbon samples was determined. The KD2 Pro® system was used to measure the effective thermal properties, while the proximate analysis was carried out applying the ASTM D 3172-89 standard. It was found for coke fines that in the range between 40.00 °C and 293.94 °C there is a loss in weight of 3.2%, which corresponds to the degradation of low molecular weight volatiles, another degradation was also observed between 90.07 °C and 336.21 °C, and the maximum devolatilization temperature was 579 °C, finally from 700 °C the melting process begins, which corresponds to the formation of coke. It was also observed that the thermal conductivity increases with increasing coke concentration in the sample, and that the mixture with the highest thermal diffusivity was the one formed with 80% coke fines and 20% carbon fines. According to the thermal properties of the samples can be to be used efficiently as fuel.
publishDate 2021
dc.date.issued.none.fl_str_mv 2021-06-04
dc.date.accessioned.none.fl_str_mv 2022-11-22T20:50:46Z
dc.date.available.none.fl_str_mv 2022-11-22T20:50:46Z
dc.type.spa.fl_str_mv Artículo de revista
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dc.identifier.uri.none.fl_str_mv https://repositorio.ufps.edu.co/handle/ufps/6591
dc.identifier.doi.none.fl_str_mv 10.1088/1742-6596/2046/1/012045
url https://repositorio.ufps.edu.co/handle/ufps/6591
identifier_str_mv 10.1088/1742-6596/2046/1/012045
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.ispartof.none.fl_str_mv Journal of Physics: Conference Series, Volume 2046, 5+1 International Meeting for Researchers in Materials and Plasma Technology (5+1 IMRMPT), 2 - 4 June 2021, Medellín, Colombia
dc.relation.citationedition.spa.fl_str_mv Vol. 2046 N0.012045 (2021)
dc.relation.citationendpage.spa.fl_str_mv 5
dc.relation.citationissue.spa.fl_str_mv 012045 (2021)
dc.relation.citationstartpage.spa.fl_str_mv 1
dc.relation.citationvolume.spa.fl_str_mv Vol.2046
dc.relation.cites.none.fl_str_mv M F Soto-Rivero et al 2021 J. Phys.: Conf. Ser. 2046 012045
dc.relation.ispartofjournal.spa.fl_str_mv Journal of Physics: Conference Series
dc.rights.eng.fl_str_mv Published under licence by IOP Publishing Ltd
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dc.rights.creativecommons.spa.fl_str_mv Atribución 4.0 Internacional (CC BY 4.0)
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Atribución 4.0 Internacional (CC BY 4.0)
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eu_rights_str_mv openAccess
dc.format.extent.spa.fl_str_mv 06 Páginas
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dc.publisher.place.spa.fl_str_mv Reino Unido
dc.source.spa.fl_str_mv https://iopscience.iop.org/article/10.1088/1742-6596/2046/1/012045
institution Universidad Francisco de Paula Santander
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spelling Soto Rivero, M F1b963c910fd06ff61957cf6836afde3aQuintero Garzón, A C1ea8afc90d5c9dda805fa26f93f90c59Peña Rodríguez, G22d347192d653febb4a2d674a799b1c6600Miranda Molina, L Ae1abeb9ed2ce8328d26c2e2fd01e4b72Sepulveda Solano, Gf8bdb0bb23fb14403fd9dc420999360aJournal of Physics: Conference Series2022-11-22T20:50:46Z2022-11-22T20:50:46Z2021-06-04https://repositorio.ufps.edu.co/handle/ufps/659110.1088/1742-6596/2046/1/012045We report the effective thermal properties at room temperature and proximate analysis of three mixtures of coke and carbon fines formed by uniaxial pressing at 30 MPa. Using differential scanning calorimetry and thermogravimetry, the thermal behavior of the carbon samples was determined. The KD2 Pro® system was used to measure the effective thermal properties, while the proximate analysis was carried out applying the ASTM D 3172-89 standard. It was found for coke fines that in the range between 40.00 °C and 293.94 °C there is a loss in weight of 3.2%, which corresponds to the degradation of low molecular weight volatiles, another degradation was also observed between 90.07 °C and 336.21 °C, and the maximum devolatilization temperature was 579 °C, finally from 700 °C the melting process begins, which corresponds to the formation of coke. It was also observed that the thermal conductivity increases with increasing coke concentration in the sample, and that the mixture with the highest thermal diffusivity was the one formed with 80% coke fines and 20% carbon fines. According to the thermal properties of the samples can be to be used efficiently as fuel.06 Páginasapplication/pdfengJournal of Physics: Conference Series, Volume 2046, 5+1 International Meeting for Researchers in Materials and Plasma Technology (5+1 IMRMPT), 2 - 4 June 2021, Medellín, ColombiaVol. 2046 N0.012045 (2021)5012045 (2021)1Vol.2046M F Soto-Rivero et al 2021 J. Phys.: Conf. Ser. 2046 012045Journal of Physics: Conference SeriesPublished under licence by IOP Publishing Ltdhttps://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessAtribución 4.0 Internacional (CC BY 4.0)http://purl.org/coar/access_right/c_abf2https://iopscience.iop.org/article/10.1088/1742-6596/2046/1/012045Effective thermal properties and proximate analysis of coke-coal fines mixturesArtículo de revistahttp://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Reino UnidoHuntington H, Barrios J, Arora V 2019 Review of key international demand elasticities for major industrializing economies Energy Policy 133 110878Höök M, Zittel W, Schindler J, Aleklett K 2010 Global coal production outlooks based on a logistic model Fuel 89(11) 3546Charriau P, Desbrosses N 2016 Global energy trends: towards a peak in energy demand and CO2 emissions (Grenoble: Enerdata)Deng J, Li Q, Xiao Y, Shu C 2017 Experimental study on the thermal properties of coal during pyrolysis, oxidation, and re-oxidation Applied Thermal Engineering 110 1137Shi Q, Qin Y, Chen Y 2020 Relationship between thermal conductivity and chemical structures of chinese coals ACS Omega 5(29) 18424Barrera Zapata R, Perez Bayer J F, Salazar Jiménez C 2014 Carbones colombianos: clasificación y caracterización termoquímica para aplicaciones energéticas Revista ION 27(2) 43Deng J, Li, Xiao Y, Shu C, Zhang Y 2017 Predictive models for thermal diffusivity and specific heat capacity of coals in Huainan mining area, China Thermochimica Acta 656 101Vosteen H D, Schellschmidt R 2003 Influence of temperature on thermal conductivity, thermal capacity and thermal diffusivity for different types of rock Physics and Chemistry of the Earth 28(9-11) 499Gutiérrez J, Mora W, Rodríguez L, Ramírez J, Díaz J 2011 Aprovechamiento de partículas de ultrafinos de carbón de una planta lavadora en la producción de coque metalúrgico Ingeniería e Investigación 31(1) 56American Society for Testing and Materials (ASTM) 2002 Standard Practice for Proximate Analysis of Coal and Coke, ASTM D3172-89 (United States of America: American Society for Testing and Materials)Ma X, Omer S, Zhang W, Riffat S B 2008 Thermal conductivity measurement of two microencapsulated phase change slurries International Journal of Low-Carbon Technologies 3(4) 245Abramowitz M, Stegun I 1972 Handbook of Mathematical Functions with Formulas, Graphs, and Mathematical Tables (Washington: National Bureau of Standards)Decagon Devices Inc 2016 KD2 Pro Thermal Properties Analyzer, Operator’s Manual (Pullman: Decagon Devices Inc)Sahu S G, Sarkar P, Chakraborty N, Adak A K 2010 Thermogravimetric assessment of combustion characteristics of blends of a coal with different biomass chars Fuel Processing Technology 91(3) 369Khorami M, Chelgani S, Hower J, Jorjani E 2011 Studies of relationships between free swelling index (FSI) and coal quality by regression and adaptive neuro fuzzy inference system Int. J. Coal. Geo. 85(1) 65Jain R, Yadav S, Bisht S, Kodavaty J, Yatirajula S 2021 Effect of concentration, size, granularity, shear time and temperature on rheological properties of coal water slurries IOP Conf. Series: Materials Science and Engineering 1126 012027Kasai A, Murayama T, Ono Y 1993 Measurement of effective thermal conductivity of coke J Stage Iron and Steel 79(1) 20ORIGINALEffective thermal properties and proximate analysis of coke-coal fines mixtures.pdfEffective thermal properties and proximate analysis of coke-coal fines mixtures.pdfapplication/pdf611035https://repositorio.ufps.edu.co/bitstream/ufps/6591/1/Effective%20thermal%20properties%20and%20proximate%20analysis%20of%20coke-coal%20fines%20mixtures.pdf85261a17a0a9b94945e44182c62b7da6MD51open accessLICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.ufps.edu.co/bitstream/ufps/6591/2/license.txt2f9959eaf5b71fae44bbf9ec84150c7aMD52open accessTEXTEffective thermal properties and proximate analysis of coke-coal fines mixtures.pdf.txtEffective thermal properties and proximate analysis of coke-coal fines mixtures.pdf.txtExtracted 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 incorporada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.
