Mechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying technique
The mechanical and tribological performance of red clay ceramic tiles uncoated and coated by oxy-fuel thermal spraying process from fly ash powders was evaluated. The ceramic tile substrates were manufactured by uniaxial pressing at 26.17 bar pressure, and sintered at 1100 °C. The coating thickness...
- Autores:
-
Peña Rodriguez, Gabriel
Hector Jaime, Dulce-Moreno
Daza-Ramírez, J
Orozco-Hernández, S.
Vargas, Fabio
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2017
- Institución:
- Universidad Francisco de Paula Santander
- Repositorio:
- Repositorio Digital UFPS
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.ufps.edu.co:ufps/1489
- Acceso en línea:
- http://repositorio.ufps.edu.co/handle/ufps/1489
- Palabra clave:
- Rights
- openAccess
- License
- Atribución 4.0 Internacional (CC BY 4.0)
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Mechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying technique |
| title |
Mechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying technique |
| spellingShingle |
Mechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying technique |
| title_short |
Mechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying technique |
| title_full |
Mechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying technique |
| title_fullStr |
Mechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying technique |
| title_full_unstemmed |
Mechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying technique |
| title_sort |
Mechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying technique |
| dc.creator.fl_str_mv |
Peña Rodriguez, Gabriel Hector Jaime, Dulce-Moreno Daza-Ramírez, J Orozco-Hernández, S. Vargas, Fabio |
| dc.contributor.author.none.fl_str_mv |
Peña Rodriguez, Gabriel Hector Jaime, Dulce-Moreno Daza-Ramírez, J Orozco-Hernández, S. Vargas, Fabio |
| description |
The mechanical and tribological performance of red clay ceramic tiles uncoated and coated by oxy-fuel thermal spraying process from fly ash powders was evaluated. The ceramic tile substrates were manufactured by uniaxial pressing at 26.17 bar pressure, and sintered at 1100 °C. The coating thickness was determined based on the number of projection-cycles oxyacetylene flame over substrate. Coal fly ash coatings were deposited, with average thickness of 56.18±12.18 μm, 180.42±20.32 μm, and 258.26±25.88μm. The mechanical resistance to bending and wear by abrasion deep, were studied using ISO 10545-4 standards and ISO 10545-6 respectively; adhesion was measured using Elcometer equipment Type III according to ASTM D-4541-02 and the average roughness (Ra) was found according to ASTM standard D7127-13, using the profilometer Mitutoyo SJ 201. The surface morphology presented the heterogeneous molten or semi molten splats with average size of 35.262±3.48 micrometers with good adhesion, justifying increased mechanical resistance to bending by 5%, as well as wear by abrasion deep. These results contribute to the development of ceramic products with added value, to be used in various technological applications. |
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2017 |
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2017 |
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2021-11-27T14:01:36Z |
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2021-11-27T14:01:36Z |
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Artículo de revista |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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http://repositorio.ufps.edu.co/handle/ufps/1489 |
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10.1088/1742-6596/792/1/012026 |
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eng |
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eng |
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Journal of Physics: Conference Series |
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Vol.792 No.1.(2017) |
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5 |
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1 (2017) |
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Peña-Rodríguez, G., Dulce-Moreno, H., Daza-Ramírez, J., Orozco-Hernández, S., & Vargas-Galvis, F. (2017). Mechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying technique. In Journal of Physics: Conference Series (Vol. 792, No. 1, p. 012026). IOP Publishing. |
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Journal of Physics: Conference Series |
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Atribución 4.0 Internacional (CC BY 4.0) |
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openAccess |
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Atribución 4.0 Internacional (CC BY 4.0) http://purl.org/coar/access_right/c_abf2 |
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Journal of Physics: Conference Series |
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Bogota , Colombia |
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Peña Rodriguez, Gabriel4eaba0408a3f49f82929dc957fa8eee1600Hector Jaime, Dulce-Morenoc52224ce51e899c549360dec1879609d600Daza-Ramírez, J173fad80a3986dae38a0b100cf106d90Orozco-Hernández, S.6570bc9e9d8f4b8d078030c8875173d8Vargas, Fabioba1314c868b24bcb723660218a8987676002021-11-27T14:01:36Z2021-11-27T14:01:36Z2017http://repositorio.ufps.edu.co/handle/ufps/148910.1088/1742-6596/792/1/012026The mechanical and tribological performance of red clay ceramic tiles uncoated and coated by oxy-fuel thermal spraying process from fly ash powders was evaluated. The ceramic tile substrates were manufactured by uniaxial pressing at 26.17 bar pressure, and sintered at 1100 °C. The coating thickness was determined based on the number of projection-cycles oxyacetylene flame over substrate. Coal fly ash coatings were deposited, with average thickness of 56.18±12.18 μm, 180.42±20.32 μm, and 258.26±25.88μm. The mechanical resistance to bending and wear by abrasion deep, were studied using ISO 10545-4 standards and ISO 10545-6 respectively; adhesion was measured using Elcometer equipment Type III according to ASTM D-4541-02 and the average roughness (Ra) was found according to ASTM standard D7127-13, using the profilometer Mitutoyo SJ 201. The surface morphology presented the heterogeneous molten or semi molten splats with average size of 35.262±3.48 micrometers with good adhesion, justifying increased mechanical resistance to bending by 5%, as well as wear by abrasion deep. These results contribute to the development of ceramic products with added value, to be used in various technological applications.application/pdfengJournal of Physics: Conference SeriesBogota , ColombiaJournal of Physics: Conference SeriesVol.792 No.1.(2017)51 (2017)1792Peña-Rodríguez, G., Dulce-Moreno, H., Daza-Ramírez, J., Orozco-Hernández, S., & Vargas-Galvis, F. (2017). Mechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying technique. In Journal of Physics: Conference Series (Vol. 792, No. 1, p. 012026). IOP Publishing.Journal of Physics: Conference SeriesContent from this work may be used under the terms of the Creative Commons Attribution 3.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI. Published under licence by IOP Publishing Ltdinfo:eu-repo/semantics/openAccessAtribución 4.0 Internacional (CC BY 4.0)http://purl.org/coar/access_right/c_abf2https://iopscience.iop.org/article/10.1088/1742-6596/792/1/012026/metaMechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying techniqueArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Chávez A, Vargas G and Almanza J M 2008 Caracterización y preparación de ceniza volante para su uso como recubrimientos cerámicos sobre substratos metálicos Bol. Soc. Esp. Ceram. V. 47 333-8Cheng T W and Chen Y S 2004 Characterisation of glass ceramics made from incinerator fly ash Departamento de Materiales y Recursos Minerales Ingeniería de la Universidad Nacional de Tecnología de Taipei, Taipei, Taiwán, República de China Ceram. Int. 30 343-9Ulrichs C, Schmidt U, Mucha-Pelzer T, Goswami A and Mewis I 2009 Hard Coal Fly Ash and Silica-Effect of Fine Particulate Matter Deposits on Brassica chinensis Am. J. Agric. Bio. Sci. 4 24-31Shanthakumar S, Singh D N and Phadke R C 2008 Characterization of Fly Ash from Various Locations of Electrostatic Precipitator The 12th International Conference of International Association for Computer Methods and Advances in Geomechanics (Goa, India: IACMAG)Arango-Martínez N, Pérez-Bueno J, Gochi-Poncel Y and Sánchez-Rubiol M 2011 Zeolitas a partir de cenizas volantes generadas en las centrales carboeléctricas para el tratamiento de agua contaminada con Mn y Pb 26 ed CienciaChávez-Valdez A, Arizmendi-Morquecho A, Vargas G, Almanza J M and Alvarez-Quintana J 2011 Ultra-low thermal conductivity thermal barrier coatings from recycled fly-ash cenospheres Acta Mater. 59 2556-62Khanra S, Mallick D, Dutta S N and Chaudhuri S K 1998 Studies on the phase mineralogy and leaching characteristics of coal fly ash Water Air Soil Pollut 251-75Peña-Rodríguez G and Ortega-Triana L R Morphological and structural characterization of fly ash powders 2014 I+D 14 14-19Vucini D, Miljanovic I, Rosic A and Lazic P 2003 Effect of Na2O/SiO2 mole ratio on the crystal type of zeolite synthesized from coal fly ash J.Serb.Chem.Soc. 68 471-78Gomes S and François M 2000 Characterization of mullite in silicoaluminous fly ash by XRD, TEM and 29Si MAS NMR Cement Concr. Res. 30 175-81Valencia S L 2001 Caracterización física química y mineralógica de las cenizas volantes Ciencia e Ingeniería Neogranadina, núm 10 (Colombia: Universidad Militar Nueva Granada) 47-62Norton G, Markuszewskl R and Shanks H 1986 Morphological and Chemical Characterization of Iron-Rich Fly Ash Fractions Envlron. Sci. Technol 20 (Iowa: Ames Laboratory, Iowa State University, Ames) 409-413Ruiz-Román J M, Santos C, Cambronero L, Corpas F, Alfonso M and Morano A J 2000 Aprovechamiento de las cenizas volantes, clase F, de centrales térmicas para la fabricación de materiales cerámicos Bol. Soc. Esp. Ceram. V. 39 229-31Lira-Olivares J, González-Rodulfo S and De Abreu J 2011 Recubrimientos metálicos y cerámicos solucionan el problema económico y ambiental de países desarrollados y en desarrollo Rev. Latinam. Metal. Mat. 31 106-121Morales J, Olaya-Flórez J and Rojas-Molano H 2012 An approach to thermal spray technology AVANCES Inv. Ing. 9 60-71Chata S, Sidhu H and Sidhu B 2012 Characterisation and corrosión-Erosion Behaviour of Carbide based Thermal Spray Coatings J. Miner. Mater. Charact. Eng. 11 569-86Vargas F 2010 Élaboration de couches céramiques épaisses á structures micrométriques et nanométriques par projections thermiques pour des applications tribologiques Tesis de Doctorado Faculté des sicences et techniquesGonzález A, Henao J, Díaz A, López E and Vargas F 2013 Influence of thermal spray parameters on the microestructure of Zirconia-Aluminia and Zirconia-Ceria coatings used as a thermal barrier Rev. Latinam.Metal.Mat 33 272-81Cano C 2008 Recubrimientos cerámicos con aplicación en barreras térmicas y ambientales Tesis doctoral Universidad Autónoma de Madrid2008 Observatorio Tecnológico del Metal Proyección Térmica para Matrices (Parque Tecnológico: AIMME-Instituto Tecnológico Metalmecánico)Restrepo E, Vargas F, López M, Cardona R and Duarte G 2012 Elaboración de recubrimientos cerámicos mediante proyección térmica por combustión a partir de residuos sólidos industriales Rev. Mat. 17 1176-85Pawlowski L 2008 The Science and Engineering of Thermal Spray Coatings. Second Edition Ecole Nationale Supérieure de Chimie de Lille Villeneuve d’AscqAraque-Pabón M, Peña-Rodríguez G and Vargas-Galvis F 2015 Desempeño mecánico y tribológico de baldosas cerámicas de arcilla roja recubiertas por proyección térmica a partir de alúmina Tecno Lógicas 18 35-35Vallejo-Pérez M, Gómez-García I C, Zuluaga-Castrillon D, Hernández-Ruiz J F, Vargas-Galvis F and López-Gómez M E 2013 Estudio de la estructura de recubrimientos de silicio depositados mediante proyección térmica por llama oxiacetilénica Rev. Col. Mat. 145-151http://www.ceramicaitalia.com/inf/images/stories/WebPageFiles/FichaTecnicaRV.pdf consultado abril 01 de 2016https://alfa.com.co/uploads/fichas/99099cf35dbaf3e6c02f2ee692fa3bedb7e8c238.pdf consultado abril 01 de 2016ORIGINALMechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying technique.pdfMechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying technique.pdfapplication/pdf1052576https://repositorio.ufps.edu.co/bitstream/ufps/1489/1/Mechanical%20and%20tribological%20behavior%20of%20red%20clay%20ceramic%20tiles%20coated%20with%20fly%20ash%20powders%20by%20thermal%20spraying%20technique.pdfe162564a5bc0e29f929b2a37e685e092MD51open accessLICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.ufps.edu.co/bitstream/ufps/1489/2/license.txt2f9959eaf5b71fae44bbf9ec84150c7aMD52open accessTEXTMechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying technique.pdf.txtMechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying technique.pdf.txtExtracted texttext/plain20691https://repositorio.ufps.edu.co/bitstream/ufps/1489/3/Mechanical%20and%20tribological%20behavior%20of%20red%20clay%20ceramic%20tiles%20coated%20with%20fly%20ash%20powders%20by%20thermal%20spraying%20technique.pdf.txt82a682d89edb55054215e5902a185eefMD53open accessTHUMBNAILMechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying technique.pdf.jpgMechanical and tribological behavior of red clay ceramic tiles coated with fly ash powders by thermal spraying technique.pdf.jpgGenerated 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 incorporada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.
0000-0002-9811-4297c52224ce51e899c549360dec1879609d600 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