Niobium Pentoxide Samples with Addition of Manganese at Different Concentrations and Calcination Temperatures Applied in the Photocatalytic Degradation of Rhodamine B

In order to improve the photocatalytic effect of Nb2O5, manganese from 1% to 10% was added by the polymeric precursor’s method. The samples obtained were subjected to different calcination temperatures from 400 to 700 °C. Characterization of the synthesized materials was performed by XRD, IR, Raman...

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Autores:
Raba, Angela
Falcony, Ciro
Supelano, Ivan
Rincón Joya, Miryam
Tipo de recurso:
Article of journal
Fecha de publicación:
2020
Institución:
Universidad Francisco de Paula Santander
Repositorio:
Repositorio Digital UFPS
Idioma:
eng
OAI Identifier:
oai:repositorio.ufps.edu.co:ufps/988
Acceso en línea:
http://repositorio.ufps.edu.co/handle/ufps/988
https://doi.org/10.3390/app10124257
Palabra clave:
Mn-doped Nb2O5
polymeric precursor
characterization
photocatalysis
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openAccess
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Atribución 4.0 Internacional (CC BY 4.0)
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oai_identifier_str oai:repositorio.ufps.edu.co:ufps/988
network_acronym_str RUFPS2
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repository_id_str
dc.title.eng.fl_str_mv Niobium Pentoxide Samples with Addition of Manganese at Different Concentrations and Calcination Temperatures Applied in the Photocatalytic Degradation of Rhodamine B
title Niobium Pentoxide Samples with Addition of Manganese at Different Concentrations and Calcination Temperatures Applied in the Photocatalytic Degradation of Rhodamine B
spellingShingle Niobium Pentoxide Samples with Addition of Manganese at Different Concentrations and Calcination Temperatures Applied in the Photocatalytic Degradation of Rhodamine B
Mn-doped Nb2O5
polymeric precursor
characterization
photocatalysis
title_short Niobium Pentoxide Samples with Addition of Manganese at Different Concentrations and Calcination Temperatures Applied in the Photocatalytic Degradation of Rhodamine B
title_full Niobium Pentoxide Samples with Addition of Manganese at Different Concentrations and Calcination Temperatures Applied in the Photocatalytic Degradation of Rhodamine B
title_fullStr Niobium Pentoxide Samples with Addition of Manganese at Different Concentrations and Calcination Temperatures Applied in the Photocatalytic Degradation of Rhodamine B
title_full_unstemmed Niobium Pentoxide Samples with Addition of Manganese at Different Concentrations and Calcination Temperatures Applied in the Photocatalytic Degradation of Rhodamine B
title_sort Niobium Pentoxide Samples with Addition of Manganese at Different Concentrations and Calcination Temperatures Applied in the Photocatalytic Degradation of Rhodamine B
dc.creator.fl_str_mv Raba, Angela
Falcony, Ciro
Supelano, Ivan
Rincón Joya, Miryam
dc.contributor.author.none.fl_str_mv Raba, Angela
Falcony, Ciro
Supelano, Ivan
Rincón Joya, Miryam
dc.subject.proposal.eng.fl_str_mv Mn-doped Nb2O5
polymeric precursor
characterization
photocatalysis
topic Mn-doped Nb2O5
polymeric precursor
characterization
photocatalysis
description In order to improve the photocatalytic effect of Nb2O5, manganese from 1% to 10% was added by the polymeric precursor’s method. The samples obtained were subjected to different calcination temperatures from 400 to 700 °C. Characterization of the synthesized materials was performed by XRD, IR, Raman and Diffuse Reflectance Spectroscopy (DRS) spectroscopy, FE-SEM, Brunauer–Emmett–Teller (BET) method, Photoluminescence (PL) and Dynamic Light Scattering (DLS). Photocatalytic performance for degradation of Rhodamine B was also evaluated. The Rietveld refined X-Ray Diffraction (XRD) pattern of Nb2O5:Mn 1.0 wt.% (700 °C) sample was similar to that of the un-doped oxide, therefore indicating that Nb was replaced by Mn and, consequently, there are not significant variations in the oxide structure. The Nb2O5:Mn 10.0 wt.% (700 °C) sample has the lowest band gap energy. The specific surface area (SBET) PL value increased as manganese concentration increased. The Nb2O5:Mn 5.0 wt.% (700 °C) sample has an Eg of 3.15 eV and morphological and surface characteristics that made it an appropriate photocatalyst in the Rhodamine B degradation. The novelty of this work relies on the use of a small quantity of Mn ions as dopants leading to Nb2O5:Mn nanostructured particles without using any surfactant or other additives
publishDate 2020
dc.date.issued.none.fl_str_mv 2020-06-21
dc.date.accessioned.none.fl_str_mv 2021-11-15T16:29:02Z
dc.date.available.none.fl_str_mv 2021-11-15T16:29:02Z
dc.type.spa.fl_str_mv Artículo de revista
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dc.identifier.uri.none.fl_str_mv http://repositorio.ufps.edu.co/handle/ufps/988
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url http://repositorio.ufps.edu.co/handle/ufps/988
https://doi.org/10.3390/app10124257
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.ispartof.none.fl_str_mv Applied Sciences
dc.relation.citationedition.spa.fl_str_mv Vol.10 No.12.(2020)
dc.relation.citationendpage.spa.fl_str_mv 14
dc.relation.citationissue.spa.fl_str_mv 12 (2020)
dc.relation.citationstartpage.spa.fl_str_mv 1
dc.relation.citationvolume.spa.fl_str_mv 10
dc.relation.cites.none.fl_str_mv Raba-Paéz, A. M., Falcony-Guajardo, C., Supelano-García, I., & Joya, M. R. (2020). Niobium pentoxide samples with addition of manganese at different concentrations and calcination temperatures applied in the photocatalytic degradation of rhodamine B. Applied Sciences, 10(12), 4257.
dc.relation.ispartofjournal.spa.fl_str_mv Applied Sciences
dc.rights.coar.fl_str_mv http://purl.org/coar/access_right/c_abf2
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dc.rights.creativecommons.spa.fl_str_mv Atribución 4.0 Internacional (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv Atribución 4.0 Internacional (CC BY 4.0)
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dc.format.mimetype.spa.fl_str_mv application/pdf
dc.publisher.spa.fl_str_mv Applied Sciences
dc.publisher.place.spa.fl_str_mv Berna , Suiza
dc.source.spa.fl_str_mv https://www.mdpi.com/2076-3417/10/12/4257
institution Universidad Francisco de Paula Santander
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spelling Raba, Angelab0f49e94494cfd0b31d200ab57002927600Falcony, Ciroda0e0c74afa25e52c0d727406e038753600Supelano, Ivan8044d61a84cdcd7e4fd6427036148d06600Rincón Joya, Miryamc0b8ca13fba2cb3b97bde3a3b5f95b0c6002021-11-15T16:29:02Z2021-11-15T16:29:02Z2020-06-21http://repositorio.ufps.edu.co/handle/ufps/988https://doi.org/10.3390/app10124257In order to improve the photocatalytic effect of Nb2O5, manganese from 1% to 10% was added by the polymeric precursor’s method. The samples obtained were subjected to different calcination temperatures from 400 to 700 °C. Characterization of the synthesized materials was performed by XRD, IR, Raman and Diffuse Reflectance Spectroscopy (DRS) spectroscopy, FE-SEM, Brunauer–Emmett–Teller (BET) method, Photoluminescence (PL) and Dynamic Light Scattering (DLS). Photocatalytic performance for degradation of Rhodamine B was also evaluated. The Rietveld refined X-Ray Diffraction (XRD) pattern of Nb2O5:Mn 1.0 wt.% (700 °C) sample was similar to that of the un-doped oxide, therefore indicating that Nb was replaced by Mn and, consequently, there are not significant variations in the oxide structure. The Nb2O5:Mn 10.0 wt.% (700 °C) sample has the lowest band gap energy. The specific surface area (SBET) PL value increased as manganese concentration increased. The Nb2O5:Mn 5.0 wt.% (700 °C) sample has an Eg of 3.15 eV and morphological and surface characteristics that made it an appropriate photocatalyst in the Rhodamine B degradation. The novelty of this work relies on the use of a small quantity of Mn ions as dopants leading to Nb2O5:Mn nanostructured particles without using any surfactant or other additivesapplication/pdfengApplied SciencesBerna , SuizaApplied SciencesVol.10 No.12.(2020)1412 (2020)110Raba-Paéz, A. M., Falcony-Guajardo, C., Supelano-García, I., & Joya, M. R. (2020). Niobium pentoxide samples with addition of manganese at different concentrations and calcination temperatures applied in the photocatalytic degradation of rhodamine B. Applied Sciences, 10(12), 4257.Applied Sciences2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).info:eu-repo/semantics/openAccessAtribución 4.0 Internacional (CC BY 4.0)http://purl.org/coar/access_right/c_abf2https://www.mdpi.com/2076-3417/10/12/4257Niobium Pentoxide Samples with Addition of Manganese at Different Concentrations and Calcination Temperatures Applied in the Photocatalytic Degradation of Rhodamine BArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Mn-doped Nb2O5polymeric precursorcharacterizationphotocatalysisAlexandre, P.; Lucas, B.; Carolina, P.; Aline, M.; Leonardo, C. Nb2O5 as Efficient and Recyclable Photocatalyst for Indigo Carmine Degradation. Appl. Catal. B 2008, 82, 219–224.Wonyong, C.; Andreas, T.; Michael, H.R. The role of metal ion dopants in quantum-sized TiO2: Correlation between photoreactivity and charge carrier recombination dynamics. J. Phys. Chem. 1994, 98, 13669–13679.Siddiki, M.K.; Venkatesan, S.; Qiao, Q. Nb2O5 as a new electron transport layer for double junction polymer solar cells. Phys. Chem. Chem. Phys. 2012, 14, 4682–4686. [CrossRef] [PubMed]Yoshimura, K.; Miki, T.; Iwama, S.; Tanemura, S. Characterization of niobium oxide electrochromic thin films prepared by reactive d.c. magnetron sputtering. Thin Solid Films 1996, 281, 235–238. [CrossRef]Fang, X.; Hu, L.; Huo, K.; Gao, B.; Zhao, L.; Liao, M.; Chu, P.K.; Bando, Y.; Golberg, D. New ultraviolet photodetector based on individual Nb2O5 nanobelts. Adv. Funct. Mater. 2011, 21, 3907–3915. [CrossRef]Jung, S.C.; Imaishi, N.; Park, H.C. Reaction engineering modeling of low-pressure metalorganic chemical vapor deposition of Nb2O5 thin film. Jpn. J. Appl. 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ACS Omega 2019, 4, 17477–17486. [CrossRef] [PubMed]. Raba, A.M.; Falcony, C.; Joya, M.R. Evaluación de la actividad fotocatalítica de nanoestructuras de T-Nb2O5 obtenidas por el método sol-gel. Respuestas 2016, 21, 80–91. [CrossRef]Rania, B.J.; Ravina, M.; Ravia, G.; Ravichandranb, S.; Ganeshc, V.; Yuvakkumar, R. Synthesis and characterization of hausmannite (Mn3O4 ) nanostructures. Surf. Interface 2018, 11, 28–36. [CrossRef]Masloboeva, S.M.; Sidorov, N.V.; Palatnikov, M.N.; Arutyunyan, L.G.; Chufyrev, P.G. Niobium(V) oxide doped with Mg2+ and Gd3+ cations: Synthesis and structural studies. Russ. J. Inorg. Chem. 2011, 56, 1194–1198. [CrossRef]Jehng, J.M.; Wachs, I.E. Structural chemistry and Raman spectra of niobium oxides. Chem. Mater. 1991, 3, 100–107. [CrossRef]Braynera, R.; Bozon-Verduraz, F. Niobium pentoxide prepared by soft chemical routes: Morphology, structure, defects and quantum size effect. Phys. Chem. Chem. Phys. 2003, 5, 1457–1466. [CrossRef]Ristic, M.; Popovic, S.; Music, S. Sol-gel synthesis and characterization of Nb2O5 powders. Mater. Lett. 2004, 58, 2658–2663. [CrossRef]Escobedo, A.; Sánchez, E.; Pal, U. Use of diffuse reflectance spectroscopy for optical characterization of un-supported nanostructures. Rev. Mex. Fis. 2007, 53, 18–22.Tauc, J. Absorption edge and internal electric fields in amorphous semiconductors. Mater. Res. Bull. 1970, 5, 721–729. [CrossRef]Raba, A.M.; Bautista-Ruíz, J.; Joya, M.R. Synthesis and structural properties of niobium pentoxide powders: A comparative study of the growth process. Mater. Res. 2016, 19, 1381. [CrossRef]Raba, A.; Barba-Ortega, J.; Joya, M.R. Effects of metal doping agent on the properties of Nb2−xMxO5 (M = Mn, Fe, and Ni) system. Int. J. Appl. Ceram. Technol. 2018, 15, 1577–1583. [CrossRef]Liqiang, J.; Yichun, Q.; Baiqi, W.; Shudan, L.; Baojiang, J.; Libin, Y.; Wei, F.; Honggang, F.; Jiazhong, S. 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 incorporada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.
