Determination of the efficiency of hafnium carbide and tantalum carbide coatings deposited on exchange membrane fuel cells

The energy efficiency of the hafnium carbide and tantalum carbide membranes (electrolyte) deposited through the PVD technique was determined from the systems simulation under operating conditions of parallel plates connected in series. Bipolar plates are used for two purposes: to conduct electrical...

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Autores:
Ruiz Madera, C
Bautista-Ruiz, Jorge
Aperador, W
Tipo de recurso:
Article of investigation
Fecha de publicación:
2021
Institución:
Universidad Francisco de Paula Santander
Repositorio:
Repositorio Digital UFPS
Idioma:
eng
OAI Identifier:
oai:repositorio.ufps.edu.co:ufps/6523
Acceso en línea:
https://repositorio.ufps.edu.co/handle/ufps/6523
Palabra clave:
Corrosion
Pitting
Leachates
Corrosion Rate
Membrane Fuel Cells
Rights
openAccess
License
© 2021, Rasayan Journal of Chemistry, c/o Dr. Pratima Sharma. All rights reserved.
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network_name_str Repositorio Digital UFPS
repository_id_str
dc.title.eng.fl_str_mv Determination of the efficiency of hafnium carbide and tantalum carbide coatings deposited on exchange membrane fuel cells
title Determination of the efficiency of hafnium carbide and tantalum carbide coatings deposited on exchange membrane fuel cells
spellingShingle Determination of the efficiency of hafnium carbide and tantalum carbide coatings deposited on exchange membrane fuel cells
Corrosion
Pitting
Leachates
Corrosion Rate
Membrane Fuel Cells
title_short Determination of the efficiency of hafnium carbide and tantalum carbide coatings deposited on exchange membrane fuel cells
title_full Determination of the efficiency of hafnium carbide and tantalum carbide coatings deposited on exchange membrane fuel cells
title_fullStr Determination of the efficiency of hafnium carbide and tantalum carbide coatings deposited on exchange membrane fuel cells
title_full_unstemmed Determination of the efficiency of hafnium carbide and tantalum carbide coatings deposited on exchange membrane fuel cells
title_sort Determination of the efficiency of hafnium carbide and tantalum carbide coatings deposited on exchange membrane fuel cells
dc.creator.fl_str_mv Ruiz Madera, C
Bautista-Ruiz, Jorge
Aperador, W
dc.contributor.author.none.fl_str_mv Ruiz Madera, C
Bautista-Ruiz, Jorge
Aperador, W
dc.subject.proposal.eng.fl_str_mv Corrosion
Pitting
Leachates
Corrosion Rate
Membrane Fuel Cells
topic Corrosion
Pitting
Leachates
Corrosion Rate
Membrane Fuel Cells
description The energy efficiency of the hafnium carbide and tantalum carbide membranes (electrolyte) deposited through the PVD technique was determined from the systems simulation under operating conditions of parallel plates connected in series. Bipolar plates are used for two purposes: to conduct electrical current between the cells, and the other is to distribute hydrogen and oxygen. Thus, bipolar plates are used for two functions: one is to conduct electrical current between the cells, and the other is to distribute hydrogen and oxygen. We have developed two bipolar plate patterns, which include serpentine patterns and the bio-inspired flow field pattern. The coatings (serpentine) characterization was carried out using surface characterization techniques such as atomic force microscopy and structural identification by X-ray diffraction, allowing the analysis of the coating structure to determine the efficiency of carbide-based cathodes for hydrogen production from electrochemical impedance spectroscopy.
publishDate 2021
dc.date.issued.none.fl_str_mv 2021-10
dc.date.accessioned.none.fl_str_mv 2022-11-17T20:20:18Z
dc.date.available.none.fl_str_mv 2022-11-17T20:20:18Z
dc.type.spa.fl_str_mv Artículo de Investigación
dc.type.coarversion.fl_str_mv http://purl.org/coar/version/c_970fb48d4fbd8a85
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dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/article
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dc.identifier.uri.none.fl_str_mv https://repositorio.ufps.edu.co/handle/ufps/6523
dc.identifier.doi.none.fl_str_mv 10.31788/RJC.2021.1446268
url https://repositorio.ufps.edu.co/handle/ufps/6523
identifier_str_mv 10.31788/RJC.2021.1446268
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.ispartof.none.fl_str_mv Rasayan Journal of Chemistry. Vol. 14 No. 4 (2021)
dc.relation.citationendpage.spa.fl_str_mv 2528
dc.relation.citationissue.spa.fl_str_mv 4 (2021)
dc.relation.citationstartpage.spa.fl_str_mv 2521
dc.relation.citationvolume.spa.fl_str_mv Vol. 14
dc.relation.ispartofjournal.spa.fl_str_mv Rasayan Journal of Chemistry
dc.rights.eng.fl_str_mv © 2021, Rasayan Journal of Chemistry, c/o Dr. Pratima Sharma. All rights reserved.
dc.rights.coar.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.rights.uri.spa.fl_str_mv https://creativecommons.org/licenses/by/4.0/
dc.rights.accessrights.spa.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.creativecommons.spa.fl_str_mv Atribución 4.0 Internacional (CC BY 4.0)
rights_invalid_str_mv © 2021, Rasayan Journal of Chemistry, c/o Dr. Pratima Sharma. All rights reserved.
https://creativecommons.org/licenses/by/4.0/
Atribución 4.0 Internacional (CC BY 4.0)
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.extent.spa.fl_str_mv 08 Páginas
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dc.publisher.spa.fl_str_mv Rasayan Journal of Chemistry
dc.publisher.place.spa.fl_str_mv India
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institution Universidad Francisco de Paula Santander
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spelling Ruiz Madera, Ce883e5b65f6c359eab0775c579a7e41cBautista-Ruiz, Jorged2ad76c1874f15a36c3360ca84fbcb66600Aperador, W0dc91374fc76008cfb64bececf7bb3db2022-11-17T20:20:18Z2022-11-17T20:20:18Z2021-10https://repositorio.ufps.edu.co/handle/ufps/652310.31788/RJC.2021.1446268The energy efficiency of the hafnium carbide and tantalum carbide membranes (electrolyte) deposited through the PVD technique was determined from the systems simulation under operating conditions of parallel plates connected in series. Bipolar plates are used for two purposes: to conduct electrical current between the cells, and the other is to distribute hydrogen and oxygen. Thus, bipolar plates are used for two functions: one is to conduct electrical current between the cells, and the other is to distribute hydrogen and oxygen. We have developed two bipolar plate patterns, which include serpentine patterns and the bio-inspired flow field pattern. The coatings (serpentine) characterization was carried out using surface characterization techniques such as atomic force microscopy and structural identification by X-ray diffraction, allowing the analysis of the coating structure to determine the efficiency of carbide-based cathodes for hydrogen production from electrochemical impedance spectroscopy.08 Páginasapplication/pdfengRasayan Journal of ChemistryIndiaRasayan Journal of Chemistry. Vol. 14 No. 4 (2021)25284 (2021)2521Vol. 14Rasayan Journal of Chemistry© 2021, Rasayan Journal of Chemistry, c/o Dr. Pratima Sharma. All rights reserved.https://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessAtribución 4.0 Internacional (CC BY 4.0)http://purl.org/coar/access_right/c_abf2https://www.scopus.com/record/display.uri?eid=2-s2.0-85121226821&doi=10.31788%2fRJC.2021.1446268&origin=inward&txGid=7111aeec7b6c15d538ed9301fc36fa06Determination of the efficiency of hafnium carbide and tantalum carbide coatings deposited on exchange membrane fuel cellsArtículo de Investigaciónhttp://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85CorrosionPittingLeachatesCorrosion RateMembrane Fuel CellsK. Ahmad, H.R. Ghatak and S.M. Ahuja, Environmental Technology & Innovation, 19, 100893(2020)A.G. Stern, International Journal of Hydrogen Energy, 40(32), 9885(2015)C.J. Winter, International Journal of Hydrogen Energy, 34(14), 1(2009)S. Jyothi, Y.V. Subba Rao and P.S. Samuel Ratnakumar, Rasayan Journal of Chemistry, 12(2), 537 (2019)J. Bautista-Ruiz, W. Aperador and J.J. Olaya, Rasayan Journal of Chemistry, 11(2), 597(2018)Y. Zhou, W. Wang, C. Zhang, D. Huang, C. Lai, M. Cheng, L. Qin, Y. Yang, C. Zhou, B. Li, H. Luo and D. He, Advances in Colloid and Interface Science, 279, 102144(2020)P. Valencia, L. Yate, W. Aperador, Y. Li, and E. Coy, The Journal of Physical Chemistry C, 122(44), 25433 (2018)T. Demirdelen, F. Ekinci, B.D. Mert, İ. Karasu and M. Tümay, International Journal of Hydrogen Energy, 45(18), 10680 (2020)R. Thilagavathi, A. Prithiba and R. Rajalakshmi, Rasayan Journal of Chemistry, 12(2), 431(2019)Z. Huang, J. Shen, S.H. Chan and Z. Tu, Energy Conversion and Management, 226, 113492(2020),H. Yuan, H. Dai, X. Wei and P. Ming, Journal of Power Sources, 468, 228376(2020)A. Ozden, M. Ercelik, D. Ouellette, C. Ozgur-Colpan, H. Ganjehsarabi and F. Hamdullahpur, International Journal of Hydrogen Energy, 42(33), 21546(2017)R. Roshandel, F. Arbabi, and G. Karimi Moghaddam, Renewable Energy, 41, 86(2012)M.Z. Chowdhury and B. Timurkutluk, Energy, 161, 104(2018)J. Zhang, Y. Zhang, Y. Fu, T. Li, and J. Meng, Vacuum, 169, 108886(2019)G. Feng, H. Li, X. Yao, D. Hu, L. Yang, B. Li and J. Lu, Surface and Coatings Technology, 400, 126219(2020)C.G. Lee, Journal of Electroanalytical Chemistry, 810, 48(2018)S. Chen, W. Xiong, Z. Yao, G. Zhang, X. Chen, B. Huang, and Q. Yang, International Journal of Refractory Metals and Hard Materials, 47, 139(2014)M. Hosseini, H.H. Afrouzi, H. Arasteh, and D. Toghraie, Energy, 188, 116090(2019)J. P. Kloess, X. Wang, J. Liu, Z. Shi, and L. Guessous, Jounal of Power Sources, 188(1), 132(2009)ORIGINALDetermination of the efficiency of hafnium carbide and tantalum carbide coatings deposited on exchange membrane fuel cells(Article)(Open Access).pdfDetermination of the efficiency of hafnium carbide and tantalum carbide coatings deposited on exchange membrane fuel cells(Article)(Open Access).pdfapplication/pdf2069389https://repositorio.ufps.edu.co/bitstream/ufps/6523/1/Determination%20of%20the%20efficiency%20of%20hafnium%20carbide%20and%20tantalum%20carbide%20coatings%20deposited%20on%20exchange%20membrane%20fuel%20cells%28Article%29%28Open%20Access%29.pdf5d316304d740ec0dc5aa1009200e8622MD51open accessLICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.ufps.edu.co/bitstream/ufps/6523/2/license.txt2f9959eaf5b71fae44bbf9ec84150c7aMD52open accessTEXTDetermination of the efficiency of hafnium carbide and tantalum carbide coatings deposited on exchange membrane fuel cells(Article)(Open 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 incorporada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.
0000-0003-3430-2173d2ad76c1874f15a36c3360ca84fbcb66600