Clay surface characteristics using atomic force microscopy

The first component for the manufacture of masonry products used in construction is clay, which provides the plasticity that facilitates the molding and handling of the product. The second component is the feldspar in form of alumina (Al2O3) which is used as flux. The third one is silica (SiO2) whic...

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Autores:
Acevedo Peñaloza, Carlos Humberto
Florez, Eder
García León, Ricardo Andres
Tipo de recurso:
Article of journal
Fecha de publicación:
2018
Institución:
Universidad Francisco de Paula Santander
Repositorio:
Repositorio Digital UFPS
Idioma:
eng
OAI Identifier:
oai:repositorio.ufps.edu.co:ufps/605
Acceso en línea:
http://repositorio.ufps.edu.co/handle/ufps/605
https://doi.org/10.17533/udea.redin.n87a04
Palabra clave:
Clays
masonry
FRX
DRX
AFM
mampostería
Arcillas
Rights
openAccess
License
Atribución-NoComercial-CompartirIgual 4.0 Internacional (CC BY-NC-SA 4.0)
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dc.title.eng.fl_str_mv Clay surface characteristics using atomic force microscopy
dc.title.spa.fl_str_mv Características superficiales de la arcilla utilizando microscopía de fuerza atómica
title Clay surface characteristics using atomic force microscopy
spellingShingle Clay surface characteristics using atomic force microscopy
Clays
masonry
FRX
DRX
AFM
mampostería
Arcillas
title_short Clay surface characteristics using atomic force microscopy
title_full Clay surface characteristics using atomic force microscopy
title_fullStr Clay surface characteristics using atomic force microscopy
title_full_unstemmed Clay surface characteristics using atomic force microscopy
title_sort Clay surface characteristics using atomic force microscopy
dc.creator.fl_str_mv Acevedo Peñaloza, Carlos Humberto
Florez, Eder
García León, Ricardo Andres
dc.contributor.author.none.fl_str_mv Acevedo Peñaloza, Carlos Humberto
Florez, Eder
García León, Ricardo Andres
dc.subject.proposal.eng.fl_str_mv Clays
masonry
FRX
DRX
AFM
mampostería
topic Clays
masonry
FRX
DRX
AFM
mampostería
Arcillas
dc.subject.proposal.spa.fl_str_mv Arcillas
description The first component for the manufacture of masonry products used in construction is clay, which provides the plasticity that facilitates the molding and handling of the product. The second component is the feldspar in form of alumina (Al2O3) which is used as flux. The third one is silica (SiO2) which is used as a filling material and stabilizer. These elements are determined by chemical composition using fluorescence analysis or X-ray diffraction, which is the basis of the modern classification of minerals. Thereby, the main objective of this research is to study the surface characteristics of clay samples from an industrial company producing H-10 blocks in the region of Norte de Santander, by studying the surfaces of the samples selected through the analysis by Atomic Force Microscopy, in order to compare the results with those found in the literature, and at the same time taking into account the chemical elements in their highest composition. The results show that this is a technique that allows the identification of clay components, thus validating what has been found in physical and chemical analysis, expecting to provide a scientific contribution by AFM, because there is little information related to the characterization topography of clay materials.
publishDate 2018
dc.date.issued.none.fl_str_mv 2018-06-07
dc.date.accessioned.none.fl_str_mv 2021-11-02T19:35:44Z
dc.date.available.none.fl_str_mv 2021-11-02T19:35:44Z
dc.type.spa.fl_str_mv Artículo de revista
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dc.language.iso.spa.fl_str_mv eng
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dc.relation.ispartof.none.fl_str_mv Revista Facultad de Ingeniería Universidad de Antioquia
dc.relation.citationedition.spa.fl_str_mv No.87.(2018)
dc.relation.citationendpage.spa.fl_str_mv 34
dc.relation.citationissue.spa.fl_str_mv 87(2018)
dc.relation.citationstartpage.spa.fl_str_mv 23
dc.relation.cites.none.fl_str_mv García-León, R. A., Flórez-Solano, E. N., & Acevedo-Peñaloza, C. H. (2018). Clay surface characteristics using atomic force microscopy. Revista Facultad de Ingeniería Universidad de Antioquia, (87), 23-34.
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dc.format.extent.spa.fl_str_mv 12 páginas
dc.format.mimetype.spa.fl_str_mv application/pdf
dc.publisher.spa.fl_str_mv Revista Facultad de Ingeniería Universidad de Antioquia
dc.publisher.place.spa.fl_str_mv Colombia
dc.source.spa.fl_str_mv https://revistas.udea.edu.co/index.php/ingenieria/article/view/327987
institution Universidad Francisco de Paula Santander
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spelling Acevedo Peñaloza, Carlos Humberto1f12a99f8d5bcc67d1eb10c7c07c76a3600Florez, Ederab89489b9ee8e021693a0cc109902957600García León, Ricardo Andres1af15301da2a405546d832e5088df96f6002021-11-02T19:35:44Z2021-11-02T19:35:44Z2018-06-07http://repositorio.ufps.edu.co/handle/ufps/605https://doi.org/10.17533/udea.redin.n87a04The first component for the manufacture of masonry products used in construction is clay, which provides the plasticity that facilitates the molding and handling of the product. The second component is the feldspar in form of alumina (Al2O3) which is used as flux. The third one is silica (SiO2) which is used as a filling material and stabilizer. These elements are determined by chemical composition using fluorescence analysis or X-ray diffraction, which is the basis of the modern classification of minerals. Thereby, the main objective of this research is to study the surface characteristics of clay samples from an industrial company producing H-10 blocks in the region of Norte de Santander, by studying the surfaces of the samples selected through the analysis by Atomic Force Microscopy, in order to compare the results with those found in the literature, and at the same time taking into account the chemical elements in their highest composition. The results show that this is a technique that allows the identification of clay components, thus validating what has been found in physical and chemical analysis, expecting to provide a scientific contribution by AFM, because there is little information related to the characterization topography of clay materials.El primer componente para la fabricación de productos de mampostería para la construcción es la arcilla, la cual aporta la plasticidad que facilita el moldeo y el manejo del producto. El segundo componente es el feldespato en su formación como alúmina (Al2O3) que se utiliza como fundente. La tercera es la sílice (SiO2) que se utiliza como un material de relleno y estabilizador. Estos elementos se determinan mediante la composición química por análisis de fluorescencia o difracción de rayos X, la cual es la base de la clasificación moderna de los minerales. De esta manera, el principal objetivo de este trabajo es estudiar las características superficiales de muestras de arcilla de una empresa dedicada a producción de bloques H-10 en la región Norte Santandereana, mediante el estudio de las superficies de las muestras seleccionadas a través de la técnica de Microscopía de Fuerza Atómica con el propósito de comparar los resultados con los obtenidos en la bibliografía teniendo en cuenta los elementos químicos en su mayor composición. Los resultados demuestran que ésta es una técnica que permite identificar los componentes de la arcilla validando de esta manera lo encontrado en los análisis físicos y químicos, con lo cual se espera brindar un aporte científico por AFM o MFA, debido a que existe poca información relacionada en la caracterización topográfica de materiales arcillosos.12 páginasapplication/pdfengRevista Facultad de Ingeniería Universidad de AntioquiaColombiaRevista Facultad de Ingeniería Universidad de AntioquiaNo.87.(2018)3487(2018)23García-León, R. A., Flórez-Solano, E. N., & Acevedo-Peñaloza, C. H. (2018). Clay surface characteristics using atomic force microscopy. Revista Facultad de Ingeniería Universidad de Antioquia, (87), 23-34.Revista Facultad de Ingeniería Universidad de AntioquiaThis is an open-access article distributed under the terms of the Creative Commons Attribution Licenseinfo:eu-repo/semantics/openAccessAtribución-NoComercial-CompartirIgual 4.0 Internacional (CC BY-NC-SA 4.0)http://purl.org/coar/access_right/c_abf2https://revistas.udea.edu.co/index.php/ingenieria/article/view/327987Clay surface characteristics using atomic force microscopyCaracterísticas superficiales de la arcilla utilizando microscopía de fuerza atómicaArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85ClaysmasonryFRXDRXAFMmamposteríaArcillasO. Sahin, S. Magonov, C. Su, C. F. Quate, and O. Solgaard, “An atomic force microscope tip designed to measure time-varying nanomechanical forces,” Nature Nanotechnology , vol. 2, no. 8, pp. 507–514, Jul. 2007.E. A. López and S. D. Solares, “El microscopio de fuerza atómica: métodos y aplicaciones,” Revista de la Universidad del Valle Guatemala , vol. 28, no. 1, pp. 14–28, 2014.(2012) Atomic force microscopy. University of Rochester. Accessed Apr. 24, 2017. [Online]. Available: www.optics.rochester.edu/workgroups/cml/opt307/spr12/nilotpal/ HTMLfiles/AFM.htmV. Ivanov, J. Chu, V. Stabnikov, and B. Li, “Estrengthening of soft marine clay using bioencapsulation,” Journal Marine Georesources & Geotechnology , vol. 33, no. 4, pp. 320–324, Jan. 2015.S. Pineda, Z. J. Han, and K. Ostrikov, “Plasma-enabled carbon nanostructures for early diagnosis of neurodegenerative diseases,” Materials , vol. 7, no. 7, pp. 4896–4929, Jun. 2014.L. Vázquez. Afm (atomic force microscope). [Online]. Available: www.icmm.csic.es/fis/espa/afm.htmlN. 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Antioquia , no. 80, pp. 31–37, Jul. 2016.ORIGINALClay surface characteristics using atomic force microscopy.pdfClay surface characteristics using atomic force microscopy.pdfapplication/pdf2547385https://repositorio.ufps.edu.co/bitstream/ufps/605/1/Clay%20surface%20characteristics%20using%20atomic%20force%20microscopy.pdf2523af83270e60fe00316e699c5ee97bMD51open accessLICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.ufps.edu.co/bitstream/ufps/605/2/license.txt2f9959eaf5b71fae44bbf9ec84150c7aMD52open accessTEXTClay surface characteristics using atomic force microscopy.pdf.txtClay surface characteristics using atomic force microscopy.pdf.txtExtracted texttext/plain34405https://repositorio.ufps.edu.co/bitstream/ufps/605/3/Clay%20surface%20characteristics%20using%20atomic%20force%20microscopy.pdf.txte5bec126438f7fc1b354998dd3b5d1f3MD53open accessTHUMBNAILClay surface characteristics using atomic force microscopy.pdf.jpgClay surface characteristics using atomic 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 incorporada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.
0000-0002-5049-87541f12a99f8d5bcc67d1eb10c7c07c76a36000000-0003-2527-0413ab89489b9ee8e021693a0cc109902957600

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