Effect of the addition of rice husk in technological properties of materials for the manufacture of ceramic
In this study, the rice husk discarded by the agro-industrial rice company in the department of Norte de Santander (Colombia) was used to replace clay material in the manufacture of tile-type ceramics. The materials were used to make test specimens with the presence of 5%, 10%, 15%, and 20% (weight)...
- Autores:
-
Bautista-Ruiz, Jorge
Sanchez Molina, Jorge
Sánchez Zúñiga, Jessica Viviana
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2021
- Institución:
- Universidad Francisco de Paula Santander
- Repositorio:
- Repositorio Digital UFPS
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.ufps.edu.co:ufps/6390
- Acceso en línea:
- http://repositorio.ufps.edu.co/handle/ufps/6390
http://dx.doi.org/10.31788/ RJC.2021.1425900
- Palabra clave:
- Rice Husk
Circular Economy
Ceramics
Clay Material
Physical-ceramic Properties
- Rights
- openAccess
- License
- © Copyright 2020 RJC. All rights reserved.
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dc.title.eng.fl_str_mv |
Effect of the addition of rice husk in technological properties of materials for the manufacture of ceramic |
title |
Effect of the addition of rice husk in technological properties of materials for the manufacture of ceramic |
spellingShingle |
Effect of the addition of rice husk in technological properties of materials for the manufacture of ceramic Rice Husk Circular Economy Ceramics Clay Material Physical-ceramic Properties |
title_short |
Effect of the addition of rice husk in technological properties of materials for the manufacture of ceramic |
title_full |
Effect of the addition of rice husk in technological properties of materials for the manufacture of ceramic |
title_fullStr |
Effect of the addition of rice husk in technological properties of materials for the manufacture of ceramic |
title_full_unstemmed |
Effect of the addition of rice husk in technological properties of materials for the manufacture of ceramic |
title_sort |
Effect of the addition of rice husk in technological properties of materials for the manufacture of ceramic |
dc.creator.fl_str_mv |
Bautista-Ruiz, Jorge Sanchez Molina, Jorge Sánchez Zúñiga, Jessica Viviana |
dc.contributor.author.none.fl_str_mv |
Bautista-Ruiz, Jorge Sanchez Molina, Jorge Sánchez Zúñiga, Jessica Viviana |
dc.subject.proposal.eng.fl_str_mv |
Rice Husk Circular Economy Ceramics Clay Material Physical-ceramic Properties |
topic |
Rice Husk Circular Economy Ceramics Clay Material Physical-ceramic Properties |
description |
In this study, the rice husk discarded by the agro-industrial rice company in the department of Norte de Santander (Colombia) was used to replace clay material in the manufacture of tile-type ceramics. The materials were used to make test specimens with the presence of 5%, 10%, 15%, and 20% (weight) of scale and with three different types of grain size (1180 µm, 180 µm, and 75 µm mesh through). The specimens were molded using the extrusion technique. The shaped materials were subjected to different firing temperatures (900 °C, 1000 °C, 1100 °C, 1150 °C, and 1200 °C) to establish correlations between the microstructure/topography of the material and some of the technological properties of the ceramic such as the mechanical resistance to bending, resistance to deep abrasion, percentage of water absorption and linear drying/cooking shrinkage. The results show that proportions higher than 10% of rice husk do not obtain ceramics with ideal technological properties for use as pavement or coating. The best results were obtained when the husk was used at 5% and 180 µm mesh through grain size. The X-ray diffraction analysis of the cooked samples shows significant changes in the proportion of phases formed (test tubes with and without substitution of clay material) as the temperature increases. |
publishDate |
2021 |
dc.date.accessioned.none.fl_str_mv |
2021-12-15T16:44:22Z |
dc.date.available.none.fl_str_mv |
2021-12-15T16:44:22Z |
dc.date.issued.none.fl_str_mv |
2021-06 |
dc.type.spa.fl_str_mv |
Artículo de revista |
dc.type.coar.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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http://purl.org/coar/resource_type/c_6501 |
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Text |
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http://purl.org/redcol/resource_type/ART |
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info:eu-repo/semantics/publishedVersion |
format |
http://purl.org/coar/resource_type/c_6501 |
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publishedVersion |
dc.identifier.uri.none.fl_str_mv |
http://repositorio.ufps.edu.co/handle/ufps/6390 |
dc.identifier.doi.none.fl_str_mv |
http://dx.doi.org/10.31788/ RJC.2021.1425900 |
url |
http://repositorio.ufps.edu.co/handle/ufps/6390 http://dx.doi.org/10.31788/ RJC.2021.1425900 |
dc.language.iso.spa.fl_str_mv |
eng |
language |
eng |
dc.relation.ispartof.none.fl_str_mv |
Rasayan Journal of Chemistry |
dc.relation.citationedition.spa.fl_str_mv |
Vol.14 No.2.(2021) |
dc.relation.citationendpage.spa.fl_str_mv |
718 |
dc.relation.citationissue.spa.fl_str_mv |
2(2021) |
dc.relation.citationstartpage.spa.fl_str_mv |
712 |
dc.relation.citationvolume.spa.fl_str_mv |
14 |
dc.relation.cites.none.fl_str_mv |
Bautista-Ruiz, J., Sánchez-Molina, J., & Sánchez-Zúñiga, J. V. (2021). EFFECT OF THE ADDITION OF RICE HUSK IN TECHNOLOGICAL PROPERTIES OF MATERIALS FOR THE MANUFACTURE OF CERAMIC. RASAYAN JOURNAL OF CHEMISTRY, 14(2), 712-718. |
dc.relation.ispartofjournal.spa.fl_str_mv |
Rasayan Journal of Chemistry |
dc.rights.eng.fl_str_mv |
© Copyright 2020 RJC. All rights reserved. |
dc.rights.coar.fl_str_mv |
http://purl.org/coar/access_right/c_abf2 |
dc.rights.accessrights.spa.fl_str_mv |
info:eu-repo/semantics/openAccess |
dc.rights.creativecommons.spa.fl_str_mv |
Atribución 4.0 Internacional (CC BY 4.0) |
rights_invalid_str_mv |
© Copyright 2020 RJC. All rights reserved. Atribución 4.0 Internacional (CC BY 4.0) http://purl.org/coar/access_right/c_abf2 |
eu_rights_str_mv |
openAccess |
dc.format.extent.spa.fl_str_mv |
07 páginas |
dc.format.mimetype.spa.fl_str_mv |
application/pdf |
dc.publisher.spa.fl_str_mv |
Rasayan Journal of Chemistry |
dc.publisher.place.spa.fl_str_mv |
India |
dc.source.spa.fl_str_mv |
http://rasayanjournal.co.in/archiveissue.php?issueid=59 |
institution |
Universidad Francisco de Paula Santander |
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Bautista-Ruiz, Jorged2ad76c1874f15a36c3360ca84fbcb66600Sanchez Molina, Jorge7763542bd7973b0f1a7a8a305d08b0ab600Sánchez Zúñiga, Jessica Vivianacb4c4903655922a20ed2867fa63e5a736002021-12-15T16:44:22Z2021-12-15T16:44:22Z2021-06http://repositorio.ufps.edu.co/handle/ufps/6390http://dx.doi.org/10.31788/ RJC.2021.1425900In this study, the rice husk discarded by the agro-industrial rice company in the department of Norte de Santander (Colombia) was used to replace clay material in the manufacture of tile-type ceramics. The materials were used to make test specimens with the presence of 5%, 10%, 15%, and 20% (weight) of scale and with three different types of grain size (1180 µm, 180 µm, and 75 µm mesh through). The specimens were molded using the extrusion technique. The shaped materials were subjected to different firing temperatures (900 °C, 1000 °C, 1100 °C, 1150 °C, and 1200 °C) to establish correlations between the microstructure/topography of the material and some of the technological properties of the ceramic such as the mechanical resistance to bending, resistance to deep abrasion, percentage of water absorption and linear drying/cooking shrinkage. The results show that proportions higher than 10% of rice husk do not obtain ceramics with ideal technological properties for use as pavement or coating. The best results were obtained when the husk was used at 5% and 180 µm mesh through grain size. The X-ray diffraction analysis of the cooked samples shows significant changes in the proportion of phases formed (test tubes with and without substitution of clay material) as the temperature increases.07 páginasapplication/pdfengRasayan Journal of ChemistryIndiaRasayan Journal of ChemistryVol.14 No.2.(2021)7182(2021)71214Bautista-Ruiz, J., Sánchez-Molina, J., & Sánchez-Zúñiga, J. V. (2021). EFFECT OF THE ADDITION OF RICE HUSK IN TECHNOLOGICAL PROPERTIES OF MATERIALS FOR THE MANUFACTURE OF CERAMIC. RASAYAN JOURNAL OF CHEMISTRY, 14(2), 712-718.Rasayan Journal of Chemistry© Copyright 2020 RJC. All rights reserved.info:eu-repo/semantics/openAccessAtribución 4.0 Internacional (CC BY 4.0)http://purl.org/coar/access_right/c_abf2http://rasayanjournal.co.in/archiveissue.php?issueid=59Effect of the addition of rice husk in technological properties of materials for the manufacture of ceramicArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Rice HuskCircular EconomyCeramicsClay MaterialPhysical-ceramic PropertiesM.I. Almeida, A.C. Dias, M. Demertzi, and L. Arroja, Journal of Cleaner Production, 131, 583 (2016), DOI:10.1016/j.jclepro.2016.04.131S. Prakash Chandar, K. Gunasekaran, K. Prasanth, and G. Senthil-Kumar. Rasayan Journal of Chemistry, 11(2), 702 (2018), DOI:10.31788/RJC.2018.1123003M. Vidya Vijay, J.S. Sudarsan, and S. Nithiyanantham, Rasayan Journal of Chemistry, 10(3), 1056(2017), DOI:10.7324/RJC.2017.1031738J. Sharma, and B. Janveja, Rasayan Journal of Chemistry, 1(4), 936(2008).L. Zhang, Construction and Building Materials, 47, 643(2013), DOI:10.1016/j.conbuildmat.2013.05.043N.V. Boltakova, G.R. Faseeva, R.R. Kabirov, R.M. Nafikov, and Y.A. Zakharov, Waste Management, 60, 230(2017), DOI:10.1016/j.wasman.2016.11.008D. Eliche, C. Martínez, M.L. Martínez, M.T. Cotes, L. Pérez, N. Cruz, and F.A. Corpas, Applied Clay Science, 52, 270(2011), DOI:10.1016/j.clay.2011.03.003J Sánches-Molina, D.C. Alvarez-Rozo, J.F. Gelves-Díaz. Revista Respuestas, 23(1), 27(2018), DOI:10.22463/0122820X.1326A. Souza, S.R. Teixeira, G.T. A. Santos, F.B. Costa, and E. Longo, Journal of Environmental Management, 92(10), 277(2011), DOI:10.1016/j.jenvman.2011.06.020E.G. García, and L. Lizárraga, Revista Académica de la Facultad de Ingeniería Universidad Autónoma de Yucatán, 19(2), 91(2015).D. Chen, A. Gao, Z. Ma, D. Fei, Y. Chang, and C. Shen, Bioresource Technology, 253, 148(2018), DOI:10.1016/j.biortech.2018.01.009P.W. Olupot, A. Candia, E. Menya, and R. Walozi, Chemical Engineering Research and Design, 107, 63(2016), DOI:10.1016/j.cherd.2015.11.010A. Guzmán, J. Torres, M. Cedeño, S. Delvasto, V. Amigó, and E. Sánchez, Boletín de la Sociedad Española de Cerámica y Vidrio, 52(6), 283(2013), DOI:10.3989/cyv.352013G. Görhan, and O. Şimşek, Construction and Building Materials, 40, 390(2013), DOI:10.1016/j.conbuildmat.2012.09.110S. Janbuala, and T. Wasanapiarnpong, Key Engineering Materials, 659, 74(2015), DOI:10.4028/www.scientific.net/kem.659.74K.Y. Chiang, P.H. Chou, C.R. Hua, K.L. Chien, and C. Cheeseman, Journal of Hazardous Materials, 171, 76(2009), DOI:10.1016/j.jhazmat.2009.05.144G. Peña-Rodríguez, J. Sánchez-Molina, and R. Monroy. Revista Colombiana de Física, 40(2), 285(2008).G.S. De Silva, and M.L.C. 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Huynh, Construction and Building Materials, 93, 335(2015), DOI:10.1016/j.conbuildmat.2015.04.061ORIGINALEffect of the addition of rice husk in technological properties of materials for the manufacture of ceramic.pdfEffect of the addition of rice husk in technological properties of materials for the manufacture of ceramic.pdfapplication/pdf1564342https://repositorio.ufps.edu.co/bitstream/ufps/6390/1/Effect%20of%20the%20addition%20of%20rice%20husk%20in%20technological%20properties%20of%20materials%20for%20the%20manufacture%20of%20ceramic.pdfa6f182479c4b7dbda7dac6d6c2c83f11MD51open accessLICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.ufps.edu.co/bitstream/ufps/6390/2/license.txt2f9959eaf5b71fae44bbf9ec84150c7aMD52open accessTEXTEffect of the addition of rice husk in technological properties of materials for the manufacture of ceramic.pdf.txtEffect of the addition of rice husk in technological properties of materials for the manufacture of 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 incorporada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.
0000-0003-3430-2173d2ad76c1874f15a36c3360ca84fbcb666000000-0002-9080-85267763542bd7973b0f1a7a8a305d08b0ab6000000-0001-7831-127Xcb4c4903655922a20ed2867fa63e5a73600 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