Phosphine-free Suzuki cross-coupling reaction using an efficient and reusable Pd catalyst in an aqueous medium under microwave irradia
We report here an improved, highly efficient, and general method for the ligand-free Suzuki cross-coupling reaction to the synthesis of biaryls, bipyridyls, thienylpyridine, and allylphenols. Microwave irradiation of (het)aryl halides and (hetaryl, allyl)arylboronic acid N-methyl-iminodiacetic acid...
- Autores:
-
Da Silva, Joaquim F. M.
De Almeida, Natália P.
Yepes Pérez, Andres Felipe
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2015
- Institución:
- Universidad de Santander
- Repositorio:
- Repositorio Universidad de Santander
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.udes.edu.co:001/3503
- Acceso en línea:
- https://repositorio.udes.edu.co/handle/001/3503
- Palabra clave:
- Microwave irradiation
Pd EnCat30
Phosphine-free reactions
Organoboronic acid MIDA ester
Suzuki coupling
- Rights
- openAccess
- License
- Derechos Reservados - Taylor & Francis, 2015
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Da Silva, Joaquim F. M.bd7e64a6-2111-445b-a7da-320f6dccb18f-1De Almeida, Natália P.e394fe3b-0b77-4e0b-aada-7fec06623573-1Yepes Pérez, Andres Felipe5028f8f9-6318-46ca-829b-d8dd790d248f-12019-08-01T15:00:58Z2019-08-01T15:00:58Z2015-06-17We report here an improved, highly efficient, and general method for the ligand-free Suzuki cross-coupling reaction to the synthesis of biaryls, bipyridyls, thienylpyridine, and allylphenols. Microwave irradiation of (het)aryl halides and (hetaryl, allyl)arylboronic acid N-methyl-iminodiacetic acid (MIDA) ester, using polyurea microencapsulated palladium catalyst (Pd EnCat 30), gave the coupling adducts 1a–x in excellent yields in just 10–18 min.application/pdf10.1080/00397911.2015.10572891532-24320039-7911https://repositorio.udes.edu.co/handle/001/3503engSynthetic CommunicationsDerechos Reservados - Taylor & Francis, 2015info:eu-repo/semantics/openAccessAtribución-NoComercial 4.0 Internacional (CC BY-NC 4.0)https://creativecommons.org/licenses/by-nc/4.0/http://purl.org/coar/access_right/c_abf2https://www.tandfonline.com/doi/abs/10.1080/00397911.2015.1057289?journalCode=lsyc20Microwave irradiationPd EnCat30Phosphine-free reactionsOrganoboronic acid MIDA esterSuzuki couplingPhosphine-free Suzuki cross-coupling reaction using an efficient and reusable Pd catalyst in an aqueous medium under microwave irradiaArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85PublicationTEXTPhosphine-free Suzuki cross-coupling reaction using an efficient and reusable Pd catalyst in an aqueous medium under microwave irradia.pdf.txtPhosphine-free Suzuki cross-coupling reaction using an efficient and reusable Pd catalyst in an aqueous medium under microwave irradia.pdf.txtExtracted texttext/plain2https://repositorio.udes.edu.co/bitstreams/3684fa97-88b3-4b56-9ba0-02558911cca4/downloadd784fa8b6d98d27699781bd9a7cf19f0MD54THUMBNAILPhosphine-free Suzuki cross-coupling reaction using an efficient and reusable Pd catalyst in an aqueous medium under microwave irradia.pdf.jpgPhosphine-free Suzuki cross-coupling reaction using an efficient and reusable Pd catalyst in an aqueous medium under microwave irradia.pdf.jpgGenerated Thumbnailimage/jpeg1878https://repositorio.udes.edu.co/bitstreams/24e4a777-369f-4071-a24c-b781814c5b4a/download49ce21481f30587eb3d5aa373bb7c8f3MD55ORIGINALPhosphine-free Suzuki cross-coupling reaction using an efficient and reusable Pd catalyst in an aqueous medium under microwave irradia.pdfPhosphine-free Suzuki cross-coupling reaction using an efficient and reusable Pd catalyst in an aqueous medium under microwave irradia.pdfapplication/pdf244092https://repositorio.udes.edu.co/bitstreams/62cf344d-0b1e-4f22-be86-569574f38657/download85ffd94038538ced3e1626707af31f2cMD53LICENSElicense.txtlicense.txttext/plain; charset=utf-859https://repositorio.udes.edu.co/bitstreams/ad7ed8c0-b9d8-4ca5-aaa6-c1bff92b7fcb/download38d94cf55aa1bf2dac1a736ac45c881cMD52001/3503oai:repositorio.udes.edu.co:001/35032023-10-11 10:25:39.648https://creativecommons.org/licenses/by-nc/4.0/Derechos Reservados - Taylor & Francis, 2015https://repositorio.udes.edu.coRepositorio Universidad de Santandersoporte@metabiblioteca.comTGljZW5jaWEgZGUgUHVibGljYWNpw7NuIFVERVMKRGlyZWN0cmljZXMgZGUgVVNPIHkgQUNDRVNPCgo= |
| dc.title.eng.fl_str_mv |
Phosphine-free Suzuki cross-coupling reaction using an efficient and reusable Pd catalyst in an aqueous medium under microwave irradia |
| title |
Phosphine-free Suzuki cross-coupling reaction using an efficient and reusable Pd catalyst in an aqueous medium under microwave irradia |
| spellingShingle |
Phosphine-free Suzuki cross-coupling reaction using an efficient and reusable Pd catalyst in an aqueous medium under microwave irradia Microwave irradiation Pd EnCat30 Phosphine-free reactions Organoboronic acid MIDA ester Suzuki coupling |
| title_short |
Phosphine-free Suzuki cross-coupling reaction using an efficient and reusable Pd catalyst in an aqueous medium under microwave irradia |
| title_full |
Phosphine-free Suzuki cross-coupling reaction using an efficient and reusable Pd catalyst in an aqueous medium under microwave irradia |
| title_fullStr |
Phosphine-free Suzuki cross-coupling reaction using an efficient and reusable Pd catalyst in an aqueous medium under microwave irradia |
| title_full_unstemmed |
Phosphine-free Suzuki cross-coupling reaction using an efficient and reusable Pd catalyst in an aqueous medium under microwave irradia |
| title_sort |
Phosphine-free Suzuki cross-coupling reaction using an efficient and reusable Pd catalyst in an aqueous medium under microwave irradia |
| dc.creator.fl_str_mv |
Da Silva, Joaquim F. M. De Almeida, Natália P. Yepes Pérez, Andres Felipe |
| dc.contributor.author.spa.fl_str_mv |
Da Silva, Joaquim F. M. De Almeida, Natália P. Yepes Pérez, Andres Felipe |
| dc.subject.proposal.eng.fl_str_mv |
Microwave irradiation Pd EnCat30 Phosphine-free reactions Organoboronic acid MIDA ester Suzuki coupling |
| topic |
Microwave irradiation Pd EnCat30 Phosphine-free reactions Organoboronic acid MIDA ester Suzuki coupling |
| description |
We report here an improved, highly efficient, and general method for the ligand-free Suzuki cross-coupling reaction to the synthesis of biaryls, bipyridyls, thienylpyridine, and allylphenols. Microwave irradiation of (het)aryl halides and (hetaryl, allyl)arylboronic acid N-methyl-iminodiacetic acid (MIDA) ester, using polyurea microencapsulated palladium catalyst (Pd EnCat 30), gave the coupling adducts 1a–x in excellent yields in just 10–18 min. |
| publishDate |
2015 |
| dc.date.issued.spa.fl_str_mv |
2015-06-17 |
| dc.date.accessioned.spa.fl_str_mv |
2019-08-01T15:00:58Z |
| dc.date.available.spa.fl_str_mv |
2019-08-01T15:00:58Z |
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Artículo de revista |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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http://purl.org/coar/resource_type/c_6501 |
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Text |
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info:eu-repo/semantics/article |
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http://purl.org/redcol/resource_type/ART |
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info:eu-repo/semantics/publishedVersion |
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http://purl.org/coar/resource_type/c_6501 |
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publishedVersion |
| dc.identifier.doi.spa.fl_str_mv |
10.1080/00397911.2015.1057289 |
| dc.identifier.issn.spa.fl_str_mv |
1532-2432 0039-7911 |
| dc.identifier.uri.spa.fl_str_mv |
https://repositorio.udes.edu.co/handle/001/3503 |
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10.1080/00397911.2015.1057289 1532-2432 0039-7911 |
| url |
https://repositorio.udes.edu.co/handle/001/3503 |
| dc.language.iso.spa.fl_str_mv |
eng |
| language |
eng |
| dc.relation.ispartof.eng.fl_str_mv |
Synthetic Communications |
| dc.rights.spa.fl_str_mv |
Derechos Reservados - Taylor & Francis, 2015 |
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http://purl.org/coar/access_right/c_abf2 |
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info:eu-repo/semantics/openAccess |
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Atribución-NoComercial 4.0 Internacional (CC BY-NC 4.0) |
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https://creativecommons.org/licenses/by-nc/4.0/ |
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Derechos Reservados - Taylor & Francis, 2015 Atribución-NoComercial 4.0 Internacional (CC BY-NC 4.0) https://creativecommons.org/licenses/by-nc/4.0/ http://purl.org/coar/access_right/c_abf2 |
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openAccess |
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application/pdf |
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