Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2
Digital
- Autores:
-
Martinez-Quiñonez, Henry
Amaya, Alvaro A.
Paez-Mozo, Edgar A.
Martinez-Ortega, Fernando
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2022
- Institución:
- Universidad de Santander
- Repositorio:
- Repositorio Universidad de Santander
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.udes.edu.co:001/7330
- Acceso en línea:
- https://doi.org/10.1007/s11244-022-01656-9
https://repositorio.udes.edu.co/handle/001/7330
- Palabra clave:
- Aminothiazole ligand
Dioxo-molybdenum complexes
TiO2 nanotubes
Selective oxidation
- Rights
- closedAccess
- License
- © The Authors, Springer Nature Switzerland AG. Part of Springer Nature, 2022
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Martinez-Quiñonez, Henry4ebf4ed3-5e90-469a-9236-99c15b30e26d-1Amaya, Alvaro A.f252d1ce-f107-4a82-862e-3fc0f92a851b-1Paez-Mozo, Edgar A.b13d6c01-0bdf-417c-81fb-7f932fb08aae-1Martinez-Ortega, Fernandod3e30ec8-251c-43ec-8d39-1fd067a33595-1Ciencias UDES2022-08-03T14:59:26Z2022-08-03T14:59:26Z2022-06-27DigitalSelective Oxygen Atom Transfer to α-pinene, β-pinene, (R)-limonene and camphene by dioxo-Mo(VI)Ln complex {Ln = 2-aminothiazole-4-carboxylic acid} anchored on TiO2 nanotubes (TiO2-NT) using O2 as oxidant and UV light was studied at ambient conditions. The Catalytic system was characterized by FTIR, 1H NMR and 13C, and elemental analysis. Molecular oxygen reoxidizes the (Mo(IV)=O) reduced unit in the darkness, forming an oxo-peroxo-Mo intermediate. The catalyst under UV radiation transfers two oxygen atoms to the olefin. The α-pinene is found to be the most reactive monoterpene.Ciencias Médicas y de la Saludapplication/pdfhttps://doi.org/10.1007/s11244-022-01656-91022-55281572-9028https://repositorio.udes.edu.co/handle/001/7330engSuizaMartinez Quiñonez, H., Amaya, Á., Paez-Mozo, E.A. et al. Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2. Top Catal (2022). https://doi.org/10.1007/s11244-022-01656-9ScopusSpringer LinkTopics in Catalysis© The Authors, Springer Nature Switzerland AG. Part of Springer Nature, 2022info:eu-repo/semantics/closedAccessAtribución-NoComercial 4.0 Internacional (CC BY-NC 4.0)https://creativecommons.org/licenses/by-nc/4.0/http://purl.org/coar/access_right/c_14cbhttps://link.springer.com/article/10.1007/s11244-022-01656-9Aminothiazole ligandDioxo-molybdenum complexesTiO2 nanotubesSelective oxidationAminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2Artículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Todas las AudienciasPublicationORIGINALAminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2.pdfAminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2.pdfapplication/pdf214770https://repositorio.udes.edu.co/bitstreams/4d4648fc-9a04-4a1f-a1d3-6032501a314d/downloadf870a03a196d25f7f3c8ff64780bd422MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-859https://repositorio.udes.edu.co/bitstreams/419d94b4-de6c-4caa-a16f-7472de9a11d8/download38d94cf55aa1bf2dac1a736ac45c881cMD52TEXTAminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2.pdf.txtAminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2.pdf.txtExtracted texttext/plain5https://repositorio.udes.edu.co/bitstreams/bebc508f-f40e-48d6-8a79-dabe56a5bb74/download5dbe86c1111d64f45ba435df98fdc825MD53THUMBNAILAminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2.pdf.jpgAminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2.pdf.jpgGenerated Thumbnailimage/jpeg9743https://repositorio.udes.edu.co/bitstreams/dc8ca3cd-6bcd-4699-b399-f44d858b9c51/downloadfee09e5a63413a81d9b8f5b079cabadfMD54001/7330oai:repositorio.udes.edu.co:001/73302023-10-10 17:10:14.643https://creativecommons.org/licenses/by-nc/4.0/© The Authors, Springer Nature Switzerland AG. Part of Springer Nature, 2022https://repositorio.udes.edu.coRepositorio Universidad de Santandersoporte@metabiblioteca.comTGljZW5jaWEgZGUgUHVibGljYWNpw7NuIFVERVMKRGlyZWN0cmljZXMgZGUgVVNPIHkgQUNDRVNPCgo= |
| dc.title.spa.fl_str_mv |
Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2 |
| title |
Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2 |
| spellingShingle |
Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2 Aminothiazole ligand Dioxo-molybdenum complexes TiO2 nanotubes Selective oxidation |
| title_short |
Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2 |
| title_full |
Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2 |
| title_fullStr |
Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2 |
| title_full_unstemmed |
Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2 |
| title_sort |
Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2 |
| dc.creator.fl_str_mv |
Martinez-Quiñonez, Henry Amaya, Alvaro A. Paez-Mozo, Edgar A. Martinez-Ortega, Fernando |
| dc.contributor.author.none.fl_str_mv |
Martinez-Quiñonez, Henry Amaya, Alvaro A. Paez-Mozo, Edgar A. Martinez-Ortega, Fernando |
| dc.contributor.researchgroup.spa.fl_str_mv |
Ciencias UDES |
| dc.subject.proposal.eng.fl_str_mv |
Aminothiazole ligand Dioxo-molybdenum complexes TiO2 nanotubes Selective oxidation |
| topic |
Aminothiazole ligand Dioxo-molybdenum complexes TiO2 nanotubes Selective oxidation |
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Digital |
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2022 |
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2022-08-03T14:59:26Z |
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2022-08-03T14:59:26Z |
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2022-06-27 |
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https://doi.org/10.1007/s11244-022-01656-9 |
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1022-5528 |
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Martinez Quiñonez, H., Amaya, Á., Paez-Mozo, E.A. et al. Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2. Top Catal (2022). https://doi.org/10.1007/s11244-022-01656-9 |
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Scopus |
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Topics in Catalysis |
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© The Authors, Springer Nature Switzerland AG. Part of Springer Nature, 2022 |
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Atribución-NoComercial 4.0 Internacional (CC BY-NC 4.0) |
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© The Authors, Springer Nature Switzerland AG. Part of Springer Nature, 2022 Atribución-NoComercial 4.0 Internacional (CC BY-NC 4.0) https://creativecommons.org/licenses/by-nc/4.0/ http://purl.org/coar/access_right/c_14cb |
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