Anticorrosive evaluation of Sio2-Tio2-Zro2 ceramic trilayers synthesized by the Sol-Gel method

The conformation of trilayers of ceramic coatings of the SiO2-TiO2-ZrO2 system is shown, synthesized by the Sol-gel method, using Si (OC2H5) 4, Ti (OBu) 4 and Zr (OC3H7) 4 as precursors, as EtOH and water, and as a complexing agent 2,4 pentanedione. The ceramic coatings were deposited on AISI / SAE...

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Autores:
Tipo de recurso:
Fecha de publicación:
2009
Institución:
Universidad Pedagógica y Tecnológica de Colombia
Repositorio:
RiUPTC: Repositorio Institucional UPTC
Idioma:
spa
OAI Identifier:
oai:repositorio.uptc.edu.co:001/13980
Acceso en línea:
https://revistas.uptc.edu.co/index.php/ingenieria/article/view/1339
https://repositorio.uptc.edu.co/handle/001/13980
Palabra clave:
corrosion
sol-gel
electrochemical techniques
corrosion
sol-gel
técnicas elecroquimicas
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Copyright (c) 2007 Jorge Hernando Bautista Ruiz, César Armando Ortiz Otálora
Description
Summary:The conformation of trilayers of ceramic coatings of the SiO2-TiO2-ZrO2 system is shown, synthesized by the Sol-gel method, using Si (OC2H5) 4, Ti (OBu) 4 and Zr (OC3H7) 4 as precursors, as EtOH and water, and as a complexing agent 2,4 pentanedione. The ceramic coatings were deposited on AISI / SAE 304 stainless steel substrates using the dip-coating technique. The influence of the coatings on the anticorrosive behavior of the substrate in a 3% HCl solution was studied using Electrochemical Impedance Spectroscopy (EIS) techniques and potentiodynamic polarization curves. Additionally, a morphological study was performed using the Atomic Force Microscopy (AFM) technique. The values of the electrochemical parameters were found to change substantially with the concentration of the precursors added to the effects of the film on the substrate.