Exploration of chemical activation using Mg and Ca chlorides for obtaining biochars from soursop seeds (Annona muricata).

Autores:: Camargo López, Jhoan Miguel
Esteves, Laura M.
Brijaldo, Maria H

Tipo de recurso:: Article of journal

Fecha de publicación:: 2025

Institución:: Universidad Pedagógica y Tecnológica de Colombia

Repositorio:: RiUPTC: Repositorio Institucional UPTC

Idioma:

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dc.title.es-ES.fl_str_mv	Exploration of chemical activation using Mg and Ca chlorides for obtaining biochars from soursop seeds (Annona muricata).
title	Exploration of chemical activation using Mg and Ca chlorides for obtaining biochars from soursop seeds (Annona muricata).
spellingShingle	Exploration of chemical activation using Mg and Ca chlorides for obtaining biochars from soursop seeds (Annona muricata). environmental crisis, biomass, biochars, chemical activation, environmental remediation.
title_short	Exploration of chemical activation using Mg and Ca chlorides for obtaining biochars from soursop seeds (Annona muricata).
title_full	Exploration of chemical activation using Mg and Ca chlorides for obtaining biochars from soursop seeds (Annona muricata).
title_fullStr	Exploration of chemical activation using Mg and Ca chlorides for obtaining biochars from soursop seeds (Annona muricata).
title_full_unstemmed	Exploration of chemical activation using Mg and Ca chlorides for obtaining biochars from soursop seeds (Annona muricata).
title_sort	Exploration of chemical activation using Mg and Ca chlorides for obtaining biochars from soursop seeds (Annona muricata).
dc.creator.fl_str_mv	Camargo López, Jhoan Miguel Esteves, Laura M. Brijaldo, Maria H
dc.contributor.author.spa.fl_str_mv	Camargo López, Jhoan Miguel Esteves, Laura M. Brijaldo, Maria H
dc.subject.none.fl_str_mv	environmental crisis, biomass, biochars, chemical activation, environmental remediation.
topic	environmental crisis, biomass, biochars, chemical activation, environmental remediation.
publishDate	2025
dc.date.accessioned.none.fl_str_mv	2025-01-20 00:00:00 2026-04-16T17:12:42Z
dc.date.available.none.fl_str_mv	2025-01-20 00:00:00
dc.date.issued.none.fl_str_mv	2025-01-20
dc.type.spa.fl_str_mv	Artículo de revista
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dc.relation.references.none.fl_str_mv	M. A. Yahya, Z. Al-Qodah, and C. W. Z. Ngah, “Agricultural bio-waste materials as potential sustainable precursors used for activated carbon production: A review,” Renew. Sustain. Energy Rev., vol. 46, pp. 218–235, 2015, doi: 10.1016/j.rser.2015.02.051. M. do C. Rangel, F. M. Mayer, M. da S. Carvalho, G. Saboia, and A. M. de Andrade, “Selecting Catalysts for Pyrolysis of Lignocellulosic Biomass,” Biomass, vol. 3, no. 1, pp. 31–63, 2023, doi: 10.3390/biomass3010003. D. P. Vargas, L. Giraldo, and J. C. Moreno-Piraján, “CO2 adsorption on activated carbon honeycomb-monoliths: A comparison of Langmuir and Tóth models,” Int. J. Mol. Sci., vol. 13, no. 7, pp. 8388–8397, 2012, doi: 10.3390/ijms13078388. Y. Shi, Sajjadi, Baharak Chen, Wei Yin Egiebor, Nosa O., “Synergistic effect of floatable hydroxyapatite-modified biochar adsorption and low-level CaCl2 leaching on Cd removal from paddy soil,” Sci. Total Environ., vol. 807, p. 150872, 2022, doi: https://doi.org/10.1016/j.scitotenv.2021.150872. S. Acevedo, L. Giraldo, and J. C. Moreno, “Caracterização textural e química de carvões ativados prearados a partir de casca da palmeira africana (Elaeis guineensis) por ativação química com CaCl2 y MgCl2,” Rev. Colomb. Quim., vol. 44, no. 3, pp. 18–24, Sep. 2015, doi: 10.15446/rev.colomb.quim.v44n3.55606. B. B. Vera Raza, R. A. Mero Intriago, G. A. Burgos Briones, and R. E. Cevallos Cedeño, “Lignocellulosic waste and activated carbon production method,” Minerva, vol. 1, no. Special, pp. 122–130, 2022, doi: 10.47460/minerva.v1ispecial.87. N. Kiggundu and J. Sittamukyoto, “Pryloysis of Coffee Husks for Biochar Production,” J. Environ. Prot. (Irvine,. Calif)., vol. 10, no. 12, pp. 1553–1564, 2019, doi: 10.4236/jep.2019.1012092. J. E. Vargas, L. G. Gutierrez, and J. C. Moreno-Piraján, “Preparation of activated carbons from seeds of Mucuna mutisiana by physical activation with steam,” J. Anal. Appl. Pyrolysis, vol. 89, no. 2, pp. 307–312, 2010, doi: 10.1016/j.jaap.2010.09.009. L. A. Alonso-Gómez, D. D. Celis-Carmona, Y. F. Rodríguez-Sánchez, J. R. Castro-Ladino, and J. C. Solarte-Toro, “Biochar production from cassava waste biomass: A techno-economic development approach in the Colombian context,” Bioresour. Technol. Reports, vol. 26, p. 101872, 2024, doi: https://doi.org/10.1016/j.biteb.2024.101872. M. Lay, A. Rusli, M. Khalil, Z. Ain, A. Hamid, and R. Khimi, “Converting dead leaf biomass into activated carbon as a potential replacement for carbon black filler in rubber composites,” Compos. Part B, vol. 201, no. August, p. 108366, 2020, doi: 10.1016/j.compositesb.2020.108366. W. J. Liu, H. Jiang, K. Tian, Y. W. Ding, and H. Q. Yu, “Mesoporous carbon stabilized MgO nanoparticles synthesized by pyrolysis of MgCl2 preloaded waste biomass for highly efficient CO2 capture,” Environ. Sci. Technol., vol. 47, no. 16, pp. 9397–9403, Aug. 2013, doi: 10.1021/es401286p. L. Sanabria, C. Lederhos, M. Quiroga, and J. Cubillos, “Pt and Pd on activated carbon for oxidation of Pt y Pd soportado en carbón activado para la oxidación de,” vol. 43, no. 2, pp. 37–43, 2017. https://doi.org/10.25100/iyc.v19i2.5291 S. Alberto and A. Corredor, “Preparación y caracterización de carbón activado granular obtenido a partir de cuesco de palma africana (Elaeis Guineensis) para la adsorción de CO2,” Doctoral disertation, UNAL Co. Bogotá D.C. 2014. L. M. Esteves, M. H. Brijaldo, and F. B. Passos, “Decomposition of acetic acid for hydrogen production over Pd/Al2O3 and Pd/TiO2: Influence of metal precursor,” J. Mol. Catal. A Chem., vol. 422, pp. 275–288, 2016, doi: 10.1016/j.molcata.2016.02.001. C. Castañeda, F. Tzompantzi, R. Gómez, and H. Rojas, “Enhanced photocatalytic degradation of 4-chlorophenol and 2,4-dichlorophenol on in situ phosphated sol-gel TiO2,” J. Chem. Technol. Biotechnol., vol. 91, no. 8, pp. 2170–2178, 2016, doi: 10.1002/jctb.4943. M. H. Brijaldo, S. Mancipe, H. A. Rojas, P. L. Viviana, D. G. Araiza, and G. Díaz, “Effect of boron on the surface properties of nickel supported on hydrotalcite-type mixed oxides in methanol decomposition,” vol. 498, no. October, 2020, doi: 10.1016/j.mcat.2020.111262. L. Giraldo and J. C. Moreno, “Adsorción de CO2 en carbón activado con diferente grado de activación,” Afinidad, vol. 67, no. 548, 2010. URL: https://www.raco.cat/index.php/afinidad/article/view/269277 H. A. Rojas, J. J. Martínez, M. H. Brijaldo, and F. Passos, “Producción de alcohol cinamílico a partir de la hidrogenación selectiva de cinamaldehído usando catalizadores de oro soportados en óxidos metálicos,” Rev. la Acad. Colomb. Ciencias Exactas, Físicas y Nat., vol. 43, no. 168, pp. 539–549, 2019, doi: 10.18257/raccefyn.852. P. Schroeder, B. P. do Nascimento, G. A. Romeiro, M. K. K. Figueiredo, and M. C. da C. Veloso, “Chemical and physical analysis of the liquid fractions from soursop seed cake obtained using slow pyrolysis conditions,” J. Anal. Appl. Pyrolysis, vol. 124, pp. 161–174, 2017, doi: 10.1016/j.jaap.2017.02.010. J. M. C. López, J. J. Martínez, M. H. Brijaldo, and S. Acevedo, “CO2 adsorption in biochars obtained from soursop (Anonna muricata) seeds by chemical activation with metallic salts,” Adsorption, no. 0123456789, 2024, doi: 10.1007/s10450-024-00528-w. V. Palermo, Palermo, Valeria, Camargo López, Jhoan M., Brijaldo, María H., Acevedo, Sergio, Mancipe, Sonia, Castillo, Juan Carlos, Rojas, Hugo A., Passos, Fabio B., Romanelli, Gustavo P., Martínez, José J., “Biochar-MgO from Soursop Seeds in the Production of Biofuel Additive Intermediates,” Chempluschem, vol. 88, no. 11, 2023, doi: 10.1002/cplu.202300401. S. Acevedo, L. Giraldo, and J. C. Moreno-Piraján, “Kinetic study of CO2 adsorption of granular-type activated carbons prepared from palm shells,” Environ. Sci. Pollut. Res., pp. 1–10, 2023, doi: 10.1007/s11356-023-26423-5. B. Petrovic, M. Gorbounov, and S. Masoudi Soltani, “Influence of surface modification on selective CO2 adsorption: A technical review on mechanisms and methods,” Microporous Mesoporous Mater., vol. 312, no. October 2020, p. 110751, 2021, doi: 10.1016/j.micromeso.2020.110751. J. I. Mora, “Extraction of cellulose and preparation of nanocellulose from sisal fibers,” pp. 149–159, 2008, doi: 10.1007/s10570-007-9145-9. E. Yagmur, Y. Gokce, S. Tekin, N. I. Semerci, and Z. Aktas, “Characteristics and comparison of activated carbons prepared from oleaster (Elaeagnus angustifolia L.) fruit using KOH and ZnCl2,” Fuel, vol. 267, no. September 2019, p. 117232, 2020, doi: 10.1016/j.fuel.2020.117232. D. P. Vargas, L. Giraldo, and J. C. Moreno-Piraján, “Accessible area and hydrophobicity of activated carbons obtained from the enthalpy characterization,” Adsorption, vol. 22, no. 1, pp. 3–11, Jan. 2016, doi: 10.1007/s10450-015-9721-5. R. Azargohar and A. K. Dalai, “Steam and KOH activation of biochar: Experimental and modeling studies,” Microporous Mesoporous Mater., vol. 110, no. 2, pp. 413–421, 2008, doi: https://doi.org/10.1016/j.micromeso.2007.06.047. A. S. Ello, L. K. C. De Souza, A. Trokourey, and M. Jaroniec, “Development of microporous carbons for CO2 capture by KOH activation of African palm shells,” J. CO2 Util., vol. 2, pp. 35–38, 2013, doi: 10.1016/j.jcou.2013.07.003. L. Proaño, E. Tello, M. A. Arellano-trevino, S. Wang, R. J. Farrauto, and M. Cobo, “Applied Surface Science In-situ DRIFTS study of two-step CO2 capture and catalytic methanation over,” Appl. Surf. Sci., vol. 479, no. October 2018, pp. 25–30, 2019, doi: 10.1016/j.apsusc.2019.01.281. A. Mukhtar, N. Mellon, S. Saqib, S. P. Lee, and M. A. Bustam, “Extension of BET theory to CO2 adsorption isotherms for ultra-microporosity of covalent organic polymers,” SN Appl. Sci., vol. 2, no. 7, pp. 1–4, 2020, doi: 10.1007/s42452-020-2968-9. A. Selvarajoo, D. Muhammad, and S. K. Arumugasamy, “An experimental and modelling approach to produce biochar from banana peels through pyrolysis as potential renewable energy resources,” Model. Earth Syst. Environ., vol. 6, no. 1, pp. 115–128, 2020, doi: 10.1007/s40808-019-00663-2. K. Yang, J. Peng, C. Srinivasakannan, L. Zhang, H. Xia, and X. Duan, “Preparation of high surface area activated carbon from coconut shells using microwave heating,” Bioresour. Technol., vol. 101, no. 15, pp. 6163–6169, 2010, doi: https://doi.org/10.1016/j.biortech.2010.03.001. A. C. Lua, “A comparative study of the pore characteristics and phenol adsorption performance of activated carbons prepared from oil-palm shell wastes by steam and combined steam-chemical activation,” Green Chem. Eng., no. September, 2023, doi: 10.1016/j.gce.2022.11.004. B. Flores, C. Chacón, and B. Galia, “El desarrollo sostenible y la agenda 21 Sustainable Development, Agenda 21,” Agenda, vol. 11, no. 2, pp. 164–181, 2009. URL: https://www.redalyc.org/articulo.oa?id=99312517003 F. Rodríguez-Reinoso and J. Silvestre-Albero, Nanoporous Materials for Gas Storage. 2019. DOI: https://doi.org/10.1007/978-981-13-3504-4_8 B. Sajjadi, W. Y. Chen, and N. O. Egiebor, “A comprehensive review on physical activation of biochar for energy and environmental applications,” Rev. Chem. Eng., vol. 35, no. 6, pp. 735–776, 2019, doi: 10.1515/revce-2017-0113.
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spelling	Camargo López, Jhoan MiguelEsteves, Laura M.Brijaldo, Maria H2025-01-20 00:00:002026-04-16T17:12:42Z2025-01-20 00:00:002025-01-200121-7488https://repositorio.uptc.edu.co/handle/001/1876310.19053/uptc.01217488.v16.n1.2025.169292462-7658https://doi.org/10.19053/uptc.01217488.v16.n1.2025.16929application/pdfUniversidad Pedagógica y Tecnológica de Colombiahttps://creativecommons.org/licenses/by-nc-nd/4.0/deed.esinfo:eu-repo/semantics/openAccessEsta obra está bajo una licencia internacional Creative Commons Atribución-NoComercial-SinDerivadas 4.0.http://purl.org/coar/access_right/c_abf2https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/16929environmental crisis, biomass, biochars, chemical activation, environmental remediation.Exploration of chemical activation using Mg and Ca chlorides for obtaining biochars from soursop seeds (Annona muricata).Artículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1info:eu-repo/semantics/articleJournal articleinfo:eu-repo/semantics/publishedVersionTexthttp://purl.org/coar/version/c_970fb48d4fbd8a85M. A. Yahya, Z. Al-Qodah, and C. W. Z. Ngah, “Agricultural bio-waste materials as potential sustainable precursors used for activated carbon production: A review,” Renew. Sustain. Energy Rev., vol. 46, pp. 218–235, 2015, doi: 10.1016/j.rser.2015.02.051.M. do C. Rangel, F. M. Mayer, M. da S. Carvalho, G. Saboia, and A. M. de Andrade, “Selecting Catalysts for Pyrolysis of Lignocellulosic Biomass,” Biomass, vol. 3, no. 1, pp. 31–63, 2023, doi: 10.3390/biomass3010003.D. P. Vargas, L. Giraldo, and J. C. Moreno-Piraján, “CO2 adsorption on activated carbon honeycomb-monoliths: A comparison of Langmuir and Tóth models,” Int. J. Mol. Sci., vol. 13, no. 7, pp. 8388–8397, 2012, doi: 10.3390/ijms13078388.Y. Shi, Sajjadi, Baharak Chen, Wei Yin Egiebor, Nosa O., “Synergistic effect of floatable hydroxyapatite-modified biochar adsorption and low-level CaCl2 leaching on Cd removal from paddy soil,” Sci. Total Environ., vol. 807, p. 150872, 2022, doi: https://doi.org/10.1016/j.scitotenv.2021.150872.S. Acevedo, L. Giraldo, and J. C. Moreno, “Caracterização textural e química de carvões ativados prearados a partir de casca da palmeira africana (Elaeis guineensis) por ativação química com CaCl2 y MgCl2,” Rev. Colomb. Quim., vol. 44, no. 3, pp. 18–24, Sep. 2015, doi: 10.15446/rev.colomb.quim.v44n3.55606.B. B. Vera Raza, R. A. Mero Intriago, G. A. Burgos Briones, and R. E. Cevallos Cedeño, “Lignocellulosic waste and activated carbon production method,” Minerva, vol. 1, no. Special, pp. 122–130, 2022, doi: 10.47460/minerva.v1ispecial.87.N. Kiggundu and J. Sittamukyoto, “Pryloysis of Coffee Husks for Biochar Production,” J. Environ. Prot. (Irvine,. Calif)., vol. 10, no. 12, pp. 1553–1564, 2019, doi: 10.4236/jep.2019.1012092.J. E. Vargas, L. G. Gutierrez, and J. C. Moreno-Piraján, “Preparation of activated carbons from seeds of Mucuna mutisiana by physical activation with steam,” J. Anal. Appl. Pyrolysis, vol. 89, no. 2, pp. 307–312, 2010, doi: 10.1016/j.jaap.2010.09.009.L. A. Alonso-Gómez, D. D. Celis-Carmona, Y. F. Rodríguez-Sánchez, J. R. Castro-Ladino, and J. C. Solarte-Toro, “Biochar production from cassava waste biomass: A techno-economic development approach in the Colombian context,” Bioresour. Technol. Reports, vol. 26, p. 101872, 2024, doi: https://doi.org/10.1016/j.biteb.2024.101872.M. Lay, A. Rusli, M. Khalil, Z. Ain, A. Hamid, and R. Khimi, “Converting dead leaf biomass into activated carbon as a potential replacement for carbon black filler in rubber composites,” Compos. Part B, vol. 201, no. August, p. 108366, 2020, doi: 10.1016/j.compositesb.2020.108366.W. J. Liu, H. Jiang, K. Tian, Y. W. Ding, and H. Q. Yu, “Mesoporous carbon stabilized MgO nanoparticles synthesized by pyrolysis of MgCl2 preloaded waste biomass for highly efficient CO2 capture,” Environ. Sci. Technol., vol. 47, no. 16, pp. 9397–9403, Aug. 2013, doi: 10.1021/es401286p.L. Sanabria, C. Lederhos, M. Quiroga, and J. Cubillos, “Pt and Pd on activated carbon for oxidation of Pt y Pd soportado en carbón activado para la oxidación de,” vol. 43, no. 2, pp. 37–43, 2017. https://doi.org/10.25100/iyc.v19i2.5291S. Alberto and A. Corredor, “Preparación y caracterización de carbón activado granular obtenido a partir de cuesco de palma africana (Elaeis Guineensis) para la adsorción de CO2,” Doctoral disertation, UNAL Co. Bogotá D.C. 2014.L. M. Esteves, M. H. Brijaldo, and F. B. Passos, “Decomposition of acetic acid for hydrogen production over Pd/Al2O3 and Pd/TiO2: Influence of metal precursor,” J. Mol. Catal. A Chem., vol. 422, pp. 275–288, 2016, doi: 10.1016/j.molcata.2016.02.001.C. Castañeda, F. Tzompantzi, R. Gómez, and H. Rojas, “Enhanced photocatalytic degradation of 4-chlorophenol and 2,4-dichlorophenol on in situ phosphated sol-gel TiO2,” J. Chem. Technol. Biotechnol., vol. 91, no. 8, pp. 2170–2178, 2016, doi: 10.1002/jctb.4943.M. H. Brijaldo, S. Mancipe, H. A. Rojas, P. L. Viviana, D. G. Araiza, and G. Díaz, “Effect of boron on the surface properties of nickel supported on hydrotalcite-type mixed oxides in methanol decomposition,” vol. 498, no. October, 2020, doi: 10.1016/j.mcat.2020.111262.L. Giraldo and J. C. Moreno, “Adsorción de CO2 en carbón activado con diferente grado de activación,” Afinidad, vol. 67, no. 548, 2010. URL: https://www.raco.cat/index.php/afinidad/article/view/269277H. A. Rojas, J. J. Martínez, M. H. Brijaldo, and F. Passos, “Producción de alcohol cinamílico a partir de la hidrogenación selectiva de cinamaldehído usando catalizadores de oro soportados en óxidos metálicos,” Rev. la Acad. Colomb. Ciencias Exactas, Físicas y Nat., vol. 43, no. 168, pp. 539–549, 2019, doi: 10.18257/raccefyn.852.P. Schroeder, B. P. do Nascimento, G. A. Romeiro, M. K. K. Figueiredo, and M. C. da C. Veloso, “Chemical and physical analysis of the liquid fractions from soursop seed cake obtained using slow pyrolysis conditions,” J. Anal. Appl. Pyrolysis, vol. 124, pp. 161–174, 2017, doi: 10.1016/j.jaap.2017.02.010.J. M. C. López, J. J. Martínez, M. H. Brijaldo, and S. Acevedo, “CO2 adsorption in biochars obtained from soursop (Anonna muricata) seeds by chemical activation with metallic salts,” Adsorption, no. 0123456789, 2024, doi: 10.1007/s10450-024-00528-w.V. Palermo, Palermo, Valeria, Camargo López, Jhoan M., Brijaldo, María H., Acevedo, Sergio, Mancipe, Sonia, Castillo, Juan Carlos, Rojas, Hugo A., Passos, Fabio B., Romanelli, Gustavo P., Martínez, José J., “Biochar-MgO from Soursop Seeds in the Production of Biofuel Additive Intermediates,” Chempluschem, vol. 88, no. 11, 2023, doi: 10.1002/cplu.202300401.S. Acevedo, L. Giraldo, and J. C. Moreno-Piraján, “Kinetic study of CO2 adsorption of granular-type activated carbons prepared from palm shells,” Environ. Sci. Pollut. Res., pp. 1–10, 2023, doi: 10.1007/s11356-023-26423-5.B. Petrovic, M. Gorbounov, and S. 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Exploration of chemical activation using Mg and Ca chlorides for obtaining biochars from soursop seeds (Annona muricata).

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