Glycerol oxidation by fluorinated and platinized Titania
In this work, fluorinated and platinized TiO2 was evaluated in the glycerol oxidation. Fluorination led to increase the specific surface area of titania, and platinization treatment led to obtain the highest absorption in the visible region of the electromagnetic spectrum; thus, 0.5 wt.% Pt-F-TiO2 w...
- Autores:
- Tipo de recurso:
- Fecha de publicación:
- 2021
- Institución:
- Universidad Pedagógica y Tecnológica de Colombia
- Repositorio:
- RiUPTC: Repositorio Institucional UPTC
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.uptc.edu.co:001/15306
- Acceso en línea:
- https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/12417
https://repositorio.uptc.edu.co/handle/001/15306
- Palabra clave:
- Glycerol; 0.5wt.% Pt-F-TiO2; 2wt.% Pt-F-TiO2; Glyceraldehyde; Dihydroxyacetone.
Glicerol
0.5wt.% Pt-F-TiO2
2wt.% Pt-F-TiO2
Glyceraldehyde
Dihydroxyacetone.
- Rights
- License
- Derechos de autor 2021 CIENCIA EN DESARROLLO
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2021-01-082024-07-08T14:24:02Z2024-07-08T14:24:02Zhttps://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/1241710.19053/01217488.v12.n1.2021.12417https://repositorio.uptc.edu.co/handle/001/15306In this work, fluorinated and platinized TiO2 was evaluated in the glycerol oxidation. Fluorination led to increase the specific surface area of titania, and platinization treatment led to obtain the highest absorption in the visible region of the electromagnetic spectrum; thus, 0.5 wt.% Pt-F-TiO2 was the best catalyst in the obtention of highest yield and selectivity to glyceraldehyde (GAL). It was also found that 2wt.% of Pt content had a detrimental effect in the glycerol conversion. Fluorination and platinum addition led to modify the reaction mechanism and selectivity.En el presente trabajo se evaluó TiO2 fluorizado y platinizado en la oxidación del glicerol. La fluorización permitió incrementar el área superficial de la titania y la platinización llevó a obtener una mayor absorción en la región visible del espectro electromagnético; así, 0.5 wt.% Pt-F-TiO2 fue el mejor catalizador en la obtención del mayor rendimiento y selectividad hacia gliceraldehído (GAL). También se encontró que un contenido de 2% de Pt tiene un efecto negativo sobre la conversión de glicerol. La fluorización y la adición de platino llevaron a modificar el mecanismo de reacción y la selectividad.application/pdfspaspaUniversidad Pedagógica y Tecnológica de Colombiahttps://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/12417/10684Derechos de autor 2021 CIENCIA EN DESARROLLOhttp://purl.org/coar/access_right/c_abf2Ciencia En Desarrollo; Vol. 12 No. 1 (2021): Vol 12, Núm.1 (2021): Enero-Junio; 135-142Ciencia en Desarrollo; Vol. 12 Núm. 1 (2021): Vol 12, Núm.1 (2021): Enero-Junio; 135-1422462-76580121-7488Glycerol; 0.5wt.% Pt-F-TiO2; 2wt.% Pt-F-TiO2; Glyceraldehyde; Dihydroxyacetone.Glicerol0.5wt.% Pt-F-TiO22wt.% Pt-F-TiO2GlyceraldehydeDihydroxyacetone.Glycerol oxidation by fluorinated and platinized TitaniaOxidación de glicerol por titania fluorada y platinizadainfo:eu-repo/semantics/articlehttp://purl.org/coar/version/c_970fb48d4fbd8a85http://purl.org/coar/resource_type/c_2df8fbb1Bautista, E.Ávila-Martínez, E.G.Natividad, R.Murcia Mesa, JulieRomero, R.Cubillos, J.Hernández, J.S.Cardenas, O.Hidalgo, M.C.Navío, J.ABaeza-Jiménez, R.001/15306oai:repositorio.uptc.edu.co:001/153062025-07-18 10:56:46.178metadata.onlyhttps://repositorio.uptc.edu.coRepositorio Institucional UPTCrepositorio.uptc@uptc.edu.co |
| dc.title.en-US.fl_str_mv |
Glycerol oxidation by fluorinated and platinized Titania |
| dc.title.es-ES.fl_str_mv |
Oxidación de glicerol por titania fluorada y platinizada |
| title |
Glycerol oxidation by fluorinated and platinized Titania |
| spellingShingle |
Glycerol oxidation by fluorinated and platinized Titania Glycerol; 0.5wt.% Pt-F-TiO2; 2wt.% Pt-F-TiO2; Glyceraldehyde; Dihydroxyacetone. Glicerol 0.5wt.% Pt-F-TiO2 2wt.% Pt-F-TiO2 Glyceraldehyde Dihydroxyacetone. |
| title_short |
Glycerol oxidation by fluorinated and platinized Titania |
| title_full |
Glycerol oxidation by fluorinated and platinized Titania |
| title_fullStr |
Glycerol oxidation by fluorinated and platinized Titania |
| title_full_unstemmed |
Glycerol oxidation by fluorinated and platinized Titania |
| title_sort |
Glycerol oxidation by fluorinated and platinized Titania |
| dc.subject.es-ES.fl_str_mv |
Glycerol; 0.5wt.% Pt-F-TiO2; 2wt.% Pt-F-TiO2; Glyceraldehyde; Dihydroxyacetone. |
| topic |
Glycerol; 0.5wt.% Pt-F-TiO2; 2wt.% Pt-F-TiO2; Glyceraldehyde; Dihydroxyacetone. Glicerol 0.5wt.% Pt-F-TiO2 2wt.% Pt-F-TiO2 Glyceraldehyde Dihydroxyacetone. |
| dc.subject.en-US.fl_str_mv |
Glicerol 0.5wt.% Pt-F-TiO2 2wt.% Pt-F-TiO2 Glyceraldehyde Dihydroxyacetone. |
| description |
In this work, fluorinated and platinized TiO2 was evaluated in the glycerol oxidation. Fluorination led to increase the specific surface area of titania, and platinization treatment led to obtain the highest absorption in the visible region of the electromagnetic spectrum; thus, 0.5 wt.% Pt-F-TiO2 was the best catalyst in the obtention of highest yield and selectivity to glyceraldehyde (GAL). It was also found that 2wt.% of Pt content had a detrimental effect in the glycerol conversion. Fluorination and platinum addition led to modify the reaction mechanism and selectivity. |
| publishDate |
2021 |
| dc.date.accessioned.none.fl_str_mv |
2024-07-08T14:24:02Z |
| dc.date.available.none.fl_str_mv |
2024-07-08T14:24:02Z |
| dc.date.none.fl_str_mv |
2021-01-08 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article |
| dc.type.coarversion.fl_str_mv |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| dc.type.coar.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.identifier.none.fl_str_mv |
https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/12417 10.19053/01217488.v12.n1.2021.12417 |
| dc.identifier.uri.none.fl_str_mv |
https://repositorio.uptc.edu.co/handle/001/15306 |
| url |
https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/12417 https://repositorio.uptc.edu.co/handle/001/15306 |
| identifier_str_mv |
10.19053/01217488.v12.n1.2021.12417 |
| dc.language.none.fl_str_mv |
spa |
| dc.language.iso.none.fl_str_mv |
spa |
| language |
spa |
| dc.relation.none.fl_str_mv |
https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/12417/10684 |
| dc.rights.es-ES.fl_str_mv |
Derechos de autor 2021 CIENCIA EN DESARROLLO |
| dc.rights.coar.fl_str_mv |
http://purl.org/coar/access_right/c_abf2 |
| rights_invalid_str_mv |
Derechos de autor 2021 CIENCIA EN DESARROLLO http://purl.org/coar/access_right/c_abf2 |
| dc.format.none.fl_str_mv |
application/pdf |
| dc.publisher.es-ES.fl_str_mv |
Universidad Pedagógica y Tecnológica de Colombia |
| dc.source.en-US.fl_str_mv |
Ciencia En Desarrollo; Vol. 12 No. 1 (2021): Vol 12, Núm.1 (2021): Enero-Junio; 135-142 |
| dc.source.es-ES.fl_str_mv |
Ciencia en Desarrollo; Vol. 12 Núm. 1 (2021): Vol 12, Núm.1 (2021): Enero-Junio; 135-142 |
| dc.source.none.fl_str_mv |
2462-7658 0121-7488 |
| institution |
Universidad Pedagógica y Tecnológica de Colombia |
| repository.name.fl_str_mv |
Repositorio Institucional UPTC |
| repository.mail.fl_str_mv |
repositorio.uptc@uptc.edu.co |
| _version_ |
1839633882361626624 |