Método de la correlación en un cristal de ZnO
1 recurso en línea (páginas 57-67).
- Autores:
-
Jaimes Suárez, Oslen Dilayder
Rincón, Isabel Cristina
Peña Pedraza, Heriberto
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2018
- Institución:
- Universidad Pedagógica y Tecnológica de Colombia
- Repositorio:
- RiUPTC: Repositorio Institucional UPTC
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.uptc.edu.co:001/2370
- Acceso en línea:
- http://repositorio.uptc.edu.co/handle/001/2370
- Palabra clave:
- Modos normales
Espectroscopia Raman
Wurzita
Correlación
- Rights
- openAccess
- License
- Copyright (c) 2018 Universidad Pedagógica y Tecnológica de Colombia
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Método de la correlación en un cristal de ZnO |
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Correlation Method in a ZnO Crystal |
| title |
Método de la correlación en un cristal de ZnO |
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Método de la correlación en un cristal de ZnO Modos normales Espectroscopia Raman Wurzita Correlación |
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Método de la correlación en un cristal de ZnO |
| title_full |
Método de la correlación en un cristal de ZnO |
| title_fullStr |
Método de la correlación en un cristal de ZnO |
| title_full_unstemmed |
Método de la correlación en un cristal de ZnO |
| title_sort |
Método de la correlación en un cristal de ZnO |
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Jaimes Suárez, Oslen Dilayder Rincón, Isabel Cristina Peña Pedraza, Heriberto |
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Jaimes Suárez, Oslen Dilayder Rincón, Isabel Cristina Peña Pedraza, Heriberto |
| dc.subject.proposal.spa.fl_str_mv |
Modos normales Espectroscopia Raman Wurzita Correlación |
| topic |
Modos normales Espectroscopia Raman Wurzita Correlación |
| description |
1 recurso en línea (páginas 57-67). |
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2018 |
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2018-07-04 |
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2019-01-31T20:51:44Z |
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Jaimes Suárez, O. D., Rincón, I. C., & Peña Pedraza, H. (2018). Método de la correlación en un cristal de ZnO. Ciencia en Desarrollo, 9(2), 57-67. https://doi.org/10.19053/01217488.v9.n2.2018.8753. http://repositorio.uptc.edu.co/handle/001/2370 |
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Jaimes Suárez, O. D., Rincón, I. C., & Peña Pedraza, H. (2018). Método de la correlación en un cristal de ZnO. Ciencia en Desarrollo, 9(2), 57-67. https://doi.org/10.19053/01217488.v9.n2.2018.8753. http://repositorio.uptc.edu.co/handle/001/2370 2462-7658 10.19053/01217488.v9.n2.2018.8753 |
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C.J Youn, T.S Jeong, M.S Han, J.H Kim, Optical properties of Znterminated ZnO bulk. Journal of Crystal Growth, Volume 261, Issue 4, Pages 526-532, 2004. D. C. Look, Recent Advances in ZnO Material and Devices, Materials Science and Engineering: B, Vol. 80, No. 1, pp. 383-387. doi:10.1016/S0921-5107(00)00604-8, 2001. R. S. Wagner and W. C. Ellis, Vapor-Liquid-Solid Mechanism of Single Crystal Growth, Applied Physics Letters, Vol. 4, No. 5, pp. 89-90. doi:10.1063/1.1753975, 1994 Improvement of crystallinity of ZnO thin film and electrical characteristics of film bulk acoustic wave resonator by using Pt buffer layer. Vacuum, Volume 74, Issues 3–4, Pages 689-692, 2004. Y. Polyakov, A.V. Govorkov, N.B. Smirnov, N.V. Pashkova, S.J. Pearton, K. Ip, R.M. Frazier, C.R. Abernathy, D.P. Norton, J.M. Zavada, R.G. Wilson, Y. Li, G. W. Meng, L. D. Zhang and F., Optical and magnetic properties of ZnO bulk crystals implanted with Cr and Fe. Materials Science in Semiconductor Processing, Volume 7, Issues 1–2, Pages 77-81, 2004. G. Tobin, E. McGlynn, M.O. Henry, J.P. Mosnier, J.G. Lunney, D. O’Mahony, E. de Posada, Ultraviolet stimulated emission from bulk and polycrystalline ZnO thin films with varying grain sizes Physica B: Condensed Matter, Volumes 340–342, Pages 245-249, 2003. Semiconductor ZnO Nanowires Arrays and Their Photoluminescence Properties, Applied Physics Letters, Vol. 76, No. 15, pp. 2011-2013. doi:10.1063/1.126238, 2000. Y. Xia, P. Yang, Y. Sun. Yin, F. Kim and H. Yan, “One Dimensional Nanostructures; Synthesis, Characterization, and Applications,” Advanced Materials, Vol. 15, No. 5, pp. 353-389. doi:10.1002/adma.200390087, 2003. Metal Oxides: Chemistry Applications. Fie rro, J. L. G. CRC Press. p. 182. ISBN 0824723716, 2006. Ran Cai, Jiagen Wu, Li Sun y Yanjun Liu, 3D graphene/ZnO composite with enhanced photocatalytic activity, Materials and Design, 90, pags. 839–844 , 2016. Yu-Tsui Chang, Jui-Yuan Chen, Tzu-Ping Yang, Chun-Wei Huang, Chung-Hua Chiu, Ping-Hung Yeh y Wen-Wei Wu, Excellent pie-zoelectric and electrical properties of lithiumdoped ZnO nanowires for nanogenerator applications, Nano Energy, 8, pags. 291-296 , 2014 Khalaf Al Abdullah, Sahar Awad, Jean Zaraket and Chafic Salame, Synthesis of ZnO Nanopowders By Using Sol-Gel and Studying Their Structural y Electrical Properties at Different Temperature, Energy Procedia, volume 119, pages 565 - 570, International Conference on Technologies and Materials for Renewable Energy, Environment and Sustainability, TMREES17, 21-24 April 2017, Beirut Lebanon, issn 1876-6102, doi 10.1016/j.egypro.2017.07.080, 2017. O.F. Kolomys, V.V. Strelchuk, S.V. Rarata, R. Hayn, A. Savoyant, F. Giovannelli, F. Delorme, V.Tkach, Optical and structural properties of individual Codoped ZnO microwires, Superlattices and Microstructures, Available online 5 April 2018, ISSN 0749-6036, https://doi.org/10.1016/j.spmi.2018.04.005, 2018 Norton et al.; Chopra et al., 1983; Dayan et al., 1998, Kiriakidis y Katsakaris, 2004. S. Bhagavantam y T. Venkavantam, Theory of groups and its application to physical problems, 1962. William G. Fateley y Francis R. Dollish, Infrared and Raman Selection Rules for Molécular and Lattice Vibrations: The Co-rrelation Method, WILEY-INTERSGIENCE, pags. 177, 1972. Marius Millot, Ramon Tena-Zaera , Vicen te Munoz-Sanjose, Jean-Marc Broto y Jesus Gonzalez Anharmonic effects in ZnO optical phonons probed by Raman spectroscopy, APPLIED PHYSICS LETTERS, 96, https:// doi.org/10.1063/1.3387843, 2010. http://www.originlab.com. A. W. Hewat, Solid State Commun. 8,187, 1970 |
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Ciencia en Desarrollo;Volumen 9, número 2 (Julio-Diciembre 2018) |
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Copyright (c) 2018 Universidad Pedagógica y Tecnológica de Colombia |
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Jaimes Suárez, Oslen DilayderRincón, Isabel CristinaPeña Pedraza, Heriberto2019-01-31T20:51:44Z2019-01-31T20:51:44Z2018-07-04Jaimes Suárez, O. D., Rincón, I. C., & Peña Pedraza, H. (2018). Método de la correlación en un cristal de ZnO. Ciencia en Desarrollo, 9(2), 57-67. https://doi.org/10.19053/01217488.v9.n2.2018.8753. http://repositorio.uptc.edu.co/handle/001/23702462-7658http://repositorio.uptc.edu.co/handle/001/237010.19053/01217488.v9.n2.2018.87531 recurso en línea (páginas 57-67).La predicción de los modos de vibración de las moléculas o estructuras cristalinas basados en sus propiedades de simetría, nos permiten utilizar un poderoso método para caracterizar nuevos materiales. En el siguiente trabajo, se realizó el análisis modal teórico por medio del método de correlación, y se obtuvo los modos de vibración Raman opticamente activos para un sistema cristalino con estructura de tipo Hexagonal Wurzita. Utilizando la técnica de espectroscopia Raman, se registró el espectro de vibración Raman Stokes para un cristal de ZnO. A partir del análisis teórico y del espectro Raman registrado experimentalmente para el ZnO, se pudo observar y comparar el método teórico (método de correlación) con el experimental (técnica de espectroscopia Raman). Este análisis, sugiere que el método de correlación es preciso en la predicción de los modos de vibración de cualquier red cristalina, sin embargo, su poder se puede extender al usarse conjuntamente con los datos experimentales Raman en la caracterización de la calidad cristalina y estructural de nuevos materiales de interés tecnológico.The prediction of vibrational modes of the crystalline molecules or structures based on their properties of symmetry, allow us to use a powerful method to characterize new materials. In this work, the theoretical modal analysis was performed by the correlation method, and the optically active Raman vibration modes were obtained for a crystalline system with hexagonal Wurzite type structure. Using the Raman spectroscopy technique, the Raman Stokes vibration spectrum was obtained for a ZnO crystal. From the theoretical analysis and the experimentally recorded Raman spectrum for ZnO, it was possible to observe and compare the theoretical method (correlation method) with the experimental method (Raman spectroscopy technique). This analysis suggests that the correlation method is accurate in predicting the modes of vibration of any crystal lattice, which can be used in conjunction with the Raman experimental data in characterizing the crystalline and structural quality of new materials of technological interest.Bibliografía y webgrafía: páginas 66-67.application/pdfspaUniversidad Pedagógica y Tecnológica de ColombiaCopyright (c) 2018 Universidad Pedagógica y Tecnológica de Colombiahttps://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccessAtribución-NoComercial 4.0 Internacional (CC BY-NC 4.0)http://purl.org/coar/access_right/c_abf2https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/8753/7260Método de la correlación en un cristal de ZnOCorrelation Method in a ZnO CrystalArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionTexthttps://purl.org/redcol/resource_type/ARThttp://purl.org/coar/version/c_970fb48d4fbd8a85C.J Youn, T.S Jeong, M.S Han, J.H Kim, Optical properties of Znterminated ZnO bulk. Journal of Crystal Growth, Volume 261, Issue 4, Pages 526-532, 2004.D. C. Look, Recent Advances in ZnO Material and Devices, Materials Science and Engineering: B, Vol. 80, No. 1, pp. 383-387. doi:10.1016/S0921-5107(00)00604-8, 2001.R. S. Wagner and W. C. Ellis, Vapor-Liquid-Solid Mechanism of Single Crystal Growth, Applied Physics Letters, Vol. 4, No. 5, pp. 89-90. doi:10.1063/1.1753975, 1994Improvement of crystallinity of ZnO thin film and electrical characteristics of film bulk acoustic wave resonator by using Pt buffer layer. Vacuum, Volume 74, Issues 3–4, Pages 689-692, 2004.Y. Polyakov, A.V. Govorkov, N.B. Smirnov, N.V. Pashkova, S.J. Pearton, K. Ip, R.M. Frazier, C.R. Abernathy, D.P. Norton, J.M. Zavada, R.G. Wilson, Y. Li, G. W. Meng, L. D. Zhang and F., Optical and magnetic properties of ZnO bulk crystals implanted with Cr and Fe. Materials Science in Semiconductor Processing, Volume 7, Issues 1–2, Pages 77-81, 2004.G. Tobin, E. McGlynn, M.O. Henry, J.P. Mosnier, J.G. Lunney, D. O’Mahony, E. de Posada, Ultraviolet stimulated emission from bulk and polycrystalline ZnO thin films with varying grain sizes Physica B: Condensed Matter, Volumes 340–342, Pages 245-249, 2003.Semiconductor ZnO Nanowires Arrays and Their Photoluminescence Properties, Applied Physics Letters, Vol. 76, No. 15, pp. 2011-2013. doi:10.1063/1.126238, 2000.Y. Xia, P. Yang, Y. Sun. Yin, F. Kim and H. Yan, “One Dimensional Nanostructures; Synthesis, Characterization, and Applications,” Advanced Materials, Vol. 15, No. 5, pp. 353-389. doi:10.1002/adma.200390087, 2003.Metal Oxides: Chemistry Applications. Fie rro, J. L. G. CRC Press. p. 182. ISBN 0824723716, 2006.Ran Cai, Jiagen Wu, Li Sun y Yanjun Liu, 3D graphene/ZnO composite with enhanced photocatalytic activity, Materials and Design, 90, pags. 839–844 , 2016.Yu-Tsui Chang, Jui-Yuan Chen, Tzu-Ping Yang, Chun-Wei Huang, Chung-Hua Chiu, Ping-Hung Yeh y Wen-Wei Wu, Excellent pie-zoelectric and electrical properties of lithiumdoped ZnO nanowires for nanogenerator applications, Nano Energy, 8, pags. 291-296 , 2014Khalaf Al Abdullah, Sahar Awad, Jean Zaraket and Chafic Salame, Synthesis of ZnO Nanopowders By Using Sol-Gel and Studying Their Structural y Electrical Properties at Different Temperature, Energy Procedia, volume 119, pages 565 - 570, International Conference on Technologies and Materials for Renewable Energy, Environment and Sustainability, TMREES17, 21-24 April 2017, Beirut Lebanon, issn 1876-6102, doi 10.1016/j.egypro.2017.07.080, 2017.O.F. Kolomys, V.V. Strelchuk, S.V. Rarata, R. Hayn, A. Savoyant, F. Giovannelli, F. Delorme, V.Tkach, Optical and structural properties of individual Codoped ZnO microwires, Superlattices and Microstructures, Available online 5 April 2018, ISSN 0749-6036, https://doi.org/10.1016/j.spmi.2018.04.005, 2018Norton et al.; Chopra et al., 1983; Dayan et al., 1998, Kiriakidis y Katsakaris, 2004.S. Bhagavantam y T. Venkavantam, Theory of groups and its application to physical problems, 1962.William G. Fateley y Francis R. Dollish, Infrared and Raman Selection Rules for Molécular and Lattice Vibrations: The Co-rrelation Method, WILEY-INTERSGIENCE, pags. 177, 1972.Marius Millot, Ramon Tena-Zaera , Vicen te Munoz-Sanjose, Jean-Marc Broto y Jesus Gonzalez Anharmonic effects in ZnO optical phonons probed by Raman spectroscopy, APPLIED PHYSICS LETTERS, 96, https:// doi.org/10.1063/1.3387843, 2010.http://www.originlab.com.A. W. Hewat, Solid State Commun. 8,187, 1970Ciencia en Desarrollo;Volumen 9, número 2 (Julio-Diciembre 2018)Modos normalesEspectroscopia RamanWurzitaCorrelaciónORIGINALPPS_963_Metodo_correlacion_cristal.pdfPPS_963_Metodo_correlacion_cristal.pdfArchivo principalapplication/pdf1026220https://repositorio.uptc.edu.co/bitstreams/b8b4ef00-a045-429a-894b-92ea012b00e6/downloadde66aad23c24163fe201b93a3338fbedMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-814798https://repositorio.uptc.edu.co/bitstreams/7fc1e172-5fcd-44cb-b08f-13ed665ffa80/download88794144ff048353b359a3174871b0d5MD52TEXTPPS-963.pdf.txtPPS-963.pdf.txtExtracted texttext/plain26156https://repositorio.uptc.edu.co/bitstreams/9b71a058-1a51-4b73-a57f-f242d50c2234/download071619ebf5473a80e13390b772c8c227MD53PPS_963_Metodo_correlacion_cristal.pdf.txtPPS_963_Metodo_correlacion_cristal.pdf.txtExtracted 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