Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions
Sulfonated alumina was synthetized and tested for the first time in furfural valorization through a multicomponent reaction for the preparation of a nitrogenated heterocyclic compound containing the furan substructure. Ten polysubstituted heterocycles, belonging to the dihydropyrimidinones (thiones)...
- Autores:
- Tipo de recurso:
- Fecha de publicación:
- 2021
- Institución:
- Universidad Pedagógica y Tecnológica de Colombia
- Repositorio:
- RiUPTC: Repositorio Institucional UPTC
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.uptc.edu.co:001/15323
- Acceso en línea:
- https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/12821
https://repositorio.uptc.edu.co/handle/001/15323
- Palabra clave:
- valorización furfural, sílice sulfonada, reacción multicomponente, compuestos heterocíclicos nitrogenados, análisis de métricas verdes
furfural valorization, sulfonated silica, multicomponent reaction, nitrogenated heterocyclic compounds, green metrics analysis
- Rights
- License
- Derechos de autor 2021 CIENCIA EN DESARROLLO
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2021-05-102024-07-08T14:24:04Z2024-07-08T14:24:04Zhttps://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/1282110.19053/01217488.v12.n1.2021.12821https://repositorio.uptc.edu.co/handle/001/15323Sulfonated alumina was synthetized and tested for the first time in furfural valorization through a multicomponent reaction for the preparation of a nitrogenated heterocyclic compound containing the furan substructure. Ten polysubstituted heterocycles, belonging to the dihydropyrimidinones (thiones) and 1,4-dihydropyridines, were obtained with very good yields (70% – 85%) using the tandem methodology and green reaction conditions. The catalyst was easily separated from the reaction medium, giving a high yield in the reusability studies. Green metrics were analyzed in order to consider the reaction suitability.La alúmina sulfonada se sintetizó y ensayó por primera vez en la valorización del furfural mediante una reacción multicomponente para la preparación de un compuesto heterocíclico nitrogenado que contiene la subestructura de furano. Se obtuvieron diez heterociclos polisustituidos, pertenecientes a las dihidropirimidinonas (tiones) y 1,4-dihidropiridinas, con muy buenos rendimientos (70% - 85%) utilizando la metodología tándem y las condiciones de reacción verde. El catalizador se separó fácilmente del medio de reacción, dando un alto rendimiento en los estudios de reutilización. Se analizaron las métricas verdes para considerar la idoneidad de la reacción.application/pdfspaspaUniversidad Pedagógica y Tecnológica de Colombiahttps://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/12821/10697Derechos de autor 2021 CIENCIA EN DESARROLLOhttp://purl.org/coar/access_right/c_abf2Ciencia En Desarrollo; Vol. 12 No. 1 (2021): Vol 12, Núm.1 (2021): Enero-Junio; 113-123Ciencia en Desarrollo; Vol. 12 Núm. 1 (2021): Vol 12, Núm.1 (2021): Enero-Junio; 113-1232462-76580121-7488valorización furfural, sílice sulfonada, reacción multicomponente, compuestos heterocíclicos nitrogenados, análisis de métricas verdesfurfural valorization, sulfonated silica, multicomponent reaction, nitrogenated heterocyclic compounds, green metrics analysisSulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactionsAlúmina sulfonada: un catalizador adecuado para la valorización de componentes básicos de biomasa furfural a través de reacciones multicomponente.info:eu-repo/semantics/articlehttp://purl.org/coar/version/c_970fb48d4fbd8a85http://purl.org/coar/resource_type/c_2df8fbb1Nope, ElianaRuiz, D.Sathicq, AngelRomanelli, Gustavo001/15323oai:repositorio.uptc.edu.co:001/153232025-07-18 10:56:46.199metadata.onlyhttps://repositorio.uptc.edu.coRepositorio Institucional UPTCrepositorio.uptc@uptc.edu.co |
| dc.title.en-US.fl_str_mv |
Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions |
| dc.title.es-ES.fl_str_mv |
Alúmina sulfonada: un catalizador adecuado para la valorización de componentes básicos de biomasa furfural a través de reacciones multicomponente. |
| title |
Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions |
| spellingShingle |
Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions valorización furfural, sílice sulfonada, reacción multicomponente, compuestos heterocíclicos nitrogenados, análisis de métricas verdes furfural valorization, sulfonated silica, multicomponent reaction, nitrogenated heterocyclic compounds, green metrics analysis |
| title_short |
Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions |
| title_full |
Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions |
| title_fullStr |
Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions |
| title_full_unstemmed |
Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions |
| title_sort |
Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions |
| dc.subject.es-ES.fl_str_mv |
valorización furfural, sílice sulfonada, reacción multicomponente, compuestos heterocíclicos nitrogenados, análisis de métricas verdes |
| topic |
valorización furfural, sílice sulfonada, reacción multicomponente, compuestos heterocíclicos nitrogenados, análisis de métricas verdes furfural valorization, sulfonated silica, multicomponent reaction, nitrogenated heterocyclic compounds, green metrics analysis |
| dc.subject.en-US.fl_str_mv |
furfural valorization, sulfonated silica, multicomponent reaction, nitrogenated heterocyclic compounds, green metrics analysis |
| description |
Sulfonated alumina was synthetized and tested for the first time in furfural valorization through a multicomponent reaction for the preparation of a nitrogenated heterocyclic compound containing the furan substructure. Ten polysubstituted heterocycles, belonging to the dihydropyrimidinones (thiones) and 1,4-dihydropyridines, were obtained with very good yields (70% – 85%) using the tandem methodology and green reaction conditions. The catalyst was easily separated from the reaction medium, giving a high yield in the reusability studies. Green metrics were analyzed in order to consider the reaction suitability. |
| publishDate |
2021 |
| dc.date.accessioned.none.fl_str_mv |
2024-07-08T14:24:04Z |
| dc.date.available.none.fl_str_mv |
2024-07-08T14:24:04Z |
| dc.date.none.fl_str_mv |
2021-05-10 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article |
| dc.type.coarversion.fl_str_mv |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| dc.type.coar.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.identifier.none.fl_str_mv |
https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/12821 10.19053/01217488.v12.n1.2021.12821 |
| dc.identifier.uri.none.fl_str_mv |
https://repositorio.uptc.edu.co/handle/001/15323 |
| url |
https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/12821 https://repositorio.uptc.edu.co/handle/001/15323 |
| identifier_str_mv |
10.19053/01217488.v12.n1.2021.12821 |
| dc.language.none.fl_str_mv |
spa |
| dc.language.iso.none.fl_str_mv |
spa |
| language |
spa |
| dc.relation.none.fl_str_mv |
https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/12821/10697 |
| dc.rights.es-ES.fl_str_mv |
Derechos de autor 2021 CIENCIA EN DESARROLLO |
| dc.rights.coar.fl_str_mv |
http://purl.org/coar/access_right/c_abf2 |
| rights_invalid_str_mv |
Derechos de autor 2021 CIENCIA EN DESARROLLO http://purl.org/coar/access_right/c_abf2 |
| dc.format.none.fl_str_mv |
application/pdf |
| dc.publisher.es-ES.fl_str_mv |
Universidad Pedagógica y Tecnológica de Colombia |
| dc.source.en-US.fl_str_mv |
Ciencia En Desarrollo; Vol. 12 No. 1 (2021): Vol 12, Núm.1 (2021): Enero-Junio; 113-123 |
| dc.source.es-ES.fl_str_mv |
Ciencia en Desarrollo; Vol. 12 Núm. 1 (2021): Vol 12, Núm.1 (2021): Enero-Junio; 113-123 |
| dc.source.none.fl_str_mv |
2462-7658 0121-7488 |
| institution |
Universidad Pedagógica y Tecnológica de Colombia |
| repository.name.fl_str_mv |
Repositorio Institucional UPTC |
| repository.mail.fl_str_mv |
repositorio.uptc@uptc.edu.co |
| _version_ |
1839633885351116800 |