Sulfonated alumina: A suitable catalyst for furfural biomass building-block valorization through multicomponent reactions
Sulfonated alumina was synthetized and tested for the first time in furfural valorization through a multicomponent reaction for the preparation of a nitrogenated heterocyclic compound containing the furan substructure. Ten polysubstituted heterocycles, belonging to the dihydropyrimidinones (thiones)...
- Autores:
- Tipo de recurso:
- Fecha de publicación:
- 2021
- Institución:
- Universidad Pedagógica y Tecnológica de Colombia
- Repositorio:
- RiUPTC: Repositorio Institucional UPTC
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.uptc.edu.co:001/15323
- Acceso en línea:
- https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/12821
https://repositorio.uptc.edu.co/handle/001/15323
- Palabra clave:
- valorización furfural, sílice sulfonada, reacción multicomponente, compuestos heterocíclicos nitrogenados, análisis de métricas verdes
furfural valorization, sulfonated silica, multicomponent reaction, nitrogenated heterocyclic compounds, green metrics analysis
- Rights
- License
- Derechos de autor 2021 CIENCIA EN DESARROLLO
| Summary: | Sulfonated alumina was synthetized and tested for the first time in furfural valorization through a multicomponent reaction for the preparation of a nitrogenated heterocyclic compound containing the furan substructure. Ten polysubstituted heterocycles, belonging to the dihydropyrimidinones (thiones) and 1,4-dihydropyridines, were obtained with very good yields (70% – 85%) using the tandem methodology and green reaction conditions. The catalyst was easily separated from the reaction medium, giving a high yield in the reusability studies. Green metrics were analyzed in order to consider the reaction suitability. |
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