Physicochemical study of synthetic dyes adsorption on TiO2 thin films for dye sensitized solar cells

In this work we study equilibrium and kinetic adsorption process of Methylene Blue (MB) and Copper phthalocyanine (CuPhTh) dyes on TiO2 thin films. We synthesized phthalocyanines through Achar method; dyes were characterized by Fourier-Transform Infrared spectroscopy (FTIR) and Diffuse reflectance....

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Fecha de publicación:
2015
Institución:
Universidad de Medellín
Repositorio:
Repositorio UDEM
Idioma:
eng
OAI Identifier:
oai:repository.udem.edu.co:11407/2492
Acceso en línea:
http://hdl.handle.net/11407/2492
Palabra clave:
heterojunctions
semiconductor devices
Solar Energy
thin films devices
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restrictedAccess
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http://purl.org/coar/access_right/c_16ec
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oai_identifier_str oai:repository.udem.edu.co:11407/2492
network_acronym_str REPOUDEM2
network_name_str Repositorio UDEM
repository_id_str
spelling 2016-07-27T22:09:53Z2016-07-27T22:09:53Z20159781479979448http://hdl.handle.net/11407/249210.1109/PVSC.2015.7356083In this work we study equilibrium and kinetic adsorption process of Methylene Blue (MB) and Copper phthalocyanine (CuPhTh) dyes on TiO2 thin films. We synthesized phthalocyanines through Achar method; dyes were characterized by Fourier-Transform Infrared spectroscopy (FTIR) and Diffuse reflectance. TiO2 thin films were fabricated by Doctor Blade method for using Degussa P25 as TiO2 source. We used Langmuir and Freundlich adsorption models to describe adsorption equilibrium, and besides, we used Largergren model to describe kinetic adsorption process. Characterization results reveal typical signals of phthalocyaninaes, and besides, TiO2 thin films had a polycrystalline structure. Results indicated dyes adsorption to occur through chemisorption process and Langmuir adsorption model describes suitably dye adsorption process on TiO2 thin films. © 2015 IEEE.engInstitute of Electrical and Electronics Engineers Inc.http://www.scopus.com/inward/record.url?eid=2-s2.0-84961575645&partnerID=40&md5=0533f98bd6d3ae8260a40c7b054f79a62015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015 14 December 2015, Article number 7356083ScopusPhysicochemical study of synthetic dyes adsorption on TiO2 thin films for dye sensitized solar cellsConference Paperinfo:eu-repo/semantics/conferenceObjecthttp://purl.org/coar/resource_type/c_c94finfo:eu-repo/semantics/restrictedAccesshttp://purl.org/coar/access_right/c_16ecVallejo, W., Grupo de Investigación en Fotoquímica y Fotobiología, Facultad de Ciencias Básicas, Universidad Del Atlántico, Km 7 Antigua Vía Puerto Colombia, Barranquilla, ColombiaDiaz-Uribe, C., Grupo de Investigación en Fotoquímica y Fotobiología, Facultad de Ciencias Básicas, Universidad Del Atlántico, Km 7 Antigua Vía Puerto Colombia, Barranquilla, ColombiaNavarro, K., Grupo de Investigación en Fotoquímica y Fotobiología, Facultad de Ciencias Básicas, Universidad Del Atlántico, Km 7 Antigua Vía Puerto Colombia, Barranquilla, ColombiaFajardo, C., Grupo de Investigación en Fotoquímica y Fotobiología, Facultad de Ciencias Básicas, Universidad Del Atlántico, Km 7 Antigua Vía Puerto Colombia, Barranquilla, ColombiaHernandez, J., Departamento de Ingeniería, Universidad Distrital Francisco José de Caldas, Carrera 7 No. 40B - 53, Bogota, ColombiaArredondo, C., Facultad de Ingeniería, Universidad de Medellín, Carrera 87 No 30 - 65, Medellín, ColombiaVallejo W.Diaz-Uribe C.Navarro K.Fajardo C.Hernandez J.Arredondo C.Grupo de Investigación en Fotoquímica y Fotobiología, Facultad de Ciencias Básicas, Universidad Del Atlántico, Km 7 Antigua Vía Puerto Colombia, Barranquilla, ColombiaDepartamento de Ingeniería, Universidad Distrital Francisco José de Caldas, Carrera 7 No. 40B - 53, Bogota, ColombiaFacultad de Ingeniería, Universidad de Medellín, Carrera 87 No 30 - 65, Medellín, Colombiaheterojunctionssemiconductor devicesSolar Energythin films devicesIn this work we study equilibrium and kinetic adsorption process of Methylene Blue (MB) and Copper phthalocyanine (CuPhTh) dyes on TiO2 thin films. We synthesized phthalocyanines through Achar method; dyes were characterized by Fourier-Transform Infrared spectroscopy (FTIR) and Diffuse reflectance. TiO2 thin films were fabricated by Doctor Blade method for using Degussa P25 as TiO2 source. We used Langmuir and Freundlich adsorption models to describe adsorption equilibrium, and besides, we used Largergren model to describe kinetic adsorption process. Characterization results reveal typical signals of phthalocyaninaes, and besides, TiO2 thin films had a polycrystalline structure. Results indicated dyes adsorption to occur through chemisorption process and Langmuir adsorption model describes suitably dye adsorption process on TiO2 thin films. © 2015 IEEE.11407/2492oai:repository.udem.edu.co:11407/24922020-05-27 17:44:19.038Repositorio Institucional Universidad de Medellinrepositorio@udem.edu.co
dc.title.spa.fl_str_mv Physicochemical study of synthetic dyes adsorption on TiO2 thin films for dye sensitized solar cells
title Physicochemical study of synthetic dyes adsorption on TiO2 thin films for dye sensitized solar cells
spellingShingle Physicochemical study of synthetic dyes adsorption on TiO2 thin films for dye sensitized solar cells
heterojunctions
semiconductor devices
Solar Energy
thin films devices
title_short Physicochemical study of synthetic dyes adsorption on TiO2 thin films for dye sensitized solar cells
title_full Physicochemical study of synthetic dyes adsorption on TiO2 thin films for dye sensitized solar cells
title_fullStr Physicochemical study of synthetic dyes adsorption on TiO2 thin films for dye sensitized solar cells
title_full_unstemmed Physicochemical study of synthetic dyes adsorption on TiO2 thin films for dye sensitized solar cells
title_sort Physicochemical study of synthetic dyes adsorption on TiO2 thin films for dye sensitized solar cells
dc.contributor.affiliation.spa.fl_str_mv Vallejo, W., Grupo de Investigación en Fotoquímica y Fotobiología, Facultad de Ciencias Básicas, Universidad Del Atlántico, Km 7 Antigua Vía Puerto Colombia, Barranquilla, Colombia
Diaz-Uribe, C., Grupo de Investigación en Fotoquímica y Fotobiología, Facultad de Ciencias Básicas, Universidad Del Atlántico, Km 7 Antigua Vía Puerto Colombia, Barranquilla, Colombia
Navarro, K., Grupo de Investigación en Fotoquímica y Fotobiología, Facultad de Ciencias Básicas, Universidad Del Atlántico, Km 7 Antigua Vía Puerto Colombia, Barranquilla, Colombia
Fajardo, C., Grupo de Investigación en Fotoquímica y Fotobiología, Facultad de Ciencias Básicas, Universidad Del Atlántico, Km 7 Antigua Vía Puerto Colombia, Barranquilla, Colombia
Hernandez, J., Departamento de Ingeniería, Universidad Distrital Francisco José de Caldas, Carrera 7 No. 40B - 53, Bogota, Colombia
Arredondo, C., Facultad de Ingeniería, Universidad de Medellín, Carrera 87 No 30 - 65, Medellín, Colombia
dc.subject.keyword.eng.fl_str_mv heterojunctions
semiconductor devices
Solar Energy
thin films devices
topic heterojunctions
semiconductor devices
Solar Energy
thin films devices
description In this work we study equilibrium and kinetic adsorption process of Methylene Blue (MB) and Copper phthalocyanine (CuPhTh) dyes on TiO2 thin films. We synthesized phthalocyanines through Achar method; dyes were characterized by Fourier-Transform Infrared spectroscopy (FTIR) and Diffuse reflectance. TiO2 thin films were fabricated by Doctor Blade method for using Degussa P25 as TiO2 source. We used Langmuir and Freundlich adsorption models to describe adsorption equilibrium, and besides, we used Largergren model to describe kinetic adsorption process. Characterization results reveal typical signals of phthalocyaninaes, and besides, TiO2 thin films had a polycrystalline structure. Results indicated dyes adsorption to occur through chemisorption process and Langmuir adsorption model describes suitably dye adsorption process on TiO2 thin films. © 2015 IEEE.
publishDate 2015
dc.date.created.none.fl_str_mv 2015
dc.date.accessioned.none.fl_str_mv 2016-07-27T22:09:53Z
dc.date.available.none.fl_str_mv 2016-07-27T22:09:53Z
dc.type.eng.fl_str_mv Conference Paper
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_c94f
dc.type.driver.none.fl_str_mv info:eu-repo/semantics/conferenceObject
dc.identifier.isbn.none.fl_str_mv 9781479979448
dc.identifier.uri.none.fl_str_mv http://hdl.handle.net/11407/2492
dc.identifier.doi.none.fl_str_mv 10.1109/PVSC.2015.7356083
identifier_str_mv 9781479979448
10.1109/PVSC.2015.7356083
url http://hdl.handle.net/11407/2492
dc.language.iso.none.fl_str_mv eng
language eng
dc.relation.isversionof.spa.fl_str_mv http://www.scopus.com/inward/record.url?eid=2-s2.0-84961575645&partnerID=40&md5=0533f98bd6d3ae8260a40c7b054f79a6
dc.relation.ispartofen.eng.fl_str_mv 2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015 14 December 2015, Article number 7356083
dc.rights.coar.fl_str_mv http://purl.org/coar/access_right/c_16ec
dc.rights.accessrights.none.fl_str_mv info:eu-repo/semantics/restrictedAccess
eu_rights_str_mv restrictedAccess
rights_invalid_str_mv http://purl.org/coar/access_right/c_16ec
dc.publisher.spa.fl_str_mv Institute of Electrical and Electronics Engineers Inc.
dc.source.spa.fl_str_mv Scopus
institution Universidad de Medellín
repository.name.fl_str_mv Repositorio Institucional Universidad de Medellin
repository.mail.fl_str_mv repositorio@udem.edu.co
_version_ 1808481170254462976

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