Adsorption of Cadmium Using Biochars Produced from Agro-Residues
Biochars have been shown as promising materials for cadmium remediation. However, the different precursors and the pyrolysis process operating conditions can yield very different surface functional groups, and as a result, different cadmium sorption mechanisms can be observed in biochars. Herein we...
- Autores:
- Tipo de recurso:
- Fecha de publicación:
- 2020
- Institución:
- Universidad de Medellín
- Repositorio:
- Repositorio UDEM
- Idioma:
- eng
- OAI Identifier:
- oai:repository.udem.edu.co:11407/5914
- Acceso en línea:
- http://hdl.handle.net/11407/5914
- Palabra clave:
- Cadmium
Palm oil
Positive ions
Pyrolysis
Sorption
Critical factors
Different precursors
Operating condition
Physicochemical characteristics
Pyrolysis process
Sorption behaviors
Sorption mechanism
Surface functional groups
Chemicals removal (water treatment)
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Adsorption of Cadmium Using Biochars Produced from Agro-Residues |
| title |
Adsorption of Cadmium Using Biochars Produced from Agro-Residues |
| spellingShingle |
Adsorption of Cadmium Using Biochars Produced from Agro-Residues Cadmium Palm oil Positive ions Pyrolysis Sorption Critical factors Different precursors Operating condition Physicochemical characteristics Pyrolysis process Sorption behaviors Sorption mechanism Surface functional groups Chemicals removal (water treatment) |
| title_short |
Adsorption of Cadmium Using Biochars Produced from Agro-Residues |
| title_full |
Adsorption of Cadmium Using Biochars Produced from Agro-Residues |
| title_fullStr |
Adsorption of Cadmium Using Biochars Produced from Agro-Residues |
| title_full_unstemmed |
Adsorption of Cadmium Using Biochars Produced from Agro-Residues |
| title_sort |
Adsorption of Cadmium Using Biochars Produced from Agro-Residues |
| dc.subject.keyword.eng.fl_str_mv |
Cadmium Palm oil Positive ions Pyrolysis Sorption Critical factors Different precursors Operating condition Physicochemical characteristics Pyrolysis process Sorption behaviors Sorption mechanism Surface functional groups Chemicals removal (water treatment) |
| topic |
Cadmium Palm oil Positive ions Pyrolysis Sorption Critical factors Different precursors Operating condition Physicochemical characteristics Pyrolysis process Sorption behaviors Sorption mechanism Surface functional groups Chemicals removal (water treatment) |
| description |
Biochars have been shown as promising materials for cadmium remediation. However, the different precursors and the pyrolysis process operating conditions can yield very different surface functional groups, and as a result, different cadmium sorption mechanisms can be observed in biochars. Herein we present the results of cadmium sorption on biochars produced from the pyrolysis of different agro-residues, namely, coffee husk, quinoa straw, and oil palm kernel shell. The adsorption isotherms were used to determine the influence of the biochar's physicochemical characteristics to their sorption behavior. The biochars prepared from quinoa residues showed much higher cadmium uptakes than the other biochars. The concentration of base cations was found to be a critical factor for cadmium sorption. Although the quinoa biochars presented large uptakes, it was found that base cations were supported on the biochars and could be removed by leaching. Results from this study suggest that concentration of base cations on biochars could be used as predictors of the biochar capabilities for the removal of cadmium in aqueous solution. Copyright © 2020 American Chemical Society. |
| publishDate |
2020 |
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2021-02-05T14:57:52Z |
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2021-02-05T14:57:52Z |
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2020 |
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Article |
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info:eu-repo/semantics/article |
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19327447 |
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http://hdl.handle.net/11407/5914 |
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10.1021/acs.jpcc.0c02216 |
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19327447 10.1021/acs.jpcc.0c02216 |
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http://hdl.handle.net/11407/5914 |
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eng |
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eng |
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Shahid, M., Dumat, C., Khalid, S., Niazi, N.K., Antunes, P.M.C., de Voogt, P., Cadmium Bioavailability, Uptake, Toxicity and Detoxification in Soil-Plant System (2017) Reviews of Environmental Contamination and Toxicology, 241, pp. 73-137. , In Springer International Publishing: Cham, Switzerland, Vol Ali, A., Ahmed, A., Gad, A., Chemical and microstructural analyses for heavy metals removal from water media by ceramic membrane filtration (2017) Water Sci. Technol., 75 (2), pp. 439-450 Cardoso, S.P., Azenha, I.S., Lin, Z., Portugal, I., Rodrigues, A.E., Silva, C.M., Experimental measurement and modeling of ion exchange equilibrium and kinetics of cadmium (II) solutions over microporous stannosilicate AV-6 (2016) Chem. Eng. J. (Amsterdam, Neth.), 295, pp. 139-151 Bhadrinarayana, N.S., Basha, C.A., Anantharaman, N., Electrochemical Oxidation of Cyanide and Simultaneous Cathodic Removal of Cadmium Present in the Plating Rinse Water (2007) Ind. Eng. Chem. Res., 46 (20), pp. 6417-6424 Kim, H.S., Seo, B.-H., Kuppusamy, S., Lee, Y.B., Lee, J.-H., Yang, J.-E., Owens, G., Kim, K.-R., A DOC coagulant, gypsum treatment can simultaneously reduce As, Cd and Pb uptake by medicinal plants grown in contaminated soil (2018) Ecotoxicol. Environ. Saf., 148, pp. 615-619 Bailey, S.E., Olin, T.J., Bricka, R.M., Adrian, D.D., A review of potentially low-cost sorbents for heavy metals (1999) Water Res., 33 (11), pp. 2469-2479 Boudrahem, F., Soualah, A., Aissani-Benissad, F., Pb(II) and Cd(II) Removal from Aqueous Solutions Using Activated Carbon Developed from Coffee Residue Activated with Phosphoric Acid and Zinc Chloride (2011) J. Chem. Eng. Data, 56 (5), pp. 1946-1955 Božić, D., Stanković, V., Gorgievski, M., Bogdanović, G., Kovačević, R., Adsorption of heavy metal ions by sawdust of deciduous trees (2009) J. Hazard. Mater., 171 (13), pp. 684-692 Nayak, A., Bhushan, B., Gupta, V., Sharma, P., Chemically activated carbon from lignocellulosic wastes for heavy metal wastewater remediation: Effect of activation conditions (2017) J. Colloid Interface Sci., 493, pp. 228-240 Aguayo-Villarreal, I.A., Bonilla-Petriciolet, A., Muñiz-Valencia, R., Preparation of activated carbons from pecan nutshell and their application in the antagonistic adsorption of heavy metal ions (2017) J. Mol. Liq., 230, pp. 686-695 Rashidi, N.A., Yusup, S., A review on recent technological advancement in the activated carbon production from oil palm wastes (2017) Chem. Eng. J. (Amsterdam, Neth.), 314, pp. 277-290 Fiol, N., Villaescusa, I., Martínez, M., Miralles, N., Poch, J., Serarols, J., Sorption of Pb(II), Ni(II), Cu(II) and Cd(II) from aqueous solution by olive stone waste (2006) Sep. Purif. Technol., 50 (1), pp. 132-140 Akhtar, A., Krepl, V., Ivanova, T., A Combined Overview of Combustion, Pyrolysis, and Gasification of Biomass (2018) Energy Fuels, 32 (7), pp. 7294-7318 Salgado, M.A.H., Tarelho, L.A.C., Matos, A., Robaina, M., Narváez, R., Peralta, M.E., Thermoeconomic analysis of integrated production of biochar and process heat from quinoa and lupin residual biomass (2018) Energy Policy, 114, pp. 332-341 Salgado, M.A.H., Tarelho, L.A., Matos, A., Analysis of Combined Biochar and Torrefied Biomass Fuel Production as Alternative for Residual Biomass Valorization Generated in Small-Scale Palm Oil Mills (2020) Waste Biomass Valorization, 11 (1), pp. 343-356 Neves, D., Thunman, H., Matos, A., Tarelho, L., Gómez-Barea, A., Characterization and prediction of biomass pyrolysis products (2011) Prog. Energy Combust. 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Ecol., 34 (2), pp. 177-197 Builes, S., Vega, L.F., Effect of Immobilized Amines on the Sorption Properties of Solid Materials: Impregnation versus Grafting (2013) Langmuir, 29 (1), pp. 199-206 El-Sheikh, A.H., Al-Salamin, R.M., Alshamaly, H.S., Tahboub, D.a.M., Al-Degs, Y.S., Fasfous, I.I., Al-Hashimi, N.N., Abdelghani, J.I., Effect of varying deposition conditions of magnetite on sawdust on the physiochemical properties of the prepared composites (2019) J. Environ. Chem. Eng., 7 (6), p. 103497 Stavropoulos, G.G., Precursor materials suitability for super activated carbons production (2005) Fuel Process. Technol., 86 (11), pp. 1165-1173 Reed, B.E., Matsumoto, M.R., Modeling Cadmium Adsorption by Activated Carbon Using the Langmuir and Freundlich Isotherm Expressions (1993) Sep. Sci. Technol., 28 (1314), pp. 2179-2195 Yuan, J.-H., Xu, R.-K., Zhang, H., The forms of alkalis in the biochar produced from crop residues at different temperatures (2011) Bioresour. Technol., 102 (3), pp. 3488-3497 |
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Ingeniería Ambiental |
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Journal of Physical Chemistry C |
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20202021-02-05T14:57:52Z2021-02-05T14:57:52Z19327447http://hdl.handle.net/11407/591410.1021/acs.jpcc.0c02216Biochars have been shown as promising materials for cadmium remediation. However, the different precursors and the pyrolysis process operating conditions can yield very different surface functional groups, and as a result, different cadmium sorption mechanisms can be observed in biochars. Herein we present the results of cadmium sorption on biochars produced from the pyrolysis of different agro-residues, namely, coffee husk, quinoa straw, and oil palm kernel shell. The adsorption isotherms were used to determine the influence of the biochar's physicochemical characteristics to their sorption behavior. The biochars prepared from quinoa residues showed much higher cadmium uptakes than the other biochars. The concentration of base cations was found to be a critical factor for cadmium sorption. Although the quinoa biochars presented large uptakes, it was found that base cations were supported on the biochars and could be removed by leaching. Results from this study suggest that concentration of base cations on biochars could be used as predictors of the biochar capabilities for the removal of cadmium in aqueous solution. Copyright © 2020 American Chemical Society.engAmerican Chemical SocietyIngeniería AmbientalFacultad de Ingenieríashttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85089280277&doi=10.1021%2facs.jpcc.0c02216&partnerID=40&md5=1b13fd14cc8f7905158d219f8eea8c05124271459214602Shahid, M., Dumat, C., Khalid, S., Niazi, N.K., Antunes, P.M.C., de Voogt, P., Cadmium Bioavailability, Uptake, Toxicity and Detoxification in Soil-Plant System (2017) Reviews of Environmental Contamination and Toxicology, 241, pp. 73-137. , InSpringer International Publishing: Cham, Switzerland, VolAli, A., Ahmed, A., Gad, A., Chemical and microstructural analyses for heavy metals removal from water media by ceramic membrane filtration (2017) Water Sci. Technol., 75 (2), pp. 439-450Cardoso, S.P., Azenha, I.S., Lin, Z., Portugal, I., Rodrigues, A.E., Silva, C.M., Experimental measurement and modeling of ion exchange equilibrium and kinetics of cadmium (II) solutions over microporous stannosilicate AV-6 (2016) Chem. Eng. J. (Amsterdam, Neth.), 295, pp. 139-151Bhadrinarayana, N.S., Basha, C.A., Anantharaman, N., Electrochemical Oxidation of Cyanide and Simultaneous Cathodic Removal of Cadmium Present in the Plating Rinse Water (2007) Ind. Eng. Chem. Res., 46 (20), pp. 6417-6424Kim, H.S., Seo, B.-H., Kuppusamy, S., Lee, Y.B., Lee, J.-H., Yang, J.-E., Owens, G., Kim, K.-R., A DOC coagulant, gypsum treatment can simultaneously reduce As, Cd and Pb uptake by medicinal plants grown in contaminated soil (2018) Ecotoxicol. Environ. Saf., 148, pp. 615-619Bailey, S.E., Olin, T.J., Bricka, R.M., Adrian, D.D., A review of potentially low-cost sorbents for heavy metals (1999) Water Res., 33 (11), pp. 2469-2479Boudrahem, F., Soualah, A., Aissani-Benissad, F., Pb(II) and Cd(II) Removal from Aqueous Solutions Using Activated Carbon Developed from Coffee Residue Activated with Phosphoric Acid and Zinc Chloride (2011) J. Chem. Eng. Data, 56 (5), pp. 1946-1955Božić, D., Stanković, V., Gorgievski, M., Bogdanović, G., Kovačević, R., Adsorption of heavy metal ions by sawdust of deciduous trees (2009) J. Hazard. Mater., 171 (13), pp. 684-692Nayak, A., Bhushan, B., Gupta, V., Sharma, P., Chemically activated carbon from lignocellulosic wastes for heavy metal wastewater remediation: Effect of activation conditions (2017) J. Colloid Interface Sci., 493, pp. 228-240Aguayo-Villarreal, I.A., Bonilla-Petriciolet, A., Muñiz-Valencia, R., Preparation of activated carbons from pecan nutshell and their application in the antagonistic adsorption of heavy metal ions (2017) J. Mol. Liq., 230, pp. 686-695Rashidi, N.A., Yusup, S., A review on recent technological advancement in the activated carbon production from oil palm wastes (2017) Chem. Eng. J. 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Technol., 102 (3), pp. 3488-3497Journal of Physical Chemistry CAdsorption of Cadmium Using Biochars Produced from Agro-ResiduesArticleinfo:eu-repo/semantics/articlehttp://purl.org/coar/version/c_970fb48d4fbd8a85http://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1CadmiumPalm oilPositive ionsPyrolysisSorptionCritical factorsDifferent precursorsOperating conditionPhysicochemical characteristicsPyrolysis processSorption behaviorsSorption mechanismSurface functional groupsChemicals removal (water treatment)López, J.E., Environmental Engineering Faculty, Universidad de Medellín, Medellín, 050026, ColombiaBuiles, S., Departamento de Ingeniería de Procesos, Universidad EAFIT, Carrera 49 No. 7 sur-50, Medellín, 050022, ColombiaHeredia Salgado, M.A., Department of Environment and Planning, Centre for Environmental and Marine Studies (CESAM), University of Aveiro, Aveiro, 3810-193, PortugalTarelho, L.A.C., Department of Environment and Planning, Centre for Environmental and Marine Studies (CESAM), University of Aveiro, Aveiro, 3810-193, PortugalArroyave, C., Environmental Engineering Faculty, Universidad de Medellín, Medellín, 050026, ColombiaAristizábal, A., Departamento de Ingeniería de Procesos, Universidad EAFIT, Carrera 49 No. 7 sur-50, Medellín, 050022, ColombiaChavez, E., Facultad de Ciencias de la Vida, Escuela Superior Politécnica del Litoral, ESPOL, Campus Gustavo Galindo Km. 30.5 Vía Perimetral, P.O. Box 09-01-5863, Guayaquil, Ecuadorhttp://purl.org/coar/access_right/c_16ecLópez J.E.Builes S.Heredia Salgado M.A.Tarelho L.A.C.Arroyave C.Aristizábal A.Chavez E.11407/5914oai:repository.udem.edu.co:11407/59142021-02-05 09:57:53.016Repositorio Institucional Universidad de Medellinrepositorio@udem.edu.co |