Removal of dyes from aqueous solutions by adsorbent prepared from coffee residues
This study reports the production of an adsorbent material derived from extracted coffee residues using phosphoric acid and zinc chloride as activating agents. The structural features of the materials were characterized using different analytical techniques. The BET surface areas were found between...
- Autores:
- Tipo de recurso:
- Fecha de publicación:
- 2019
- Institución:
- Universidad de Medellín
- Repositorio:
- Repositorio UDEM
- Idioma:
- eng
- OAI Identifier:
- oai:repository.udem.edu.co:11407/5684
- Acceso en línea:
- http://hdl.handle.net/11407/5684
- Palabra clave:
- Aromatic compounds
Chlorine compounds
Dyes
Isotherms
Kinetics
Monolayers
Stripping (dyes)
Zinc chloride
Adsorbent materials
Batch adsorption tests
Diffusion controlled
Equilibrium adsorption
Initial dye concentration
Langmuir isotherm models
Monolayer adsorption
Pseudo-second order model
Adsorption
- Rights
- License
- http://purl.org/coar/access_right/c_16ec
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| dc.title.none.fl_str_mv |
Removal of dyes from aqueous solutions by adsorbent prepared from coffee residues |
| title |
Removal of dyes from aqueous solutions by adsorbent prepared from coffee residues |
| spellingShingle |
Removal of dyes from aqueous solutions by adsorbent prepared from coffee residues Aromatic compounds Chlorine compounds Dyes Isotherms Kinetics Monolayers Stripping (dyes) Zinc chloride Adsorbent materials Batch adsorption tests Diffusion controlled Equilibrium adsorption Initial dye concentration Langmuir isotherm models Monolayer adsorption Pseudo-second order model Adsorption |
| title_short |
Removal of dyes from aqueous solutions by adsorbent prepared from coffee residues |
| title_full |
Removal of dyes from aqueous solutions by adsorbent prepared from coffee residues |
| title_fullStr |
Removal of dyes from aqueous solutions by adsorbent prepared from coffee residues |
| title_full_unstemmed |
Removal of dyes from aqueous solutions by adsorbent prepared from coffee residues |
| title_sort |
Removal of dyes from aqueous solutions by adsorbent prepared from coffee residues |
| dc.subject.none.fl_str_mv |
Aromatic compounds Chlorine compounds Dyes Isotherms Kinetics Monolayers Stripping (dyes) Zinc chloride Adsorbent materials Batch adsorption tests Diffusion controlled Equilibrium adsorption Initial dye concentration Langmuir isotherm models Monolayer adsorption Pseudo-second order model Adsorption |
| topic |
Aromatic compounds Chlorine compounds Dyes Isotherms Kinetics Monolayers Stripping (dyes) Zinc chloride Adsorbent materials Batch adsorption tests Diffusion controlled Equilibrium adsorption Initial dye concentration Langmuir isotherm models Monolayer adsorption Pseudo-second order model Adsorption |
| description |
This study reports the production of an adsorbent material derived from extracted coffee residues using phosphoric acid and zinc chloride as activating agents. The structural features of the materials were characterized using different analytical techniques. The BET surface areas were found between 3.81 m2.g-1 y 176.27 m2.g-1, while the FTIR analysis showed the formation of oxygenated functional groups, which are active in the adsorption process. These materials were evaluated as adsorbents for the removal of methylene blue from aqueous solution. Batch adsorption tests were performed at room temperature and the effects of contact time and, initial dye concentration was investigated. The equilibrium adsorption results were complied with Langmuir isotherm model and its maximum monolayer adsorption capacity was 15.92 mg.g-1. Adsorption kinetics studies indicated that the pseudo second order model yielded the best fit for the kinetic data. This typical dependence of methylene blue uptake on kinetic studies indicated the adsorption process to be both chemisorption and diffusion controlled. The experimental data obtained in the present study indicate that coffee residues are suitable candidates for use as adsorbents in the removal of cationic dyes. © 2019 Published under licence by IOP Publishing Ltd. |
| publishDate |
2019 |
| dc.date.accessioned.none.fl_str_mv |
2020-04-29T14:53:39Z |
| dc.date.available.none.fl_str_mv |
2020-04-29T14:53:39Z |
| dc.date.none.fl_str_mv |
2019 |
| dc.type.eng.fl_str_mv |
Conference Paper |
| dc.type.coarversion.fl_str_mv |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| dc.type.coar.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.driver.none.fl_str_mv |
info:eu-repo/semantics/article |
| dc.identifier.issn.none.fl_str_mv |
17426588 |
| dc.identifier.uri.none.fl_str_mv |
http://hdl.handle.net/11407/5684 |
| dc.identifier.doi.none.fl_str_mv |
10.1088/1742-6596/1386/1/012035 |
| identifier_str_mv |
17426588 10.1088/1742-6596/1386/1/012035 |
| url |
http://hdl.handle.net/11407/5684 |
| dc.language.iso.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.isversionof.none.fl_str_mv |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85077018900&doi=10.1088%2f1742-6596%2f1386%2f1%2f012035&partnerID=40&md5=8b8dde44320bab8e672a4d2c9160e0d7 |
| dc.relation.citationvolume.none.fl_str_mv |
1386 |
| dc.relation.citationissue.none.fl_str_mv |
1 |
| dc.relation.references.none.fl_str_mv |
Osorio Rencoret, E.R., (2018) Determinación Del Potencial de Remoción de Azul de Metileno en Solución Acuosa de Hueso de Palta y Carbón de Hueso de Palta Arrieta, A.A., Reales, H.L., Gil, J.G., Moreno, D.G., (2018) Rev. Ion, 31, pp. 99-110 Arami, M., Yousefi Limaee, N., Mahmoodi, N.M., (2006) Chemosphere, 65 (11), pp. 1999-2008 Tejada Tovar, C., Villabona Ortiz, Á., Núñez Zarur, J., (2015) Ingenium, 9 (24), pp. 41-51 Rodríguez Valencia, N., Zambrano Franco, D., (2010) Av. Técnicos Cenicafé, 393, pp. 1-8 Grisales Motato, A.L., Rojas Arrieta, W., (2016) Obtencion de Carbon Activado A Partir de Activación Quimica de Pulpa de Café y Su Aplicación en la Remoción de Colorantes en Aguas Residuales Industriales Ramirez, A.P., Giraldo, S., Ulloa, M., Flórez, E., Acelas, N.Y., (2017) J. Phys.Conf. Ser., 935 (1) Giraldo, S., Ramirez, A.P., Ulloa, M., Flórez, E., Acelas, N.Y., (2017) J. Phys.Conf. Ser., 935 (1) Ramirez, A., Giraldo, S., Flórez Yepes, E., Acelas Soto, N.Y., (2017) Rev. Colomb. Química, 46 (1), pp. 33-41 Misran, E., Bani, O., Situmeang, E.M., Purba, A.S., (2018) IOP Conf. Ser. Earth Environ. Sci., 122, p. 01285 Tian, D., Xu, Z., Zhang, D., Chen, W., Cai, J., Deng, H., Sun, Z., Zhou, Y., T (2019) J. Solid State Chem., 269, pp. 580-587 Franca, A.S., Oliveira, L.S., Ferreira, M.E., (2009) Desalination, 249 (1), pp. 267-272 Pavlovic, M.D., Buntic, A.V., Mihajlovski, K.R., iler-Marinkovic, S.S., Antonovic, D.G., Radovanovic, Z., Dimitrijevic-Brankovic, S.I., (2014) J. Taiwan Inst. Chem. Eng., 45 (4), pp. 1691-1699 Oliveira, L.C.A., Pereira, E., Guimaraes, I.R., Vallone, A., Pereira, M., Mesquita, J.P., Sapag, K., (2009) J. Hazard. Mater., 165 (1-3), pp. 87-94 Uddin, M.T., Islam, M.A., Mahmud, S., Rukanuzzaman, M., (2009) J. Hazard. Mater., 164 (1), pp. 53-60 Vasco, A.P., Betancur, M.V., (2014) Rev. Investig. Apl., 8, pp. 131-139 Hormaza, A., García, E.S., (2009) Rev. Soc.Quím. Perú, 75, pp. 329-338 Sharma, Y., Uma, (2010) J. Chem. Eng. Data, 55 (1), pp. 435-439 |
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http://purl.org/coar/access_right/c_16ec |
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http://purl.org/coar/access_right/c_16ec |
| dc.publisher.none.fl_str_mv |
Institute of Physics Publishing |
| dc.publisher.program.none.fl_str_mv |
Facultad de Ciencias Básicas |
| dc.publisher.faculty.none.fl_str_mv |
Facultad de Ciencias Básicas |
| publisher.none.fl_str_mv |
Institute of Physics Publishing |
| dc.source.none.fl_str_mv |
Journal of Physics: Conference Series |
| institution |
Universidad de Medellín |
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Repositorio Institucional Universidad de Medellin |
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repositorio@udem.edu.co |
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1808481175620026368 |
| spelling |
20192020-04-29T14:53:39Z2020-04-29T14:53:39Z17426588http://hdl.handle.net/11407/568410.1088/1742-6596/1386/1/012035This study reports the production of an adsorbent material derived from extracted coffee residues using phosphoric acid and zinc chloride as activating agents. The structural features of the materials were characterized using different analytical techniques. The BET surface areas were found between 3.81 m2.g-1 y 176.27 m2.g-1, while the FTIR analysis showed the formation of oxygenated functional groups, which are active in the adsorption process. These materials were evaluated as adsorbents for the removal of methylene blue from aqueous solution. Batch adsorption tests were performed at room temperature and the effects of contact time and, initial dye concentration was investigated. The equilibrium adsorption results were complied with Langmuir isotherm model and its maximum monolayer adsorption capacity was 15.92 mg.g-1. Adsorption kinetics studies indicated that the pseudo second order model yielded the best fit for the kinetic data. This typical dependence of methylene blue uptake on kinetic studies indicated the adsorption process to be both chemisorption and diffusion controlled. The experimental data obtained in the present study indicate that coffee residues are suitable candidates for use as adsorbents in the removal of cationic dyes. © 2019 Published under licence by IOP Publishing Ltd.engInstitute of Physics PublishingFacultad de Ciencias BásicasFacultad de Ciencias Básicashttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85077018900&doi=10.1088%2f1742-6596%2f1386%2f1%2f012035&partnerID=40&md5=8b8dde44320bab8e672a4d2c9160e0d713861Osorio Rencoret, E.R., (2018) Determinación Del Potencial de Remoción de Azul de Metileno en Solución Acuosa de Hueso de Palta y Carbón de Hueso de PaltaArrieta, A.A., Reales, H.L., Gil, J.G., Moreno, D.G., (2018) Rev. Ion, 31, pp. 99-110Arami, M., Yousefi Limaee, N., Mahmoodi, N.M., (2006) Chemosphere, 65 (11), pp. 1999-2008Tejada Tovar, C., Villabona Ortiz, Á., Núñez Zarur, J., (2015) Ingenium, 9 (24), pp. 41-51Rodríguez Valencia, N., Zambrano Franco, D., (2010) Av. Técnicos Cenicafé, 393, pp. 1-8Grisales Motato, A.L., Rojas Arrieta, W., (2016) Obtencion de Carbon Activado A Partir de Activación Quimica de Pulpa de Café y Su Aplicación en la Remoción de Colorantes en Aguas Residuales IndustrialesRamirez, A.P., Giraldo, S., Ulloa, M., Flórez, E., Acelas, N.Y., (2017) J. Phys.Conf. Ser., 935 (1)Giraldo, S., Ramirez, A.P., Ulloa, M., Flórez, E., Acelas, N.Y., (2017) J. Phys.Conf. Ser., 935 (1)Ramirez, A., Giraldo, S., Flórez Yepes, E., Acelas Soto, N.Y., (2017) Rev. Colomb. Química, 46 (1), pp. 33-41Misran, E., Bani, O., Situmeang, E.M., Purba, A.S., (2018) IOP Conf. Ser. Earth Environ. Sci., 122, p. 01285Tian, D., Xu, Z., Zhang, D., Chen, W., Cai, J., Deng, H., Sun, Z., Zhou, Y., T (2019) J. Solid State Chem., 269, pp. 580-587Franca, A.S., Oliveira, L.S., Ferreira, M.E., (2009) Desalination, 249 (1), pp. 267-272Pavlovic, M.D., Buntic, A.V., Mihajlovski, K.R., iler-Marinkovic, S.S., Antonovic, D.G., Radovanovic, Z., Dimitrijevic-Brankovic, S.I., (2014) J. Taiwan Inst. Chem. Eng., 45 (4), pp. 1691-1699Oliveira, L.C.A., Pereira, E., Guimaraes, I.R., Vallone, A., Pereira, M., Mesquita, J.P., Sapag, K., (2009) J. Hazard. Mater., 165 (1-3), pp. 87-94Uddin, M.T., Islam, M.A., Mahmud, S., Rukanuzzaman, M., (2009) J. Hazard. Mater., 164 (1), pp. 53-60Vasco, A.P., Betancur, M.V., (2014) Rev. Investig. Apl., 8, pp. 131-139Hormaza, A., García, E.S., (2009) Rev. Soc.Quím. Perú, 75, pp. 329-338Sharma, Y., Uma, (2010) J. Chem. Eng. Data, 55 (1), pp. 435-439Journal of Physics: Conference SeriesAromatic compoundsChlorine compoundsDyesIsothermsKineticsMonolayersStripping (dyes)Zinc chlorideAdsorbent materialsBatch adsorption testsDiffusion controlledEquilibrium adsorptionInitial dye concentrationLangmuir isotherm modelsMonolayer adsorptionPseudo-second order modelAdsorptionRemoval of dyes from aqueous solutions by adsorbent prepared from coffee residuesConference Paperinfo:eu-repo/semantics/articlehttp://purl.org/coar/version/c_970fb48d4fbd8a85http://purl.org/coar/resource_type/c_2df8fbb1López, L., Grupo de Investigación de Materiales Con Impacto, Universidad de Medellín, Medellín, Colombia; Ramirez, A.P., Grupo de Investigación de Materiales Con Impacto, Universidad de Medellín, Medellín, Colombia; Giraldo, S., Grupo de Investigación de Materiales Con Impacto, Universidad de Medellín, Medellín, Colombia; Flórez, E., Grupo de Investigación de Materiales Con Impacto, Universidad de Medellín, Medellín, Colombia; Acelas, N.Y., Grupo de Investigación de Materiales Con Impacto, Universidad de Medellín, Medellín, Colombiahttp://purl.org/coar/access_right/c_16ecLópez L.Ramirez A.P.Giraldo S.Flórez E.Acelas N.Y.11407/5684oai:repository.udem.edu.co:11407/56842020-05-27 18:23:10.165Repositorio Institucional Universidad de Medellinrepositorio@udem.edu.co |