Effect of pH on Dimethylamine Borane Reduced Electroless Nickel Deposits on AISI/SAE 1045 Steel Surface

Abstract: Electroless Ni B coatings using DMAB-reduced plating baths at different pH conditions were formed on AISI/SAE 1045 carbon steel. Substrates were grit-blasted with alumina, generating a rough surface suitable for anchorage and nucleation of the coating. The surface of the substrates were ex...

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Tipo de recurso:
Fecha de publicación:
2019
Institución:
Universidad de Medellín
Repositorio:
Repositorio UDEM
Idioma:
eng
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oai:repository.udem.edu.co:11407/5799
Acceso en línea:
http://hdl.handle.net/11407/5799
Palabra clave:
Contact plating
DMAB
Electroless
Ferrous alloys
Ni B coatings
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http://purl.org/coar/access_right/c_16ec
id REPOUDEM2_9b452e4a1658443be84eb5bd71ae7840
oai_identifier_str oai:repository.udem.edu.co:11407/5799
network_acronym_str REPOUDEM2
network_name_str Repositorio UDEM
repository_id_str
dc.title.none.fl_str_mv Effect of pH on Dimethylamine Borane Reduced Electroless Nickel Deposits on AISI/SAE 1045 Steel Surface
title Effect of pH on Dimethylamine Borane Reduced Electroless Nickel Deposits on AISI/SAE 1045 Steel Surface
spellingShingle Effect of pH on Dimethylamine Borane Reduced Electroless Nickel Deposits on AISI/SAE 1045 Steel Surface
Contact plating
DMAB
Electroless
Ferrous alloys
Ni B coatings
title_short Effect of pH on Dimethylamine Borane Reduced Electroless Nickel Deposits on AISI/SAE 1045 Steel Surface
title_full Effect of pH on Dimethylamine Borane Reduced Electroless Nickel Deposits on AISI/SAE 1045 Steel Surface
title_fullStr Effect of pH on Dimethylamine Borane Reduced Electroless Nickel Deposits on AISI/SAE 1045 Steel Surface
title_full_unstemmed Effect of pH on Dimethylamine Borane Reduced Electroless Nickel Deposits on AISI/SAE 1045 Steel Surface
title_sort Effect of pH on Dimethylamine Borane Reduced Electroless Nickel Deposits on AISI/SAE 1045 Steel Surface
dc.subject.none.fl_str_mv Contact plating
DMAB
Electroless
Ferrous alloys
Ni B coatings
topic Contact plating
DMAB
Electroless
Ferrous alloys
Ni B coatings
description Abstract: Electroless Ni B coatings using DMAB-reduced plating baths at different pH conditions were formed on AISI/SAE 1045 carbon steel. Substrates were grit-blasted with alumina, generating a rough surface suitable for anchorage and nucleation of the coating. The surface of the substrates were examined at selected times of electroless treatment using scanning electron microscopy. The structure of the coating was studied by means of X-ray diffraction. A low-cost boron determination procedure was implemented in order to determine the amount of boron incorporated into the electroless coatings. Coatings nucleate faster at acid and neutral pH conditions; however, at the end of the plating process all coatings were adherent, with the typical morphology of Ni B electroless coatings. Substrates slightly corroded inside the plating bath at acid pH condition. The amount of boron into the coatings was approximately 2.15, 2.14 and 1.10% (wt%) for the acid, neutral and alkaline pH plating baths, respectively. Graphic Abstract: [Figure not available: see fulltext.]. © 2019, The Korean Institute of Metals and Materials.
publishDate 2019
dc.date.accessioned.none.fl_str_mv 2020-04-29T14:54:04Z
dc.date.available.none.fl_str_mv 2020-04-29T14:54:04Z
dc.date.none.fl_str_mv 2019
dc.type.eng.fl_str_mv Article
dc.type.coarversion.fl_str_mv http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_6501
http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.driver.none.fl_str_mv info:eu-repo/semantics/article
dc.identifier.issn.none.fl_str_mv 15989623
dc.identifier.uri.none.fl_str_mv http://hdl.handle.net/11407/5799
dc.identifier.doi.none.fl_str_mv 10.1007/s12540-019-00362-8
identifier_str_mv 15989623
10.1007/s12540-019-00362-8
url http://hdl.handle.net/11407/5799
dc.language.iso.none.fl_str_mv eng
language eng
dc.relation.isversionof.none.fl_str_mv https://www.scopus.com/inward/record.uri?eid=2-s2.0-85069172242&doi=10.1007%2fs12540-019-00362-8&partnerID=40&md5=dab187171f9943b250915f16336ebd5e
dc.relation.references.none.fl_str_mv Vitry, V., Bonin, L., Effect of temperature on ultrasound-assisted electroless nickel-boron plating (2019) Ultrason. Sonochem., 56, pp. 327-336
Huang, Z., Nguyen, T.T., Zhou, Y., Qi, G., A low temperature electroless nickel plating chemistry (2019) Surf. Coat. Technol., 372, pp. 160-165
Ta?ci, S., Özden, R.C., Anik, M., Corrosion and wear characteristics of electroless Ni P, Ni P W and composite Ni P W/Al2O3 coatings on AZ91 sheet (2019) Met. Mater. Int., 25, pp. 313-323
Thakur, A., Gharde, S., Kandasubramanian, B., Electroless nickel fabrication on surface modified magnesium substrates (2019) Def. Technol., 1, p. 11
Qian, W., Wei, H., Chen, H., The effect of heat treatment on Ni B Ce electroless coatings (2019) Surf. Eng., 35, pp. 144-152
Mukhopadhyay, A., Barman, T.K., Sahoo, P., Tribological behavior of sodium borohydride reduced electroless nickel alloy coatings at room and elevated temperatures (2017) Surf. Coat. Technol., 321, pp. 464-476
Mukhopadhyay, A., Barman, T.K., Sahoo, P., Tribological characteristics of electroless Ni B Mo coatings at different operating temperatures (2019) Surf. Rev. Lett., 26, p. 1850175
Mukhopadhyay, A., Barman, T.K., Sahoo, P., Friction and wear performance of electroless Ni B coatings at different operating temperatures (2019) Silicon, 11, pp. 721-731
Chiba, A., Haijima, H., Wu, W., Effect of sonication on the electroless Ni B deposited powder from acid bath (2004) Ultrasonics, 42, pp. 617-620
Dabalà, M., Brunelli, K., Frattini, R., Magrini, M., Surface hardening of Ti 6Al 4V alloy by diffusion treatment of electroless Ni B coatings (2004) Surf. Eng., 20, pp. 103-107
Rha, S.-K., Baek, S.-D., Lee, Y.-S., Effects of dimethylamine borane in electroless Ni B plating (2015) J. Nanosci. Nanotechnol., 15, pp. 7444-7450
Hamid, Z.A., Hassan, H.B., Attyia, A.M., Influence of deposition temperature and heat treatment on the performance of electroless Ni B films (2010) Surf. Coat. Technol., 205, pp. 2348-2354
Domínguez-Ríos, C., Hurtado-Macias, A., Torres-Sánchez, R., Measurement of mechanical properties of an electroless Ni B coating using nanoindentation (2012) Ind. Eng. Chem. Res., 51, pp. 7762-7768
Baskaran, I., Sankara Narayanan, T.S.N., Stephen, A., Corrosion resistance of electroless Ni low B coatings (2009) Trans. IMF, 87, pp. 221-224
Anik, M., Körpe, E., ?en, E., Effect of coating bath composition on the properties of electroless nickel boron films (2008) Surf. Coat. Technol., 202, pp. 1718-1727
Das, S.K., Sahoo, P., Influence of process parameters on microhardness of electroless Ni B coatings (2012) Adv. Mech. Eng., 4, p. 703168
Wang, Z.C., Jia, F., Yu, L., Direct electroless nickel boron plating on AZ91D magnesium alloy (2012) Surf. Coat. Technol., 206, pp. 3676-3685
Cai, Y., Chang, Z.Z., Chen, C.M., Complexing agent on the surface of magnesium alloy plating of Ni B alloy (2011) Adv. Mater. Res., 311-313, pp. 327-330
Chang, Q.H., Chang, Z.Z., Bai, Y.T., The effect of NaOH on the surface of magnesium alloy Ni B alloy plating properties (2011) Adv. Mater. Res., 189-193, pp. 347-350
Vitry, V., Kanta, A.-F., Delaunois, F., Application of nitriding to electroless nickel boron coatings: chemical and structural effects
mechanical characterization
corrosion resistance (2012) Mater. Des., 39, pp. 269-278
Vitry, V., Sens, A., Kanta, A.-F., Delaunois, F., Experimental study on the formation and growth of electroless nickel boron coatings from borohydride-reduced bath on mild steel (2012) Appl. Surf. Sci., 263, pp. 640-647
Vitry, V., Sens, A., Kanta, A.-F., Delaunois, F., Wear and corrosion resistance of heat treated and as-plated duplex NiP/NiB coatings on 2024 aluminum alloys (2012) Surf. Coat. Technol., 206, pp. 3421-3427
Brunelli, K., Dabalà, M., Dughiero, F., Magrini, M., Diffusion treatment of Ni B coatings by induction heating to harden the surface of Ti 6Al 4V alloy (2009) Mater. Chem. Phys., 115, pp. 467-472
Gilley, K.L., Nino, J.C., Riddle, Y.W., Heat treatments modify the tribological properties of nickel boron coatings (2012) ACS Appl. Mater. Interfaces, 4, pp. 3069-3076
Srinivasan, K.N., Meenakshi, R., Santhi, A., Studies on development of electroless Ni B bath for corrosion resistance and wear resistance applications (2010) Surf. Eng., 26, pp. 153-158
Vitry, V., Kanta, A.-F., Delaunois, F., Evolution of reactive concentration during borohydride-reduced electroless nickel boron plating and design of a replenishment procedure (2012) Ind. Eng. Chem. Res., 51, pp. 9227-9234
(2011) Standard Terminology Relating to Electroplating, , ASTM B374-06, West Conshohocken
Wang, H.-Y., Chung, S.-T., Chuang, Y.-C., Tsai, W.-T., Electroless Ni B deposition from an emulsified supercritical carbon dioxide bath (2010) Thin Solid Films, 518, pp. 7505-7508
Blumenthal, H., Fall, W., Potentiometric determination of boron in nickel boride (1953) Anal. Chem., 25, pp. 1120-1122
(2016) Standard guide for determining mass per unit area of electrodeposited and related coatings by gravimetric and other chemical analysis procedures, , ASTM B767-88, West Conshohocken
Vitry, V., Kanta, A.-F., Delaunois, F., Initiation and formation of electroless nickel boron coatings on mild steel: effect of substrate roughness (2010) Mater. Sci. Eng. B, 175, pp. 266-273
Bagheri, S., Guagliano, M., Review of shot peening processes to obtain nanocrystalline surfaces in metal alloys (2009) Surf. Eng., 25, pp. 3-14
Lee, S.B., Kim, Y.-M., Signature of surface energy dependence of partial dislocation slip in a gold nanometer-sized protrusion (2011) Scr. Mater., 64, pp. 1125-1128
Pourbaix, M., (1974) Atlas of Electrochemical Equilibria in Aqueous Solutions, , National Association of Corrosion Engineers, Houston
(2015) Standard Specification for Autocatalytic Nickel Boron Coatings for Engineering Use, , ASTM, West Conshohocken
Khalili, K., Safaei, M., FEM analysis of edge preparation for chamfered tools (2009) Int. J. Mater. Form., 2, pp. 217-224
Yamamoto, T., Nagayama, T., Nakamura, T., Thermal Expansion and Thermal Stress Behavior of Electroless-Plated Fe Ni B Alloy Thin Film for High-Density Packaging (2019) J. Electrochem. Soc., 166, pp. D3238-D3245
Agarwala, R.C., Agarwala, V., Electroless alloy/composite coatings: a review (2003) Sadhana, 28, pp. 475-493
Beygi, H., Vafaeenezhad, H., Sajjadi, S.A., Modeling the electroless nickel deposition on aluminum nanoparticles (2012) Appl. Surf. Sci., 258, pp. 7744-7750
Yoon, J.-W., Koo, J.-M., Kim, J.-W., Effect of boron content in electroless Ni B layer on plating layer properties and soldering characteristics with Sn Ag solder (2008) J. Alloys Compd., 466, pp. 73-79
Krishnaveni, K., Sankara Narayanan, T.S.N., Seshadri, S.K., Electroless Ni B coatings: preparation and evaluation of hardness and wear resistance (2005) Surf. Coat. Technol., 190, pp. 115-121
Narayanan, T.S.N.S., Krishnaveni, K., Seshadri, S.K., Electroless Ni P/Ni B duplex coatings: preparation and evaluation of microhardness, wear and corrosion resistance (2003) Mater. Chem. Phys., 82, pp. 771-779
Gaevskaya, T.V., Novotortseva, I.G., Tsybulskaya, L.S., The effect of boron on the microstructure and properties of electrodeposited nickel films (1996) Met. Finish., 94, pp. 100-103
Zheng, L., Peng, X., Temperature-dependent thermal and chemical stabilities as well as mechanical properties of electrodeposited nanocrystalline Ni (2018) Met. Mater. Int., 24, pp. 1293-1302
Liu, S., Zhou, W., Yu, T., Preparation of layered nanoporous Ti/TiO2/Ni W B electrode for electrocatalytic reduction of coal (2014) Fuel, 134, pp. 151-158
Salicio-Paz, A., Grande, H., Pellicer, E., Monolayered versus multilayered electroless NiP coatings: impact of the plating approach on the microstructure, mechanical and corrosion properties of the coatings (2019) Surf. Coat. Technol., 368, pp. 138-146
Choi, J.W., Hwang, G.H., Han, W.K., Kang, S.G., Phase transformation of Ni B, Ni P diffusion barrier deposited electrolessly on Cu interconnect (2006) Appl. Surf. Sci., 253, pp. 2171-2178
Owen, B.B., The dissociation constant of boric acid from 10 to 50° (1934) J. Am. Chem. Soc., 56, pp. 1695-1697
Azevedo, M.C.C., Cavaleiro, A.M.V., The acid base titration of a very weak acid: boric acid (2012) J. Chem. Educ., 89, pp. 767-770
Knoeck, J., Taylor, J.K., Aqueous boric acid-borate-mannitol equilibriums (1969) Anal. Chem., 41, pp. 1730-1734
Hollander, M., Rieman, W., III, Titration of boric acid in presence of mannitol (1945) Ind. Eng. Chem. Anal. Ed., 17, pp. 602-603
Balintova, M., Petrilakova, A., Study of pH influence on the selective precipitation of heavy metals from acid mine drainage (2011) Chem. Eng. Trans., 25, pp. 345-350
dc.rights.coar.fl_str_mv http://purl.org/coar/access_right/c_16ec
rights_invalid_str_mv http://purl.org/coar/access_right/c_16ec
dc.publisher.none.fl_str_mv Korean Institute of Metals and Materials
dc.publisher.program.none.fl_str_mv Ingeniería de Materiales
dc.publisher.faculty.none.fl_str_mv Facultad de Ingenierías
publisher.none.fl_str_mv Korean Institute of Metals and Materials
dc.source.none.fl_str_mv Metals and Materials International
institution Universidad de Medellín
repository.name.fl_str_mv Repositorio Institucional Universidad de Medellin
repository.mail.fl_str_mv repositorio@udem.edu.co
_version_ 1814159121851613184
spelling 20192020-04-29T14:54:04Z2020-04-29T14:54:04Z15989623http://hdl.handle.net/11407/579910.1007/s12540-019-00362-8Abstract: Electroless Ni B coatings using DMAB-reduced plating baths at different pH conditions were formed on AISI/SAE 1045 carbon steel. Substrates were grit-blasted with alumina, generating a rough surface suitable for anchorage and nucleation of the coating. The surface of the substrates were examined at selected times of electroless treatment using scanning electron microscopy. The structure of the coating was studied by means of X-ray diffraction. A low-cost boron determination procedure was implemented in order to determine the amount of boron incorporated into the electroless coatings. Coatings nucleate faster at acid and neutral pH conditions; however, at the end of the plating process all coatings were adherent, with the typical morphology of Ni B electroless coatings. Substrates slightly corroded inside the plating bath at acid pH condition. The amount of boron into the coatings was approximately 2.15, 2.14 and 1.10% (wt%) for the acid, neutral and alkaline pH plating baths, respectively. Graphic Abstract: [Figure not available: see fulltext.]. © 2019, The Korean Institute of Metals and Materials.engKorean Institute of Metals and MaterialsIngeniería de MaterialesFacultad de Ingenieríashttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85069172242&doi=10.1007%2fs12540-019-00362-8&partnerID=40&md5=dab187171f9943b250915f16336ebd5eVitry, V., Bonin, L., Effect of temperature on ultrasound-assisted electroless nickel-boron plating (2019) Ultrason. Sonochem., 56, pp. 327-336Huang, Z., Nguyen, T.T., Zhou, Y., Qi, G., A low temperature electroless nickel plating chemistry (2019) Surf. Coat. Technol., 372, pp. 160-165Ta?ci, S., Özden, R.C., Anik, M., Corrosion and wear characteristics of electroless Ni P, Ni P W and composite Ni P W/Al2O3 coatings on AZ91 sheet (2019) Met. Mater. Int., 25, pp. 313-323Thakur, A., Gharde, S., Kandasubramanian, B., Electroless nickel fabrication on surface modified magnesium substrates (2019) Def. Technol., 1, p. 11Qian, W., Wei, H., Chen, H., The effect of heat treatment on Ni B Ce electroless coatings (2019) Surf. Eng., 35, pp. 144-152Mukhopadhyay, A., Barman, T.K., Sahoo, P., Tribological behavior of sodium borohydride reduced electroless nickel alloy coatings at room and elevated temperatures (2017) Surf. Coat. Technol., 321, pp. 464-476Mukhopadhyay, A., Barman, T.K., Sahoo, P., Tribological characteristics of electroless Ni B Mo coatings at different operating temperatures (2019) Surf. Rev. Lett., 26, p. 1850175Mukhopadhyay, A., Barman, T.K., Sahoo, P., Friction and wear performance of electroless Ni B coatings at different operating temperatures (2019) Silicon, 11, pp. 721-731Chiba, A., Haijima, H., Wu, W., Effect of sonication on the electroless Ni B deposited powder from acid bath (2004) Ultrasonics, 42, pp. 617-620Dabalà, M., Brunelli, K., Frattini, R., Magrini, M., Surface hardening of Ti 6Al 4V alloy by diffusion treatment of electroless Ni B coatings (2004) Surf. Eng., 20, pp. 103-107Rha, S.-K., Baek, S.-D., Lee, Y.-S., Effects of dimethylamine borane in electroless Ni B plating (2015) J. Nanosci. Nanotechnol., 15, pp. 7444-7450Hamid, Z.A., Hassan, H.B., Attyia, A.M., Influence of deposition temperature and heat treatment on the performance of electroless Ni B films (2010) Surf. Coat. Technol., 205, pp. 2348-2354Domínguez-Ríos, C., Hurtado-Macias, A., Torres-Sánchez, R., Measurement of mechanical properties of an electroless Ni B coating using nanoindentation (2012) Ind. Eng. Chem. Res., 51, pp. 7762-7768Baskaran, I., Sankara Narayanan, T.S.N., Stephen, A., Corrosion resistance of electroless Ni low B coatings (2009) Trans. IMF, 87, pp. 221-224Anik, M., Körpe, E., ?en, E., Effect of coating bath composition on the properties of electroless nickel boron films (2008) Surf. Coat. Technol., 202, pp. 1718-1727Das, S.K., Sahoo, P., Influence of process parameters on microhardness of electroless Ni B coatings (2012) Adv. Mech. Eng., 4, p. 703168Wang, Z.C., Jia, F., Yu, L., Direct electroless nickel boron plating on AZ91D magnesium alloy (2012) Surf. Coat. Technol., 206, pp. 3676-3685Cai, Y., Chang, Z.Z., Chen, C.M., Complexing agent on the surface of magnesium alloy plating of Ni B alloy (2011) Adv. Mater. Res., 311-313, pp. 327-330Chang, Q.H., Chang, Z.Z., Bai, Y.T., The effect of NaOH on the surface of magnesium alloy Ni B alloy plating properties (2011) Adv. Mater. Res., 189-193, pp. 347-350Vitry, V., Kanta, A.-F., Delaunois, F., Application of nitriding to electroless nickel boron coatings: chemical and structural effectsmechanical characterizationcorrosion resistance (2012) Mater. Des., 39, pp. 269-278Vitry, V., Sens, A., Kanta, A.-F., Delaunois, F., Experimental study on the formation and growth of electroless nickel boron coatings from borohydride-reduced bath on mild steel (2012) Appl. Surf. Sci., 263, pp. 640-647Vitry, V., Sens, A., Kanta, A.-F., Delaunois, F., Wear and corrosion resistance of heat treated and as-plated duplex NiP/NiB coatings on 2024 aluminum alloys (2012) Surf. Coat. Technol., 206, pp. 3421-3427Brunelli, K., Dabalà, M., Dughiero, F., Magrini, M., Diffusion treatment of Ni B coatings by induction heating to harden the surface of Ti 6Al 4V alloy (2009) Mater. Chem. Phys., 115, pp. 467-472Gilley, K.L., Nino, J.C., Riddle, Y.W., Heat treatments modify the tribological properties of nickel boron coatings (2012) ACS Appl. Mater. Interfaces, 4, pp. 3069-3076Srinivasan, K.N., Meenakshi, R., Santhi, A., Studies on development of electroless Ni B bath for corrosion resistance and wear resistance applications (2010) Surf. Eng., 26, pp. 153-158Vitry, V., Kanta, A.-F., Delaunois, F., Evolution of reactive concentration during borohydride-reduced electroless nickel boron plating and design of a replenishment procedure (2012) Ind. Eng. Chem. Res., 51, pp. 9227-9234(2011) Standard Terminology Relating to Electroplating, , ASTM B374-06, West ConshohockenWang, H.-Y., Chung, S.-T., Chuang, Y.-C., Tsai, W.-T., Electroless Ni B deposition from an emulsified supercritical carbon dioxide bath (2010) Thin Solid Films, 518, pp. 7505-7508Blumenthal, H., Fall, W., Potentiometric determination of boron in nickel boride (1953) Anal. Chem., 25, pp. 1120-1122(2016) Standard guide for determining mass per unit area of electrodeposited and related coatings by gravimetric and other chemical analysis procedures, , ASTM B767-88, West ConshohockenVitry, V., Kanta, A.-F., Delaunois, F., Initiation and formation of electroless nickel boron coatings on mild steel: effect of substrate roughness (2010) Mater. Sci. Eng. B, 175, pp. 266-273Bagheri, S., Guagliano, M., Review of shot peening processes to obtain nanocrystalline surfaces in metal alloys (2009) Surf. Eng., 25, pp. 3-14Lee, S.B., Kim, Y.-M., Signature of surface energy dependence of partial dislocation slip in a gold nanometer-sized protrusion (2011) Scr. Mater., 64, pp. 1125-1128Pourbaix, M., (1974) Atlas of Electrochemical Equilibria in Aqueous Solutions, , National Association of Corrosion Engineers, Houston(2015) Standard Specification for Autocatalytic Nickel Boron Coatings for Engineering Use, , ASTM, West ConshohockenKhalili, K., Safaei, M., FEM analysis of edge preparation for chamfered tools (2009) Int. J. Mater. Form., 2, pp. 217-224Yamamoto, T., Nagayama, T., Nakamura, T., Thermal Expansion and Thermal Stress Behavior of Electroless-Plated Fe Ni B Alloy Thin Film for High-Density Packaging (2019) J. Electrochem. Soc., 166, pp. D3238-D3245Agarwala, R.C., Agarwala, V., Electroless alloy/composite coatings: a review (2003) Sadhana, 28, pp. 475-493Beygi, H., Vafaeenezhad, H., Sajjadi, S.A., Modeling the electroless nickel deposition on aluminum nanoparticles (2012) Appl. Surf. Sci., 258, pp. 7744-7750Yoon, J.-W., Koo, J.-M., Kim, J.-W., Effect of boron content in electroless Ni B layer on plating layer properties and soldering characteristics with Sn Ag solder (2008) J. Alloys Compd., 466, pp. 73-79Krishnaveni, K., Sankara Narayanan, T.S.N., Seshadri, S.K., Electroless Ni B coatings: preparation and evaluation of hardness and wear resistance (2005) Surf. Coat. Technol., 190, pp. 115-121Narayanan, T.S.N.S., Krishnaveni, K., Seshadri, S.K., Electroless Ni P/Ni B duplex coatings: preparation and evaluation of microhardness, wear and corrosion resistance (2003) Mater. Chem. Phys., 82, pp. 771-779Gaevskaya, T.V., Novotortseva, I.G., Tsybulskaya, L.S., The effect of boron on the microstructure and properties of electrodeposited nickel films (1996) Met. Finish., 94, pp. 100-103Zheng, L., Peng, X., Temperature-dependent thermal and chemical stabilities as well as mechanical properties of electrodeposited nanocrystalline Ni (2018) Met. Mater. Int., 24, pp. 1293-1302Liu, S., Zhou, W., Yu, T., Preparation of layered nanoporous Ti/TiO2/Ni W B electrode for electrocatalytic reduction of coal (2014) Fuel, 134, pp. 151-158Salicio-Paz, A., Grande, H., Pellicer, E., Monolayered versus multilayered electroless NiP coatings: impact of the plating approach on the microstructure, mechanical and corrosion properties of the coatings (2019) Surf. Coat. Technol., 368, pp. 138-146Choi, J.W., Hwang, G.H., Han, W.K., Kang, S.G., Phase transformation of Ni B, Ni P diffusion barrier deposited electrolessly on Cu interconnect (2006) Appl. Surf. Sci., 253, pp. 2171-2178Owen, B.B., The dissociation constant of boric acid from 10 to 50° (1934) J. Am. Chem. Soc., 56, pp. 1695-1697Azevedo, M.C.C., Cavaleiro, A.M.V., The acid base titration of a very weak acid: boric acid (2012) J. Chem. Educ., 89, pp. 767-770Knoeck, J., Taylor, J.K., Aqueous boric acid-borate-mannitol equilibriums (1969) Anal. Chem., 41, pp. 1730-1734Hollander, M., Rieman, W., III, Titration of boric acid in presence of mannitol (1945) Ind. Eng. Chem. Anal. Ed., 17, pp. 602-603Balintova, M., Petrilakova, A., Study of pH influence on the selective precipitation of heavy metals from acid mine drainage (2011) Chem. Eng. Trans., 25, pp. 345-350Metals and Materials InternationalContact platingDMABElectrolessFerrous alloysNi B coatingsEffect of pH on Dimethylamine Borane Reduced Electroless Nickel Deposits on AISI/SAE 1045 Steel SurfaceArticleinfo:eu-repo/semantics/articlehttp://purl.org/coar/version/c_970fb48d4fbd8a85http://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Guerra, L., Centro de Investigación, Innovación y Desarrollo de Materiales CIDEMAT, Facultad de Ingeniería, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín, Colombia; Echeverría, F., Centro de Investigación, Innovación y Desarrollo de Materiales CIDEMAT, Facultad de Ingeniería, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín, Colombia; Correa, E., Grupo de Investigación Materiales con Impacto MAT&MPAC, Facultad de Ingenierías, Universidad de Medellín, Carrera 87 No 30 65, Medellín, Colombiahttp://purl.org/coar/access_right/c_16ecGuerra L.Echeverría F.Correa E.11407/5799oai:repository.udem.edu.co:11407/57992020-05-27 15:55:45.605Repositorio Institucional Universidad de Medellinrepositorio@udem.edu.co