A brief discussion of the magnetocaloric effect in thin films of manganite doped with chromium
In this work we report on the magnetocaloric effect of La2/3Ca1/3MnO3 (LCMO) and La2/3Ca1/3Mn0.94Cr0.06O3 (LCMCrO) manganite thin films grown by DC magnetron sputtering on LaAlO3 (100) substrates. X-ray diffraction shows that both doped and undoped films crystallize in the orthorhombic structure. Ma...
- Autores:
- Tipo de recurso:
- Fecha de publicación:
- 2019
- Institución:
- Universidad de Medellín
- Repositorio:
- Repositorio UDEM
- Idioma:
- eng
- OAI Identifier:
- oai:repository.udem.edu.co:11407/5754
- Acceso en línea:
- http://hdl.handle.net/11407/5754
- Palabra clave:
- Aluminum compounds
Chromium
Circular dichroism spectroscopy
Dichroism
Engineering research
Entropy
Lanthanum compounds
Magnetic materials
Magnetocaloric effects
Manganites
Saturation magnetization
X ray absorption spectroscopy
Antiferromagnetic coupling
Dc magnetron sputtering
Magnetic interactions
Manganite thin films
Orthorhombic structures
Paramagnetic transition
Refrigeration cooling
X-ray magnetic circular dichroism
Thin films
- Rights
- License
- http://purl.org/coar/access_right/c_16ec
Summary: | In this work we report on the magnetocaloric effect of La2/3Ca1/3MnO3 (LCMO) and La2/3Ca1/3Mn0.94Cr0.06O3 (LCMCrO) manganite thin films grown by DC magnetron sputtering on LaAlO3 (100) substrates. X-ray diffraction shows that both doped and undoped films crystallize in the orthorhombic structure. Magnetic measurements show a decrease in both the Curie temperature, TC , and the saturation magnetization, MS , for the LCMCrO sample. The change in the magnetic entropy (?Sm ) was extracted from hysteresis loops at different temperatures around the ferromagnetic to paramagnetic transition, displaying a maximum of entropy change (?Sm ) max near TC in both films. Moreover, a shift in (?Sm ) max toward temperatures above TC with increasing magnetic field and a broadening of the entropy change curve were observed. Results of refrigeration cooling power show a lower efficiency for LCMCrO. In order to obtain a local insight into the magnetic interactions of these films, measurements of X-ray absorption spectroscopy and X-ray magnetic circular dichroism (XMCD) were performed. XMCD suggests that an antiferromagnetic coupling between Mn4+ - Mn3+ is favored with Cr3+ incorporation, which reduces the Mn L 2,3 XMCD signal and results in a decrease of MS and (?Sm ) max in LCMCrO films. © Published under licence by IOP Publishing Ltd. |
---|