Dry-co-grinding of doped TiO2 with nitrogen, silicon or selenium for enhanced photocatalytic activity under UV/visible and visible light irradiation for environmental applications
TiO2 doped with nitrogen (N), silicon (Si), or selenium (Se) (N-TiO2, Si-TiO2, and Se-TiO2) were obtained by the integrated sol-gel and solvothermal method with short time of crystallization and low temperature. The UV/visible and visible light absorption and photocatalytic activity of these doped T...
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- 2019
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Dry-co-grinding of doped TiO2 with nitrogen, silicon or selenium for enhanced photocatalytic activity under UV/visible and visible light irradiation for environmental applications |
| title |
Dry-co-grinding of doped TiO2 with nitrogen, silicon or selenium for enhanced photocatalytic activity under UV/visible and visible light irradiation for environmental applications |
| spellingShingle |
Dry-co-grinding of doped TiO2 with nitrogen, silicon or selenium for enhanced photocatalytic activity under UV/visible and visible light irradiation for environmental applications |
| title_short |
Dry-co-grinding of doped TiO2 with nitrogen, silicon or selenium for enhanced photocatalytic activity under UV/visible and visible light irradiation for environmental applications |
| title_full |
Dry-co-grinding of doped TiO2 with nitrogen, silicon or selenium for enhanced photocatalytic activity under UV/visible and visible light irradiation for environmental applications |
| title_fullStr |
Dry-co-grinding of doped TiO2 with nitrogen, silicon or selenium for enhanced photocatalytic activity under UV/visible and visible light irradiation for environmental applications |
| title_full_unstemmed |
Dry-co-grinding of doped TiO2 with nitrogen, silicon or selenium for enhanced photocatalytic activity under UV/visible and visible light irradiation for environmental applications |
| title_sort |
Dry-co-grinding of doped TiO2 with nitrogen, silicon or selenium for enhanced photocatalytic activity under UV/visible and visible light irradiation for environmental applications |
| description |
TiO2 doped with nitrogen (N), silicon (Si), or selenium (Se) (N-TiO2, Si-TiO2, and Se-TiO2) were obtained by the integrated sol-gel and solvothermal method with short time of crystallization and low temperature. The UV/visible and visible light absorption and photocatalytic activity of these doped TiO2 materials were improved by a dry-co-grinding process with a short grinding time and low rotational speed (30 min at 200 rpm) to obtain N-TiO2/Si-TiO2 and N-TiO2/Se-TiO2 catalysts. The materials were characterized by XRD, Raman, BET surface area and porosity, XRF, SEM, TEM, FTIR-ATR, and UV/vis-DRS analyses. The photocatalytic activity of these materials was evaluated by the degradation of phenol under UV/visible and visible light irradiation. The integrated sol-gel and solvothermal methods with short time of crystallization (2 h) and low temperature (225 °C), and the dry-co-grinding process during 30 min at 200 rpm led to materials (N-TiO2/Si-TiO2 and N-TiO2/Se-TiO2) with higher specific surface area, a reduction in the band gap value, and an enhancement of the absorption in the visible light spectrum. Moreover, N-TiO2/Si-TiO2 and N-TiO2/Se-TiO2 exhibited higher photocatalytic activities for degradation of phenol under UV/visible and visible light irradiation than those obtained with the doped TiO2, synthesized TiO2 or TiO2 P25. © 2018 Elsevier Ltd |
| publishDate |
2019 |
| dc.date.accessioned.none.fl_str_mv |
2021-02-05T14:59:04Z |
| dc.date.available.none.fl_str_mv |
2021-02-05T14:59:04Z |
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2019 |
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Article |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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http://purl.org/coar/resource_type/c_6501 http://purl.org/coar/resource_type/c_2df8fbb1 |
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info:eu-repo/semantics/article |
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13698001 |
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http://hdl.handle.net/11407/6067 |
| dc.identifier.doi.none.fl_str_mv |
10.1016/j.mssp.2018.10.032 |
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13698001 10.1016/j.mssp.2018.10.032 |
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http://hdl.handle.net/11407/6067 |
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eng |
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eng |
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https://www.scopus.com/inward/record.uri?eid=2-s2.0-85056447917&doi=10.1016%2fj.mssp.2018.10.032&partnerID=40&md5=6f1257beec245a025044bbf8ddc0b7c3 |
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91 |
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Eng., 136, pp. 31-35 Bergamonti, L., Predieri, G., Paz, Y., Fornasini, L., Lottici, P.P., Bondioli, F., Enhanced self-cleaning properties of N-doped TiO2 coating for cultural heritage (2017) Microchem. J., 133, pp. 1-12 Bui, D., Kang, S., Li, X., Mu, J., Effect of Si doping on the photocatalytic activity and photoelectrochemical property of TiO2 nanoparticles (2011) Catal. Commun., 13, pp. 14-17 Cheng, X., Yu, X., Xing, Z., Wan, J., Enhanced photocatalytic activity of nitrogen doped TiO2 anatase nano-particles under simulated sunlight irradiation (2012) Energy Procedia, 16, pp. 598-605 Chi, B., Zhao, L., Jin, T., One-step template-free route for synthesis of mesoporous N-doped titania spheres (2007) J. Phys. Chem. C, 11, pp. 6189-6193 Chong, M., Jin, B., Chow, C., Saint, C., Recent development in photocatalytic water treatment technology: a review (2010) Water Res., 44, pp. 2997-3027 Choi, H., Jung, Y., Kim, S., Size effects in the raman spectra of TiO2 nanoparticles (2005) Vib. Spectrosc., 37, pp. 33-38 Dong, H., Zeng, G., Tang, L., Fan, C., Zhang, C., He, X., He, Y., An overview on limitations of TiO2-based particles for photocatalytic degradation of organic pollutants and the corresponding countermeasures (2015) Water Res., 79, pp. 128-146 Du, J., Li, X., Li, K., Gu, X., Qi, W., Zhang, K., High hydrophilic Si-doped nanowires by chemical vapor deposition (2016) J. Alloy. Compd., 687, pp. 893-897 Du, J., Zhao, G., Shi, Y., Yang, H., Li, Y., Zhu, G., Mao, Y., Wang, W., A facile method for synthesis of N-doped TiO2 nanooctahedra, nanoparticles, and nanospheres and enhanced photocatalytic activity (2013) Appl. Surf. Sci., 273, pp. 278-286 Estruga, M., Domingo, C., Doménech, X., Ayllón, J., Zirconium-doped and silicon-doped TiO2 photocatalysts synthesis from ionic-liquid-like precursors (2010) J. Colloid Interface Sci., 344, pp. 327-333 Fang, W., Xing, M., Zhang, J., Modifications on reduced titanium dioxide photocatalysts: a review (2017) J. Photochem. 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Elsevier Ltd |
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Ingeniería Ambiental |
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Elsevier Ltd |
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Materials Science in Semiconductor Processing |
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20192021-02-05T14:59:04Z2021-02-05T14:59:04Z13698001http://hdl.handle.net/11407/606710.1016/j.mssp.2018.10.032TiO2 doped with nitrogen (N), silicon (Si), or selenium (Se) (N-TiO2, Si-TiO2, and Se-TiO2) were obtained by the integrated sol-gel and solvothermal method with short time of crystallization and low temperature. The UV/visible and visible light absorption and photocatalytic activity of these doped TiO2 materials were improved by a dry-co-grinding process with a short grinding time and low rotational speed (30 min at 200 rpm) to obtain N-TiO2/Si-TiO2 and N-TiO2/Se-TiO2 catalysts. The materials were characterized by XRD, Raman, BET surface area and porosity, XRF, SEM, TEM, FTIR-ATR, and UV/vis-DRS analyses. The photocatalytic activity of these materials was evaluated by the degradation of phenol under UV/visible and visible light irradiation. The integrated sol-gel and solvothermal methods with short time of crystallization (2 h) and low temperature (225 °C), and the dry-co-grinding process during 30 min at 200 rpm led to materials (N-TiO2/Si-TiO2 and N-TiO2/Se-TiO2) with higher specific surface area, a reduction in the band gap value, and an enhancement of the absorption in the visible light spectrum. Moreover, N-TiO2/Si-TiO2 and N-TiO2/Se-TiO2 exhibited higher photocatalytic activities for degradation of phenol under UV/visible and visible light irradiation than those obtained with the doped TiO2, synthesized TiO2 or TiO2 P25. © 2018 Elsevier LtdengElsevier LtdIngeniería AmbientalFacultad de Ingenieríashttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85056447917&doi=10.1016%2fj.mssp.2018.10.032&partnerID=40&md5=6f1257beec245a025044bbf8ddc0b7c3914757Akpan, U., Hameed, B.H., The advances in sol-gel method of doped-TiO2 photocatalyst (2017) Appl. Catal. A: Gen., 375, pp. 1-11Ali, M., Transformation and powder characteristics of TiO2 during high-energy milling (2014) Ceram. Process. Res., 15, pp. 290-293Aman, N., Das, N.N., Mishra, T., Effect of N-doping on visible light activity of TiO2-SiO2 mixed oxide photocatalyst (2016) J. Environ. Chem. Eng., 4, pp. 191-196Appavu, B., Thiripuranthagan, S., Visible active N, S codoped TiO2/graphite photocatalyst for the degradation of hazardous dyes (2017) J. Photochem. Photobiol. A: Chem., 340, pp. 146-156Asiah, M.N., Mamat, M.H., Khusaimi, Z., Abdullah, S., Rusop, M., Qurashi, Z., Structural and optical properties of hydrothermally synthesized mesoporous Si/TiO2 nanowire composites (2015) Microelectron. Eng., 136, pp. 31-35Bergamonti, L., Predieri, G., Paz, Y., Fornasini, L., Lottici, P.P., Bondioli, F., Enhanced self-cleaning properties of N-doped TiO2 coating for cultural heritage (2017) Microchem. J., 133, pp. 1-12Bui, D., Kang, S., Li, X., Mu, J., Effect of Si doping on the photocatalytic activity and photoelectrochemical property of TiO2 nanoparticles (2011) Catal. Commun., 13, pp. 14-17Cheng, X., Yu, X., Xing, Z., Wan, J., Enhanced photocatalytic activity of nitrogen doped TiO2 anatase nano-particles under simulated sunlight irradiation (2012) Energy Procedia, 16, pp. 598-605Chi, B., Zhao, L., Jin, T., One-step template-free route for synthesis of mesoporous N-doped titania spheres (2007) J. Phys. Chem. C, 11, pp. 6189-6193Chong, M., Jin, B., Chow, C., Saint, C., Recent development in photocatalytic water treatment technology: a review (2010) Water Res., 44, pp. 2997-3027Choi, H., Jung, Y., Kim, S., Size effects in the raman spectra of TiO2 nanoparticles (2005) Vib. Spectrosc., 37, pp. 33-38Dong, H., Zeng, G., Tang, L., Fan, C., Zhang, C., He, X., He, Y., An overview on limitations of TiO2-based particles for photocatalytic degradation of organic pollutants and the corresponding countermeasures (2015) Water Res., 79, pp. 128-146Du, J., Li, X., Li, K., Gu, X., Qi, W., Zhang, K., High hydrophilic Si-doped nanowires by chemical vapor deposition (2016) J. Alloy. Compd., 687, pp. 893-897Du, J., Zhao, G., Shi, Y., Yang, H., Li, Y., Zhu, G., Mao, Y., Wang, W., A facile method for synthesis of N-doped TiO2 nanooctahedra, nanoparticles, and nanospheres and enhanced photocatalytic activity (2013) Appl. Surf. Sci., 273, pp. 278-286Estruga, M., Domingo, C., Doménech, X., Ayllón, J., Zirconium-doped and silicon-doped TiO2 photocatalysts synthesis from ionic-liquid-like precursors (2010) J. Colloid Interface Sci., 344, pp. 327-333Fang, W., Xing, M., Zhang, J., Modifications on reduced titanium dioxide photocatalysts: a review (2017) J. Photochem. Photobiol. 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Sci., 60, pp. 1447-1457Materials Science in Semiconductor ProcessingDry-co-grinding of doped TiO2 with nitrogen, silicon or selenium for enhanced photocatalytic activity under UV/visible and visible light irradiation for environmental applicationsArticleinfo:eu-repo/semantics/articlehttp://purl.org/coar/version/c_970fb48d4fbd8a85http://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Galeano, L., Grupo de Investigaciones y Mediciones Ambientales (GEMA), Universidad de Medellín, Carrera 87 No 30-65, Medellín, Colombia, Grupo Procesos Fisicoquímicos Aplicados, Departamento de Ingeniería Química, Facultad de Ingeniería, Sede de Investigación Universit:aria, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín, ColombiaValencia, S., Grupo de investigación Integra, Tecnológico de Antioquia, Calle 78B No 72A-220, Medellín, Colombia, Grupo Procesos Fisicoquímicos Aplicados, Departamento de Ingeniería Química, Facultad de Ingeniería, Sede de Investigación Universit:aria, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín, ColombiaRestrepo, G., Grupo Procesos Fisicoquímicos Aplicados, Departamento de Ingeniería Química, Facultad de Ingeniería, Sede de Investigación Universit:aria, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín, ColombiaMarín, J.M., Grupo Procesos Fisicoquímicos Aplicados, Departamento de Ingeniería Química, Facultad de Ingeniería, Sede de Investigación Universit:aria, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín, Colombiahttp://purl.org/coar/access_right/c_16ecGaleano L.Valencia S.Restrepo G.Marín J.M.11407/6067oai:repository.udem.edu.co:11407/60672021-02-05 09:59:04.972Repositorio Institucional Universidad de Medellinrepositorio@udem.edu.co |