Nature in corrosion–erosion surface for [TiN/TiAlN]n nanometric multilayers growth on AISI 1045 steel
The aim of this work is to characterize the electrochemical behavior of [TiN/TiAlN]n multilayer coatings under corrosion–erosion condition. The multilayers with bilayer numbers (n) of 2, 6, 12, and 24 and/or bilayer period (Λ) of 1500 nm, 500 nm, 250 nm, 150 nm and 125 nm were deposited by magnetron...
- Autores:
-
Caicedo Angulo, Julio Cesar
Cabrera Cifuentes, Gerardo
Caicedo, H.H.
Amaya, César
Aperador, William
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2012
- Institución:
- Universidad Autónoma de Occidente
- Repositorio:
- RED: Repositorio Educativo Digital UAO
- Idioma:
- eng
- OAI Identifier:
- oai:red.uao.edu.co:10614/12164
- Acceso en línea:
- http://red.uao.edu.co//handle/10614/12164
https://doi.org/10.1016/j.tsf.2012.02.061
- Palabra clave:
- Hard coatings
Wear
Multilayers
Tafel
Corrosion–erosion
- Rights
- openAccess
- License
- Derechos Reservados - Elsevier, 2012
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Nature in corrosion–erosion surface for [TiN/TiAlN]n nanometric multilayers growth on AISI 1045 steel |
| title |
Nature in corrosion–erosion surface for [TiN/TiAlN]n nanometric multilayers growth on AISI 1045 steel |
| spellingShingle |
Nature in corrosion–erosion surface for [TiN/TiAlN]n nanometric multilayers growth on AISI 1045 steel Hard coatings Wear Multilayers Tafel Corrosion–erosion |
| title_short |
Nature in corrosion–erosion surface for [TiN/TiAlN]n nanometric multilayers growth on AISI 1045 steel |
| title_full |
Nature in corrosion–erosion surface for [TiN/TiAlN]n nanometric multilayers growth on AISI 1045 steel |
| title_fullStr |
Nature in corrosion–erosion surface for [TiN/TiAlN]n nanometric multilayers growth on AISI 1045 steel |
| title_full_unstemmed |
Nature in corrosion–erosion surface for [TiN/TiAlN]n nanometric multilayers growth on AISI 1045 steel |
| title_sort |
Nature in corrosion–erosion surface for [TiN/TiAlN]n nanometric multilayers growth on AISI 1045 steel |
| dc.creator.fl_str_mv |
Caicedo Angulo, Julio Cesar Cabrera Cifuentes, Gerardo Caicedo, H.H. Amaya, César Aperador, William |
| dc.contributor.author.none.fl_str_mv |
Caicedo Angulo, Julio Cesar Cabrera Cifuentes, Gerardo Caicedo, H.H. Amaya, César Aperador, William |
| dc.subject.proposal.eng.fl_str_mv |
Hard coatings Wear Multilayers Tafel Corrosion–erosion |
| topic |
Hard coatings Wear Multilayers Tafel Corrosion–erosion |
| description |
The aim of this work is to characterize the electrochemical behavior of [TiN/TiAlN]n multilayer coatings under corrosion–erosion condition. The multilayers with bilayer numbers (n) of 2, 6, 12, and 24 and/or bilayer period (Λ) of 1500 nm, 500 nm, 250 nm, 150 nm and 125 nm were deposited by magnetron sputtering technique on Si (100) and AISI 1045 steel substrates. Both, the TiN and the TiAlN structures for multilayer coatings were evaluated via X-ray diffraction analysis. Mechanical and tribological properties were evaluated via nanoindentation measurements and scratch test respectively. Silica particles were used as abrasive material on corrosion–erosion test in 0.5 M of H2SO4 solution at impact angles of 30° and 90° over surface. The electrochemical characterization was carried out using polarization resistance technique (Tafel), in order to observe changes in corrosion rate as a function of the bilayer number (n) or the bilayer period (Λ) and the impact angle. Corrosion rate values of 9115 μm y for uncoated steel substrate and 2615 μm y for substrate coated with n = 24 (Λ = 125 nm) under an impact angle of 30° were found. On the other hand, for an impact angle of 90° the corrosion rate exhibited 16401 μm y for uncoated steel substrate and 5331 μm y for substrate coated with n = 24 (Λ = 125 nm). This behavior was correlated with the curves of mass loss for both coated samples and the surface damage was analyzed via scanning electron microscopy images for the two different impact angles. These results indicate that TiN/TiAlN multilayer coatings deposited on AISI 1045 steel represent a practical solution for applications in corrosive–erosive environments |
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2012 |
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2012-04 |
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2020-03-25T18:02:54Z |
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2020-03-25T18:02:54Z |
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0040-6090 |
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http://red.uao.edu.co//handle/10614/12164 |
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https://doi.org/10.1016/j.tsf.2012.02.061 |
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Universidad Autónoma de Occidente |
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Repositorio Educativo Digital |
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eng |
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eng |
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Thin Solid Films. Volumen 520, número 13, (abril 2012); páginas 4350-4361 |
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4361 |
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13 |
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4350 |
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520 |
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Caicedo Angulo, J. C., Cabrera, G., Caicedo, H.H., Amaya, C., Aperador, W. (2012). Nature in corrosion–erosion surface for [TiN/TiAlN]n nanometric multilayers growth on AISI 1045 steel. Thin Solid Films. 520(13), 4350-4361. http://red.uao.edu.co//handle/10614/12164 |
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Thin Solid Films |
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L.R. Katipelli, A. Agarwal, N.B. Dahotre Mater. Sci. Eng., A, 289 (2000), p. 34 U. Helmersson, S. Todovora, S.A. Barnett, J.S. Sundgren, H. Markett, J.E. Greene J. Appl. Phys., 62 (1987), p. 481 C.J. Tabares, L. Rebouta, B. Almeida, J. Bessa e Sousa, M.F. da Silva, J.C. Soares Thin Solid Films, 317 (1998), p. 124 J.C. Caicedo, C. Amaya, L. Yate, W. Aperador, G. Zambrano, M.E. Gómez, J. Alvarado-Rivera, J. Muñoz-Saldaña, P. Prieto Appl. Surf. Sci., 256 (2010), p. 2876 L. Yate, J.C. Caicedo, A. Hurtado Macias, F.J. Espinoza-Beltrán, G. Zambrano, J. Muñoz-Saldaña, P. Prieto Surf. Coat. Technol., 203 (2009), p. 1904 C. Amaya, W. Aperador, J.C. Caicedo, F.J. Espinoza-Beltrán, J. Muñoz-Saldaña, G. Zambrano, P. Prieto Corros. Sci., 51 (2009), p. 2994 J.C. Caicedo, C. Amaya, L. Yate, O. Nos, M.E. Gómez, P. Prieto Mater. Sci. Eng., B, 171 (2010), p. 56 J.C. Caicedo, C. Amaya, L. Yate, G. Zambrano, M.E. Gómez, J. Alvarado-Rivera, J. Muñoz-Saldaña, P. Prieto Appl. Surf. Sci., 256 (2010), p. 5898 V. Braic, M. Balaceanu, M. Braic, A. Vladescu Rom. Rep. Phys., 56 (2004), p. 3481 N.J.M. Carvalho, E. Zoestbergen, B.J. Kooi, J.Th.M. De Hosson Thin Solid Films, 429 (2003), p. 179 B.K. Tay, X. Shi, H.S. Yang, H.S. Tan, Daniel Chua, S.Y. Teo Surf. Coat. Technol., 111 (1999), p. 229 S.H.N. Lim, D.G. McCulloch, M.M. MBilek, D. RMcKenzie, S.P. Russo, A.S. Barnard, A. Torpy J. Phys. Condens. Matter, 17 (2005), p. 2791 J. Romero, A. Lousa, E. Martínez, J. Esteve Surf. Coat. Technol., 163–164 (2003), p. 392 Z.R. Wasilewski, S. Fafard, J.P. McCaffrey J. Cryst. Growth, 201/202 (1999), p. 1131 S.J. Bull, A.M. Jones Surf. Coat. Technol., 78 (1996), p. 173 G. Cabrera, J.C. Caicedo, C. Amaya, L. Yate, J. Muñoz Saldaña, P. Prieto Mater. Chem. Phys., 125 (2011), p. 576 H. Moreno, J.C. Caicedo, C. Amaya, J. Muñoz-Saldaña, L. Yate, J. Esteve, P. Prieto Appl. Surf. Sci., 257 (2010), p. 1098 L. Ipaz, J.C. Caicedo, J. Esteve, F.J. Espinoza-Beltran, G. Zambrano Applied Surface Science, 258 (2012), pp. 3805-3814 M. Fenker, M. Balzer, H.A. Jehn, H. Kappl, J.-J. Lee, K.-H. Lee, H.-S. Park Surf. Coat. Technol., 150 (2002), p. 101 P.V. Nazarenko, A.G. Molyar, I.E. Polishchuk, O.G. Yachinskaya, A. Il'in Met. Sci. Heat Treat., 32 (4) (1990), p. 305 M. Stern, A.L. Geary J. Electrochem. Soc., 104 (1957), p. 56 V.K. William Harish, C. Barshilia, V. Ezhil Selvi, Kalavati, K.S. Rajam Thin Solid Films, 514 (2006), p. 204 J.C. Caicedo, C. Amaya, G. Cabrera, J. Esteve, W. Aperador, M.E. Gómez, P. Prieto Thin Solid Films, 519 (2011), p. 6362 |
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Caicedo Angulo, Julio Cesar588c46af99ce16873a825719b0613777Cabrera Cifuentes, Gerardoaa1138802f76e38083bc4df921b7fe7fCaicedo, H.H.7b38b3d5b3995e592409855232ae6611Amaya, César0d71ec06608452d3b1d9e3d811348b8cAperador, William22f23595993c3e95414c1bb06d41b3b12020-03-25T18:02:54Z2020-03-25T18:02:54Z2012-040040-6090http://red.uao.edu.co//handle/10614/12164https://doi.org/10.1016/j.tsf.2012.02.061Universidad Autónoma de OccidenteRepositorio Educativo DigitalThe aim of this work is to characterize the electrochemical behavior of [TiN/TiAlN]n multilayer coatings under corrosion–erosion condition. The multilayers with bilayer numbers (n) of 2, 6, 12, and 24 and/or bilayer period (Λ) of 1500 nm, 500 nm, 250 nm, 150 nm and 125 nm were deposited by magnetron sputtering technique on Si (100) and AISI 1045 steel substrates. Both, the TiN and the TiAlN structures for multilayer coatings were evaluated via X-ray diffraction analysis. Mechanical and tribological properties were evaluated via nanoindentation measurements and scratch test respectively. Silica particles were used as abrasive material on corrosion–erosion test in 0.5 M of H2SO4 solution at impact angles of 30° and 90° over surface. The electrochemical characterization was carried out using polarization resistance technique (Tafel), in order to observe changes in corrosion rate as a function of the bilayer number (n) or the bilayer period (Λ) and the impact angle. Corrosion rate values of 9115 μm y for uncoated steel substrate and 2615 μm y for substrate coated with n = 24 (Λ = 125 nm) under an impact angle of 30° were found. On the other hand, for an impact angle of 90° the corrosion rate exhibited 16401 μm y for uncoated steel substrate and 5331 μm y for substrate coated with n = 24 (Λ = 125 nm). This behavior was correlated with the curves of mass loss for both coated samples and the surface damage was analyzed via scanning electron microscopy images for the two different impact angles. These results indicate that TiN/TiAlN multilayer coatings deposited on AISI 1045 steel represent a practical solution for applications in corrosive–erosive environmentsapplication/pdf12 páginasengElsevierThin Solid Films. Volumen 520, número 13, (abril 2012); páginas 4350-43614361134350520Caicedo Angulo, J. C., Cabrera, G., Caicedo, H.H., Amaya, C., Aperador, W. (2012). Nature in corrosion–erosion surface for [TiN/TiAlN]n nanometric multilayers growth on AISI 1045 steel. Thin Solid Films. 520(13), 4350-4361. http://red.uao.edu.co//handle/10614/12164Thin Solid FilmsL.R. Katipelli, A. Agarwal, N.B. Dahotre Mater. Sci. Eng., A, 289 (2000), p. 34U. Helmersson, S. Todovora, S.A. Barnett, J.S. Sundgren, H. Markett, J.E. Greene J. Appl. Phys., 62 (1987), p. 481C.J. Tabares, L. Rebouta, B. Almeida, J. Bessa e Sousa, M.F. da Silva, J.C. Soares Thin Solid Films, 317 (1998), p. 124J.C. Caicedo, C. Amaya, L. Yate, W. Aperador, G. Zambrano, M.E. Gómez, J. Alvarado-Rivera, J. Muñoz-Saldaña, P. Prieto Appl. Surf. Sci., 256 (2010), p. 2876L. Yate, J.C. Caicedo, A. Hurtado Macias, F.J. Espinoza-Beltrán, G. Zambrano, J. Muñoz-Saldaña, P. Prieto Surf. Coat. Technol., 203 (2009), p. 1904C. Amaya, W. Aperador, J.C. Caicedo, F.J. Espinoza-Beltrán, J. Muñoz-Saldaña, G. Zambrano, P. Prieto Corros. Sci., 51 (2009), p. 2994J.C. Caicedo, C. Amaya, L. Yate, O. Nos, M.E. Gómez, P. Prieto Mater. Sci. Eng., B, 171 (2010), p. 56J.C. Caicedo, C. Amaya, L. Yate, G. Zambrano, M.E. Gómez, J. Alvarado-Rivera, J. Muñoz-Saldaña, P. Prieto Appl. Surf. Sci., 256 (2010), p. 5898V. Braic, M. Balaceanu, M. Braic, A. Vladescu Rom. Rep. Phys., 56 (2004), p. 3481N.J.M. Carvalho, E. Zoestbergen, B.J. Kooi, J.Th.M. De Hosson Thin Solid Films, 429 (2003), p. 179B.K. Tay, X. Shi, H.S. Yang, H.S. Tan, Daniel Chua, S.Y. Teo Surf. Coat. Technol., 111 (1999), p. 229S.H.N. Lim, D.G. McCulloch, M.M. MBilek, D. RMcKenzie, S.P. Russo, A.S. Barnard, A. Torpy J. Phys. Condens. Matter, 17 (2005), p. 2791J. Romero, A. Lousa, E. Martínez, J. Esteve Surf. Coat. Technol., 163–164 (2003), p. 392Z.R. Wasilewski, S. Fafard, J.P. McCaffrey J. Cryst. Growth, 201/202 (1999), p. 1131S.J. Bull, A.M. Jones Surf. Coat. Technol., 78 (1996), p. 173G. Cabrera, J.C. Caicedo, C. Amaya, L. Yate, J. Muñoz Saldaña, P. Prieto Mater. Chem. Phys., 125 (2011), p. 576H. Moreno, J.C. Caicedo, C. Amaya, J. Muñoz-Saldaña, L. Yate, J. Esteve, P. Prieto Appl. Surf. Sci., 257 (2010), p. 1098L. Ipaz, J.C. Caicedo, J. Esteve, F.J. Espinoza-Beltran, G. Zambrano Applied Surface Science, 258 (2012), pp. 3805-3814M. Fenker, M. Balzer, H.A. Jehn, H. Kappl, J.-J. Lee, K.-H. Lee, H.-S. Park Surf. Coat. Technol., 150 (2002), p. 101P.V. Nazarenko, A.G. Molyar, I.E. Polishchuk, O.G. Yachinskaya, A. Il'in Met. Sci. Heat Treat., 32 (4) (1990), p. 305M. Stern, A.L. Geary J. Electrochem. Soc., 104 (1957), p. 56V.K. William Harish, C. Barshilia, V. Ezhil Selvi, Kalavati, K.S. Rajam Thin Solid Films, 514 (2006), p. 204J.C. Caicedo, C. Amaya, G. Cabrera, J. Esteve, W. Aperador, M.E. Gómez, P. Prieto Thin Solid Films, 519 (2011), p. 6362Derechos Reservados - Elsevier, 2012https://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessAtribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)http://purl.org/coar/access_right/c_abf2Nature in corrosion–erosion surface for [TiN/TiAlN]n nanometric multilayers growth on AISI 1045 steelArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTREFinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Hard coatingsWearMultilayersTafelCorrosion–erosionPublicationCC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8805https://dspace7-uao.metacatalogo.com/bitstreams/454b1b7f-97e6-4866-89e7-dc330e934278/download4460e5956bc1d1639be9ae6146a50347MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81665https://dspace7-uao.metacatalogo.com/bitstreams/571a23c6-c31f-4039-9ae9-1ca6da1e4f77/download20b5ba22b1117f71589c7318baa2c560MD5310614/12164oai:dspace7-uao.metacatalogo.com:10614/121642024-01-19 16:02:16.834https://creativecommons.org/licenses/by-nc-nd/4.0/Derechos Reservados - Elsevier, 2012metadata.onlyhttps://dspace7-uao.metacatalogo.comRepositorio UAOrepositorio@uao.edu.coRUwgQVVUT1IgYXV0b3JpemEgYSBsYSBVbml2ZXJzaWRhZCBBdXTDs25vbWEgZGUgT2NjaWRlbnRlLCBkZSBmb3JtYSBpbmRlZmluaWRhLCBwYXJhIHF1ZSBlbiBsb3MgdMOpcm1pbm9zIGVzdGFibGVjaWRvcyBlbiBsYSBMZXkgMjMgZGUgMTk4MiwgbGEgTGV5IDQ0IGRlIDE5OTMsIGxhIERlY2lzacOzbiBhbmRpbmEgMzUxIGRlIDE5OTMsIGVsIERlY3JldG8gNDYwIGRlIDE5OTUgeSBkZW3DoXMgbGV5ZXMgeSBqdXJpc3BydWRlbmNpYSB2aWdlbnRlIGFsIHJlc3BlY3RvLCBoYWdhIHB1YmxpY2FjacOzbiBkZSBlc3RlIGNvbiBmaW5lcyBlZHVjYXRpdm9zLiBQQVJBR1JBRk86IEVzdGEgYXV0b3JpemFjacOzbiBhZGVtw6FzIGRlIHNlciB2w6FsaWRhIHBhcmEgbGFzIGZhY3VsdGFkZXMgeSBkZXJlY2hvcyBkZSB1c28gc29icmUgbGEgb2JyYSBlbiBmb3JtYXRvIG8gc29wb3J0ZSBtYXRlcmlhbCwgdGFtYmnDqW4gcGFyYSBmb3JtYXRvIGRpZ2l0YWwsIGVsZWN0csOzbmljbywgdmlydHVhbCwgcGFyYSB1c29zIGVuIHJlZCwgSW50ZXJuZXQsIGV4dHJhbmV0LCBpbnRyYW5ldCwgYmlibGlvdGVjYSBkaWdpdGFsIHkgZGVtw6FzIHBhcmEgY3VhbHF1aWVyIGZvcm1hdG8gY29ub2NpZG8gbyBwb3IgY29ub2Nlci4gRUwgQVVUT1IsIGV4cHJlc2EgcXVlIGVsIGRvY3VtZW50byAodHJhYmFqbyBkZSBncmFkbywgcGFzYW50w61hLCBjYXNvcyBvIHRlc2lzKSBvYmpldG8gZGUgbGEgcHJlc2VudGUgYXV0b3JpemFjacOzbiBlcyBvcmlnaW5hbCB5IGxhIGVsYWJvcsOzIHNpbiBxdWVicmFudGFyIG5pIHN1cGxhbnRhciBsb3MgZGVyZWNob3MgZGUgYXV0b3IgZGUgdGVyY2Vyb3MsIHkgZGUgdGFsIGZvcm1hLCBlbCBkb2N1bWVudG8gKHRyYWJham8gZGUgZ3JhZG8sIHBhc2FudMOtYSwgY2Fzb3MgbyB0ZXNpcykgZXMgZGUgc3UgZXhjbHVzaXZhIGF1dG9yw61hIHkgdGllbmUgbGEgdGl0dWxhcmlkYWQgc29icmUgw6lzdGUuIFBBUkFHUkFGTzogZW4gY2FzbyBkZSBwcmVzZW50YXJzZSBhbGd1bmEgcmVjbGFtYWNpw7NuIG8gYWNjacOzbiBwb3IgcGFydGUgZGUgdW4gdGVyY2VybywgcmVmZXJlbnRlIGEgbG9zIGRlcmVjaG9zIGRlIGF1dG9yIHNvYnJlIGVsIGRvY3VtZW50byAoVHJhYmFqbyBkZSBncmFkbywgUGFzYW50w61hLCBjYXNvcyBvIHRlc2lzKSBlbiBjdWVzdGnDs24sIEVMIEFVVE9SLCBhc3VtaXLDoSBsYSByZXNwb25zYWJpbGlkYWQgdG90YWwsIHkgc2FsZHLDoSBlbiBkZWZlbnNhIGRlIGxvcyBkZXJlY2hvcyBhcXXDrSBhdXRvcml6YWRvczsgcGFyYSB0b2RvcyBsb3MgZWZlY3RvcywgbGEgVW5pdmVyc2lkYWQgIEF1dMOzbm9tYSBkZSBPY2NpZGVudGUgYWN0w7phIGNvbW8gdW4gdGVyY2VybyBkZSBidWVuYSBmZS4gVG9kYSBwZXJzb25hIHF1ZSBjb25zdWx0ZSB5YSBzZWEgZW4gbGEgYmlibGlvdGVjYSBvIGVuIG1lZGlvIGVsZWN0csOzbmljbyBwb2Ryw6EgY29waWFyIGFwYXJ0ZXMgZGVsIHRleHRvIGNpdGFuZG8gc2llbXByZSBsYSBmdWVudGUsIGVzIGRlY2lyIGVsIHTDrXR1bG8gZGVsIHRyYWJham8geSBlbCBhdXRvci4gRXN0YSBhdXRvcml6YWNpw7NuIG5vIGltcGxpY2EgcmVudW5jaWEgYSBsYSBmYWN1bHRhZCBxdWUgdGllbmUgRUwgQVVUT1IgZGUgcHVibGljYXIgdG90YWwgbyBwYXJjaWFsbWVudGUgbGEgb2JyYS4K |