Actividad catalítica de complejos de rodio (I) con ligandos bidentados a base de fósforo en reacciones de hidroformilación de limoneno
We have prepared the com¬plexes RhCl(dppe)2, RhCl(dppp)2 and RhCl(dppb)2, where dppe = diphenylphosphinoethane; dppp = diphenylphosphinopropane; dppb = diphenylphosphinobutane. The above complexes were used as catalytic precursor in the hydroformylation of limonene at differents concentrations and t...
- Autores:
-
Montalvo, Liliana
Bolaños Rivera, Alberto
Cabrera, Armando
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2007
- Institución:
- Universidad Autónoma de Occidente
- Repositorio:
- RED: Repositorio Educativo Digital UAO
- Idioma:
- spa
- OAI Identifier:
- oai:red.uao.edu.co:10614/174
- Acceso en línea:
- http://hdl.handle.net/10614/174
- Palabra clave:
- Catálisis homogénea
Rodio
Homogeneous catalysis
Rhodium
- Rights
- openAccess
- License
- Derechos Reservados - Universidad Autónoma de Occidente
| Summary: | We have prepared the com¬plexes RhCl(dppe)2, RhCl(dppp)2 and RhCl(dppb)2, where dppe = diphenylphosphinoethane; dppp = diphenylphosphinopropane; dppb = diphenylphosphinobutane. The above complexes were used as catalytic precursor in the hydroformylation of limonene at differents concentrations and temperatures. It has found that the best catalytic precursor was the Rhodium complex with dppb as ligand it seems that the P-Rh-P angle is very important in substrate activation |
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