Mössbauer and X-ray study of the Fe 65 Ni 35 invar alloy obtained by mechanical alloying

Fe65Ni35 samples were prepared by mechanical alloying (MA) with milling times of 5, 6, 7, 10 and 11 h, using a ball mass to powder mass ratio of 20:1 and at 280 rpm. The samples were characterized by X-ray diffraction (XRD) and transmission 57Fe Mössbauer spectrometry. The X-ray diffraction pattern showed the coexistence of one body centered cubic (BCC) and two face centered cubic (FCC1 and FCC2) structural phases. The lattice parameters of these phases did not change significantly with the milling time (2.866 Å, 3.597 Å and 3.538 Å, respectively). After 10 h of milling, the X-ray diffraction pattern showed clearly the coexistence of these three phases. Hence, Mössbauer spectrometry measurements at low temperatures from 20 to 300 K of this sample were also carried out. The Mössbauer spectra were fitted using a model with three components: the first one is a hyperfine magnetic field distributions at high fields, related to the BCC phase; the second one is a hyperfine magnetic field distribution involving low hyperfine fields related to a FCC phase rich in Ni, and the third one is a singlet related to a FCC phase rich in Fe, with paramagnetic behavior. As proposed by some authors, the last phase is related with the antitaenite phase

• Autores: Rodríguez Jacobo, Ruby Rocío; Valenzuela, J. L; Tabares Giraldo, Jesús Anselmo; Pérez Alcázar, German Antonio
• Tipo de recurso: Article of journal
• Fecha de publicación: 2013
• Institución: Universidad Autónoma de Occidente
• Repositorio: RED: Repositorio Educativo Digital UAO
• Idioma: spa
• OAI Identifier: oai:red.uao.edu.co:10614/11848
• Acceso en línea: http://hdl.handle.net/10614/11848
• Palabra clave: Aleación mecánica; FeNi; Mechanical alloying; Invar composition; Mössbauer spectrometry
• Rights: openAccess
• License: Derechos Reservados - Universidad Autónoma de Occidente