Natural pozzolan-and granulated blast furnace slag-based binary geopolymers

Geopolímeros de tipo binario basados en una puzolana natural y escoria siderúrgica de alto horno. Este trabajo describe la síntesis a temperatura ambiente (25±3 °C) de sistemas geopoliméricos de tipo binario basados en una puzolana natural de origen volcánico y escoria siderúrgica de alto horno usan...

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Autores:: Gordillo Suárez, Marisol
Robayo Salazar, Rafael Andrés
Mejía De Gutiérrez, Ruby

Tipo de recurso:: Article of journal

Fecha de publicación:: 2016

Institución:: Universidad Autónoma de Occidente

Repositorio:: RED: Repositorio Educativo Digital UAO

Idioma:: eng

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dc.title.eng.fl_str_mv	Natural pozzolan-and granulated blast furnace slag-based binary geopolymers
title	Natural pozzolan-and granulated blast furnace slag-based binary geopolymers
spellingShingle	Natural pozzolan-and granulated blast furnace slag-based binary geopolymers Metales alcalinoterreos Agregados (materiales de construcción) Alkaline earth metals Aggregates (building materials) Cristales de haluros alcalinos Ingeniería industrial Alkaline metal halide, crystals Industrial engineering Cemento activado alcalinamente Puzolana volcánica Escoria siderúrgica de alto horno Resistencia a la compresión Alkaline-activated cement Volcanic pozzolan Blast furnace slag Compressive strength
title_short	Natural pozzolan-and granulated blast furnace slag-based binary geopolymers
title_full	Natural pozzolan-and granulated blast furnace slag-based binary geopolymers
title_fullStr	Natural pozzolan-and granulated blast furnace slag-based binary geopolymers
title_full_unstemmed	Natural pozzolan-and granulated blast furnace slag-based binary geopolymers
title_sort	Natural pozzolan-and granulated blast furnace slag-based binary geopolymers
dc.creator.fl_str_mv	Gordillo Suárez, Marisol Robayo Salazar, Rafael Andrés Mejía De Gutiérrez, Ruby
dc.contributor.author.none.fl_str_mv	Gordillo Suárez, Marisol Robayo Salazar, Rafael Andrés Mejía De Gutiérrez, Ruby
dc.subject.lemb.spa.fl_str_mv	Metales alcalinoterreos Agregados (materiales de construcción)
topic	Metales alcalinoterreos Agregados (materiales de construcción) Alkaline earth metals Aggregates (building materials) Cristales de haluros alcalinos Ingeniería industrial Alkaline metal halide, crystals Industrial engineering Cemento activado alcalinamente Puzolana volcánica Escoria siderúrgica de alto horno Resistencia a la compresión Alkaline-activated cement Volcanic pozzolan Blast furnace slag Compressive strength
dc.subject.lemb.eng.fl_str_mv	Alkaline earth metals Aggregates (building materials)
dc.subject.armarc.spa.fl_str_mv	Cristales de haluros alcalinos Ingeniería industrial
dc.subject.armarc.eng.fl_str_mv	Alkaline metal halide, crystals Industrial engineering
dc.subject.proposal.spa.fl_str_mv	Cemento activado alcalinamente Puzolana volcánica Escoria siderúrgica de alto horno Resistencia a la compresión
dc.subject.proposal.eng.fl_str_mv	Alkaline-activated cement Volcanic pozzolan Blast furnace slag Compressive strength
description	Geopolímeros de tipo binario basados en una puzolana natural y escoria siderúrgica de alto horno. Este trabajo describe la síntesis a temperatura ambiente (25±3 °C) de sistemas geopoliméricos de tipo binario basados en una puzolana natural de origen volcánico y escoria siderúrgica de alto horno usando activadores alcalinos basados en la combinación de Na2SiO3 y NaOH. Se estudió el efecto de la relación SiO2/Al2O3, Na2O/Al2O3 y la cantidad de escoria adicionada en niveles entre el 0 y 30% sobre la cinética de reacción, la resistencia a la compresión y la microestructura del producto final. Para la caracterización de las pastas geopoliméricas se utilizaron técnicas como difracción de rayos X (DRX), espectroscopia infrarroja (FTIR) y microscopia electrónica de barrido (MEB). Los resultados conseguidos revelan la posibilidad de obtener un cementante geopolimérico con una resistencia a la compresión de hasta 48,11 MPa a los 28 días de curado a temperatura ambiente cuyas características son comparables a las de un cemento portland comercial
publishDate	2016
dc.date.issued.none.fl_str_mv	2016-01-18
dc.date.accessioned.none.fl_str_mv	2019-09-09T18:39:04Z
dc.date.available.none.fl_str_mv	2019-09-09T18:39:04Z
dc.type.spa.fl_str_mv	Artículo de revista
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dc.identifier.uri.none.fl_str_mv	http://hdl.handle.net/10614/11072 http://materconstrucc.revistas.csic.es/index.php/materconstrucc/article/view/1979/2422
dc.identifier.doi.spa.fl_str_mv	http://dx.doi.org/10.3989/mc.2016.03615
identifier_str_mv	1988-3226 (en línea)
url	http://hdl.handle.net/10614/11072 http://materconstrucc.revistas.csic.es/index.php/materconstrucc/article/view/1979/2422 http://dx.doi.org/10.3989/mc.2016.03615
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dc.relation.spa.fl_str_mv	Materiales de Construcción, volumen 66, número 321, páginas 077, (january-march, 2016)
dc.relation.citationedition.spa.fl_str_mv	Volumen 66, número 321, (enero -marzo 2016)
dc.relation.citationissue.spa.fl_str_mv	Número 321
dc.relation.citationvolume.spa.fl_str_mv	Volumen 66
dc.relation.cites.spa.fl_str_mv	Robayo, R. A., De Gutiérrez, R. M., & Gordillo, M. (2016). Natural pozzolan-and granulated blast furnace slag-based binary geopolymers. Materiales de construcción, volumen 66 (321), 077
dc.relation.ispartofjournal.spa.fl_str_mv	Materiales de construcción
dc.relation.references.spa.fl_str_mv	Pacheco-Torgal, F.; Castro-Gomez, J.; Jalali, S. (2008) Alkali-activated binders: A review Part 1. Historical background, terminology, reaction mechanisms and hydration products. Constr. Build. Mater. 22. 1305–1314. http://dx.doi.org/10.1016/j.conbuildmat.2007.10.015 Komnitsas, K.; Zaharaki, D. (2007) Geopolymerisation: A review and prospects for the minerals industry. Mater. Eng. 20, 1261–1277. http://dx.doi.org/10.1016/j.mineng.2007.07.011 Majidi, B. (2009) Geopolymer technology, from fundamentals to advanced applications: a review Mater. Tech. 24 [2], 79–87. http://dx.doi.org/10.1179/175355509X449355 Davidovits, J. (2013) Geopolymer Cement. A review. Geopolymer Institute, Technical papers 21, 1-11 Provis, L.; Lukey, G.; Van Deventer, J. (2005) Reviews: Do geopolymers actually contain nanocrystalline zeolites? A re-examination of existing results. Chem. Mater. 17, 3075–3085. http://dx.doi.org/10.1021/cm050230i Palomo, A.; Krivenko, P.; Garcia-Lodeiro, I.; Kavalerova, E.; Maltseva, O.; Fernandez-Jimenez, A. (2014) A review on alkaline activation: new analytical perspectives. Mater. Construcc. 64 [315], 1–24. http://dx.doi.org/10.3989/mc.2014.00314 Lizcano, A.; Herrera, M.; Santamarina, J. (2006) Suelos derivados de cenizas volcánicas en Colombia. Rev. Int. de desastres naturales, accidentes e infraestructura civil 6 [2], 167–197 Lemougna, P.; Melo, U.F.; Delplancke, M.P.; Rahier H. (2014) Influence of the chemical and mineralogical composition on the reactivity of volcanic ashes during alkali activation. Ceram. Inter. 40, 811–820. http://dx.doi.org/10.1016/j.ceramint.2013.06.072 Tchakoute, H.K.; Elimbi, A.; Yanne, E.; Djangang, C.N. (2013) Utilization of volcanic ashes for the production of Geopolymers cured at ambient temperature. Cem. Concr. Compos. 38, 75–81. http://dx.doi.org/10.1016/j.cemconcomp.2013.03.010 Bondar, D.; Lynsdale, C.J.; Milestone, N.B.; Hassani, N.; Ramezanianpour, A.A. (2011) Effect of heat treatment on reactivity-strength of alkali-activated natural pozzolans. Constr. Build. Mater. 25, 4065–4071. http://dx.doi.org/10.1016/j.conbuildmat.2011.04.044 Kani, E.N.; Allahverdi, A. (2009a) Effect of chemical composition on basic engineering properties of inorganic polymeric binder based on natural pozzolan. Ceramics-Silikaty 53 [3], 195–204 Kani, E.N.; Allahverdi, A. (2009b) Effects of curing time and temperature on strength development of inorganic polymeric binder based on natural pozzolan. J. Mater. Sci. 44, 3088–3097. http://dx.doi.org/10.1007/s10853-009-3411-1 Allahverdi, A.; Kani, N.; Yazdanipour, M. (2011) Effects of blast-furnace slag on natural pozzolan-based geopolymer cement. Ceramics-Silikáty 55 [1], 68–78 Djobo, J.N.Y.; Tchadjié, L.N.; Tchakoute, H.K.; Kenne, B.B.D., Elimbi, A.; Njopwouo, D. (2014) Synthesis of geopolymer composites from a mixture of volcanic scoria and metakaolin. Journal of Asian Ceramic Societies 2 [4], 387–398. http://dx.doi.org/10.1016/j.jascer.2014.08.003 Rodríguez, E.; Bernal, S.; Mejía de Gutiérrez, R.; Puertas, F. (2008) Hormigón alternativo basado en escorias activadas alcalinamente. Mater. Construcc. 58 [291], 53–57. http://dx.doi.org/10.3989/mc.2008.v58.i291.104 Li, Ch.; Sun, H.; Li, L. (2010) A review: The comparison between alkali-activated slag (Si+Ca) and metakaolin (Si+Al) cements. Cem. Concr. Res. 40, 1341–1349. http://dx.doi.org/10.1016/j.cemconres.2010.03.020 Bernal, S.A.; Mejía de Gutierrez, R.; Pedraza, A., Provis, J.L.; Rodriguez, E.D.; Delvasto, S. (2011) Effect of binder content on the performance of alkali-activated slag concretes. Cem. Concr. Res. 41, 1–8. http://dx.doi.org/10.1016/j.cemconres.2010.08.017 Allahverdi, A.; Saffari M. (2011) Imparting cementing properties to natural pozzolan with a solid compound chemical activator. 4th International Conference Non-Traditional Cement & Concrete, 565–572 Kani, N.; Allahverdi, A.; Provis, J.L. (2012) Efflorescence control in geopolymer binders based on natural pozzolan. Cem. Concr. Compos. 34, 25–33. http://dx.doi.org/10.1016/j.cemconcomp.2011.07.007 Tironi, A.; Trezza, M.; Irassar, E.; Scian, A. (2012) Activación térmica de bentonitas para su utilización como puzolanas. Revista de la Construcción 11 [1], 44–53. http://dx.doi.org/10.4067/S0718-915X2012000100005 Davidovits, J. (2011) Application of Ca-based geopolymer with blast furnace slag, a review. 2nd International Slag Valorisation Symposium, 33–49 Zhang, Z.; Wang, H.; Zhu, Y.; Reid, A.; Provis, J.; Bullen, F. (2014) Using fly ash to partially substitute metakaolin in geopolymer synthesis. App. Clay Sci. 88–89, 194–201. http://dx.doi.org/10.1016/j.clay.2013.12.025 Allahverdi, A.; Mehrpour, K.; Kani, E.N. (2008) Investigating the possibility of utilizing pumice-type natural pozzolan in production of Geopolymer cement. Ceramics-Silikaty 52 [1], 16–23 Xu, H.; Gong, W.; Syltebo, L.; Lutze, W.; Pegg, I.L. (2014) DuraLith geopolymer waste form for Hanford secondary waste: Correlating setting behavior to hydration heat evolution. J. Hazardous Mater. 278, 34–39. http://dx.doi.org/10.1016/j.jhazmat.2014.05.070 Fernández - Jiménez, A.; Puertas, F. (1997) Influence of the activator concentration on the kinetics of the alkaline activation process of a blast furnace slag. Mater. Construcc. 47 [246], 31–42. http://dx.doi.org/10.3989/mc.1997.v47.i246.505 Snellings, R.; Mertens, G.; Elsen, J. (2010) Calorimetric evolution of the early pozzolanic reaction of natural zeolites. J. Therm. Anal. Calorim. 101, 97–105. http://dx.doi.org/10.1007/s10973-009-0449-x Rahhal, V.; Talero, R. (2010) Fast physics-chemical and calorimetric characterization of natural pozzolans and other aspects. J. Therm. Anal. Calorim. 99, 479–486. http://dx.doi.org/10.1007/s10973-009-0016-5 Lemougna, P.; MacKenzie, J.D.; Melo, U.F. (2011) Synthesis and thermal properties of inorganic polymers (geopolymers) for structural and refractory applications from volcanic ash. Ceram. Inter. 37, 3011–3018. http://dx.doi.org/10.1016/j.ceramint.2011.05.002 Puertas, F.; Torres-Carrasco, M. (2014) Use of glass waste as an activator in the preparation of alkali-activated slag. Mechanical strength and paste characterization. Cem. Concr. Res. 57, 95–104. http://dx.doi.org/10.1016/j.cemconres.2013.12.005 Tchakoute, H.K.; Elimbi, A.; Mbey, J.A.; Ngally, C.J.; Njopwouo, D. (2012) The effect of adding alumina-oxide to metakaolin and volcanic ash on geopolymer products: A comparative study. Constr. Build. Mater. 35, 960–969. http://dx.doi.org/10.1016/j.conbuildmat.2012.04.023
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spelling	Gordillo Suárez, Marisolvirtual::2012-1Robayo Salazar, Rafael Andrésd700754b61976feb60960f8f06f21bb0Mejía De Gutiérrez, Rubye9681b3ece6863bf653eec5eccdc28a8Universidad Autónoma de Occidente. Calle 25 115-85. Km 2 vía Cali-Jamundí2019-09-09T18:39:04Z2019-09-09T18:39:04Z2016-01-181988-3226 (en línea)http://hdl.handle.net/10614/11072http://materconstrucc.revistas.csic.es/index.php/materconstrucc/article/view/1979/2422http://dx.doi.org/10.3989/mc.2016.03615Geopolímeros de tipo binario basados en una puzolana natural y escoria siderúrgica de alto horno. Este trabajo describe la síntesis a temperatura ambiente (25±3 °C) de sistemas geopoliméricos de tipo binario basados en una puzolana natural de origen volcánico y escoria siderúrgica de alto horno usando activadores alcalinos basados en la combinación de Na2SiO3 y NaOH. Se estudió el efecto de la relación SiO2/Al2O3, Na2O/Al2O3 y la cantidad de escoria adicionada en niveles entre el 0 y 30% sobre la cinética de reacción, la resistencia a la compresión y la microestructura del producto final. Para la caracterización de las pastas geopoliméricas se utilizaron técnicas como difracción de rayos X (DRX), espectroscopia infrarroja (FTIR) y microscopia electrónica de barrido (MEB). Los resultados conseguidos revelan la posibilidad de obtener un cementante geopolimérico con una resistencia a la compresión de hasta 48,11 MPa a los 28 días de curado a temperatura ambiente cuyas características son comparables a las de un cemento portland comercialThis study describes the synthesis at ambient temperature (25±3 °C) of binary geopolymer systems based on natural volcanic pozzolan and granulated blast furnace slag. Na2SiO3 and NaOH were used as alkaline activators. The effects of the SiO2/Al2O3, Na2O/Al2O3 ratio and the amount of slag added (from 0 to 30%) on the reaction kinetics, compressive strength and microstructure of the final product were studied. To characterise the geopolymer pastes, techniques such as X-ray diffraction (XRD), infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) were used. The results indicate the possibility of obtaining a geopolymer cement with a compressive strength of up to 48.11 MPa after 28 days of curing at ambient temperature whose characteristics are comparable to those of commercial portland cementapplication/pdfpáginas 077engInstituto de Ciencias de la Construcción Eduardo TorrojaMateriales de Construcción, volumen 66, número 321, páginas 077, (january-march, 2016)Volumen 66, número 321, (enero -marzo 2016)Número 321Volumen 66Robayo, R. A., De Gutiérrez, R. M., & Gordillo, M. (2016). Natural pozzolan-and granulated blast furnace slag-based binary geopolymers. Materiales de construcción, volumen 66 (321), 077Materiales de construcciónPacheco-Torgal, F.; Castro-Gomez, J.; Jalali, S. (2008) Alkali-activated binders: A review Part 1. Historical background, terminology, reaction mechanisms and hydration products. Constr. Build. Mater. 22. 1305–1314. http://dx.doi.org/10.1016/j.conbuildmat.2007.10.015Komnitsas, K.; Zaharaki, D. (2007) Geopolymerisation: A review and prospects for the minerals industry. Mater. Eng. 20, 1261–1277. http://dx.doi.org/10.1016/j.mineng.2007.07.011Majidi, B. (2009) Geopolymer technology, from fundamentals to advanced applications: a review Mater. Tech. 24 [2], 79–87. http://dx.doi.org/10.1179/175355509X449355Davidovits, J. (2013) Geopolymer Cement. A review. Geopolymer Institute, Technical papers 21, 1-11Provis, L.; Lukey, G.; Van Deventer, J. (2005) Reviews: Do geopolymers actually contain nanocrystalline zeolites? A re-examination of existing results. Chem. Mater. 17, 3075–3085. http://dx.doi.org/10.1021/cm050230iPalomo, A.; Krivenko, P.; Garcia-Lodeiro, I.; Kavalerova, E.; Maltseva, O.; Fernandez-Jimenez, A. (2014) A review on alkaline activation: new analytical perspectives. Mater. Construcc. 64 [315], 1–24. http://dx.doi.org/10.3989/mc.2014.00314Lizcano, A.; Herrera, M.; Santamarina, J. (2006) Suelos derivados de cenizas volcánicas en Colombia. Rev. Int. de desastres naturales, accidentes e infraestructura civil 6 [2], 167–197Lemougna, P.; Melo, U.F.; Delplancke, M.P.; Rahier H. (2014) Influence of the chemical and mineralogical composition on the reactivity of volcanic ashes during alkali activation. Ceram. Inter. 40, 811–820. http://dx.doi.org/10.1016/j.ceramint.2013.06.072Tchakoute, H.K.; Elimbi, A.; Yanne, E.; Djangang, C.N. (2013) Utilization of volcanic ashes for the production of Geopolymers cured at ambient temperature. Cem. Concr. Compos. 38, 75–81. http://dx.doi.org/10.1016/j.cemconcomp.2013.03.010Bondar, D.; Lynsdale, C.J.; Milestone, N.B.; Hassani, N.; Ramezanianpour, A.A. (2011) Effect of heat treatment on reactivity-strength of alkali-activated natural pozzolans. Constr. Build. Mater. 25, 4065–4071. http://dx.doi.org/10.1016/j.conbuildmat.2011.04.044Kani, E.N.; Allahverdi, A. (2009a) Effect of chemical composition on basic engineering properties of inorganic polymeric binder based on natural pozzolan. Ceramics-Silikaty 53 [3], 195–204Kani, E.N.; Allahverdi, A. (2009b) Effects of curing time and temperature on strength development of inorganic polymeric binder based on natural pozzolan. J. Mater. Sci. 44, 3088–3097. http://dx.doi.org/10.1007/s10853-009-3411-1Allahverdi, A.; Kani, N.; Yazdanipour, M. (2011) Effects of blast-furnace slag on natural pozzolan-based geopolymer cement. Ceramics-Silikáty 55 [1], 68–78Djobo, J.N.Y.; Tchadjié, L.N.; Tchakoute, H.K.; Kenne, B.B.D., Elimbi, A.; Njopwouo, D. (2014) Synthesis of geopolymer composites from a mixture of volcanic scoria and metakaolin. Journal of Asian Ceramic Societies 2 [4], 387–398. http://dx.doi.org/10.1016/j.jascer.2014.08.003Rodríguez, E.; Bernal, S.; Mejía de Gutiérrez, R.; Puertas, F. (2008) Hormigón alternativo basado en escorias activadas alcalinamente. Mater. Construcc. 58 [291], 53–57. http://dx.doi.org/10.3989/mc.2008.v58.i291.104Li, Ch.; Sun, H.; Li, L. (2010) A review: The comparison between alkali-activated slag (Si+Ca) and metakaolin (Si+Al) cements. Cem. Concr. Res. 40, 1341–1349. http://dx.doi.org/10.1016/j.cemconres.2010.03.020Bernal, S.A.; Mejía de Gutierrez, R.; Pedraza, A., Provis, J.L.; Rodriguez, E.D.; Delvasto, S. (2011) Effect of binder content on the performance of alkali-activated slag concretes. Cem. Concr. Res. 41, 1–8. http://dx.doi.org/10.1016/j.cemconres.2010.08.017Allahverdi, A.; Saffari M. (2011) Imparting cementing properties to natural pozzolan with a solid compound chemical activator. 4th International Conference Non-Traditional Cement & Concrete, 565–572Kani, N.; Allahverdi, A.; Provis, J.L. (2012) Efflorescence control in geopolymer binders based on natural pozzolan. Cem. Concr. Compos. 34, 25–33. http://dx.doi.org/10.1016/j.cemconcomp.2011.07.007Tironi, A.; Trezza, M.; Irassar, E.; Scian, A. (2012) Activación térmica de bentonitas para su utilización como puzolanas. Revista de la Construcción 11 [1], 44–53. http://dx.doi.org/10.4067/S0718-915X2012000100005Davidovits, J. (2011) Application of Ca-based geopolymer with blast furnace slag, a review. 2nd International Slag Valorisation Symposium, 33–49Zhang, Z.; Wang, H.; Zhu, Y.; Reid, A.; Provis, J.; Bullen, F. (2014) Using fly ash to partially substitute metakaolin in geopolymer synthesis. App. Clay Sci. 88–89, 194–201. http://dx.doi.org/10.1016/j.clay.2013.12.025Allahverdi, A.; Mehrpour, K.; Kani, E.N. 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Mater. 35, 960–969. http://dx.doi.org/10.1016/j.conbuildmat.2012.04.023Derechos Reservados - Universidad Autónoma de Occidentehttps://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessAtribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)http://purl.org/coar/access_right/c_abf2instname:Universidad Autónoma de Occidentereponame:Repositorio Institucional UAONatural pozzolan-and granulated blast furnace slag-based binary geopolymersArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTREFinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Metales alcalinoterreosAgregados (materiales de construcción)Alkaline earth metalsAggregates (building materials)Cristales de haluros alcalinosIngeniería industrialAlkaline metal halide, crystalsIndustrial engineeringCemento activado alcalinamentePuzolana volcánicaEscoria siderúrgica de alto hornoResistencia a la compresiónAlkaline-activated cementVolcanic pozzolanBlast furnace slagCompressive strengthPublicationef737148-ed0f-4f64-af7e-d275f09fb3ebvirtual::2012-1ef737148-ed0f-4f64-af7e-d275f09fb3ebvirtual::2012-1https://scholar.google.com/citations?user=lj0tkLsAAAAJ&hl=es&oi=sravirtual::2012-10000-0003-1602-5547virtual::2012-1https://scienti.minciencias.gov.co/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0000472255virtual::2012-1CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; 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Natural pozzolan-and granulated blast furnace slag-based binary geopolymers

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