Identification of metals and metalloids as hazardous elements in PM2.5 and PM10 collected in a coastal environment affected by diffuse contamination

The nature of the PM2.5 and PM10 varies enormously depending on the anthropogenic activities developed in the surrounding environment. These particles can include Hazardous Elements (HEs), such as heavy metals, which can be considered dangerous for the human health. For this reason, determining the...

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Autores:
Morillas, Hector
Marcaida, Iker
Maguregui, Maite
Upasen, Settakorn
Gallego-Cartagena, Euler
Madariaga, Juan Manuel
Tipo de recurso:
http://purl.org/coar/resource_type/c_816b
Fecha de publicación:
2019
Institución:
Corporación Universidad de la Costa
Repositorio:
REDICUC - Repositorio CUC
Idioma:
eng
OAI Identifier:
oai:repositorio.cuc.edu.co:11323/3177
Acceso en línea:
https://hdl.handle.net/11323/3177
https://repositorio.cuc.edu.co/
Palabra clave:
Passive sampler
Particulate matter
Marine aerosol
Hazardous elements
Raman microscopy
SEM-EDS
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openAccess
License
Attribution-NonCommercial-NoDerivatives 4.0 International
id RCUC2_fd4e8f5cb35134ff3a849e20c3d76f7c
oai_identifier_str oai:repositorio.cuc.edu.co:11323/3177
network_acronym_str RCUC2
network_name_str REDICUC - Repositorio CUC
repository_id_str
dc.title.spa.fl_str_mv Identification of metals and metalloids as hazardous elements in PM2.5 and PM10 collected in a coastal environment affected by diffuse contamination
title Identification of metals and metalloids as hazardous elements in PM2.5 and PM10 collected in a coastal environment affected by diffuse contamination
spellingShingle Identification of metals and metalloids as hazardous elements in PM2.5 and PM10 collected in a coastal environment affected by diffuse contamination
Passive sampler
Particulate matter
Marine aerosol
Hazardous elements
Raman microscopy
SEM-EDS
title_short Identification of metals and metalloids as hazardous elements in PM2.5 and PM10 collected in a coastal environment affected by diffuse contamination
title_full Identification of metals and metalloids as hazardous elements in PM2.5 and PM10 collected in a coastal environment affected by diffuse contamination
title_fullStr Identification of metals and metalloids as hazardous elements in PM2.5 and PM10 collected in a coastal environment affected by diffuse contamination
title_full_unstemmed Identification of metals and metalloids as hazardous elements in PM2.5 and PM10 collected in a coastal environment affected by diffuse contamination
title_sort Identification of metals and metalloids as hazardous elements in PM2.5 and PM10 collected in a coastal environment affected by diffuse contamination
dc.creator.fl_str_mv Morillas, Hector
Marcaida, Iker
Maguregui, Maite
Upasen, Settakorn
Gallego-Cartagena, Euler
Madariaga, Juan Manuel
dc.contributor.author.spa.fl_str_mv Morillas, Hector
Marcaida, Iker
Maguregui, Maite
Upasen, Settakorn
Gallego-Cartagena, Euler
Madariaga, Juan Manuel
dc.subject.spa.fl_str_mv Passive sampler
Particulate matter
Marine aerosol
Hazardous elements
Raman microscopy
SEM-EDS
topic Passive sampler
Particulate matter
Marine aerosol
Hazardous elements
Raman microscopy
SEM-EDS
description The nature of the PM2.5 and PM10 varies enormously depending on the anthropogenic activities developed in the surrounding environment. These particles can include Hazardous Elements (HEs), such as heavy metals, which can be considered dangerous for the human health. For this reason, determining the nature of those HEs that are present in the surrounding atmosphere can help to comprehend possible emission sources and to establish new strategies to reduce air pollution. In this work, a cost-effective self-made passive sampler (SMPS) was tested as a tool to collect different size of PM containing metals as HEs. The SMPS was installed in a 20th century historic building (Punta Begona Galleries, Getxo, ~ Basque Country, Spain), located just in front of the sea and thus, immersed in a coastal environment. This location is affected by the activities developed in a marina and in a port, and by the diffuse influence of several industries and a power station. The annual average for PM10 and PM2.5 were approximately 22 mg/ m3 and 10 mg/m3 , respectively. For develop this study, non-invasive elemental (Scanning Electron Microscope coupled to Energy Dispersive X-ray Spectrometry) and molecular (Raman microscopy) microspectroscopic techniques were used. Thanks to this methodology it was possible to determine in PM10 and PM2.5, the presence of heavy metals such as Fe, Cr, Ti, Pb, Zn, Ce, etc., most of them as oxides but also embedded in different aggregations with aluminosilicates, phosphates, halides, sulfates, etc.
publishDate 2019
dc.date.accessioned.none.fl_str_mv 2019-05-02T15:33:25Z
dc.date.available.none.fl_str_mv 2019-05-02T15:33:25Z
dc.date.issued.none.fl_str_mv 2019-04-06
dc.type.spa.fl_str_mv Pre-Publicación
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_816b
dc.type.content.spa.fl_str_mv Text
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/preprint
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/ARTOTR
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/acceptedVersion
format http://purl.org/coar/resource_type/c_816b
status_str acceptedVersion
dc.identifier.uri.spa.fl_str_mv https://hdl.handle.net/11323/3177
dc.identifier.instname.spa.fl_str_mv Corporación Universidad de la Costa
dc.identifier.reponame.spa.fl_str_mv REDICUC - Repositorio CUC
dc.identifier.repourl.spa.fl_str_mv https://repositorio.cuc.edu.co/
url https://hdl.handle.net/11323/3177
https://repositorio.cuc.edu.co/
identifier_str_mv Corporación Universidad de la Costa
REDICUC - Repositorio CUC
dc.language.iso.none.fl_str_mv eng
language eng
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spelling Morillas, HectorMarcaida, IkerMaguregui, MaiteUpasen, SettakornGallego-Cartagena, EulerMadariaga, Juan Manuel2019-05-02T15:33:25Z2019-05-02T15:33:25Z2019-04-06https://hdl.handle.net/11323/3177Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/The nature of the PM2.5 and PM10 varies enormously depending on the anthropogenic activities developed in the surrounding environment. These particles can include Hazardous Elements (HEs), such as heavy metals, which can be considered dangerous for the human health. For this reason, determining the nature of those HEs that are present in the surrounding atmosphere can help to comprehend possible emission sources and to establish new strategies to reduce air pollution. In this work, a cost-effective self-made passive sampler (SMPS) was tested as a tool to collect different size of PM containing metals as HEs. The SMPS was installed in a 20th century historic building (Punta Begona Galleries, Getxo, ~ Basque Country, Spain), located just in front of the sea and thus, immersed in a coastal environment. This location is affected by the activities developed in a marina and in a port, and by the diffuse influence of several industries and a power station. The annual average for PM10 and PM2.5 were approximately 22 mg/ m3 and 10 mg/m3 , respectively. For develop this study, non-invasive elemental (Scanning Electron Microscope coupled to Energy Dispersive X-ray Spectrometry) and molecular (Raman microscopy) microspectroscopic techniques were used. Thanks to this methodology it was possible to determine in PM10 and PM2.5, the presence of heavy metals such as Fe, Cr, Ti, Pb, Zn, Ce, etc., most of them as oxides but also embedded in different aggregations with aluminosilicates, phosphates, halides, sulfates, etc.Morillas, Hector-f45c72ec-db9c-45b4-8b4d-ea1d2f6e66c9-0Marcaida, Iker-234ff4c3-490a-43d6-aa8b-dbc603658b55-0Maguregui, Maite-7669a346-d1d3-4a4c-8689-b207baca04d9-0Upasen, Settakorn-452ae13b-f41f-4cab-a79c-1e9f48426c16-0Gallego-Cartagena, Euler-0000-0003-3316-5007-600Madariaga, Juan Manuel-2e2778a5-21ee-4def-8143-f3443dcaa560-0engUniversidad de la CostaAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Passive samplerParticulate matterMarine aerosolHazardous elementsRaman microscopySEM-EDSIdentification of metals and metalloids as hazardous elements in PM2.5 and PM10 collected in a coastal environment affected by diffuse contaminationPre-Publicaciónhttp://purl.org/coar/resource_type/c_816bTextinfo:eu-repo/semantics/preprinthttp://purl.org/redcol/resource_type/ARTOTRinfo:eu-repo/semantics/acceptedVersionAmato, F., Karanasiou, A., Moreno, T., Alastuey, A., Orza, J.A.G., Lumbreras, J., Borge, R., Boldo, E., Linares, C., Querol, X., 2012. 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Environ. 57, 1e12.PublicationORIGINALIdentification of metals and metalloids as hazardous elements in PM2.5 and PM10 collected in a coastal environment affected by diffuse contamination.pdfIdentification of metals and metalloids as hazardous elements in PM2.5 and PM10 collected in a coastal environment affected by diffuse contamination.pdfapplication/pdf180961https://repositorio.cuc.edu.co/bitstreams/f7fc73cc-a51a-4498-9bc7-37fcf41f2120/download5e240f074f59b7e533af5fe594c3051bMD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8805https://repositorio.cuc.edu.co/bitstreams/0e201136-c666-432b-8992-450b1ec2bcd4/download4460e5956bc1d1639be9ae6146a50347MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://repositorio.cuc.edu.co/bitstreams/d3b5e7b0-695b-46d4-bbdd-28e650335b55/download8a4605be74aa9ea9d79846c1fba20a33MD53THUMBNAILIdentification of metals and metalloids as hazardous elements in PM2.5 and PM10 collected in a coastal environment affected by diffuse contamination.pdf.jpgIdentification of metals and metalloids as hazardous elements in PM2.5 and PM10 collected in a coastal environment affected by diffuse contamination.pdf.jpgimage/jpeg49981https://repositorio.cuc.edu.co/bitstreams/8e402125-c52f-4282-82d9-fb329fbec219/download344248ccf05e694960835cf69c2f35b7MD55TEXTIdentification of metals and metalloids as hazardous elements in PM2.5 and PM10 collected in a coastal environment affected by diffuse contamination.pdf.txtIdentification of metals and metalloids as hazardous elements in PM2.5 and PM10 collected in a coastal environment affected by diffuse contamination.pdf.txttext/plain1937https://repositorio.cuc.edu.co/bitstreams/196cc9bb-602d-48c6-be81-dba5f7eccd7d/download33e51688d95a61b4e9b3652b289bb5e6MD5611323/3177oai:repositorio.cuc.edu.co:11323/31772024-09-17 12:45:44.282http://creativecommons.org/licenses/by-nc-nd/4.0/Attribution-NonCommercial-NoDerivatives 4.0 Internationalopen.accesshttps://repositorio.cuc.edu.coRepositorio de la Universidad de la Costa CUCrepdigital@cuc.edu.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