Surface chemistry of atmospheric nanoparticles during a haze episode in Beijing by TOF-SIMS

The atmospheric aerosol particles have a potential heavy burden on environment, climate, and human health, which were closely related to the surface physicochemical properties. Time-of-flight secondary ion mass spectrometry (TOF-SIMS) technique is a powerful tool to obtain detailed surface chemical...

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Autores:
Li, Wenjun
Shao, Longyi
Li, Zhanping
Li, Hong
Gao, Jian
Li, Jinjuan
Zhang, Hao
Zhang, Zhengzheng
Silva Oliveira, Luis Felipe
Zhang, Mengyuan
Chen, Yizhen
Silva Oliveira, Marcos Leandro
Tipo de recurso:
Article of journal
Fecha de publicación:
2022
Institución:
Corporación Universidad de la Costa
Repositorio:
REDICUC - Repositorio CUC
Idioma:
eng
OAI Identifier:
oai:repositorio.cuc.edu.co:11323/9172
Acceso en línea:
https://hdl.handle.net/11323/9172
https://doi.org/10.1016/j.gr.2022.02.013
https://repositorio.cuc.edu.co/
Palabra clave:
Air pollution
Aerosol particles
Surface chemical composition
Source appointment
TOF–SIMS
Rights
embargoedAccess
License
Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)
id RCUC2_f7342662b6c3ab5c8777d0da593b9fff
oai_identifier_str oai:repositorio.cuc.edu.co:11323/9172
network_acronym_str RCUC2
network_name_str REDICUC - Repositorio CUC
repository_id_str
dc.title.eng.fl_str_mv Surface chemistry of atmospheric nanoparticles during a haze episode in Beijing by TOF-SIMS
title Surface chemistry of atmospheric nanoparticles during a haze episode in Beijing by TOF-SIMS
spellingShingle Surface chemistry of atmospheric nanoparticles during a haze episode in Beijing by TOF-SIMS
Air pollution
Aerosol particles
Surface chemical composition
Source appointment
TOF–SIMS
title_short Surface chemistry of atmospheric nanoparticles during a haze episode in Beijing by TOF-SIMS
title_full Surface chemistry of atmospheric nanoparticles during a haze episode in Beijing by TOF-SIMS
title_fullStr Surface chemistry of atmospheric nanoparticles during a haze episode in Beijing by TOF-SIMS
title_full_unstemmed Surface chemistry of atmospheric nanoparticles during a haze episode in Beijing by TOF-SIMS
title_sort Surface chemistry of atmospheric nanoparticles during a haze episode in Beijing by TOF-SIMS
dc.creator.fl_str_mv Li, Wenjun
Shao, Longyi
Li, Zhanping
Li, Hong
Gao, Jian
Li, Jinjuan
Zhang, Hao
Zhang, Zhengzheng
Silva Oliveira, Luis Felipe
Zhang, Mengyuan
Chen, Yizhen
Silva Oliveira, Marcos Leandro
dc.contributor.author.spa.fl_str_mv Li, Wenjun
Shao, Longyi
Li, Zhanping
Li, Hong
Gao, Jian
Li, Jinjuan
Zhang, Hao
Zhang, Zhengzheng
Silva Oliveira, Luis Felipe
Zhang, Mengyuan
Chen, Yizhen
Silva Oliveira, Marcos Leandro
dc.subject.proposal.eng.fl_str_mv Air pollution
Aerosol particles
Surface chemical composition
Source appointment
TOF–SIMS
topic Air pollution
Aerosol particles
Surface chemical composition
Source appointment
TOF–SIMS
description The atmospheric aerosol particles have a potential heavy burden on environment, climate, and human health, which were closely related to the surface physicochemical properties. Time-of-flight secondary ion mass spectrometry (TOF-SIMS) technique is a powerful tool to obtain detailed surface chemical information since it has high surface sensitivity for both elements and molecular ions, and high mass resolution. In this work, size-fractioned aerosol particles in the range of 0.43–10 µm during a severe haze episode in Beijing were analyzed by TOF-SIMS, the variation characteristics of chemical species corresponding to particle size and air pollution level was investigated by the normalization of secondary ion intensities, the possible sources were identified through principal component analysis (PCA), and the influence of meteorological factors and air mass transmission were also investigated. The study results showed that the surface chemical components of PM2.5 were more complicated during haze episode than on clean days. A total of 17 organic and inorganic species were detected, including crustal elements, heavy metals, sulfate, nitrate, siliceous compounds, hydrocarbons, oxygen-containing organics, and nitrogen-containing organics. In general, the particle surface mainly contained crustal elements, hydrocarbons, and carbon-containing inorganics. Organic and secondary ions significantly increased in heavy-polluted days, indicating the aging process of particles. Inorganic compounds had a higher percentage in coarse mode, while organic compounds were higher in accumulation mode. PCA results indicated that urban aerosol during this haze episode mainly came from vehicle emissions (24.7%), coal-fired combustion (22.4%), organic aerosol (19.3%), and dust resuspension (19.6%). The northern air mass could facilitate the dilution of air pollutants with the surface secondary formed components of particles significantly decreased.
publishDate 2022
dc.date.accessioned.none.fl_str_mv 2022-05-17T19:42:19Z
dc.date.available.none.fl_str_mv 2022-05-17T19:42:19Z
2024-03-08
dc.date.issued.none.fl_str_mv 2022-03-08
dc.type.spa.fl_str_mv Artículo de revista
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_6501
dc.type.content.spa.fl_str_mv Text
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/article
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/ART
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/acceptedVersion
format http://purl.org/coar/resource_type/c_6501
status_str acceptedVersion
dc.identifier.issn.spa.fl_str_mv 1342-937X
dc.identifier.uri.spa.fl_str_mv https://hdl.handle.net/11323/9172
dc.identifier.url.spa.fl_str_mv https://doi.org/10.1016/j.gr.2022.02.013
dc.identifier.doi.spa.fl_str_mv 10.1016/j.gr.2022.02.013
dc.identifier.instname.spa.fl_str_mv Corporación Universidad de la Costa
dc.identifier.reponame.spa.fl_str_mv REDICUC - Repositorio CUC
dc.identifier.repourl.spa.fl_str_mv https://repositorio.cuc.edu.co/
identifier_str_mv 1342-937X
10.1016/j.gr.2022.02.013
Corporación Universidad de la Costa
REDICUC - Repositorio CUC
url https://hdl.handle.net/11323/9172
https://doi.org/10.1016/j.gr.2022.02.013
https://repositorio.cuc.edu.co/
dc.language.iso.none.fl_str_mv eng
language eng
dc.relation.ispartofjournal.spa.fl_str_mv Gondwana Research
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spelling Li, WenjunShao, LongyiLi, ZhanpingLi, HongGao, JianLi, JinjuanZhang, HaoZhang, ZhengzhengSilva Oliveira, Luis FelipeZhang, MengyuanChen, YizhenSilva Oliveira, Marcos Leandro2022-05-17T19:42:19Z2024-03-082022-05-17T19:42:19Z2022-03-081342-937Xhttps://hdl.handle.net/11323/9172https://doi.org/10.1016/j.gr.2022.02.01310.1016/j.gr.2022.02.013Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/The atmospheric aerosol particles have a potential heavy burden on environment, climate, and human health, which were closely related to the surface physicochemical properties. Time-of-flight secondary ion mass spectrometry (TOF-SIMS) technique is a powerful tool to obtain detailed surface chemical information since it has high surface sensitivity for both elements and molecular ions, and high mass resolution. In this work, size-fractioned aerosol particles in the range of 0.43–10 µm during a severe haze episode in Beijing were analyzed by TOF-SIMS, the variation characteristics of chemical species corresponding to particle size and air pollution level was investigated by the normalization of secondary ion intensities, the possible sources were identified through principal component analysis (PCA), and the influence of meteorological factors and air mass transmission were also investigated. The study results showed that the surface chemical components of PM2.5 were more complicated during haze episode than on clean days. A total of 17 organic and inorganic species were detected, including crustal elements, heavy metals, sulfate, nitrate, siliceous compounds, hydrocarbons, oxygen-containing organics, and nitrogen-containing organics. In general, the particle surface mainly contained crustal elements, hydrocarbons, and carbon-containing inorganics. Organic and secondary ions significantly increased in heavy-polluted days, indicating the aging process of particles. Inorganic compounds had a higher percentage in coarse mode, while organic compounds were higher in accumulation mode. PCA results indicated that urban aerosol during this haze episode mainly came from vehicle emissions (24.7%), coal-fired combustion (22.4%), organic aerosol (19.3%), and dust resuspension (19.6%). The northern air mass could facilitate the dilution of air pollutants with the surface secondary formed components of particles significantly decreased.14 páginasapplication/pdfengElsevier Inc.United StatesAtribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)2022 Published by Elsevier B.Vhttps://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/embargoedAccesshttp://purl.org/coar/access_right/c_f1cfSurface chemistry of atmospheric nanoparticles during a haze episode in Beijing by TOF-SIMSArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/acceptedVersionhttps://www.sciencedirect.com/science/article/pii/S1342937X22000764BeijingGondwana ResearchAlmstrand et al., 2016 A.C. Almstrand, E. Ljungström, J. Lausmaa, B. Bake, P. Sjövall, A.C. 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Technol, 35 (15) (2001), pp. 3113-3121, 10.1021/es0019530141Air pollutionAerosol particlesSurface chemical compositionSource appointmentTOF–SIMSPublicationORIGINALSurface chemistry of atmospheric nanoparticles during a haze episode in Beijing by TOF-SIMS.pdfSurface chemistry of atmospheric nanoparticles during a haze episode in Beijing by TOF-SIMS.pdfapplication/pdf4772446https://repositorio.cuc.edu.co/bitstreams/3cbd797a-d342-40f6-a82f-f9f6d0bb3101/download073a108546bb128179d7439e800e50e4MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-83196https://repositorio.cuc.edu.co/bitstreams/62cdd688-30ed-4d83-83db-7a006f710f4d/downloade30e9215131d99561d40d6b0abbe9badMD52TEXTSurface chemistry of atmospheric nanoparticles during a haze episode in Beijing by TOF-SIMS.pdf.txtSurface chemistry of atmospheric nanoparticles during a haze episode in Beijing by 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