Films based on thermoplastic starch blended with pine resin derivatives for food packaging

Completely biobased and biodegradable thermoplastic starch (TPS) based materials with a tunable performance were prepared for food packaging applications. Five blends were prepared by blending TPS with 10 wt%. of different pine resins derivatives: gum rosin (GR), disproportionated gum rosin (RD), ma...

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Autores:
Pavón, Cristina
Aldás, Miguel
Lopez, Juan
Hernández-Fernández, Joaquín
Arrieta, Marina Patricia
Tipo de recurso:
Article of journal
Fecha de publicación:
2021
Institución:
Corporación Universidad de la Costa
Repositorio:
REDICUC - Repositorio CUC
Idioma:
eng
OAI Identifier:
oai:repositorio.cuc.edu.co:11323/8442
Acceso en línea:
https://hdl.handle.net/11323/8442
https://doi.org/10.3390/foods10061171
https://repositorio.cuc.edu.co/
Palabra clave:
bioplastic
thermoplastic starch
pine resin
gum rosin
disintegration
packaging
Rights
openAccess
License
Attribution-NonCommercial-NoDerivatives 4.0 International
id RCUC2_f71124ab4f23fe9e56cc4b05f77f69f4
oai_identifier_str oai:repositorio.cuc.edu.co:11323/8442
network_acronym_str RCUC2
network_name_str REDICUC - Repositorio CUC
repository_id_str
dc.title.eng.fl_str_mv Films based on thermoplastic starch blended with pine resin derivatives for food packaging
title Films based on thermoplastic starch blended with pine resin derivatives for food packaging
spellingShingle Films based on thermoplastic starch blended with pine resin derivatives for food packaging
bioplastic
thermoplastic starch
pine resin
gum rosin
disintegration
packaging
title_short Films based on thermoplastic starch blended with pine resin derivatives for food packaging
title_full Films based on thermoplastic starch blended with pine resin derivatives for food packaging
title_fullStr Films based on thermoplastic starch blended with pine resin derivatives for food packaging
title_full_unstemmed Films based on thermoplastic starch blended with pine resin derivatives for food packaging
title_sort Films based on thermoplastic starch blended with pine resin derivatives for food packaging
dc.creator.fl_str_mv Pavón, Cristina
Aldás, Miguel
Lopez, Juan
Hernández-Fernández, Joaquín
Arrieta, Marina Patricia
dc.contributor.author.spa.fl_str_mv Pavón, Cristina
Aldás, Miguel
Lopez, Juan
Hernández-Fernández, Joaquín
Arrieta, Marina Patricia
dc.subject.spa.fl_str_mv bioplastic
thermoplastic starch
pine resin
gum rosin
disintegration
packaging
topic bioplastic
thermoplastic starch
pine resin
gum rosin
disintegration
packaging
description Completely biobased and biodegradable thermoplastic starch (TPS) based materials with a tunable performance were prepared for food packaging applications. Five blends were prepared by blending TPS with 10 wt%. of different pine resins derivatives: gum rosin (GR), disproportionated gum rosin (RD), maleic anhydride-modified gum rosin (CM), pentaerythritol ester of gum rosin (LF), and glycerol ester of gum rosin (UG). The materials were characterized in terms of thermo-mechanical behavior, surface wettability, color performance, water absorption, X-ray diffraction pattern, and disintegration under composting conditions. It was determined that pine resin derivatives increase the hydrophobicity of TPS and also increase the elastic component of TPS which stiffen the TPS structure. The water uptake study revealed that GR and LF were able to decrease the water absorption of TPS, while the rest of the resins kept the water uptake ability. X-ray diffraction analyses revealed that GR, CM, and RD restrain the aging of TPS after 24 months of aging. Finally, all TPS-resin blends were disintegrated under composting conditions during the thermophilic incubation period (90 days). Because of the TPS-resin blend’s performance, the prepared materials are suitable for biodegradable rigid food packaging applications.
publishDate 2021
dc.date.accessioned.none.fl_str_mv 2021-06-29T21:44:40Z
dc.date.available.none.fl_str_mv 2021-06-29T21:44:40Z
dc.date.issued.none.fl_str_mv 2021
dc.type.spa.fl_str_mv Artículo de revista
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
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dc.type.content.spa.fl_str_mv Text
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dc.identifier.uri.spa.fl_str_mv https://hdl.handle.net/11323/8442
dc.identifier.doi.spa.fl_str_mv https://doi.org/10.3390/foods10061171
dc.identifier.instname.spa.fl_str_mv Corporación Universidad de la Costa
dc.identifier.reponame.spa.fl_str_mv REDICUC - Repositorio CUC
dc.identifier.repourl.spa.fl_str_mv https://repositorio.cuc.edu.co/
url https://hdl.handle.net/11323/8442
https://doi.org/10.3390/foods10061171
https://repositorio.cuc.edu.co/
identifier_str_mv Corporación Universidad de la Costa
REDICUC - Repositorio CUC
dc.language.iso.none.fl_str_mv eng
language eng
dc.relation.references.spa.fl_str_mv Geyer, R.; Jambeck, J.R.; Law, K.L. Production, use, and fate of all plastics ever made. Sci. Adv. 2017, 3, 1–5.
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Arrieta, M.P.; Peltzer, M.A.; López, J.; Garrigós, M.D.C.; Valente, A.J.; Jiménez, A. Functional properties of sodium and calcium caseinate antimicrobial active films containing carvacrol. J. Food Eng. 2014, 121, 94–101.
Galbis, J.A.; De Gracia García-Martín, M.; Violante De Paz, M.; Galbis, E.; García-Martín, M.D.G.; De Paz, M.V.; Galbis, E. Synthetic Polymers from Sugar-Based Monomers; American Chemical Society: Washington, DC, USA, 2020; Volume 116, pp. 1600–1636.
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Díaz-Galindo, E.P.; Nesic, A.; Bautista-Baños, S.; García, O.D.; Cabrera-Barjas, G. Corn-Starch-Based Materials Incorporated with Cinnamon Oil Emulsion: Physico-Chemical Characterization and Biological Activity. Foods 2020, 9, 475.
Al-Hashimi, G.A.; Ammar, A.B.; Lakshmanan, G.; Cacciola, F.; Lakhssassi, N. Development of a Millet Starch Edible Film Containing Clove Essential Oil. Foods 2020, 9, 184.
Leon-Bejarano, M.; Durmus, Y.; Ovando-Martínez, M.; Simsek, S. Physical, Barrier, Mechanical, and Biodegradability Properties of Modified Starch Films with Nut by-Products Extracts. Foods 2020, 9, 226.
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spelling Pavón, CristinaAldás, MiguelLopez, JuanHernández-Fernández, JoaquínArrieta, Marina Patricia2021-06-29T21:44:40Z2021-06-29T21:44:40Z2021https://hdl.handle.net/11323/8442https://doi.org/10.3390/foods10061171Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/Completely biobased and biodegradable thermoplastic starch (TPS) based materials with a tunable performance were prepared for food packaging applications. Five blends were prepared by blending TPS with 10 wt%. of different pine resins derivatives: gum rosin (GR), disproportionated gum rosin (RD), maleic anhydride-modified gum rosin (CM), pentaerythritol ester of gum rosin (LF), and glycerol ester of gum rosin (UG). The materials were characterized in terms of thermo-mechanical behavior, surface wettability, color performance, water absorption, X-ray diffraction pattern, and disintegration under composting conditions. It was determined that pine resin derivatives increase the hydrophobicity of TPS and also increase the elastic component of TPS which stiffen the TPS structure. The water uptake study revealed that GR and LF were able to decrease the water absorption of TPS, while the rest of the resins kept the water uptake ability. X-ray diffraction analyses revealed that GR, CM, and RD restrain the aging of TPS after 24 months of aging. Finally, all TPS-resin blends were disintegrated under composting conditions during the thermophilic incubation period (90 days). Because of the TPS-resin blend’s performance, the prepared materials are suitable for biodegradable rigid food packaging applications.Pavon, Cristina-will be generated-orcid-0000-0003-2902-0059-600Aldás, Miguel-will be generated-orcid-0000-0003-3491-6618-600Lopez, Juan-will be generated-orcid-0000-0001-6904-2282-600Hernández-Fernández, JoaquínArrieta, Marina Patricia-will be generated-orcid-0000-0003-1816-011X-600application/pdfengAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Foodshttps://www.mdpi.com/2304-8158/10/6/1171bioplasticthermoplastic starchpine resingum rosindisintegrationpackagingFilms based on thermoplastic starch blended with pine resin derivatives for food packagingArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/acceptedVersionGeyer, R.; Jambeck, J.R.; Law, K.L. Production, use, and fate of all plastics ever made. Sci. Adv. 2017, 3, 1–5.Hong, M.; Chen, E.Y.-X. Future Directions for Sustainable Polymers. Trends Chem. 2019, 1, 148–151.Schneiderman, D.K.; Hillmyer, M.A. 50th Anniversary Perspective: There Is a Great Future in Sustainable Polymers. Macromolecules 2017, 50, 3733–3749.Gkartzou, E.; Koumoulos, E.P.; Charitidis, C.A. Production and 3D printing processing of bio-based thermoplastic filament. Manuf. Rev. 2017, 4, 1–14.Hong, M.; Chen, E.Y.-X. Chemically recyclable polymers: A circular economy approach to sustainability. Green Chem. 2017, 19, 3692–3706.Plastics Europe Market Research Group (PEMRG). Plastics-The Facts 2019 an Analysis of European Plastics Production, Demand and Waste Data; PlasticsEurope: Brussels, Belgium, 2019.Eichhorn, S.J.; Dufresne, A.; Aranguren, M.; Marcovich, N.E.; Capadona, J.R.; Rowan, S.J.; Weder, C.; Thielemans, W.; Roman, M.; Renneckar, S.; et al. Review: Current international research into cellulose nanofibres and nanocomposites. J. Mater. Sci. 2010, 45, 1–33.Wang, Z.; Ganewatta, M.S.; Tang, C. Sustainable polymers from biomass: Bridging chemistry with materials and processing. Prog. Polym. Sci. 2020, 101, 101197–101211.Pillai, C.; Paul, W.; Sharma, C.P. Chitin and chitosan polymers: Chemistry, solubility and fiber formation. Prog. Polym. Sci. 2009, 34, 641–678.Arrieta, M.P.; Peltzer, M.A.; López, J.; Garrigós, M.D.C.; Valente, A.J.; Jiménez, A. Functional properties of sodium and calcium caseinate antimicrobial active films containing carvacrol. J. Food Eng. 2014, 121, 94–101.Galbis, J.A.; De Gracia García-Martín, M.; Violante De Paz, M.; Galbis, E.; García-Martín, M.D.G.; De Paz, M.V.; Galbis, E. Synthetic Polymers from Sugar-Based Monomers; American Chemical Society: Washington, DC, USA, 2020; Volume 116, pp. 1600–1636.Papageorgiou, G.Z. Thinking Green: Sustainable Polymers from Renewable Resources. Polymers 2018, 10, 952.Arrieta, M.P.; Samper, M.D.; Aldas, M.; López, J. On the Use of PLA-PHB Blends for Sustainable Food Packaging Applications. Materials 2017, 10, 1008.Singh, A.; Gu, Y.; Castellarin, S.D.; Kitts, D.D.; Pratap-Singh, A. Development and Characterization of the Edible Packaging Films Incorporated with Blueberry Pomace. Foods 2020, 9, 1599.Díaz-Galindo, E.P.; Nesic, A.; Bautista-Baños, S.; García, O.D.; Cabrera-Barjas, G. Corn-Starch-Based Materials Incorporated with Cinnamon Oil Emulsion: Physico-Chemical Characterization and Biological Activity. Foods 2020, 9, 475.Al-Hashimi, G.A.; Ammar, A.B.; Lakshmanan, G.; Cacciola, F.; Lakhssassi, N. Development of a Millet Starch Edible Film Containing Clove Essential Oil. Foods 2020, 9, 184.Leon-Bejarano, M.; Durmus, Y.; Ovando-Martínez, M.; Simsek, S. Physical, Barrier, Mechanical, and Biodegradability Properties of Modified Starch Films with Nut by-Products Extracts. 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