Understanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling
Adsorption modeling via statistical physics theory allows to understand the adsorption mechanism of heavy metal ions. Therefore, this paper reports the analysis of the mechanism of copper ion (Cu2+) adsorption on four activated carbons using statistical physics models. These models contain parameter...
- Autores:
-
Sellaoui, Lotfi
Dhaouadi, Fatma
sonia, taamalli
Louis, Florent
Abderrahman, El Bakali
Badawi, Michael
Bonilla-Petriciolet, Adrian
Silva Oliveira, Luis Felipe
da Boit Martinello, Kátia
Dotto, Guilherme Luiz
Ben Lamine, Abdemottaleb
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2022
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/9168
- Acceso en línea:
- https://hdl.handle.net/11323/9168
https://doi.org/10.1007/s11356-022-19795-7
https://repositorio.cuc.edu.co/
- Palabra clave:
- Adsorption
Cooper
Isotherms
Statistical physics
- Rights
- embargoedAccess
- License
- © 2022 Springer Nature Switzerland AG. Part of Springer Nature.
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Understanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling |
| title |
Understanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling |
| spellingShingle |
Understanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling Adsorption Cooper Isotherms Statistical physics |
| title_short |
Understanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling |
| title_full |
Understanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling |
| title_fullStr |
Understanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling |
| title_full_unstemmed |
Understanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling |
| title_sort |
Understanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling |
| dc.creator.fl_str_mv |
Sellaoui, Lotfi Dhaouadi, Fatma sonia, taamalli Louis, Florent Abderrahman, El Bakali Badawi, Michael Bonilla-Petriciolet, Adrian Silva Oliveira, Luis Felipe da Boit Martinello, Kátia Dotto, Guilherme Luiz Ben Lamine, Abdemottaleb |
| dc.contributor.author.spa.fl_str_mv |
Sellaoui, Lotfi Dhaouadi, Fatma sonia, taamalli Louis, Florent Abderrahman, El Bakali Badawi, Michael Bonilla-Petriciolet, Adrian Silva Oliveira, Luis Felipe da Boit Martinello, Kátia Dotto, Guilherme Luiz Ben Lamine, Abdemottaleb |
| dc.subject.proposal.eng.fl_str_mv |
Adsorption Cooper Isotherms Statistical physics |
| topic |
Adsorption Cooper Isotherms Statistical physics |
| description |
Adsorption modeling via statistical physics theory allows to understand the adsorption mechanism of heavy metal ions. Therefore, this paper reports the analysis of the mechanism of copper ion (Cu2+) adsorption on four activated carbons using statistical physics models. These models contain parameters that were utilized to provide new insights into the possible adsorption mechanism at the molecular scale. In particular, a monolayer adsorption model was the best alternative to correlate the Cu2+ adsorption data at 25–55 °C and pH 5.5. Furthermore, the application of this model for copper adsorption data analysis showed that the removal of this heavy metal ion was a multi-cationic process. This theoretical finding indicated that Cu2+ ions interacted via one functional group of activated carbon surface during adsorption. In this direction, the adsorption energy was calculated thus showing that Cu2+ removal was endothermic and associated with physical interaction forces. Furthermore, these activated carbons showed saturation adsorption capacities from 54.6 to 87.0 mg/g for Cu2+ removal, and their performances outperformed other adsorbents available in the literature. Overall, these results provide new insights of the adsorption mechanism of this water pollutant using activated carbons. |
| publishDate |
2022 |
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2022-05-16T13:46:39Z |
| dc.date.available.none.fl_str_mv |
2022-05-16T13:46:39Z |
| dc.date.issued.none.fl_str_mv |
2022 |
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Artículo de revista |
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Text |
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Sellaoui, L., Dhaouadi, F., Taamalli, S. et al. Understanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling. Environ Sci Pollut Res (2022). https://doi.org/10.1007/s11356-022-19795-7 |
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0944-1344 |
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https://hdl.handle.net/11323/9168 |
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https://doi.org/10.1007/s11356-022-19795-7 |
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10.1007/s11356-022-19795-7 |
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1614-7499 |
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Corporación Universidad de la Costa |
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REDICUC - Repositorio CUC |
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https://repositorio.cuc.edu.co/ |
| identifier_str_mv |
Sellaoui, L., Dhaouadi, F., Taamalli, S. et al. Understanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling. Environ Sci Pollut Res (2022). https://doi.org/10.1007/s11356-022-19795-7 0944-1344 10.1007/s11356-022-19795-7 1614-7499 Corporación Universidad de la Costa REDICUC - Repositorio CUC |
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https://hdl.handle.net/11323/9168 https://doi.org/10.1007/s11356-022-19795-7 https://repositorio.cuc.edu.co/ |
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eng |
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eng |
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Environmental Science and Pollution Research |
| dc.relation.references.spa.fl_str_mv |
Anbazhagan S, Thiruvengadam V, Sukeri A (2021) An Amberlite IRA-400 Cl− ion-exchange resin modified with Prosopis juliflora seeds as an efficient Pb2+ adsorbent: adsorption, kinetics, thermodynamics, and computational modeling studies by density functional theory. RSC Adv 11:4478–4488. https://doi.org/10.1039/D0RA10128A Bell JG, Zhao X, Uygur Y, Thomas KM (2011) Adsorption of chloroaromatic models for dioxins on porous carbons: the influence of adsorbate structure and surface functional groups on surface interactions and adsorption kinetics. J Phys Chem C 115:2776–2789. https://doi.org/10.1021/jp1099893 CerrahoğluKaçakgil E, Çetintaş S (2021) Preparation and characterization of a novel functionalized agricultural waste-based adsorbent for Cu2+ removal: Evaluation of adsorption performance using response surface methodology. Sustain Chem Pharm 22:100468. https://doi.org/10.1016/j.scp.2021.100468 Dhaouadi F, Sellaoui L, Badawi M, Reynel-Ávila HE, Mendoza-Castillo DI, Jaime-Leal JE, Bonilla-Petriciolet A, Lamine AB (2020a) Statistical physics interpretation of the adsorption mechanism of Pb2+, Cd2+ and Ni2+ on chicken feathers. J Mol Liq 319:114168. https://doi.org/10.1016/j.molliq.2020.114168 Dhaouadi F, Sellaoui L, Chávez-González B, Elizabeth Reynel-Ávila H, Diaz-Muñoz LL, Mendoza-Castillo DI, Bonilla-Petriciolet A, Lima EC, Tapia-Picazo JC, Lamine AB (2020b) Application of a heterogeneous physical model for the adsorption of Cd2+, Ni2+, Zn2+ and Cu2+ ions on flamboyant pods functionalized with citric acid. Chem Eng J 417:127975. https://doi.org/10.1016/j.cej.2020.127975 Dhaouadi F, Sellaoui L, Dotto GL, Bonilla-Petriciolet A, Erto A, Lamine AB (2020c) Adsorption of methylene blue on comminuted raw avocado seeds: interpretation of the effect of salts via physical monolayer model. J Mol Liq 305:112815. https://doi.org/10.1016/j.molliq.2020.112815 Dhaouadi F, Sellaoui L, Reynel-Ávila HE, Landín-Sandoval V, Mendoza-Castillo DI, Jaime-Leal JE, Lima EC, Bonilla-Petriciolet A, Lamine AB (2021) Adsorption mechanism of Zn 2+, Ni 2+, Cd 2+, and Cu 2+ ions by carbon-based adsorbents: interpretation of the adsorption isotherms via physical modelling. Environ Sci Pollut Res. https://doi.org/10.1007/s11356-021-12832-x Dotto GL, Vieira MLG, Gonçalves JO, de Pinto LA, A, (2011) Removal of acid blue 9, food yellow 3 and FD&C yellow no 5 dyes from aqueous solutions using activated carbon, activated earth, diatomaceous earth, chitin and chitosan: equilibrium studies and thermodynamic. Quim Nova 34:1193–1199 Dou J, Gan D, Huang Q, Chen J, Deng F, Zhu X, Wen Y, Zhang X, Wei Y (2019) Functionalization of carbon nanotubes with chitosan based on MALI multicomponent reaction for Cu2+ removal. Int J Biol Macromol 136:476–485. https://doi.org/10.1016/j.ijbiomac.2019.06.112 Godiya CB, Cheng X, Li D, Chen Z, Lu X (2019) Carboxymethyl cellulose/polyacrylamide composite hydrogel for cascaded treatment/reuse of heavy metal ions in wastewater. J Hazard Mater 364:28–38. https://doi.org/10.1016/j.jhazmat.2018.09.076 Gu S-Y, Hsieh C-T, Gandomi YA, Yang ZF, Li L, Fu CC, Juang RS (2019) Functionalization of activated carbons with magnetic Iron oxide nanoparticles for removal of copper ions from aqueous solution. J Mol Liq 277:499–505. https://doi.org/10.1016/j.molliq.2018.12.018 Katiyar R, Patel AK, Nguyen T-B, Singhania RR, Chen CW, Dong CD (2021) Adsorption of copper (II) in aqueous solution using biochars derived from Ascophyllum nodosum seaweed. Biores Technol 328:124829. https://doi.org/10.1016/j.biortech.2021.124829 Kayalvizhi K, Alhaji NMI, Saravanakkumar D, Mohamed SB, Kaviyarasu K, Ayeshamariam A, Al-Mohaimeed AM, Abdel Gawwad MR, Elshikh MS (2022) Adsorption of copper and nickel by using sawdust chitosan nanocomposite beads – a kinetic and thermodynamic study. Environ Res 203:111814. https://doi.org/10.1016/j.envres.2021.111814 Khan J, Lin S, Nizeyimana JC, Wu Y, Wang Q, Liu X (2021) Removal of copper ions from wastewater via adsorption on modified hematite (α-Fe2O3) iron oxide coated sand. J Clean Prod 319:128687. https://doi.org/10.1016/j.jclepro.2021.128687 Lam SS, Liew RK, Lim XY, Ani FN, Jusoha A (2016) Fruit waste as feedstock for recovery by pyrolysis technique. Int Biodeterior Biodegradation 113:325–333. https://doi.org/10.1016/j.ibiod.2016.02.021 Lam SS, Liew RK, Cheng CK, Rasit N, Ooi CK, Ma NL, Ng JH, Lam WH, Chong CT, Chase HA (2018) Pyrolysis production of fruit peel biochar for potential use in treatment of palm oil mill effluent. J Environ Manage 213:400–408. https://doi.org/10.1016/j.jenvman.2018.02.092 Lemes LFR, Tarley CRT (2021) Combination of supramolecular solvent-based microextraction and ultrasound-assisted extraction for cadmium determination in flaxseed flour by thermospray flame furnace atomic absorption spectrometry. Food Chem 357:129695. https://doi.org/10.1016/j.foodchem.2021.129695 Li S-Z, Wu P-X (2010) Characterization of sodium dodecyl sulfate modified iron pillared montmorillonite and its application for the removal of aqueous Cu(II) and Co(II). J Hazard Mater 173:62–70. https://doi.org/10.1016/j.jhazmat.2009.08.047 Mariana M, Khalil H.P.S. A, Mistar EM, Yahya EB, Alfatah T, Danish M, Amayreh M (2021) Recent advances in activated carbon modification techniques for enhanced heavy metal adsorption. J Water Process Eng 43:102221. https://doi.org/10.1016/j.jwpe.2021.102221 Nyström F, Nordqvist K, Herrmann I, Nordqvist K, Herrmann I, Hedström A, Viklander M (2020) Removal of metals and hydrocarbons from stormwater using coagulation and flocculation. Water Res 182:115919. https://doi.org/10.1016/j.watres.2020.115919 Pan J, Gao Y, Gao B, Guo K, Xu X, Yue Q (2019) One-step synthesis of easily-recoverable carboxylated biogas residues for efficient removal of heavy metal ions from synthetic wastewater. J Clean Prod 240:118264. https://doi.org/10.1016/j.jclepro.2019.118264 Perondi D, Poletto P, Restelatto D, Manera C, Silva JP, Junges J, Collazzo GC, Dettmer A, Godinho M, Vilela ACF (2017) Steam gasification of poultry litter biochar for bio-syngas production. Process Saf Environ Prot 109:478–488. https://doi.org/10.1016/j.psep.2017.04.029 Rukayat OO, Usman MF, Elizabeth OM, Abosede OO, Faith IU (2021) Kinetic adsorption of heavy metal (copper) on rubber (Hevea Brasiliensis) leaf powder. S Afr J Chem Eng 37:74–80. https://doi.org/10.1016/j.sajce.2021.04.004 Sellaoui L, Soetaredjo FE, Ismadji S, Benguerba Y, Dotto GL, Bonilla-Petriciolet A, Rodrigues AE, Ben Lamine A, Erto A (2018) Equilibrium study of single and binary adsorption of lead and mercury on bentonite-alginate composite: experiments and application of two theoretical approaches. J Mol Liq 253:160–168. https://doi.org/10.1016/j.molliq.2018.01.056 Sun H, Ji Z, He Y, Wang L, Zhan J, Chen L, Zhao Y (2022) Preparation of PAMAM modified PVDF membrane and its adsorption performance for copper ions. Environ Res 204:111943. https://doi.org/10.1016/j.envres.2021.111943 Vocciante M, Trofa M, Rodríguez-Estupiñán P, Giraldo L, D’Auria T, Moreno-Piraján JC, Erto A (2014) A rigorous procedure for the design of adsorption units for the removal of cadmium and nickel from process wastewaters. J Clean Prod 77:35–46. https://doi.org/10.1016/j.jclepro.2013.12.001 |
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Sellaoui, LotfiDhaouadi, Fatmasonia, taamalliLouis, FlorentAbderrahman, El BakaliBadawi, MichaelBonilla-Petriciolet, AdrianSilva Oliveira, Luis Felipeda Boit Martinello, KátiaDotto, Guilherme LuizBen Lamine, Abdemottaleb2022-05-16T13:46:39Z2022-05-16T13:46:39Z2022Sellaoui, L., Dhaouadi, F., Taamalli, S. et al. Understanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling. Environ Sci Pollut Res (2022). https://doi.org/10.1007/s11356-022-19795-70944-1344https://hdl.handle.net/11323/9168https://doi.org/10.1007/s11356-022-19795-710.1007/s11356-022-19795-71614-7499Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/Adsorption modeling via statistical physics theory allows to understand the adsorption mechanism of heavy metal ions. Therefore, this paper reports the analysis of the mechanism of copper ion (Cu2+) adsorption on four activated carbons using statistical physics models. These models contain parameters that were utilized to provide new insights into the possible adsorption mechanism at the molecular scale. In particular, a monolayer adsorption model was the best alternative to correlate the Cu2+ adsorption data at 25–55 °C and pH 5.5. Furthermore, the application of this model for copper adsorption data analysis showed that the removal of this heavy metal ion was a multi-cationic process. This theoretical finding indicated that Cu2+ ions interacted via one functional group of activated carbon surface during adsorption. In this direction, the adsorption energy was calculated thus showing that Cu2+ removal was endothermic and associated with physical interaction forces. Furthermore, these activated carbons showed saturation adsorption capacities from 54.6 to 87.0 mg/g for Cu2+ removal, and their performances outperformed other adsorbents available in the literature. Overall, these results provide new insights of the adsorption mechanism of this water pollutant using activated carbons.1 páginaapplication/pdfengSpringer Science + Business MediaGermany© 2022 Springer Nature Switzerland AG. Part of Springer Nature.Atribución 4.0 Internacional (CC BY 4.0)https://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/embargoedAccesshttp://purl.org/coar/access_right/c_f1cfUnderstanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modellingArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARThttp://purl.org/coar/version/c_b1a7d7d4d402bccehttps://link.springer.com/article/10.1007/s11356-022-19795-7Environmental Science and Pollution ResearchAnbazhagan S, Thiruvengadam V, Sukeri A (2021) An Amberlite IRA-400 Cl− ion-exchange resin modified with Prosopis juliflora seeds as an efficient Pb2+ adsorbent: adsorption, kinetics, thermodynamics, and computational modeling studies by density functional theory. RSC Adv 11:4478–4488. https://doi.org/10.1039/D0RA10128ABell JG, Zhao X, Uygur Y, Thomas KM (2011) Adsorption of chloroaromatic models for dioxins on porous carbons: the influence of adsorbate structure and surface functional groups on surface interactions and adsorption kinetics. J Phys Chem C 115:2776–2789. https://doi.org/10.1021/jp1099893CerrahoğluKaçakgil E, Çetintaş S (2021) Preparation and characterization of a novel functionalized agricultural waste-based adsorbent for Cu2+ removal: Evaluation of adsorption performance using response surface methodology. Sustain Chem Pharm 22:100468. https://doi.org/10.1016/j.scp.2021.100468Dhaouadi F, Sellaoui L, Badawi M, Reynel-Ávila HE, Mendoza-Castillo DI, Jaime-Leal JE, Bonilla-Petriciolet A, Lamine AB (2020a) Statistical physics interpretation of the adsorption mechanism of Pb2+, Cd2+ and Ni2+ on chicken feathers. J Mol Liq 319:114168. https://doi.org/10.1016/j.molliq.2020.114168Dhaouadi F, Sellaoui L, Chávez-González B, Elizabeth Reynel-Ávila H, Diaz-Muñoz LL, Mendoza-Castillo DI, Bonilla-Petriciolet A, Lima EC, Tapia-Picazo JC, Lamine AB (2020b) Application of a heterogeneous physical model for the adsorption of Cd2+, Ni2+, Zn2+ and Cu2+ ions on flamboyant pods functionalized with citric acid. Chem Eng J 417:127975. https://doi.org/10.1016/j.cej.2020.127975Dhaouadi F, Sellaoui L, Dotto GL, Bonilla-Petriciolet A, Erto A, Lamine AB (2020c) Adsorption of methylene blue on comminuted raw avocado seeds: interpretation of the effect of salts via physical monolayer model. J Mol Liq 305:112815. https://doi.org/10.1016/j.molliq.2020.112815Dhaouadi F, Sellaoui L, Reynel-Ávila HE, Landín-Sandoval V, Mendoza-Castillo DI, Jaime-Leal JE, Lima EC, Bonilla-Petriciolet A, Lamine AB (2021) Adsorption mechanism of Zn 2+, Ni 2+, Cd 2+, and Cu 2+ ions by carbon-based adsorbents: interpretation of the adsorption isotherms via physical modelling. Environ Sci Pollut Res. https://doi.org/10.1007/s11356-021-12832-xDotto GL, Vieira MLG, Gonçalves JO, de Pinto LA, A, (2011) Removal of acid blue 9, food yellow 3 and FD&C yellow no 5 dyes from aqueous solutions using activated carbon, activated earth, diatomaceous earth, chitin and chitosan: equilibrium studies and thermodynamic. Quim Nova 34:1193–1199Dou J, Gan D, Huang Q, Chen J, Deng F, Zhu X, Wen Y, Zhang X, Wei Y (2019) Functionalization of carbon nanotubes with chitosan based on MALI multicomponent reaction for Cu2+ removal. Int J Biol Macromol 136:476–485. https://doi.org/10.1016/j.ijbiomac.2019.06.112Godiya CB, Cheng X, Li D, Chen Z, Lu X (2019) Carboxymethyl cellulose/polyacrylamide composite hydrogel for cascaded treatment/reuse of heavy metal ions in wastewater. J Hazard Mater 364:28–38. https://doi.org/10.1016/j.jhazmat.2018.09.076Gu S-Y, Hsieh C-T, Gandomi YA, Yang ZF, Li L, Fu CC, Juang RS (2019) Functionalization of activated carbons with magnetic Iron oxide nanoparticles for removal of copper ions from aqueous solution. J Mol Liq 277:499–505. https://doi.org/10.1016/j.molliq.2018.12.018Katiyar R, Patel AK, Nguyen T-B, Singhania RR, Chen CW, Dong CD (2021) Adsorption of copper (II) in aqueous solution using biochars derived from Ascophyllum nodosum seaweed. Biores Technol 328:124829. https://doi.org/10.1016/j.biortech.2021.124829Kayalvizhi K, Alhaji NMI, Saravanakkumar D, Mohamed SB, Kaviyarasu K, Ayeshamariam A, Al-Mohaimeed AM, Abdel Gawwad MR, Elshikh MS (2022) Adsorption of copper and nickel by using sawdust chitosan nanocomposite beads – a kinetic and thermodynamic study. Environ Res 203:111814. https://doi.org/10.1016/j.envres.2021.111814Khan J, Lin S, Nizeyimana JC, Wu Y, Wang Q, Liu X (2021) Removal of copper ions from wastewater via adsorption on modified hematite (α-Fe2O3) iron oxide coated sand. J Clean Prod 319:128687. https://doi.org/10.1016/j.jclepro.2021.128687Lam SS, Liew RK, Lim XY, Ani FN, Jusoha A (2016) Fruit waste as feedstock for recovery by pyrolysis technique. Int Biodeterior Biodegradation 113:325–333. https://doi.org/10.1016/j.ibiod.2016.02.021Lam SS, Liew RK, Cheng CK, Rasit N, Ooi CK, Ma NL, Ng JH, Lam WH, Chong CT, Chase HA (2018) Pyrolysis production of fruit peel biochar for potential use in treatment of palm oil mill effluent. J Environ Manage 213:400–408. https://doi.org/10.1016/j.jenvman.2018.02.092Lemes LFR, Tarley CRT (2021) Combination of supramolecular solvent-based microextraction and ultrasound-assisted extraction for cadmium determination in flaxseed flour by thermospray flame furnace atomic absorption spectrometry. Food Chem 357:129695. https://doi.org/10.1016/j.foodchem.2021.129695Li S-Z, Wu P-X (2010) Characterization of sodium dodecyl sulfate modified iron pillared montmorillonite and its application for the removal of aqueous Cu(II) and Co(II). J Hazard Mater 173:62–70. https://doi.org/10.1016/j.jhazmat.2009.08.047Mariana M, Khalil H.P.S. A, Mistar EM, Yahya EB, Alfatah T, Danish M, Amayreh M (2021) Recent advances in activated carbon modification techniques for enhanced heavy metal adsorption. J Water Process Eng 43:102221. https://doi.org/10.1016/j.jwpe.2021.102221Nyström F, Nordqvist K, Herrmann I, Nordqvist K, Herrmann I, Hedström A, Viklander M (2020) Removal of metals and hydrocarbons from stormwater using coagulation and flocculation. Water Res 182:115919. https://doi.org/10.1016/j.watres.2020.115919Pan J, Gao Y, Gao B, Guo K, Xu X, Yue Q (2019) One-step synthesis of easily-recoverable carboxylated biogas residues for efficient removal of heavy metal ions from synthetic wastewater. J Clean Prod 240:118264. https://doi.org/10.1016/j.jclepro.2019.118264Perondi D, Poletto P, Restelatto D, Manera C, Silva JP, Junges J, Collazzo GC, Dettmer A, Godinho M, Vilela ACF (2017) Steam gasification of poultry litter biochar for bio-syngas production. 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J Clean Prod 77:35–46. https://doi.org/10.1016/j.jclepro.2013.12.0011AdsorptionCooperIsothermsStatistical physicsPublicationORIGINALUnderstanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling.pdfUnderstanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling.pdfapplication/pdf57275https://repositorio.cuc.edu.co/bitstreams/2df0cd2a-6174-4efd-b59e-dfc5dad5b72e/download5fa1f803c08b382b2481f3f7c4c83e58MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-83196https://repositorio.cuc.edu.co/bitstreams/31b375ad-a174-4f96-a226-72848d7f2bc5/downloade30e9215131d99561d40d6b0abbe9badMD52TEXTUnderstanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling.pdf.txtUnderstanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling.pdf.txttext/plain1730https://repositorio.cuc.edu.co/bitstreams/04f61a7d-d916-46d4-a01c-6d19aa13dba6/downloaddcc9b7d7e81b6bae78f70b1512aa68f5MD53THUMBNAILUnderstanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling.pdf.jpgUnderstanding the Cu2+ adsorption mechanism on activated carbon using advanced statistical physics modelling.pdf.jpgimage/jpeg14373https://repositorio.cuc.edu.co/bitstreams/89a1c8fc-aace-4389-a1e6-63cf7a95a691/downloadcffa8d8d1ae8debba024a4a3e9e1057cMD5411323/9168oai:repositorio.cuc.edu.co:11323/91682024-09-17 11:02:11.534https://creativecommons.org/licenses/by/4.0/© 2022 Springer Nature Switzerland AG. Part of Springer Nature.open.accesshttps://repositorio.cuc.edu.coRepositorio de la Universidad de la Costa CUCrepdigital@cuc.edu.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 |