CaeAl, NieAl and ZneAl LDH powders as efficient materials to treat synthetic effluents containing o-nitrophenol
Powdered layered double hydroxides (LDH) based on calcium-aluminum (Ca–Al), nickel-aluminum (Ni–Al), and zinc-aluminum (Zn–Al) were synthesized with the purpose to evaluate the removal of o-nitrophenol from synthetic effluents by adsorption. It was verified that Ca–Al, Ni–Al, and Zn–Al LDHs presente...
- Autores:
-
Marques, Bianca S.
Dalmagro, Keterli
Moreira, Kelly S.
Oliveira, Marcos L.S.
Jahn, Sergio L.
De Lima Burgo, Thiago A.
Dotto, Guilherme L.
- Tipo de recurso:
- http://purl.org/coar/resource_type/c_816b
- Fecha de publicación:
- 2020
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/6300
- Acceso en línea:
- https://hdl.handle.net/11323/6300
https://doi.org/10.1016/j.jallcom.2020.155628
https://repositorio.cuc.edu.co/
- Palabra clave:
- Adsorption
General order
Layered structure
Nitrophenol
Simulated effluent
- Rights
- openAccess
- License
- CC0 1.0 Universal
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| dc.title.spa.fl_str_mv |
CaeAl, NieAl and ZneAl LDH powders as efficient materials to treat synthetic effluents containing o-nitrophenol |
| title |
CaeAl, NieAl and ZneAl LDH powders as efficient materials to treat synthetic effluents containing o-nitrophenol |
| spellingShingle |
CaeAl, NieAl and ZneAl LDH powders as efficient materials to treat synthetic effluents containing o-nitrophenol Adsorption General order Layered structure Nitrophenol Simulated effluent |
| title_short |
CaeAl, NieAl and ZneAl LDH powders as efficient materials to treat synthetic effluents containing o-nitrophenol |
| title_full |
CaeAl, NieAl and ZneAl LDH powders as efficient materials to treat synthetic effluents containing o-nitrophenol |
| title_fullStr |
CaeAl, NieAl and ZneAl LDH powders as efficient materials to treat synthetic effluents containing o-nitrophenol |
| title_full_unstemmed |
CaeAl, NieAl and ZneAl LDH powders as efficient materials to treat synthetic effluents containing o-nitrophenol |
| title_sort |
CaeAl, NieAl and ZneAl LDH powders as efficient materials to treat synthetic effluents containing o-nitrophenol |
| dc.creator.fl_str_mv |
Marques, Bianca S. Dalmagro, Keterli Moreira, Kelly S. Oliveira, Marcos L.S. Jahn, Sergio L. De Lima Burgo, Thiago A. Dotto, Guilherme L. |
| dc.contributor.author.spa.fl_str_mv |
Marques, Bianca S. Dalmagro, Keterli Moreira, Kelly S. Oliveira, Marcos L.S. Jahn, Sergio L. De Lima Burgo, Thiago A. Dotto, Guilherme L. |
| dc.subject.spa.fl_str_mv |
Adsorption General order Layered structure Nitrophenol Simulated effluent |
| topic |
Adsorption General order Layered structure Nitrophenol Simulated effluent |
| description |
Powdered layered double hydroxides (LDH) based on calcium-aluminum (Ca–Al), nickel-aluminum (Ni–Al), and zinc-aluminum (Zn–Al) were synthesized with the purpose to evaluate the removal of o-nitrophenol from synthetic effluents by adsorption. It was verified that Ca–Al, Ni–Al, and Zn–Al LDHs presented a typical layered structure confirming the successful synthesis. o-nitrophenol adsorption on the LDH powders was favored at a pH of 5.0, being attained removal percentages from 70 to 90%, depending on the material. Kinetic experimental data obeyed the general order model, while, Sips represented the experimental equilibrium behavior of the three materials adequately. The maximum adsorption capacities were 135.1 mg g−1,122.1 mg g−1 and 130.3 mg g−1 for Ca–Al, Ni–Al, and Zn–Al LDHs, respectively. For simulated effluent, it was attained a removal of up to 60.3% using Ni–Al LDH. In a general way, the layered double hydroxides based on Ca–Al, Ni–Al, and Zn–Al exhibited an interesting potential as adsorbent materials for the treatment of simulated effluents containing o-nitrophenol. Ni–Al is preferred due to its better performance in the treatment of simulated effluents and higher regeneration potential. |
| publishDate |
2020 |
| dc.date.accessioned.none.fl_str_mv |
2020-05-28T16:05:05Z |
| dc.date.available.none.fl_str_mv |
2020-05-28T16:05:05Z |
| dc.date.issued.none.fl_str_mv |
2020-05-13 |
| dc.type.spa.fl_str_mv |
Pre-Publicación |
| dc.type.coar.spa.fl_str_mv |
http://purl.org/coar/resource_type/c_816b |
| dc.type.content.spa.fl_str_mv |
Text |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/preprint |
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http://purl.org/redcol/resource_type/ARTOTR |
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info:eu-repo/semantics/acceptedVersion |
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http://purl.org/coar/resource_type/c_816b |
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acceptedVersion |
| dc.identifier.uri.spa.fl_str_mv |
https://hdl.handle.net/11323/6300 |
| dc.identifier.doi.spa.fl_str_mv |
https://doi.org/10.1016/j.jallcom.2020.155628 |
| dc.identifier.instname.spa.fl_str_mv |
Corporación Universidad de la Costa |
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REDICUC - Repositorio CUC |
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https://repositorio.cuc.edu.co/ |
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https://hdl.handle.net/11323/6300 https://doi.org/10.1016/j.jallcom.2020.155628 https://repositorio.cuc.edu.co/ |
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Corporación Universidad de la Costa REDICUC - Repositorio CUC |
| dc.language.iso.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.references.spa.fl_str_mv |
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Dash, S. Pandey, Layered double hydroxides: a brief review from fundamentals to application as evolving biomaterials, Appl. Clay Sci. 153 (2017) 172e186, https://doi.org/10.1016/j.clay.2017.12.021. [16] C. Barriga, M. Gait an, I. Pavlovic, M.A. Ulibarri, M.C. Hermos~ õn, J. Cornejo, Hydrotalcites as sorbent for 2,4,6-trinitrophenol: influence of the layer composition and interlayer anion, J. Mater. Chem. 12 (2002) 1027e1034, https://doi.org/10.1039/b107979b. [17] A. Halajnia, S. Oustan, N. Najafi, A.R. Khataee, A. Lakzian, Adsorptiondesorption characteristics of nitrate, phosphate and sulfate on Mg-Al layered double hydroxide, Appl. Clay Sci. 80e81 (2013) 305e312, https://doi.org/ 10.1016/j.clay.2013.05.002. [18] H. Hatami, A. Fotovat, A. Halajnia, Comparison of adsorption and desorption of phosphate on synthesized Zn-Al LDH by two methods in a simulated soil solution, Appl. Clay Sci. 152 (2017) 333e341, https://doi.org/10.1016/ j.clay.2017.11.032. [19] E.M. Seftel, R.G. Ciocarlan, B. 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[26] L. Cao, J. Guo, J. Tian, Y. Xu, M. Hu, M. Wang, J. Fan, Preparation of Ca/AlLayered Double Hydroxide and the influence of their structure on early strength of cement, Construct. Build. Mater. 184 (2018) 203e214, https:// doi.org/10.1016/j.conbuildmat.2018.06.186. [27] B. Li, J. He, D.G. Evans, X. Duan, Morphology, and size control of Ni-Al layered double hydroxides using chitosan as a template, J. Phys. Chem. Solid. 67 (2006) 1067e1070, https://doi.org/10.1016/j.jpcs.2006.01.027. [28] L. Cocheci, L. Lupa, M. Gheju, A. Golban, R. Lazau, R. Pode, Zn-Al-CO 3 layered double hydroxides prepared from a waste of hot-dip galvanizing process, B.S. Marques et al. / Journal of Alloys and Compounds 838 (2020) 155628 11 Clean Technol, Environ. Pol. 20 (2018) 1105e1112, https://doi.org/10.1007/ s10098-018-1533-3. [29] M. Khormaei, B. Nasernejad, M. Edrisi, T. Eslamzadeh, Copper biosorption from aqueous solutions by sour orange residue, J. 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Marques, Bianca S.438081b74cda2241b32642c9f345a1c3Dalmagro, Keterli41388cc2a1f198533e5704de97964adaMoreira, Kelly S.c97a5e75d42ff426a95efc4f8fd1df1eOliveira, Marcos L.S.6b16a4068c414ea46c2588691b7c4b54Jahn, Sergio L.73cd2ae90ce9cd771c95c2a0f966f938De Lima Burgo, Thiago A.234985d693a86873189597a2dba13614Dotto, Guilherme L.c0e5bf3f141757792fd1a91aaeb9fc0c2020-05-28T16:05:05Z2020-05-28T16:05:05Z2020-05-13https://hdl.handle.net/11323/6300https://doi.org/10.1016/j.jallcom.2020.155628Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/Powdered layered double hydroxides (LDH) based on calcium-aluminum (Ca–Al), nickel-aluminum (Ni–Al), and zinc-aluminum (Zn–Al) were synthesized with the purpose to evaluate the removal of o-nitrophenol from synthetic effluents by adsorption. It was verified that Ca–Al, Ni–Al, and Zn–Al LDHs presented a typical layered structure confirming the successful synthesis. o-nitrophenol adsorption on the LDH powders was favored at a pH of 5.0, being attained removal percentages from 70 to 90%, depending on the material. Kinetic experimental data obeyed the general order model, while, Sips represented the experimental equilibrium behavior of the three materials adequately. The maximum adsorption capacities were 135.1 mg g−1,122.1 mg g−1 and 130.3 mg g−1 for Ca–Al, Ni–Al, and Zn–Al LDHs, respectively. For simulated effluent, it was attained a removal of up to 60.3% using Ni–Al LDH. In a general way, the layered double hydroxides based on Ca–Al, Ni–Al, and Zn–Al exhibited an interesting potential as adsorbent materials for the treatment of simulated effluents containing o-nitrophenol. Ni–Al is preferred due to its better performance in the treatment of simulated effluents and higher regeneration potential.engCC0 1.0 Universalhttp://creativecommons.org/publicdomain/zero/1.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2AdsorptionGeneral orderLayered structureNitrophenolSimulated effluentCaeAl, NieAl and ZneAl LDH powders as efficient materials to treat synthetic effluents containing o-nitrophenolPre-Publicaciónhttp://purl.org/coar/resource_type/c_816bTextinfo:eu-repo/semantics/preprinthttp://purl.org/redcol/resource_type/ARTOTRinfo:eu-repo/semantics/acceptedVersion[1] R. Arasteh, M. Masoumi, A.M. Rashidi, L. Moradi, V. Samimi, S. Mostafavi, Adsorption of 2-nitrophenol by multi-wall carbon nanotubes from aqueous solutions, Appl. Surf. 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