Residual peel of pitaya fruit (Hylocereus undatus) as a precursor to obtaining an efficient carbon-based adsorbent for the removal of metanil yellow dye from water
The pitaya peel (Hylocereus undatus) was carbonized in the presence of ZnCl2 to obtain a carbon-based adsorbent to remove the Metanil Yellow dye (MY) from colored waters. The characterization techniques confirmed that the material had morphological changes with the appearance of new irregularities a...
- Autores:
-
georgin, jordana
DA BOIT MARTINELLO, KATIA
Dison S.P., Franco
Netto, Matias S.
Piccilli, Daniel G.A.
Yilmaz, Murat
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2022
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/9206
- Acceso en línea:
- https://hdl.handle.net/11323/9206
https://repositorio.cuc.edu.co/
- Palabra clave:
- Metanil yellow
Hylocereus undatus
Peel
Dye adsorption
HSDM model
- Rights
- embargoedAccess
- License
- © 2021 Elsevier Ltd. All rights reserved.
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Residual peel of pitaya fruit (Hylocereus undatus) as a precursor to obtaining an efficient carbon-based adsorbent for the removal of metanil yellow dye from water |
| title |
Residual peel of pitaya fruit (Hylocereus undatus) as a precursor to obtaining an efficient carbon-based adsorbent for the removal of metanil yellow dye from water |
| spellingShingle |
Residual peel of pitaya fruit (Hylocereus undatus) as a precursor to obtaining an efficient carbon-based adsorbent for the removal of metanil yellow dye from water Metanil yellow Hylocereus undatus Peel Dye adsorption HSDM model |
| title_short |
Residual peel of pitaya fruit (Hylocereus undatus) as a precursor to obtaining an efficient carbon-based adsorbent for the removal of metanil yellow dye from water |
| title_full |
Residual peel of pitaya fruit (Hylocereus undatus) as a precursor to obtaining an efficient carbon-based adsorbent for the removal of metanil yellow dye from water |
| title_fullStr |
Residual peel of pitaya fruit (Hylocereus undatus) as a precursor to obtaining an efficient carbon-based adsorbent for the removal of metanil yellow dye from water |
| title_full_unstemmed |
Residual peel of pitaya fruit (Hylocereus undatus) as a precursor to obtaining an efficient carbon-based adsorbent for the removal of metanil yellow dye from water |
| title_sort |
Residual peel of pitaya fruit (Hylocereus undatus) as a precursor to obtaining an efficient carbon-based adsorbent for the removal of metanil yellow dye from water |
| dc.creator.fl_str_mv |
georgin, jordana DA BOIT MARTINELLO, KATIA Dison S.P., Franco Netto, Matias S. Piccilli, Daniel G.A. Yilmaz, Murat |
| dc.contributor.author.spa.fl_str_mv |
georgin, jordana DA BOIT MARTINELLO, KATIA Dison S.P., Franco Netto, Matias S. Piccilli, Daniel G.A. Yilmaz, Murat |
| dc.subject.proposal.eng.fl_str_mv |
Metanil yellow Hylocereus undatus Peel Dye adsorption HSDM model |
| topic |
Metanil yellow Hylocereus undatus Peel Dye adsorption HSDM model |
| description |
The pitaya peel (Hylocereus undatus) was carbonized in the presence of ZnCl2 to obtain a carbon-based adsorbent to remove the Metanil Yellow dye (MY) from colored waters. The characterization techniques confirmed that the material had morphological changes with the appearance of new irregularities and cavities. Besides, the alternative adsorbent was formed mainly by carbon and functional groups characteristic of lignin and cellulose. Isothermal and kinetic studies were carried out at the natural pH of the solution at a dosage of 0.4 g L−1. The Langmuir model demonstrated the best adjustment of the equilibrium isotherms of the system, reaching the maximum adsorption capacity of 144.07 mg g−1 at 298 K. The thermodynamic behavior indicated that it is a spontaneous and favorable process of an exothermic nature (ΔH0=−34.02 kJ mol−1), consistent with a mechanism involving electrostatic interactions. The MY concentration influenced the kinetic. The homogeneous surface diffusion model (HSDM) showed good statistical adjustment to the kinetic values, showing a slight increase in the diffusivity coefficient from 2.4 × 10−9 to 4.5 × 10−9 cm2 s−1 with the increased MY concentration. The material application in a mixture containing several dyes and salts in the circumstances close to the real ones showed removal of 82.5%. The adsorbent could be regenerated and used 12 times. Therefore, it can be concluded that the pitaya fruit residual biomass can be used as a precursor for preparing carbon-based adsorbents. The adsorbent, in turn, is a promising alternative in the treatment of MY dye and mixtures of organic molecules. |
| publishDate |
2022 |
| dc.date.accessioned.none.fl_str_mv |
2022-06-01T22:34:13Z |
| dc.date.available.none.fl_str_mv |
2022-06-01T22:34:13Z 2024 |
| dc.date.issued.none.fl_str_mv |
2022 |
| dc.type.spa.fl_str_mv |
Artículo de revista |
| dc.type.coar.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.coar.spa.fl_str_mv |
http://purl.org/coar/resource_type/c_6501 |
| dc.type.content.spa.fl_str_mv |
Text |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/article |
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http://purl.org/redcol/resource_type/ART |
| dc.type.version.spa.fl_str_mv |
info:eu-repo/semantics/acceptedVersion |
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http://purl.org/coar/resource_type/c_6501 |
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acceptedVersion |
| dc.identifier.issn.spa.fl_str_mv |
2213-3437 |
| dc.identifier.uri.spa.fl_str_mv |
https://hdl.handle.net/11323/9206 |
| dc.identifier.instname.spa.fl_str_mv |
Corporación Universidad de la Costa |
| dc.identifier.reponame.spa.fl_str_mv |
REDICUC - Repositorio CUC |
| dc.identifier.repourl.spa.fl_str_mv |
https://repositorio.cuc.edu.co/ |
| identifier_str_mv |
2213-3437 Corporación Universidad de la Costa REDICUC - Repositorio CUC |
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https://hdl.handle.net/11323/9206 https://repositorio.cuc.edu.co/ |
| dc.language.iso.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.ispartofjournal.spa.fl_str_mv |
Journal of Environmental Chemical Engineering |
| dc.relation.references.spa.fl_str_mv |
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georgin, jordana3cb4434fbc1c630e529d2cddd15f71d4600DA BOIT MARTINELLO, KATIAed0b8787a1e1feee5bd78aea81c9fc57600Dison S.P., Franco617ef49ebc758ce5201754e858ead2a2600Netto, Matias S.bbafe7978c27efedfcbbfaf18ef632b6Piccilli, Daniel G.A.7ef1afbafe4b0172b98da9aeb6c9e13dYilmaz, Murata8375f0ecb862502ad183cc6183581862022-06-01T22:34:13Z20242022-06-01T22:34:13Z20222213-3437https://hdl.handle.net/11323/9206Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/The pitaya peel (Hylocereus undatus) was carbonized in the presence of ZnCl2 to obtain a carbon-based adsorbent to remove the Metanil Yellow dye (MY) from colored waters. The characterization techniques confirmed that the material had morphological changes with the appearance of new irregularities and cavities. Besides, the alternative adsorbent was formed mainly by carbon and functional groups characteristic of lignin and cellulose. Isothermal and kinetic studies were carried out at the natural pH of the solution at a dosage of 0.4 g L−1. The Langmuir model demonstrated the best adjustment of the equilibrium isotherms of the system, reaching the maximum adsorption capacity of 144.07 mg g−1 at 298 K. The thermodynamic behavior indicated that it is a spontaneous and favorable process of an exothermic nature (ΔH0=−34.02 kJ mol−1), consistent with a mechanism involving electrostatic interactions. The MY concentration influenced the kinetic. The homogeneous surface diffusion model (HSDM) showed good statistical adjustment to the kinetic values, showing a slight increase in the diffusivity coefficient from 2.4 × 10−9 to 4.5 × 10−9 cm2 s−1 with the increased MY concentration. The material application in a mixture containing several dyes and salts in the circumstances close to the real ones showed removal of 82.5%. The adsorbent could be regenerated and used 12 times. Therefore, it can be concluded that the pitaya fruit residual biomass can be used as a precursor for preparing carbon-based adsorbents. The adsorbent, in turn, is a promising alternative in the treatment of MY dye and mixtures of organic molecules.11 Páginasapplication/pdfengElsevier BVUnited Kingdom© 2021 Elsevier Ltd. All rights reserved.Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)https://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/embargoedAccesshttp://purl.org/coar/access_right/c_f1cfResidual peel of pitaya fruit (Hylocereus undatus) as a precursor to obtaining an efficient carbon-based adsorbent for the removal of metanil yellow dye from waterArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/acceptedVersionhttps://www.sciencedirect.com/science/article/pii/S2213343721019837Journal of Environmental Chemical EngineeringT. Robinson, G. McMullan, R. Marchant, P. Nigam Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative Bioresour. Technol., 77 (2001), pp. 247-255, 10.1016/S0960-8524(00)00080-8K. Ravikumar, K. Pakshirajan, T. 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