A novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions: Kinetics, equilibrium, thermodynamics, and statistical physics approach
A novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer was obtained by crosslinking β-CD unities and cellulosic fibers of paper towel cardboard via esterification using citric acid. C-β-CD polymer was used as an adsorbent to uptake Hg from aqueous matrices, and kinetics, equilibrium, thermodyna...
- Autores:
-
Jemli, Sonia
Frantz Lütke, Sabrina
Chamtouri, Farah
Ben Amara, Fakhreddine
Bejar, Samir
Silva Oliveira, Marcos Leandro
Knani, Salah
Silva Oliveira, Luis Felipe
Dotto, Guilherme Luiz
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2023
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/13993
- Acceso en línea:
- https://hdl.handle.net/11323/13993
https://repositorio.cuc.edu.co/
- Palabra clave:
- Adsorption
Cartoon
Mercury
Statistical physics
β-cyclodextrin polymer
- Rights
- openAccess
- License
- Atribución 4.0 Internacional (CC BY 4.0)
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| dc.title.eng.fl_str_mv |
A novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions: Kinetics, equilibrium, thermodynamics, and statistical physics approach |
| title |
A novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions: Kinetics, equilibrium, thermodynamics, and statistical physics approach |
| spellingShingle |
A novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions: Kinetics, equilibrium, thermodynamics, and statistical physics approach Adsorption Cartoon Mercury Statistical physics β-cyclodextrin polymer |
| title_short |
A novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions: Kinetics, equilibrium, thermodynamics, and statistical physics approach |
| title_full |
A novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions: Kinetics, equilibrium, thermodynamics, and statistical physics approach |
| title_fullStr |
A novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions: Kinetics, equilibrium, thermodynamics, and statistical physics approach |
| title_full_unstemmed |
A novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions: Kinetics, equilibrium, thermodynamics, and statistical physics approach |
| title_sort |
A novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions: Kinetics, equilibrium, thermodynamics, and statistical physics approach |
| dc.creator.fl_str_mv |
Jemli, Sonia Frantz Lütke, Sabrina Chamtouri, Farah Ben Amara, Fakhreddine Bejar, Samir Silva Oliveira, Marcos Leandro Knani, Salah Silva Oliveira, Luis Felipe Dotto, Guilherme Luiz |
| dc.contributor.author.none.fl_str_mv |
Jemli, Sonia Frantz Lütke, Sabrina Chamtouri, Farah Ben Amara, Fakhreddine Bejar, Samir Silva Oliveira, Marcos Leandro Knani, Salah Silva Oliveira, Luis Felipe Dotto, Guilherme Luiz |
| dc.subject.proposal.eng.fl_str_mv |
Adsorption Cartoon Mercury Statistical physics β-cyclodextrin polymer |
| topic |
Adsorption Cartoon Mercury Statistical physics β-cyclodextrin polymer |
| description |
A novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer was obtained by crosslinking β-CD unities and cellulosic fibers of paper towel cardboard via esterification using citric acid. C-β-CD polymer was used as an adsorbent to uptake Hg from aqueous matrices, and kinetics, equilibrium, thermodynamics, and statistical physics were evaluated. It was found that the C-β-CD polymer was successfully synthesized and was a promising adsorbent to remove Hg from aqueous solution, achieving a removal percentage higher than 90 % and a maximum adsorption capacity of 211.3 mg g−1. The best operational adsorption conditions were a pH of 5.0, an adsorbent dosage of 0.5 g/L, 270 min, and 328 K. Besides, the pseudo-second-order model well-described the adsorption kinetics, and the Langmuir model better represented the equilibrium. The thermodynamic studies pointed to spontaneous and endothermic adsorption. The positive effect of the temperature on the process was also confirmed by the statistical physics approach, where the number of ions adsorbed per site increased with increasing temperature. It was suggested that electrostatic interaction was the main interaction mechanism responsible for the good performance of the novel C-β-CD polymer. In addition, the adsorbent proved to be effective for three adsorption cycles. Finally, it can be concluded that a novel C-β-CD adsorbent was prepared using an easy and green technique, and the obtained material is promising to separate Hg from contaminated waters. |
| publishDate |
2023 |
| dc.date.issued.none.fl_str_mv |
2023-11-02 |
| dc.date.accessioned.none.fl_str_mv |
2025-02-26T20:15:00Z |
| dc.date.available.none.fl_str_mv |
2025-02-26T20:15:00Z |
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Artículo de revista |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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onia Jemli, Sabrina Frantz Lütke, Farah Chamtouri, Fakhreddine Ben Amara, Samir Bejar, Marcos Leandro Silva Oliveira, Salah Knani, Luis Felipe Oliveira Silva, Guilherme Luiz Dotto, A novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions: Kinetics, equilibrium, thermodynamics, and statistical physics approach, Separation and Purification Technology, Volume 330, Part C, 2024, 125578, ISSN 1383-5866, https://doi.org/10.1016/j.seppur.2023.125578. |
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1383-5866 |
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https://hdl.handle.net/11323/13993 |
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10.1016/j.seppur.2023.125578 |
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1873-3794 |
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Corporación Universidad de la Costa |
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REDICUC - Repositorio CUC |
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https://repositorio.cuc.edu.co/ |
| identifier_str_mv |
onia Jemli, Sabrina Frantz Lütke, Farah Chamtouri, Fakhreddine Ben Amara, Samir Bejar, Marcos Leandro Silva Oliveira, Salah Knani, Luis Felipe Oliveira Silva, Guilherme Luiz Dotto, A novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions: Kinetics, equilibrium, thermodynamics, and statistical physics approach, Separation and Purification Technology, Volume 330, Part C, 2024, 125578, ISSN 1383-5866, https://doi.org/10.1016/j.seppur.2023.125578. 1383-5866 10.1016/j.seppur.2023.125578 1873-3794 Corporación Universidad de la Costa REDICUC - Repositorio CUC |
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https://hdl.handle.net/11323/13993 https://repositorio.cuc.edu.co/ |
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eng |
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eng |
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Separation and Purification Technology |
| dc.relation.references.none.fl_str_mv |
S.-A. Sajjadi, A. Mohammadzadeh, H. Nguyen, I. Anastopoulos, A. Ivanets, A. Hosseini-Bandegharaei, Efficient mercury removal from wastewater by pistachio wood wastes-derived activated carbon prepared by chemical activation using a novel activating agent, J. Environ. Manage. 223 (2018) 1001–1009, https://doi. org/10.1016/j.jenvman.2018.06.077. P. Shukla, P. Singhal, S. Manivannan, D. Mandal, Silver impregnated novel adsorbents for capture of elemental Mercury: a review, Environ. Nanotechnol. Monit. Manage. 20 (2023), 100825, https://doi.org/10.1016/j. enmm.2023.100825. S. Kumari, R. Amit, N. Jamwal, D.K.S. Mishra, Recent developments in environmental mercury bioremediation and its toxicity: a review, Environ. Nanotechnol. Monit. Manage. 13 (2020), 100283, https://doi.org/10.1016/j. enmm.2020.100283. L. Yang, Y. Zhang, F. Wang, Z. Luo, S. Guo, U. Strahle, ¨ Toxicity of mercury: molecular evidence, Chemosphere 245 (2020), 125586, https://doi.org/10.1016/j. chemosphere.2019.125586. J.K. Kern, D.A. Geier, L.K. Sykes, B.E. Haley, M.R. Geier, The relationship between mercury and autism: a comprehensive review and discussion, J. Trace Elem. Med Biol. 37 (2016) 8–24, https://doi.org/10.1016/j.jtemb.2016.06.002. S. Ghosh, A. Othmani, A. Malloum, O. Ke Christ, H. Onyeaka, S.S. AlKafaas, N. D. Nnaji, C. Bornman, Z.T. Al-Sharify, S. Ahmadi, M.H. Dehghani, N.M. Mubarak, I. Tyagi, R.R. Karri, J.R. Koduru, Removal of mercury from industrial effluents by adsorption and advanced oxidation processes: a comprehensive review, J. Mol. Liq. 367 (2022), 120491, https://doi.org/10.1016/j.molliq.2022.120491. A. Gupta, S.R. Vidyarthi, N. Sankararamakrishnan, Thiol functionalized sugarcane bagasse-A low cost adsorbent for mercury remediation from compact fluorescent bulbs and contaminated water streams, J. Environ. Chem. Eng. 2 (2014) 1378–1385, https://doi.org/10.1016/j.jece.2014.05.010. H. Albatrni, H. Qiblawey, M.H. El-Naas, Comparative study between adsorption and membrane technologies for the removal of mercury, Sep. Purif. Technol. 257 (2021), 117833, https://doi.org/10.1016/j.seppur.2020.117833. T. Velempini, K. Pillay, Sulphur functionalized materials for Hg(II) adsorption: a review, J. Environ. Chem. Eng. 7 (2019), 103350, https://doi.org/10.1016/j. jece.2019.103350. B. Pagala, Characteristic evaluation of tamarind flower biomass for mercury biosorption: statistical approach, Biomass Convers. Biorefinery. (2023), https:// doi.org/10.1007/s13399-023-03769-x. A. Fathollahi, S.J. Coupe, A.H. El-Sheikh, L.A. Sanudo-Fontaneda, ˜ The biosorption of mercury by permeable pavement biofilms in stormwater attenuation, Sci. Total Environ. 741 (2020), 140411, https://doi.org/10.1016/j.scitotenv.2020.140411. E. Fabre, C. Vale, E. Pereira, C.M. Silva, Sustainable water treatment: Use of agricultural and industrial wastes to remove mercury by biosorption, water, Air. Soil Pollut. 232 (2021) 284, https://doi.org/10.1007/s11270-021-05165-5. T.F. Cova, D. Murtinho, R. Aguado, A.A.C.C. Pais, A.J.M. Valente, Cyclodextrin polymers and cyclodextrin-containing polysaccharides for water remediation, Polysaccharides. 2 (2021) 16–38, https://doi.org/10.3390/ polysaccharides2010002. S. Jemli, E. Ben Messaoud, S. Ben Mabrouk, S. Bejar, The cyclodextrin glycosyltransferase of Paenibacillus pabuli US132 strain: Molecular characterization and overproduction of the recombinant enzyme, J. Biomed. Biotechnol. 2008 (2008), 692573, https://doi.org/10.1155/2008/692573 N. Morin-Crini, S. Fourmentin, E. ´ Fenyvesi, E. Lichtfouse, G. Torri, M. Fourmentin, G. Crini, 130 years of cyclodextrin discovery for health, food, agriculture, and the industry: a review, Environ. Chem. Lett. 19 (2021) 2581–2617, https://doi.org/ 10.1007/s10311-020-01156-w. M.T. Sikder, M.M. Rahman, M. Jakariya, T. Hosokawa, M. Kurasaki, T. Saito, Remediation of water pollution with native cyclodextrins and modified cyclodextrins: a comparative overview and perspectives, Chem. Eng. J. 355 (2019) 920–941, https://doi.org/10.1016/j.cej.2018.08.218. M. Liu, C. Gao, R. Han, L. Qu, Assessment of β-cyclodextrin-immobilizing hydrolyzed polyacrylonitrile membrane for enhanced remediation of bisphenol A and tetracyclines: adsorption and antibacterial studies, J. Clean. Prod. 387 (2023), 135839, https://doi.org/10.1016/j.jclepro.2022.135839. Q. Liu, Y. Zhou, J. Lu, Y. Zhou, Novel cyclodextrin-based adsorbents for removing pollutants from wastewater: a critical review, Chemosphere 241 (2020), 125043, https://doi.org/10.1016/j.chemosphere.2019.125043. K. Kose, ¨ M. Tüysüz, D. Aksüt, L. Uzun, Modification of cyclodextrin and use in environmental applications, Environ. Sci. Pollut. Res. 29 (2022) 182–209, https:// doi.org/10.1007/s11356-021-15005-y. K. Hemine, N. Łukasik, M. Gazda, I. Nowak, β-cyclodextrin-containing polymer based on renewable cellulose resources for effective removal of ionic and non-ionic toxic organic pollutants from water, J. Hazard. Mater. 418 (2021), 126286, https://doi.org/10.1016/j.jhazmat.2021.126286. |
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Atribución 4.0 Internacional (CC BY 4.0)© 2023 Elsevier B.V.https://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Jemli, SoniaFrantz Lütke, SabrinaChamtouri, FarahBen Amara, FakhreddineBejar, SamirSilva Oliveira, Marcos LeandroKnani, SalahSilva Oliveira, Luis FelipeDotto, Guilherme Luiz2025-02-26T20:15:00Z2025-02-26T20:15:00Z2023-11-02onia Jemli, Sabrina Frantz Lütke, Farah Chamtouri, Fakhreddine Ben Amara, Samir Bejar, Marcos Leandro Silva Oliveira, Salah Knani, Luis Felipe Oliveira Silva, Guilherme Luiz Dotto, A novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions: Kinetics, equilibrium, thermodynamics, and statistical physics approach, Separation and Purification Technology, Volume 330, Part C, 2024, 125578, ISSN 1383-5866, https://doi.org/10.1016/j.seppur.2023.125578.1383-5866https://hdl.handle.net/11323/1399310.1016/j.seppur.2023.1255781873-3794Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/A novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer was obtained by crosslinking β-CD unities and cellulosic fibers of paper towel cardboard via esterification using citric acid. C-β-CD polymer was used as an adsorbent to uptake Hg from aqueous matrices, and kinetics, equilibrium, thermodynamics, and statistical physics were evaluated. It was found that the C-β-CD polymer was successfully synthesized and was a promising adsorbent to remove Hg from aqueous solution, achieving a removal percentage higher than 90 % and a maximum adsorption capacity of 211.3 mg g−1. The best operational adsorption conditions were a pH of 5.0, an adsorbent dosage of 0.5 g/L, 270 min, and 328 K. Besides, the pseudo-second-order model well-described the adsorption kinetics, and the Langmuir model better represented the equilibrium. The thermodynamic studies pointed to spontaneous and endothermic adsorption. The positive effect of the temperature on the process was also confirmed by the statistical physics approach, where the number of ions adsorbed per site increased with increasing temperature. It was suggested that electrostatic interaction was the main interaction mechanism responsible for the good performance of the novel C-β-CD polymer. In addition, the adsorbent proved to be effective for three adsorption cycles. Finally, it can be concluded that a novel C-β-CD adsorbent was prepared using an easy and green technique, and the obtained material is promising to separate Hg from contaminated waters.10 páginasapplication/pdfengElsevier B.V.Netherlandshttps://www.sciencedirect.com/science/article/pii/S1383586623024863?via%3DihubA novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions: Kinetics, equilibrium, thermodynamics, and statistical physics approachArtículo de revistahttp://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Separation and Purification TechnologyS.-A. Sajjadi, A. Mohammadzadeh, H. Nguyen, I. Anastopoulos, A. Ivanets, A. Hosseini-Bandegharaei, Efficient mercury removal from wastewater by pistachio wood wastes-derived activated carbon prepared by chemical activation using a novel activating agent, J. Environ. Manage. 223 (2018) 1001–1009, https://doi. org/10.1016/j.jenvman.2018.06.077.P. Shukla, P. Singhal, S. Manivannan, D. Mandal, Silver impregnated novel adsorbents for capture of elemental Mercury: a review, Environ. Nanotechnol. Monit. Manage. 20 (2023), 100825, https://doi.org/10.1016/j. enmm.2023.100825.S. Kumari, R. Amit, N. Jamwal, D.K.S. Mishra, Recent developments in environmental mercury bioremediation and its toxicity: a review, Environ. Nanotechnol. Monit. Manage. 13 (2020), 100283, https://doi.org/10.1016/j. enmm.2020.100283.L. Yang, Y. Zhang, F. Wang, Z. Luo, S. Guo, U. Strahle, ¨ Toxicity of mercury: molecular evidence, Chemosphere 245 (2020), 125586, https://doi.org/10.1016/j. chemosphere.2019.125586.J.K. Kern, D.A. Geier, L.K. Sykes, B.E. Haley, M.R. Geier, The relationship between mercury and autism: a comprehensive review and discussion, J. Trace Elem. Med Biol. 37 (2016) 8–24, https://doi.org/10.1016/j.jtemb.2016.06.002.S. Ghosh, A. Othmani, A. Malloum, O. Ke Christ, H. Onyeaka, S.S. AlKafaas, N. D. Nnaji, C. Bornman, Z.T. Al-Sharify, S. Ahmadi, M.H. Dehghani, N.M. Mubarak, I. Tyagi, R.R. Karri, J.R. Koduru, Removal of mercury from industrial effluents by adsorption and advanced oxidation processes: a comprehensive review, J. Mol. Liq. 367 (2022), 120491, https://doi.org/10.1016/j.molliq.2022.120491.A. Gupta, S.R. Vidyarthi, N. Sankararamakrishnan, Thiol functionalized sugarcane bagasse-A low cost adsorbent for mercury remediation from compact fluorescent bulbs and contaminated water streams, J. Environ. Chem. Eng. 2 (2014) 1378–1385, https://doi.org/10.1016/j.jece.2014.05.010.H. Albatrni, H. Qiblawey, M.H. El-Naas, Comparative study between adsorption and membrane technologies for the removal of mercury, Sep. Purif. Technol. 257 (2021), 117833, https://doi.org/10.1016/j.seppur.2020.117833.T. Velempini, K. Pillay, Sulphur functionalized materials for Hg(II) adsorption: a review, J. Environ. Chem. Eng. 7 (2019), 103350, https://doi.org/10.1016/j. jece.2019.103350.B. Pagala, Characteristic evaluation of tamarind flower biomass for mercury biosorption: statistical approach, Biomass Convers. Biorefinery. (2023), https:// doi.org/10.1007/s13399-023-03769-x.A. Fathollahi, S.J. Coupe, A.H. El-Sheikh, L.A. Sanudo-Fontaneda, ˜ The biosorption of mercury by permeable pavement biofilms in stormwater attenuation, Sci. Total Environ. 741 (2020), 140411, https://doi.org/10.1016/j.scitotenv.2020.140411.E. Fabre, C. Vale, E. Pereira, C.M. Silva, Sustainable water treatment: Use of agricultural and industrial wastes to remove mercury by biosorption, water, Air. Soil Pollut. 232 (2021) 284, https://doi.org/10.1007/s11270-021-05165-5.T.F. Cova, D. Murtinho, R. Aguado, A.A.C.C. Pais, A.J.M. Valente, Cyclodextrin polymers and cyclodextrin-containing polysaccharides for water remediation, Polysaccharides. 2 (2021) 16–38, https://doi.org/10.3390/ polysaccharides2010002.S. Jemli, E. Ben Messaoud, S. Ben Mabrouk, S. Bejar, The cyclodextrin glycosyltransferase of Paenibacillus pabuli US132 strain: Molecular characterization and overproduction of the recombinant enzyme, J. Biomed. Biotechnol. 2008 (2008), 692573, https://doi.org/10.1155/2008/692573N. Morin-Crini, S. Fourmentin, E. ´ Fenyvesi, E. Lichtfouse, G. Torri, M. Fourmentin, G. Crini, 130 years of cyclodextrin discovery for health, food, agriculture, and the industry: a review, Environ. Chem. Lett. 19 (2021) 2581–2617, https://doi.org/ 10.1007/s10311-020-01156-w.M.T. Sikder, M.M. Rahman, M. Jakariya, T. Hosokawa, M. Kurasaki, T. Saito, Remediation of water pollution with native cyclodextrins and modified cyclodextrins: a comparative overview and perspectives, Chem. Eng. J. 355 (2019) 920–941, https://doi.org/10.1016/j.cej.2018.08.218.M. Liu, C. Gao, R. Han, L. Qu, Assessment of β-cyclodextrin-immobilizing hydrolyzed polyacrylonitrile membrane for enhanced remediation of bisphenol A and tetracyclines: adsorption and antibacterial studies, J. Clean. Prod. 387 (2023), 135839, https://doi.org/10.1016/j.jclepro.2022.135839.Q. Liu, Y. Zhou, J. Lu, Y. Zhou, Novel cyclodextrin-based adsorbents for removing pollutants from wastewater: a critical review, Chemosphere 241 (2020), 125043, https://doi.org/10.1016/j.chemosphere.2019.125043.K. Kose, ¨ M. Tüysüz, D. Aksüt, L. Uzun, Modification of cyclodextrin and use in environmental applications, Environ. Sci. Pollut. Res. 29 (2022) 182–209, https:// doi.org/10.1007/s11356-021-15005-y.K. Hemine, N. Łukasik, M. Gazda, I. Nowak, β-cyclodextrin-containing polymer based on renewable cellulose resources for effective removal of ionic and non-ionic toxic organic pollutants from water, J. Hazard. Mater. 418 (2021), 126286, https://doi.org/10.1016/j.jhazmat.2021.126286.101125578330AdsorptionCartoonMercuryStatistical physicsβ-cyclodextrin polymerPublicationORIGINALA novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions Kinetics, equilibrium, thermodynamics, and statistical physics approach.pdfA novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions Kinetics, equilibrium, thermodynamics, and statistical physics approach.pdfapplication/pdf3694412https://repositorio.cuc.edu.co/bitstreams/a6c691cd-23f0-4c2c-9413-68da21707c2b/downloadd5db20cc8fcacc3a68619fc8d5f39097MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-815543https://repositorio.cuc.edu.co/bitstreams/aefbf947-30ae-473d-b3bd-d29612bb4fba/download73a5432e0b76442b22b026844140d683MD52TEXTA novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions Kinetics, equilibrium, thermodynamics, and statistical physics approach.pdf.txtA novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions Kinetics, equilibrium, thermodynamics, and statistical physics approach.pdf.txtExtracted texttext/plain65434https://repositorio.cuc.edu.co/bitstreams/17ee8aaf-2c92-48a2-8fd3-e639804b2e8a/download5f617ca94d57872e2bb4c7c527ac8a65MD53THUMBNAILA novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions Kinetics, equilibrium, thermodynamics, and statistical physics approach.pdf.jpgA novel cartoon crosslinked β-cyclodextrin (C-β-CD) polymer for effective uptake of Hg from aqueous solutions Kinetics, equilibrium, thermodynamics, and statistical physics approach.pdf.jpgGenerated 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ara ejercer estos derechos sobre la Obra tal y como se indica a continuación:</p>
    <ol type="a">
      <li>Reproducir la Obra, incorporar la Obra en una o más Obras Colectivas, y reproducir la Obra incorporada en las Obras Colectivas.</li>
      <li>Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.</li>
      <li>Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.</li>
    </ol>
    <p>Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).</p>
  </li>
  <br/>
  <li>
    Restricciones.
    <p>La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:</p>
    <ol type="a">
      <li>Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).</li>
      <li>Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.</li>
      <li>Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.</li>
      <li>
        Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:
        <ol type="i">
          <li>Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.</li>
          <li>Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.</li>
        </ol>
      </li>
      <li>Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.</li>
    </ol>
  </li>
  <br/>
  <li>
    Representaciones, Garantías y Limitaciones de Responsabilidad.
    <p>A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.</p>
  </li>
  <br/>
  <li>
    Limitación de responsabilidad.
    <p>A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.</p>
  </li>
  <br/>
  <li>
    Término.
    <ol type="a">
      <li>Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.</li>
      <li>Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.</li>
    </ol>
  </li>
  <br/>
  <li>
    Varios.
    <ol type="a">
      <li>Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.</li>
      <li>Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.</li>
      <li>Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.</li>
      <li>Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.</li>
    </ol>
  </li>
  <br/>
</ol>
 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