Detection of bisphenol a and four analogues in atmospheric emissions in petrochemical complexes producing polypropylene in South America

Because of its toxicity and impacts on the environment and human health, bisphenol A (BPA) has been controlled in numerous industrialized nations, increasing demand for bisphenol analogues (BP) for its replacement. However, the consequences of these chemicals on the environment and the health of per...

Full description

Autores:
Hernández Fernández, Joaquín
Guerra, Yoleima
CANO CUADRO, HEIDIS PATRICIA
Tipo de recurso:
Article of journal
Fecha de publicación:
2022
Institución:
Corporación Universidad de la Costa
Repositorio:
REDICUC - Repositorio CUC
Idioma:
eng
OAI Identifier:
oai:repositorio.cuc.edu.co:11323/9439
Acceso en línea:
https://hdl.handle.net/11323/9439
https://doi.org/10.3390/molecules27154832
https://repositorio.cuc.edu.co/
Palabra clave:
Bisphenol A
Bisphenol analogues
Emissions
Polypropylene
Rights
openAccess
License
Atribución 4.0 Internacional (CC BY 4.0)
id RCUC2_e4b80456c846551f9831730454811310
oai_identifier_str oai:repositorio.cuc.edu.co:11323/9439
network_acronym_str RCUC2
network_name_str REDICUC - Repositorio CUC
repository_id_str
dc.title.eng.fl_str_mv Detection of bisphenol a and four analogues in atmospheric emissions in petrochemical complexes producing polypropylene in South America
title Detection of bisphenol a and four analogues in atmospheric emissions in petrochemical complexes producing polypropylene in South America
spellingShingle Detection of bisphenol a and four analogues in atmospheric emissions in petrochemical complexes producing polypropylene in South America
Bisphenol A
Bisphenol analogues
Emissions
Polypropylene
title_short Detection of bisphenol a and four analogues in atmospheric emissions in petrochemical complexes producing polypropylene in South America
title_full Detection of bisphenol a and four analogues in atmospheric emissions in petrochemical complexes producing polypropylene in South America
title_fullStr Detection of bisphenol a and four analogues in atmospheric emissions in petrochemical complexes producing polypropylene in South America
title_full_unstemmed Detection of bisphenol a and four analogues in atmospheric emissions in petrochemical complexes producing polypropylene in South America
title_sort Detection of bisphenol a and four analogues in atmospheric emissions in petrochemical complexes producing polypropylene in South America
dc.creator.fl_str_mv Hernández Fernández, Joaquín
Guerra, Yoleima
CANO CUADRO, HEIDIS PATRICIA
dc.contributor.author.spa.fl_str_mv Hernández Fernández, Joaquín
Guerra, Yoleima
CANO CUADRO, HEIDIS PATRICIA
dc.subject.proposal.eng.fl_str_mv Bisphenol A
Bisphenol analogues
Emissions
Polypropylene
topic Bisphenol A
Bisphenol analogues
Emissions
Polypropylene
description Because of its toxicity and impacts on the environment and human health, bisphenol A (BPA) has been controlled in numerous industrialized nations, increasing demand for bisphenol analogues (BP) for its replacement. However, the consequences of these chemicals on the environment and the health of persons exposed to their emissions are still being researched. The emissions from polypropylene manufacturing facilities in Colombia and Brazil were evaluated in this study, and the presence of bisphenol A and four BPs was detected among the gaseous compounds released, with total concentrations of BPs (∑BP) between 92 and 1565 ng g−1. As the melt flow index (MFI) of the polymer rises, so does the quantity of volatiles in its matrix that are eliminated during deodorization, indicating that the MFI and the amount of bisphenol released have a directly proportional connection.
publishDate 2022
dc.date.accessioned.none.fl_str_mv 2022-08-08T16:54:22Z
dc.date.available.none.fl_str_mv 2022-08-08T16:54:22Z
dc.date.issued.none.fl_str_mv 2022-07-28
dc.type.spa.fl_str_mv Artículo de revista
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.coarversion.fl_str_mv http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_6501
dc.type.content.spa.fl_str_mv Text
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/article
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/ART
format http://purl.org/coar/resource_type/c_6501
dc.identifier.citation.spa.fl_str_mv Fernández, J.H.; Guerra, Y.; Cano, H. Detection of Bisphenol A and Four Analogues in Atmospheric Emissions in Petrochemical Complexes Producing Polypropylene in South America. Molecules 2022, 27, 4832. https://doi.org/10.3390/molecules27154832
dc.identifier.uri.spa.fl_str_mv https://hdl.handle.net/11323/9439
dc.identifier.url.spa.fl_str_mv https://doi.org/10.3390/molecules27154832
dc.identifier.doi.spa.fl_str_mv 10.3390/molecules27154832
dc.identifier.eissn.spa.fl_str_mv 1420-3049
dc.identifier.instname.spa.fl_str_mv Corporación Universidad de la Costa
dc.identifier.reponame.spa.fl_str_mv REDICUC - Repositorio CUC
dc.identifier.repourl.spa.fl_str_mv https://repositorio.cuc.edu.co/
identifier_str_mv Fernández, J.H.; Guerra, Y.; Cano, H. Detection of Bisphenol A and Four Analogues in Atmospheric Emissions in Petrochemical Complexes Producing Polypropylene in South America. Molecules 2022, 27, 4832. https://doi.org/10.3390/molecules27154832
10.3390/molecules27154832
1420-3049
Corporación Universidad de la Costa
REDICUC - Repositorio CUC
url https://hdl.handle.net/11323/9439
https://doi.org/10.3390/molecules27154832
https://repositorio.cuc.edu.co/
dc.language.iso.none.fl_str_mv eng
language eng
dc.relation.ispartofjournal.spa.fl_str_mv Molecules
dc.relation.references.spa.fl_str_mv 1. Chen, D.; Kannan, K.; Tan, H.; Zheng, Z.; Feng, Y.-L.; Wu, Y.; Widelka, M. Bisphenol Analogues Other Than BPA: Environmental Occurrence, Human Exposure, and Toxicity—A Review. Environ. Sci. Technol. 2016, 50, 5438–5453. [CrossRef]
2. Moon, M.K. Concern about the Safety of Bisphenol A Substitutes. Diabetes Metab. J. 2019, 43, 46–48. [CrossRef] [PubMed]
3. Morin, N.; Arp, H.P.H.; Hale, S.E. Bisphenol A in Solid Waste Materials, Leachate Water, and Air Particles from Norwegian Waste-Handling Facilities: Presence and Partitioning Behavior. Environ. Sci. Technol. 2015, 49, 7675–7683. [CrossRef]
4. Mihaich, E.M.; Friederich, U.; Caspers, N.; Hall, A.T.; Klecka, G.M.; Dimond, S.S.; Staples, C.A.; Ortego, L.S.; Hentges, S.G. Acute and chronic toxicity testing of bisphenol A with aquatic invertebrates and plants. Ecotoxicol. Environ. Saf. 2009, 72, 1392–1399. [CrossRef] [PubMed]
5. Belfroid, A.; van Velzen, M.; van der Horst, B.; Vethaak, D. Occurrence of bisphenol A in surface water and uptake in fish: Evaluation of field measurements. Chemosphere 2002, 49, 97–103. [CrossRef]
6. Gao, H.; Yang, B.-J.; Li, N.; Feng, L.-M.; Shi, X.-Y.; Zhao, W.-H.; Liu, S.-J. Bisphenol A and hormone-associated cancers: Current progress and perspectives. Medicine 2015, 94, e211. [CrossRef] [PubMed]
7. Catenza, C.J.; Farooq, A.; Shubear, N.S.; Donkor, K.K. A targeted review on fate, occurrence, risk and health implications of bisphenol analogues. Chemosphere 2021, 268, 129273. [CrossRef]
8. Cimmino, I.; Fiory, F.; Perruolo, G.; Miele, C.; Beguinot, F.; Formisano, P.; Oriente, F. Potential Mechanisms of Bisphenol A (BPA) Contributing to Human Disease. Int. J. Mol. Sci. 2020, 21, 5761. [CrossRef]
9. Gao, X.; Wang, H.-S. Impact of bisphenol a on the cardiovascular system-epidemiological and experimental evidence and molecular mechanisms. Int. J. Environ. Res. Public Health 2014, 11, 8399–8413. [CrossRef] [PubMed]
10. Liao, C.; Kannan, K. Concentrations and Profiles of Bisphenol A and Other Bisphenol Analogues in Foodstuffs from the United States and Their Implications for Human Exposure. J. Agric. Food Chem. 2013, 61, 4655–4662. [CrossRef]
11. Qiu, W.; Zhan, H.; Hu, J.; Zhang, T.; Xu, H.; Wong, M.; Xu, B.; Zheng, C. The occurrence, potential toxicity, and toxicity mechanism of bisphenol S, a substitute of bisphenol A: A critical review of recent progress. Ecotoxicol. Environ. Saf. 2019, 173, 192–202. [CrossRef] [PubMed]
12. Han, Y.; Fei, Y.; Wang, M.; Xue, Y.; Chen, H.; Liu, Y. Study on the Joint Toxicity of BPZ, BPS, BPC and BPF to Zebrafish. Molecules 2021, 26, 4180. [CrossRef]
13. Gao, C.; He, H.; Qiu, W.; Zheng, Y.; Chen, Y.; Hu, S.; Zhao, X. Oxidative Stress, Endocrine Disturbance, and Immune Interference in Humans Showed Relationships to Serum Bisphenol Concentrations in a Dense Industrial Area. Environ. Sci. Technol. 2021, 55, 1953–1963. [CrossRef] [PubMed]
14. Zhang, H.; Quan, Q.; Zhang, M.; Zhang, N.; Zhang, W.; Zhan, M.; Xu, W.; Lu, L.; Fan, J.; Wang, Q. Occurrence of bisphenol A and its alternatives in paired urine and indoor dust from Chinese university students: Implications for human exposure. Chemosphere 2020, 247, 125987. [CrossRef]
15. Liao, C.; Liu, F.; Kannan, K. Bisphenol S, a New Bisphenol Analogue, in Paper Products and Currency Bills and Its Association with Bisphenol A Residues. Environ. Sci. Technol. 2012, 46, 6515–6522. [CrossRef]
16. Corrales, J.; Kristofco, L.A.; Steele, W.B.; Yates, B.S.; Breed, C.S.; Williams, E.S.; Brooks, B.W. Global Assessment of Bisphenol A in the Environment: Review and Analysis of Its Occurrence and Bioaccumulation. Dose-Response Publ. Int. Hormesis Soc. 2015, 13, 15593258–15598308. [CrossRef]
17. Hernández-Fernández, J.; Lopez-Martinez, J.; Barceló, D. Quantification and elimination of substituted synthetic phenols and volatile organic compounds in the wastewater treatment plant during the production of industrial scale polypropylene. Chemosphere 2021, 263, 128027. [CrossRef] [PubMed]
18. Hernández-Fernández, J. Quantification of arsine and phosphine in industrial atmospheric emissions in Spain and Colombia. Implementation of modified zeolites to reduce the environmental impact of emissions. Atmospheric Pollut. Res. 2021, 12, 167–176. [CrossRef]
19. Hernández-Fernández, J. Quantification of oxygenates, sulphides, thiols and permanent gases in propylene. A multiple linear regression model to predict the loss of efficiency in polypropylene production on an industrial scale. J. Chromatogr. A 2020, 1628, 461–478. [CrossRef] [PubMed]
20. Joaquin, H.-F.; Juan, L. Quantification of poisons for Ziegler Natta catalysts and effects on the production of polypropylene by gas chromatographic with simultaneous detection: Pulsed discharge helium ionization, mass spectrometry and flame ionization. J. Chromatogr. A 2020, 1614, 460736. [CrossRef]
21. Joaquin, H.-F.; Juan, L.-M. Autocatalytic influence of different levels of arsine on the thermal stability and pyrolysis of polypropylene. J. Anal. Appl. Pyrolysis 2022, 161, 105385. [CrossRef]
22. Hernández-Fernandez, J.; Rodríguez, E. Determination of phenolic antioxidants additives in industrial wastewater from polypropylene production using solid phase extraction with high-performance liquid chromatography. J. Chromatogr. A 2019, 1607, 460442. [CrossRef]
23. Hernández-Fernández, J.; López-Martínez, J. Experimental study of the auto-catalytic effect of triethylaluminum and TiCl4 residuals at the onset of non-additive polypropylene degradation and their impact on thermo-oxidative degradation and pyrolysis. J. Anal. Appl. Pyrolysis 2021, 155, 105052. [CrossRef]
24. Hernández-Fernández, J.; Lopez-Martinez, J.; Barceló, D. Development and validation of a methodology for quantifying partsper-billion levels of arsine and phosphine in nitrogen, hydrogen and liquefied petroleum gas using a variable pressure sampler coupled to gas chromatography-mass spectrometry. J. Chromatogr. A 2021, 1637, 461833. [CrossRef]
25. Lee, S.; Liao, C.; Song, G.-J.; Ra, K.; Kannan, K.; Moon, H.-B. Emission of bisphenol analogues including bisphenol A and bisphenol F from wastewater treatment plants in Korea. Chemosphere 2015, 119, 1000–1006. [CrossRef]
26. Wang, W.; Abualnaja, K.O.; Asimakopoulos, A.G.; Covaci, A.; Gevao, B.; Johnson-Restrepo, B.; Kumosani, T.A.; Malarvannan, G.; BinhMinh, T.; Moon, H.-B.; et al. A comparative assessment of human exposure to tetrabromobisphenol A and eight bisphenols including bisphenol A via indoor dust ingestion in twelve countries. Environ. Int. 2015, 83, 183–191. [CrossRef] [PubMed]
27. Barroso, P.J.; Martín, J.; Santos, J.L.; Aparicio, I.; Alonso, E. Evaluation of the airborne pollution by emerging contaminants using bitter orange (Citrus aurantium) tree leaves as biosamplers. Sci. Total Environ. 2019, 677, 484–492. [CrossRef]
28. Geens, T.; Roosens, L.; Neels, H.; Covaci, A. Assessment of human exposure to Bisphenol-A, Triclosan and Tetrabromobisphenol-A through indoor dust intake in Belgium. Chemosphere 2009, 76, 755–760. [CrossRef]
dc.relation.citationendpage.spa.fl_str_mv 9
dc.relation.citationstartpage.spa.fl_str_mv 1
dc.relation.citationissue.spa.fl_str_mv 15
dc.relation.citationvolume.spa.fl_str_mv 27
dc.rights.spa.fl_str_mv Atribución 4.0 Internacional (CC BY 4.0)
© 2022 by the authors. Licensee MDPI, Basel, Switzerland.
dc.rights.uri.spa.fl_str_mv https://creativecommons.org/licenses/by/4.0/
dc.rights.accessrights.spa.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.coar.spa.fl_str_mv http://purl.org/coar/access_right/c_abf2
rights_invalid_str_mv Atribución 4.0 Internacional (CC BY 4.0)
© 2022 by the authors. Licensee MDPI, Basel, Switzerland.
https://creativecommons.org/licenses/by/4.0/
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.extent.spa.fl_str_mv 9 páginas
dc.format.mimetype.spa.fl_str_mv application/pdf
dc.coverage.region.none.fl_str_mv South America
dc.publisher.spa.fl_str_mv Multidisciplinary Digital Publishing Institute (MDPI)
dc.publisher.place.spa.fl_str_mv Switzerland
institution Corporación Universidad de la Costa
dc.source.url.spa.fl_str_mv https://www.mdpi.com/1420-3049/27/15/4832
bitstream.url.fl_str_mv https://repositorio.cuc.edu.co/bitstreams/5b8dfd66-4015-49a8-9ccf-c73e1a6f7ab2/download
https://repositorio.cuc.edu.co/bitstreams/a904ad8b-6f70-469d-9e7d-b6f6af441f5b/download
https://repositorio.cuc.edu.co/bitstreams/6fa039a1-c497-42e1-a067-e19dbea13a86/download
https://repositorio.cuc.edu.co/bitstreams/2d703462-2c64-4ef0-a054-1e07cb52b06a/download
bitstream.checksum.fl_str_mv 8b07d2fb0afc87e6d07786f605796455
e30e9215131d99561d40d6b0abbe9bad
7a40282e4cc677c4a04121d93fcb8ee2
df98ede983184edb85d741648cfa2ee5
bitstream.checksumAlgorithm.fl_str_mv MD5
MD5
MD5
MD5
repository.name.fl_str_mv Repositorio de la Universidad de la Costa CUC
repository.mail.fl_str_mv repdigital@cuc.edu.co
_version_ 1811760744723644416
spelling Hernández Fernández, JoaquínGuerra, YoleimaCANO CUADRO, HEIDIS PATRICIA2022-08-08T16:54:22Z2022-08-08T16:54:22Z2022-07-28Fernández, J.H.; Guerra, Y.; Cano, H. Detection of Bisphenol A and Four Analogues in Atmospheric Emissions in Petrochemical Complexes Producing Polypropylene in South America. Molecules 2022, 27, 4832. https://doi.org/10.3390/molecules27154832https://hdl.handle.net/11323/9439https://doi.org/10.3390/molecules2715483210.3390/molecules271548321420-3049Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/Because of its toxicity and impacts on the environment and human health, bisphenol A (BPA) has been controlled in numerous industrialized nations, increasing demand for bisphenol analogues (BP) for its replacement. However, the consequences of these chemicals on the environment and the health of persons exposed to their emissions are still being researched. The emissions from polypropylene manufacturing facilities in Colombia and Brazil were evaluated in this study, and the presence of bisphenol A and four BPs was detected among the gaseous compounds released, with total concentrations of BPs (∑BP) between 92 and 1565 ng g−1. As the melt flow index (MFI) of the polymer rises, so does the quantity of volatiles in its matrix that are eliminated during deodorization, indicating that the MFI and the amount of bisphenol released have a directly proportional connection.9 páginasapplication/pdfengMultidisciplinary Digital Publishing Institute (MDPI)SwitzerlandAtribución 4.0 Internacional (CC BY 4.0)© 2022 by the authors. Licensee MDPI, Basel, Switzerland.https://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Detection of bisphenol a and four analogues in atmospheric emissions in petrochemical complexes producing polypropylene in South AmericaArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARThttp://purl.org/coar/version/c_970fb48d4fbd8a85https://www.mdpi.com/1420-3049/27/15/4832South AmericaMolecules1. Chen, D.; Kannan, K.; Tan, H.; Zheng, Z.; Feng, Y.-L.; Wu, Y.; Widelka, M. Bisphenol Analogues Other Than BPA: Environmental Occurrence, Human Exposure, and Toxicity—A Review. Environ. Sci. Technol. 2016, 50, 5438–5453. [CrossRef]2. Moon, M.K. Concern about the Safety of Bisphenol A Substitutes. Diabetes Metab. J. 2019, 43, 46–48. [CrossRef] [PubMed]3. Morin, N.; Arp, H.P.H.; Hale, S.E. Bisphenol A in Solid Waste Materials, Leachate Water, and Air Particles from Norwegian Waste-Handling Facilities: Presence and Partitioning Behavior. Environ. Sci. Technol. 2015, 49, 7675–7683. [CrossRef]4. Mihaich, E.M.; Friederich, U.; Caspers, N.; Hall, A.T.; Klecka, G.M.; Dimond, S.S.; Staples, C.A.; Ortego, L.S.; Hentges, S.G. Acute and chronic toxicity testing of bisphenol A with aquatic invertebrates and plants. Ecotoxicol. Environ. Saf. 2009, 72, 1392–1399. [CrossRef] [PubMed]5. Belfroid, A.; van Velzen, M.; van der Horst, B.; Vethaak, D. Occurrence of bisphenol A in surface water and uptake in fish: Evaluation of field measurements. Chemosphere 2002, 49, 97–103. [CrossRef]6. Gao, H.; Yang, B.-J.; Li, N.; Feng, L.-M.; Shi, X.-Y.; Zhao, W.-H.; Liu, S.-J. Bisphenol A and hormone-associated cancers: Current progress and perspectives. Medicine 2015, 94, e211. [CrossRef] [PubMed]7. Catenza, C.J.; Farooq, A.; Shubear, N.S.; Donkor, K.K. A targeted review on fate, occurrence, risk and health implications of bisphenol analogues. Chemosphere 2021, 268, 129273. [CrossRef]8. Cimmino, I.; Fiory, F.; Perruolo, G.; Miele, C.; Beguinot, F.; Formisano, P.; Oriente, F. Potential Mechanisms of Bisphenol A (BPA) Contributing to Human Disease. Int. J. Mol. Sci. 2020, 21, 5761. [CrossRef]9. Gao, X.; Wang, H.-S. Impact of bisphenol a on the cardiovascular system-epidemiological and experimental evidence and molecular mechanisms. Int. J. Environ. Res. Public Health 2014, 11, 8399–8413. [CrossRef] [PubMed]10. Liao, C.; Kannan, K. Concentrations and Profiles of Bisphenol A and Other Bisphenol Analogues in Foodstuffs from the United States and Their Implications for Human Exposure. J. Agric. Food Chem. 2013, 61, 4655–4662. [CrossRef]11. Qiu, W.; Zhan, H.; Hu, J.; Zhang, T.; Xu, H.; Wong, M.; Xu, B.; Zheng, C. The occurrence, potential toxicity, and toxicity mechanism of bisphenol S, a substitute of bisphenol A: A critical review of recent progress. Ecotoxicol. Environ. Saf. 2019, 173, 192–202. [CrossRef] [PubMed]12. Han, Y.; Fei, Y.; Wang, M.; Xue, Y.; Chen, H.; Liu, Y. Study on the Joint Toxicity of BPZ, BPS, BPC and BPF to Zebrafish. Molecules 2021, 26, 4180. [CrossRef]13. Gao, C.; He, H.; Qiu, W.; Zheng, Y.; Chen, Y.; Hu, S.; Zhao, X. Oxidative Stress, Endocrine Disturbance, and Immune Interference in Humans Showed Relationships to Serum Bisphenol Concentrations in a Dense Industrial Area. Environ. Sci. Technol. 2021, 55, 1953–1963. [CrossRef] [PubMed]14. Zhang, H.; Quan, Q.; Zhang, M.; Zhang, N.; Zhang, W.; Zhan, M.; Xu, W.; Lu, L.; Fan, J.; Wang, Q. Occurrence of bisphenol A and its alternatives in paired urine and indoor dust from Chinese university students: Implications for human exposure. Chemosphere 2020, 247, 125987. [CrossRef]15. Liao, C.; Liu, F.; Kannan, K. Bisphenol S, a New Bisphenol Analogue, in Paper Products and Currency Bills and Its Association with Bisphenol A Residues. Environ. Sci. Technol. 2012, 46, 6515–6522. [CrossRef]16. Corrales, J.; Kristofco, L.A.; Steele, W.B.; Yates, B.S.; Breed, C.S.; Williams, E.S.; Brooks, B.W. Global Assessment of Bisphenol A in the Environment: Review and Analysis of Its Occurrence and Bioaccumulation. Dose-Response Publ. Int. Hormesis Soc. 2015, 13, 15593258–15598308. [CrossRef]17. Hernández-Fernández, J.; Lopez-Martinez, J.; Barceló, D. Quantification and elimination of substituted synthetic phenols and volatile organic compounds in the wastewater treatment plant during the production of industrial scale polypropylene. Chemosphere 2021, 263, 128027. [CrossRef] [PubMed]18. Hernández-Fernández, J. Quantification of arsine and phosphine in industrial atmospheric emissions in Spain and Colombia. Implementation of modified zeolites to reduce the environmental impact of emissions. Atmospheric Pollut. Res. 2021, 12, 167–176. [CrossRef]19. Hernández-Fernández, J. Quantification of oxygenates, sulphides, thiols and permanent gases in propylene. A multiple linear regression model to predict the loss of efficiency in polypropylene production on an industrial scale. J. Chromatogr. A 2020, 1628, 461–478. [CrossRef] [PubMed]20. Joaquin, H.-F.; Juan, L. Quantification of poisons for Ziegler Natta catalysts and effects on the production of polypropylene by gas chromatographic with simultaneous detection: Pulsed discharge helium ionization, mass spectrometry and flame ionization. J. Chromatogr. A 2020, 1614, 460736. [CrossRef]21. Joaquin, H.-F.; Juan, L.-M. Autocatalytic influence of different levels of arsine on the thermal stability and pyrolysis of polypropylene. J. Anal. Appl. Pyrolysis 2022, 161, 105385. [CrossRef]22. Hernández-Fernandez, J.; Rodríguez, E. Determination of phenolic antioxidants additives in industrial wastewater from polypropylene production using solid phase extraction with high-performance liquid chromatography. J. Chromatogr. A 2019, 1607, 460442. [CrossRef]23. Hernández-Fernández, J.; López-Martínez, J. Experimental study of the auto-catalytic effect of triethylaluminum and TiCl4 residuals at the onset of non-additive polypropylene degradation and their impact on thermo-oxidative degradation and pyrolysis. J. Anal. Appl. Pyrolysis 2021, 155, 105052. [CrossRef]24. Hernández-Fernández, J.; Lopez-Martinez, J.; Barceló, D. Development and validation of a methodology for quantifying partsper-billion levels of arsine and phosphine in nitrogen, hydrogen and liquefied petroleum gas using a variable pressure sampler coupled to gas chromatography-mass spectrometry. J. Chromatogr. A 2021, 1637, 461833. [CrossRef]25. Lee, S.; Liao, C.; Song, G.-J.; Ra, K.; Kannan, K.; Moon, H.-B. Emission of bisphenol analogues including bisphenol A and bisphenol F from wastewater treatment plants in Korea. Chemosphere 2015, 119, 1000–1006. [CrossRef]26. Wang, W.; Abualnaja, K.O.; Asimakopoulos, A.G.; Covaci, A.; Gevao, B.; Johnson-Restrepo, B.; Kumosani, T.A.; Malarvannan, G.; BinhMinh, T.; Moon, H.-B.; et al. A comparative assessment of human exposure to tetrabromobisphenol A and eight bisphenols including bisphenol A via indoor dust ingestion in twelve countries. Environ. Int. 2015, 83, 183–191. [CrossRef] [PubMed]27. Barroso, P.J.; Martín, J.; Santos, J.L.; Aparicio, I.; Alonso, E. Evaluation of the airborne pollution by emerging contaminants using bitter orange (Citrus aurantium) tree leaves as biosamplers. Sci. Total Environ. 2019, 677, 484–492. [CrossRef]28. Geens, T.; Roosens, L.; Neels, H.; Covaci, A. Assessment of human exposure to Bisphenol-A, Triclosan and Tetrabromobisphenol-A through indoor dust intake in Belgium. Chemosphere 2009, 76, 755–760. [CrossRef]911527Bisphenol ABisphenol analoguesEmissionsPolypropylenePublicationORIGINALDetection of Bisphenol A and Four Analogues in Atmospheric Emissions in Petrochemical Complexes Producing Polypropylene in South America.pdfDetection of Bisphenol A and Four Analogues in Atmospheric Emissions in Petrochemical Complexes Producing Polypropylene in South America.pdfapplication/pdf859208https://repositorio.cuc.edu.co/bitstreams/5b8dfd66-4015-49a8-9ccf-c73e1a6f7ab2/download8b07d2fb0afc87e6d07786f605796455MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-83196https://repositorio.cuc.edu.co/bitstreams/a904ad8b-6f70-469d-9e7d-b6f6af441f5b/downloade30e9215131d99561d40d6b0abbe9badMD52TEXTDetection of Bisphenol A and Four Analogues in Atmospheric Emissions in Petrochemical Complexes Producing Polypropylene in South America.pdf.txtDetection of Bisphenol A and Four Analogues in Atmospheric Emissions in Petrochemical Complexes Producing Polypropylene in South America.pdf.txttext/plain36071https://repositorio.cuc.edu.co/bitstreams/6fa039a1-c497-42e1-a067-e19dbea13a86/download7a40282e4cc677c4a04121d93fcb8ee2MD53THUMBNAILDetection of Bisphenol A and Four Analogues in Atmospheric Emissions in Petrochemical Complexes Producing Polypropylene in South America.pdf.jpgDetection of Bisphenol A and Four Analogues in Atmospheric Emissions in Petrochemical Complexes Producing Polypropylene in South America.pdf.jpgimage/jpeg16291https://repositorio.cuc.edu.co/bitstreams/2d703462-2c64-4ef0-a054-1e07cb52b06a/downloaddf98ede983184edb85d741648cfa2ee5MD5411323/9439oai:repositorio.cuc.edu.co:11323/94392024-09-17 10:56:14.959https://creativecommons.org/licenses/by/4.0/Atribución 4.0 Internacional (CC BY 4.0)open.accesshttps://repositorio.cuc.edu.coRepositorio de la Universidad de la Costa CUCrepdigital@cuc.edu.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

Publicaciones similares