Femtosecond-laser direct writing for spatially localized synthesis of PPV
Poly(p-phenylenevinylene), or PPV, is a polymer of great technological relevance due to its electroluminescence properties, which have been exploited in organic light emitting diodes, flexible displays and other optoelectronic devices. Although PPV is a material of foremost importance for many appli...
- Autores:
-
Avila, Oriana Ines
Almeida, Juliana M.P.
Henrique, Franciele Renata
Fonseca Rodriguez, Ruben Dario
Brito Almeida, Gustavo Foresto
Balogh, Debora T.
Mendonca, Cléber Renato
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2017
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/1954
- Acceso en línea:
- https://hdl.handle.net/11323/1954
https://doi.org/10.1039/C7TC00079K
https://repositorio.cuc.edu.co/
- Palabra clave:
- Display devices
Electromagnetic pulse
Flexible displays
Light emitting diodes
Optical waveguides
Optoelectronic devices
Organic light emitting diodes (OLED)
Polymers
Ultrafast lasers
- Rights
- openAccess
- License
- Atribución – No comercial – Compartir igual
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REDICUC - Repositorio CUC |
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|
dc.title.eng.fl_str_mv |
Femtosecond-laser direct writing for spatially localized synthesis of PPV |
title |
Femtosecond-laser direct writing for spatially localized synthesis of PPV |
spellingShingle |
Femtosecond-laser direct writing for spatially localized synthesis of PPV Display devices Electromagnetic pulse Flexible displays Light emitting diodes Optical waveguides Optoelectronic devices Organic light emitting diodes (OLED) Polymers Ultrafast lasers |
title_short |
Femtosecond-laser direct writing for spatially localized synthesis of PPV |
title_full |
Femtosecond-laser direct writing for spatially localized synthesis of PPV |
title_fullStr |
Femtosecond-laser direct writing for spatially localized synthesis of PPV |
title_full_unstemmed |
Femtosecond-laser direct writing for spatially localized synthesis of PPV |
title_sort |
Femtosecond-laser direct writing for spatially localized synthesis of PPV |
dc.creator.fl_str_mv |
Avila, Oriana Ines Almeida, Juliana M.P. Henrique, Franciele Renata Fonseca Rodriguez, Ruben Dario Brito Almeida, Gustavo Foresto Balogh, Debora T. Mendonca, Cléber Renato |
dc.contributor.author.spa.fl_str_mv |
Avila, Oriana Ines Almeida, Juliana M.P. Henrique, Franciele Renata Fonseca Rodriguez, Ruben Dario Brito Almeida, Gustavo Foresto Balogh, Debora T. Mendonca, Cléber Renato |
dc.subject.eng.fl_str_mv |
Display devices Electromagnetic pulse Flexible displays Light emitting diodes Optical waveguides Optoelectronic devices Organic light emitting diodes (OLED) Polymers Ultrafast lasers |
topic |
Display devices Electromagnetic pulse Flexible displays Light emitting diodes Optical waveguides Optoelectronic devices Organic light emitting diodes (OLED) Polymers Ultrafast lasers |
description |
Poly(p-phenylenevinylene), or PPV, is a polymer of great technological relevance due to its electroluminescence properties, which have been exploited in organic light emitting diodes, flexible displays and other optoelectronic devices. Although PPV is a material of foremost importance for many applications, its synthesis on the nano/microscale cannot be achieved through the standard method that uses heating of a precursor polymer. This paper shows how direct laser writing with femtosecond pulses can be employed for the synthesis of PPV in pre-determined regions, allowing a novel approach towards the precise fabrication of complex polymeric microcircuits. The physical-chemical phenomena involved in the conversion of the precursor into PPV are shown to be related to a two-photon induced thermal process, which is confined to the focal volume, resulting in the controlled synthesis of PPV. |
publishDate |
2017 |
dc.date.issued.none.fl_str_mv |
2017 |
dc.date.accessioned.none.fl_str_mv |
2018-11-27T16:38:51Z |
dc.date.available.none.fl_str_mv |
2018-11-27T16:38:51Z |
dc.type.spa.fl_str_mv |
Artículo de revista |
dc.type.coar.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
dc.type.coar.spa.fl_str_mv |
http://purl.org/coar/resource_type/c_6501 |
dc.type.content.spa.fl_str_mv |
Text |
dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.redcol.spa.fl_str_mv |
http://purl.org/redcol/resource_type/ART |
dc.type.version.spa.fl_str_mv |
info:eu-repo/semantics/acceptedVersion |
format |
http://purl.org/coar/resource_type/c_6501 |
status_str |
acceptedVersion |
dc.identifier.issn.spa.fl_str_mv |
20507534 |
dc.identifier.uri.spa.fl_str_mv |
https://hdl.handle.net/11323/1954 |
dc.identifier.doi.spa.fl_str_mv |
https://doi.org/10.1039/C7TC00079K |
dc.identifier.instname.spa.fl_str_mv |
Corporación Universidad de la Costa |
dc.identifier.reponame.spa.fl_str_mv |
REDICUC - Repositorio CUC |
dc.identifier.repourl.spa.fl_str_mv |
https://repositorio.cuc.edu.co/ |
identifier_str_mv |
20507534 Corporación Universidad de la Costa REDICUC - Repositorio CUC |
url |
https://hdl.handle.net/11323/1954 https://doi.org/10.1039/C7TC00079K https://repositorio.cuc.edu.co/ |
dc.language.iso.none.fl_str_mv |
eng |
language |
eng |
dc.rights.spa.fl_str_mv |
Atribución – No comercial – Compartir igual |
dc.rights.accessrights.spa.fl_str_mv |
info:eu-repo/semantics/openAccess |
dc.rights.coar.spa.fl_str_mv |
http://purl.org/coar/access_right/c_abf2 |
rights_invalid_str_mv |
Atribución – No comercial – Compartir igual http://purl.org/coar/access_right/c_abf2 |
eu_rights_str_mv |
openAccess |
dc.publisher.spa.fl_str_mv |
Journal of Materials Chemistry C |
institution |
Corporación Universidad de la Costa |
bitstream.url.fl_str_mv |
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spelling |
Avila, Oriana InesAlmeida, Juliana M.P.Henrique, Franciele RenataFonseca Rodriguez, Ruben DarioBrito Almeida, Gustavo ForestoBalogh, Debora T.Mendonca, Cléber Renato2018-11-27T16:38:51Z2018-11-27T16:38:51Z201720507534https://hdl.handle.net/11323/1954https://doi.org/10.1039/C7TC00079KCorporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/Poly(p-phenylenevinylene), or PPV, is a polymer of great technological relevance due to its electroluminescence properties, which have been exploited in organic light emitting diodes, flexible displays and other optoelectronic devices. Although PPV is a material of foremost importance for many applications, its synthesis on the nano/microscale cannot be achieved through the standard method that uses heating of a precursor polymer. This paper shows how direct laser writing with femtosecond pulses can be employed for the synthesis of PPV in pre-determined regions, allowing a novel approach towards the precise fabrication of complex polymeric microcircuits. The physical-chemical phenomena involved in the conversion of the precursor into PPV are shown to be related to a two-photon induced thermal process, which is confined to the focal volume, resulting in the controlled synthesis of PPV.Avila, Oriana Ines-f178902f-bddf-42ec-8355-21f987b0cf4b-0Almeida, Juliana M.P.-62e90638-6fec-4bef-b235-efd4f65b7e97-0Henrique, Franciele Renata-29c525ff-f082-4774-830e-5a59614bc7ce-0Fonseca Rodriguez, Ruben Dario-ad03b26d-04c5-4346-aa20-00a1cd7d2e87-0Brito Almeida, Gustavo Foresto-12bc9585-67d9-4510-ac44-b0cb12e4640e-0Balogh, Debora T.-c46c06fa-d1ab-4362-8f51-dcdf4fb9baa3-0Mendonca, Cléber Renato-8bcea319-748a-448c-b2e2-da4a9d8799d9-0engJournal of Materials Chemistry CAtribución – No comercial – Compartir igualinfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Display devicesElectromagnetic pulseFlexible displaysLight emitting diodesOptical waveguidesOptoelectronic devicesOrganic light emitting diodes (OLED)PolymersUltrafast lasersFemtosecond-laser direct writing for spatially localized synthesis of PPVArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/acceptedVersionPublicationORIGINALFemtosecond-laser direct writing for spatially localized synthesis.pdfFemtosecond-laser direct writing for spatially localized synthesis.pdfapplication/pdf180420https://repositorio.cuc.edu.co/bitstreams/4c786577-81e9-4a32-9b4f-6ea28f51d559/download22ffe170d98f148ed9cd801b3b92d579MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://repositorio.cuc.edu.co/bitstreams/931befc6-0b16-45c0-abb6-0c7800ebaddf/download8a4605be74aa9ea9d79846c1fba20a33MD52THUMBNAILFemtosecond-laser direct writing for spatially localized synthesis.pdf.jpgFemtosecond-laser direct writing for spatially localized synthesis.pdf.jpgimage/jpeg44379https://repositorio.cuc.edu.co/bitstreams/cd05fba5-6f0b-4ccd-89ca-01058be2d443/download4eea30b9a515dab97bc4cbded534f2c3MD54TEXTFemtosecond-laser direct writing for spatially localized synthesis.pdf.txtFemtosecond-laser direct writing for spatially localized synthesis.pdf.txttext/plain1397https://repositorio.cuc.edu.co/bitstreams/51f38d23-b34a-471d-a976-6227e9b8b3bf/download5a59832397db8675c1ca9c9118edcad0MD5511323/1954oai:repositorio.cuc.edu.co:11323/19542024-09-17 14:24:28.591open.accesshttps://repositorio.cuc.edu.coRepositorio de la Universidad de la Costa CUCrepdigital@cuc.edu.coTk9URTogUExBQ0UgWU9VUiBPV04gTElDRU5TRSBIRVJFClRoaXMgc2FtcGxlIGxpY2Vuc2UgaXMgcHJvdmlkZWQgZm9yIGluZm9ybWF0aW9uYWwgcHVycG9zZXMgb25seS4KCk5PTi1FWENMVVNJVkUgRElTVFJJQlVUSU9OIExJQ0VOU0UKCkJ5IHNpZ25pbmcgYW5kIHN1Ym1pdHRpbmcgdGhpcyBsaWNlbnNlLCB5b3UgKHRoZSBhdXRob3Iocykgb3IgY29weXJpZ2h0Cm93bmVyKSBncmFudHMgdG8gRFNwYWNlIFVuaXZlcnNpdHkgKERTVSkgdGhlIG5vbi1leGNsdXNpdmUgcmlnaHQgdG8gcmVwcm9kdWNlLAp0cmFuc2xhdGUgKGFzIGRlZmluZWQgYmVsb3cpLCBhbmQvb3IgZGlzdHJpYnV0ZSB5b3VyIHN1Ym1pc3Npb24gKGluY2x1ZGluZwp0aGUgYWJzdHJhY3QpIHdvcmxkd2lkZSBpbiBwcmludCBhbmQgZWxlY3Ryb25pYyBmb3JtYXQgYW5kIGluIGFueSBtZWRpdW0sCmluY2x1ZGluZyBidXQgbm90IGxpbWl0ZWQgdG8gYXVkaW8gb3IgdmlkZW8uCgpZb3UgYWdyZWUgdGhhdCBEU1UgbWF5LCB3aXRob3V0IGNoYW5naW5nIHRoZSBjb250ZW50LCB0cmFuc2xhdGUgdGhlCnN1Ym1pc3Npb24gdG8gYW55IG1lZGl1bSBvciBmb3JtYXQgZm9yIHRoZSBwdXJwb3NlIG9mIHByZXNlcnZhdGlvbi4KCllvdSBhbHNvIGFncmVlIHRoYXQgRFNVIG1heSBrZWVwIG1vcmUgdGhhbiBvbmUgY29weSBvZiB0aGlzIHN1Ym1pc3Npb24gZm9yCnB1cnBvc2VzIG9mIHNlY3VyaXR5LCBiYWNrLXVwIGFuZCBwcmVzZXJ2YXRpb24uCgpZb3UgcmVwcmVzZW50IHRoYXQgdGhlIHN1Ym1pc3Npb24gaXMgeW91ciBvcmlnaW5hbCB3b3JrLCBhbmQgdGhhdCB5b3UgaGF2ZQp0aGUgcmlnaHQgdG8gZ3JhbnQgdGhlIHJpZ2h0cyBjb250YWluZWQgaW4gdGhpcyBsaWNlbnNlLiBZb3UgYWxzbyByZXByZXNlbnQKdGhhdCB5b3VyIHN1Ym1pc3Npb24gZG9lcyBub3QsIHRvIHRoZSBiZXN0IG9mIHlvdXIga25vd2xlZGdlLCBpbmZyaW5nZSB1cG9uCmFueW9uZSdzIGNvcHlyaWdodC4KCklmIHRoZSBzdWJtaXNzaW9uIGNvbnRhaW5zIG1hdGVyaWFsIGZvciB3aGljaCB5b3UgZG8gbm90IGhvbGQgY29weXJpZ2h0LAp5b3UgcmVwcmVzZW50IHRoYXQgeW91IGhhdmUgb2J0YWluZWQgdGhlIHVucmVzdHJpY3RlZCBwZXJtaXNzaW9uIG9mIHRoZQpjb3B5cmlnaHQgb3duZXIgdG8gZ3JhbnQgRFNVIHRoZSByaWdodHMgcmVxdWlyZWQgYnkgdGhpcyBsaWNlbnNlLCBhbmQgdGhhdApzdWNoIHRoaXJkLXBhcnR5IG93bmVkIG1hdGVyaWFsIGlzIGNsZWFybHkgaWRlbnRpZmllZCBhbmQgYWNrbm93bGVkZ2VkCndpdGhpbiB0aGUgdGV4dCBvciBjb250ZW50IG9mIHRoZSBzdWJtaXNzaW9uLgoKSUYgVEhFIFNVQk1JU1NJT04gSVMgQkFTRUQgVVBPTiBXT1JLIFRIQVQgSEFTIEJFRU4gU1BPTlNPUkVEIE9SIFNVUFBPUlRFRApCWSBBTiBBR0VOQ1kgT1IgT1JHQU5JWkFUSU9OIE9USEVSIFRIQU4gRFNVLCBZT1UgUkVQUkVTRU5UIFRIQVQgWU9VIEhBVkUKRlVMRklMTEVEIEFOWSBSSUdIVCBPRiBSRVZJRVcgT1IgT1RIRVIgT0JMSUdBVElPTlMgUkVRVUlSRUQgQlkgU1VDSApDT05UUkFDVCBPUiBBR1JFRU1FTlQuCgpEU1Ugd2lsbCBjbGVhcmx5IGlkZW50aWZ5IHlvdXIgbmFtZShzKSBhcyB0aGUgYXV0aG9yKHMpIG9yIG93bmVyKHMpIG9mIHRoZQpzdWJtaXNzaW9uLCBhbmQgd2lsbCBub3QgbWFrZSBhbnkgYWx0ZXJhdGlvbiwgb3RoZXIgdGhhbiBhcyBhbGxvd2VkIGJ5IHRoaXMKbGljZW5zZSwgdG8geW91ciBzdWJtaXNzaW9uLgo= |