Femtosecond-laser direct writing for spatially localized synthesis of PPV

Poly(p-phenylenevinylene), or PPV, is a polymer of great technological relevance due to its electroluminescence properties, which have been exploited in organic light emitting diodes, flexible displays and other optoelectronic devices. Although PPV is a material of foremost importance for many appli...

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Autores:
Avila, Oriana Ines
Almeida, Juliana M.P.
Henrique, Franciele Renata
Fonseca Rodriguez, Ruben Dario
Brito Almeida, Gustavo Foresto
Balogh, Debora T.
Mendonca, Cléber Renato
Tipo de recurso:
Article of journal
Fecha de publicación:
2017
Institución:
Corporación Universidad de la Costa
Repositorio:
REDICUC - Repositorio CUC
Idioma:
eng
OAI Identifier:
oai:repositorio.cuc.edu.co:11323/1954
Acceso en línea:
https://hdl.handle.net/11323/1954
https://doi.org/10.1039/C7TC00079K
https://repositorio.cuc.edu.co/
Palabra clave:
Display devices
Electromagnetic pulse
Flexible displays
Light emitting diodes
Optical waveguides
Optoelectronic devices
Organic light emitting diodes (OLED)
Polymers
Ultrafast lasers
Rights
openAccess
License
Atribución – No comercial – Compartir igual
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dc.title.eng.fl_str_mv Femtosecond-laser direct writing for spatially localized synthesis of PPV
title Femtosecond-laser direct writing for spatially localized synthesis of PPV
spellingShingle Femtosecond-laser direct writing for spatially localized synthesis of PPV
Display devices
Electromagnetic pulse
Flexible displays
Light emitting diodes
Optical waveguides
Optoelectronic devices
Organic light emitting diodes (OLED)
Polymers
Ultrafast lasers
title_short Femtosecond-laser direct writing for spatially localized synthesis of PPV
title_full Femtosecond-laser direct writing for spatially localized synthesis of PPV
title_fullStr Femtosecond-laser direct writing for spatially localized synthesis of PPV
title_full_unstemmed Femtosecond-laser direct writing for spatially localized synthesis of PPV
title_sort Femtosecond-laser direct writing for spatially localized synthesis of PPV
dc.creator.fl_str_mv Avila, Oriana Ines
Almeida, Juliana M.P.
Henrique, Franciele Renata
Fonseca Rodriguez, Ruben Dario
Brito Almeida, Gustavo Foresto
Balogh, Debora T.
Mendonca, Cléber Renato
dc.contributor.author.spa.fl_str_mv Avila, Oriana Ines
Almeida, Juliana M.P.
Henrique, Franciele Renata
Fonseca Rodriguez, Ruben Dario
Brito Almeida, Gustavo Foresto
Balogh, Debora T.
Mendonca, Cléber Renato
dc.subject.eng.fl_str_mv Display devices
Electromagnetic pulse
Flexible displays
Light emitting diodes
Optical waveguides
Optoelectronic devices
Organic light emitting diodes (OLED)
Polymers
Ultrafast lasers
topic Display devices
Electromagnetic pulse
Flexible displays
Light emitting diodes
Optical waveguides
Optoelectronic devices
Organic light emitting diodes (OLED)
Polymers
Ultrafast lasers
description Poly(p-phenylenevinylene), or PPV, is a polymer of great technological relevance due to its electroluminescence properties, which have been exploited in organic light emitting diodes, flexible displays and other optoelectronic devices. Although PPV is a material of foremost importance for many applications, its synthesis on the nano/microscale cannot be achieved through the standard method that uses heating of a precursor polymer. This paper shows how direct laser writing with femtosecond pulses can be employed for the synthesis of PPV in pre-determined regions, allowing a novel approach towards the precise fabrication of complex polymeric microcircuits. The physical-chemical phenomena involved in the conversion of the precursor into PPV are shown to be related to a two-photon induced thermal process, which is confined to the focal volume, resulting in the controlled synthesis of PPV.
publishDate 2017
dc.date.issued.none.fl_str_mv 2017
dc.date.accessioned.none.fl_str_mv 2018-11-27T16:38:51Z
dc.date.available.none.fl_str_mv 2018-11-27T16:38:51Z
dc.type.spa.fl_str_mv Artículo de revista
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
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dc.type.content.spa.fl_str_mv Text
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dc.identifier.issn.spa.fl_str_mv 20507534
dc.identifier.uri.spa.fl_str_mv https://hdl.handle.net/11323/1954
dc.identifier.doi.spa.fl_str_mv https://doi.org/10.1039/C7TC00079K
dc.identifier.instname.spa.fl_str_mv Corporación Universidad de la Costa
dc.identifier.reponame.spa.fl_str_mv REDICUC - Repositorio CUC
dc.identifier.repourl.spa.fl_str_mv https://repositorio.cuc.edu.co/
identifier_str_mv 20507534
Corporación Universidad de la Costa
REDICUC - Repositorio CUC
url https://hdl.handle.net/11323/1954
https://doi.org/10.1039/C7TC00079K
https://repositorio.cuc.edu.co/
dc.language.iso.none.fl_str_mv eng
language eng
dc.rights.spa.fl_str_mv Atribución – No comercial – Compartir igual
dc.rights.accessrights.spa.fl_str_mv info:eu-repo/semantics/openAccess
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rights_invalid_str_mv Atribución – No comercial – Compartir igual
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.publisher.spa.fl_str_mv Journal of Materials Chemistry C
institution Corporación Universidad de la Costa
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spelling Avila, Oriana InesAlmeida, Juliana M.P.Henrique, Franciele RenataFonseca Rodriguez, Ruben DarioBrito Almeida, Gustavo ForestoBalogh, Debora T.Mendonca, Cléber Renato2018-11-27T16:38:51Z2018-11-27T16:38:51Z201720507534https://hdl.handle.net/11323/1954https://doi.org/10.1039/C7TC00079KCorporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/Poly(p-phenylenevinylene), or PPV, is a polymer of great technological relevance due to its electroluminescence properties, which have been exploited in organic light emitting diodes, flexible displays and other optoelectronic devices. Although PPV is a material of foremost importance for many applications, its synthesis on the nano/microscale cannot be achieved through the standard method that uses heating of a precursor polymer. This paper shows how direct laser writing with femtosecond pulses can be employed for the synthesis of PPV in pre-determined regions, allowing a novel approach towards the precise fabrication of complex polymeric microcircuits. The physical-chemical phenomena involved in the conversion of the precursor into PPV are shown to be related to a two-photon induced thermal process, which is confined to the focal volume, resulting in the controlled synthesis of PPV.Avila, Oriana Ines-f178902f-bddf-42ec-8355-21f987b0cf4b-0Almeida, Juliana M.P.-62e90638-6fec-4bef-b235-efd4f65b7e97-0Henrique, Franciele Renata-29c525ff-f082-4774-830e-5a59614bc7ce-0Fonseca Rodriguez, Ruben Dario-ad03b26d-04c5-4346-aa20-00a1cd7d2e87-0Brito Almeida, Gustavo Foresto-12bc9585-67d9-4510-ac44-b0cb12e4640e-0Balogh, Debora T.-c46c06fa-d1ab-4362-8f51-dcdf4fb9baa3-0Mendonca, Cléber Renato-8bcea319-748a-448c-b2e2-da4a9d8799d9-0engJournal of Materials Chemistry CAtribución – No comercial – Compartir igualinfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Display devicesElectromagnetic pulseFlexible displaysLight emitting diodesOptical waveguidesOptoelectronic devicesOrganic light emitting diodes (OLED)PolymersUltrafast lasersFemtosecond-laser direct writing for spatially localized synthesis of PPVArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/acceptedVersionPublicationORIGINALFemtosecond-laser direct writing for spatially localized synthesis.pdfFemtosecond-laser direct writing for spatially localized synthesis.pdfapplication/pdf180420https://repositorio.cuc.edu.co/bitstreams/4c786577-81e9-4a32-9b4f-6ea28f51d559/download22ffe170d98f148ed9cd801b3b92d579MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://repositorio.cuc.edu.co/bitstreams/931befc6-0b16-45c0-abb6-0c7800ebaddf/download8a4605be74aa9ea9d79846c1fba20a33MD52THUMBNAILFemtosecond-laser direct writing for spatially localized synthesis.pdf.jpgFemtosecond-laser direct writing for spatially localized synthesis.pdf.jpgimage/jpeg44379https://repositorio.cuc.edu.co/bitstreams/cd05fba5-6f0b-4ccd-89ca-01058be2d443/download4eea30b9a515dab97bc4cbded534f2c3MD54TEXTFemtosecond-laser direct writing for spatially localized synthesis.pdf.txtFemtosecond-laser direct writing for spatially localized synthesis.pdf.txttext/plain1397https://repositorio.cuc.edu.co/bitstreams/51f38d23-b34a-471d-a976-6227e9b8b3bf/download5a59832397db8675c1ca9c9118edcad0MD5511323/1954oai:repositorio.cuc.edu.co:11323/19542024-09-17 14:24:28.591open.accesshttps://repositorio.cuc.edu.coRepositorio de la Universidad de la Costa CUCrepdigital@cuc.edu.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