Production of adsorbent for removal of propranolol hydrochloride: Use of residues from Bactris guineensis fruit palm with economically exploitable potential from the Colombian Caribbean
The production and consequently the consumption of the pulp of the fruit of the palm tree Bactris guineensis occurs extensively in Colombia. The majority of the fruit is formed by waste (peel and core), producing high residual biomass. Thus, it is necessary to find a practical utilization of these p...
- Autores:
-
Dison S.P., Franco
georgin, jordana
Gindri Ramos, Claudete
Netto, Matias S.
Lobo, Brayan
Jiménez, Gabriel
Lima, Eder C.
Sher, Farooq
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2023
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/10475
- Acceso en línea:
- https://hdl.handle.net/11323/10475
https://repositorio.cuc.edu.co/
- Palabra clave:
- Propranolol hydrochloride
Fruit palm
Colombian Caribbean
- Rights
- embargoedAccess
- License
- Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)
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| dc.title.eng.fl_str_mv |
Production of adsorbent for removal of propranolol hydrochloride: Use of residues from Bactris guineensis fruit palm with economically exploitable potential from the Colombian Caribbean |
| title |
Production of adsorbent for removal of propranolol hydrochloride: Use of residues from Bactris guineensis fruit palm with economically exploitable potential from the Colombian Caribbean |
| spellingShingle |
Production of adsorbent for removal of propranolol hydrochloride: Use of residues from Bactris guineensis fruit palm with economically exploitable potential from the Colombian Caribbean Propranolol hydrochloride Fruit palm Colombian Caribbean |
| title_short |
Production of adsorbent for removal of propranolol hydrochloride: Use of residues from Bactris guineensis fruit palm with economically exploitable potential from the Colombian Caribbean |
| title_full |
Production of adsorbent for removal of propranolol hydrochloride: Use of residues from Bactris guineensis fruit palm with economically exploitable potential from the Colombian Caribbean |
| title_fullStr |
Production of adsorbent for removal of propranolol hydrochloride: Use of residues from Bactris guineensis fruit palm with economically exploitable potential from the Colombian Caribbean |
| title_full_unstemmed |
Production of adsorbent for removal of propranolol hydrochloride: Use of residues from Bactris guineensis fruit palm with economically exploitable potential from the Colombian Caribbean |
| title_sort |
Production of adsorbent for removal of propranolol hydrochloride: Use of residues from Bactris guineensis fruit palm with economically exploitable potential from the Colombian Caribbean |
| dc.creator.fl_str_mv |
Dison S.P., Franco georgin, jordana Gindri Ramos, Claudete Netto, Matias S. Lobo, Brayan Jiménez, Gabriel Lima, Eder C. Sher, Farooq |
| dc.contributor.author.none.fl_str_mv |
Dison S.P., Franco georgin, jordana Gindri Ramos, Claudete Netto, Matias S. Lobo, Brayan Jiménez, Gabriel Lima, Eder C. Sher, Farooq |
| dc.subject.proposal.eng.fl_str_mv |
Propranolol hydrochloride Fruit palm Colombian Caribbean |
| topic |
Propranolol hydrochloride Fruit palm Colombian Caribbean |
| description |
The production and consequently the consumption of the pulp of the fruit of the palm tree Bactris guineensis occurs extensively in Colombia. The majority of the fruit is formed by waste (peel and core), producing high residual biomass. Thus, it is necessary to find a practical utilization of these peels, making the production and consumption of the fruit of the palm tree Bactris guineensis highly sustainable. This study produced activated biochar chemically activated using ZnCl2 and utilized it as an effective adsorbent. The high micropollutant uptake is because of the high porosity and good specific surface area (SBET = 625 m2 g−1). Under basic conditions, propranolol adsorption was favored for an adsorbent dosage of 0.7 g/L. The adsorbent showed fast kinetics, with the equilibrium influenced by the concentration. Avrami's model showed a satisfactory fit having a t0.95 ranging from 47.8 to 179.3 min. Equilibrium data were best adjusted to the Liu isotherm model. The values of Qmax increased with the temperature, reaching up to 161.3 mg g−1 (45 °C). The thermodynamic data showed ΔG° < 0 for 298–328 K (adsorption process favorable) ΔH°= + 7.403 kJ mol−1 (endothermic; magnitude compatible with physical adsorption), and ΔS°= +115.2 J K−1 mol−1 (releases of water molecules of the adsorbate before it being adsorbed in the carbon surface). The biochar chemically activated with ZnCl2, produced from the leftover peels of Colombian palm fruits, is therefore inferred to be a promising option as an adsorbent for the treatment of effluents containing the medication propranolol hydrochloride. |
| publishDate |
2023 |
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2023-09-11T18:59:40Z |
| dc.date.available.none.fl_str_mv |
2023-09-11T18:59:40Z 2024 |
| dc.date.issued.none.fl_str_mv |
2023 |
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Artículo de revista |
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Dison Stracke Pfingsten Franco, Jordana Georgin, Claudete Gindri Ramos, Matias S. Netto, Brayan Lobo, Gabriel Jimenez, Eder C. Lima, Farooq Sher, Production of adsorbent for removal of propranolol hydrochloride: Use of residues from Bactris guineensis fruit palm with economically exploitable potential from the Colombian Caribbean, Journal of Molecular Liquids, Volume 380, 2023, 121677, ISSN 0167-7322, https://doi.org/10.1016/j.molliq.2023.121677. |
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0885-9701 |
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https://hdl.handle.net/11323/10475 |
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10.1016/j.molliq.2023.121677 |
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1550-509X |
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Corporación Universidad de la Costa |
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REDICUC - Repositorio CUC |
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https://repositorio.cuc.edu.co/ |
| identifier_str_mv |
Dison Stracke Pfingsten Franco, Jordana Georgin, Claudete Gindri Ramos, Matias S. Netto, Brayan Lobo, Gabriel Jimenez, Eder C. Lima, Farooq Sher, Production of adsorbent for removal of propranolol hydrochloride: Use of residues from Bactris guineensis fruit palm with economically exploitable potential from the Colombian Caribbean, Journal of Molecular Liquids, Volume 380, 2023, 121677, ISSN 0167-7322, https://doi.org/10.1016/j.molliq.2023.121677. 0885-9701 10.1016/j.molliq.2023.121677 1550-509X Corporación Universidad de la Costa REDICUC - Repositorio CUC |
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https://hdl.handle.net/11323/10475 https://repositorio.cuc.edu.co/ |
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eng |
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eng |
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Journal of Head Trauma Rehabilitation |
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J.C.V. Sposito et al. Emerging contaminants in Brazilian rivers: Occurrence and effects on gene expression in zebrafish (Danio rerio) embryos Chemosphere. (2018) J. Georgin et al. A review of the toxicology presence and removal of ketoprofen through adsorption technology J. Environ Chem. Eng. (2022) R. Ozola-Davidane et al. Bentonite-ionic liquid composites for Congo red removal from aqueous solutions J. Mol. Liq. (2021) B. Petrie et al. A review on emerging contaminants in wastewaters and the environment: Current knowledge, understudied areas and recommendations for future monitoring Water Res. (2015) N.H. Tran et al. Occurrence and the fate of emerging contaminants in municipal wastewater treatment plants from different geographical regions-a review Water Res. (2018) L. Sbardella et al. Advanced biological activated carbon filter for removing pharmaceutically active compounds from treated wastewater Sci. Total Environ. (2018) J. Menz et al. Transformation products in the water cycle and the unsolved problem of their proactive assessment: A combined in vitro/in silico approach Environ. Int. (2017) V. Arya et al. Adsorption of pharmaceuticals in water using Fe3O4 coated polymer clay composite Micropor. Mesopor. Mater. (2016) D. Ashton et al. Investigating the environmental transport of human pharmaceuticals to streams in the United Kingdom Sci. Total Environ. (2004) J. Maszkowska et al. Beta-blockers in the environment: Part II. Ecotoxicity study Sci. Total Environ. (2014) C. Peña-Guzmán et al. Emerging pollutants in the urban water cycle in Latin America: A review of the current literature J. Environ. Manage. (2019) M.C.V.M. Starling et al. Occurrence, control, and the fate of contaminants of emerging concern in environmental compartments in Brazil J. Hazard. Mater. (2019) H.T.B. Phan et al. Visible light-induced degradation of propranolol with peroxymonosulfate as an oxidant and a radical precursor Sep. Purif. Technol. (2022) A.H. Jawad et al. High surface area and mesoporous activated carbon from KOH-activated dragon fruit peels for methylene blue dye adsorption: Optimization and mechanism study, Chinese J Chem. Eng. (2021) Y. Ding et al. Lignin peroxidase-catalyzed direct oxidation of trace organic pollutants through a long-range electron transfer mechanism: Using propranolol as an example J. Hazard. Mater. (2022) A.B. Rakhym et al. Physicochemical evaluation of the effect of natural zeolite modification with didodecyl-dimethyl-ammonium bromide on the adsorption of Bisphenol-A and Propranolol Hydrochloride Micropor. Mesopor. Mater. (2021) D.S.P. Franco et al. Journal of Water Process Engineering Advances made in removing paraquat herbicide by adsorption technology : A review J. Water Process Eng. (2022) A. Bhatnagar et al. Utilization of agro-industrial and municipal waste materials as potential adsorbents for water treatment-A review Chem. Eng. J. (2010) A.H. Jawad et al. High surface area and mesoporous activated carbon from KOH-activated dragon fruit peels for methylene blue dye adsorption: Optimization and mechanism study, Chinese J Chem. Eng. (2021) N.F.G.M. Cimirro et al. Removal of diphenols using pine biochar. Kinetics, equilibrium, thermodynamics, and mechanism of uptake J. Mol. Liq. (2022) E. Brieva-Oviedo et al. Pollination of Bactris guineensis (Arecaceae), a potential economically exploitable fruit palm from the Colombian Caribbean Flora Morphol. Distrib. Funct. Ecol. Plants. (2020) C. Diaz-Uribe et al. TiO2 thin films sensitization with natural dyes extracted from Bactris guineensis for photocatalytic applications: Experimental and DFT study J. Saudi Chem. Soc. (2020) Y. Gao et al. Insight into activated carbon from different kinds of chemical activating agents: A review Sci. Total Environ. (2020) R. Leyva-Ramos et al. Model simulation and analysis of surface diffusion of liquids in porous solids Chem. Eng. Sci. (1985) E.C. Lima et al. Is one performing the treatment data of adsorption kinetics correctly? J. Environ. Chem. Eng. (2021) E.C. Lima et al. Response to “Some remarks on a critical review of the estimation of the thermodynamic parameters on adsorption equilibria. Wrong use of equilibrium constant in the van't Hoff equation for calculation of thermodynamic parameters of adsorption - Journal of J. Mol. Liq. (2019) E.C. Lima et al. A critical review of the estimation of the thermodynamic parameters on adsorption equilibria. Wrong use of equilibrium constant in the Van't Hoof equation for calculation of thermodynamic parameters of adsorption J. Mol. Liq. (2019) E.C. Lima et al. Comparison of the nonlinear and linear forms of the van't Hoff equation for calculation of adsorption thermodynamic parameters (ΔS° and ΔH°) J. Mol. Liq. (2020) H.N. Tran et al. Thermodynamic parameters of liquid–phase adsorption process calculated from different equilibrium constants related to adsorption isotherms: A comparison study J. Environ. Chem. Eng. (2021) O. Üner et al. The effect of carbonization temperature, carbonization time and impregnation ratio on the properties of activated carbon produced from Arundo donax Micropor. Mesopor. Mater. (2018) D.S.P. Franco et al. Preparation of activated carbons from fruit residues for the removal of naproxen (NPX): Analytical interpretation via statistical physical model J. Mol. Liq. (2022) J. Georgin et al. Effective adsorption of harmful herbicide diuron onto novel activated carbon from Hovenia dulcis Colloids Surfaces A Physicochem. Eng. Asp. (2022) E.M. Cuerda-Correa et al. On the use of carbon blacks as potential low-cost adsorbents for the removal of non-steroidal anti-inflammatory drugs from river water J. Hazard. Mater. (2010) M. Guo et al. Carbon nanotube-grafted chitosan and its adsorption capacity for phenol in aqueous solution Sci. Total Environ. (2019) H. Wu et al. Bifunctional porous polyethyleneimine-grafted lignin microspheres for efficient adsorption of 2,4-dichlorophenoxyacetic acid over a wide pH range and controlled release Chem. Eng. J. (2021) G. Cruz González et al. Degradation of 2,4-dichlorophenoxyacetic acid by photolysis and photo-Fenton oxidation J. Environ Chem. Eng. (2018) A.C. Lua et al. Effect of activation temperature on the textural and chemical properties of potassium hydroxide activated carbon prepared from the pistachio-nut shell J. Colloid Interface Sci. (2004) C. Bouchelta et al. Preparation and characterization of activated carbon from date stones by physical activation with steam J. Anal. Appl. Pyrolysis. (2008) X. Li et al. Inhibition of the corrosion of steel in HCl, H2SO4 solutions by bamboo leaf extract Corros. Sci. (2012) A.C. Lua et al. Effects of pyrolysis conditions on the properties of activated carbons prepared from pistachio-nut shells J. Anal. Appl. Pyrolysis. (2004) A.T. Mohd Din et al. Batch adsorption of phenol onto physiochemical-activated coconut shell J. Hazard. Mater. (2009) Y.L. Salomón et al. Adsorption of atrazine herbicide from water by diospyros kaki fruit waste activated carbon J. Mol. Liq. (2022) Y. Vieira et al. An advanced combination of density functional theory simulations and statistical physics modeling in the unveiling and prediction of adsorption mechanisms of 2,4-D pesticide to activated carbon J. Mol. Liq. (2022) D.S.P. Franco et al. Highly effective adsorption of synthetic phenol effluent by a novel activated carbon prepared from fruit wastes of the Ceiba speciosa forest species J. Environ. Chem. Eng. (2021) J.S. Lazarotto et al. Microporous activated carbon from the fruits of the invasive species Hovenia dulcis to remove the herbicide atrazine from waters J. Mol. Liq. (2022) |
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Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)https://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/embargoedAccesshttp://purl.org/coar/access_right/c_f1cfDison S.P., Francogeorgin, jordanaGindri Ramos, ClaudeteNetto, Matias S.Lobo, BrayanJiménez, GabrielLima, Eder C.Sher, Farooq2023-09-11T18:59:40Z20242023-09-11T18:59:40Z2023Dison Stracke Pfingsten Franco, Jordana Georgin, Claudete Gindri Ramos, Matias S. Netto, Brayan Lobo, Gabriel Jimenez, Eder C. Lima, Farooq Sher, Production of adsorbent for removal of propranolol hydrochloride: Use of residues from Bactris guineensis fruit palm with economically exploitable potential from the Colombian Caribbean, Journal of Molecular Liquids, Volume 380, 2023, 121677, ISSN 0167-7322, https://doi.org/10.1016/j.molliq.2023.121677.0885-9701https://hdl.handle.net/11323/1047510.1016/j.molliq.2023.1216771550-509XCorporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/The production and consequently the consumption of the pulp of the fruit of the palm tree Bactris guineensis occurs extensively in Colombia. The majority of the fruit is formed by waste (peel and core), producing high residual biomass. Thus, it is necessary to find a practical utilization of these peels, making the production and consumption of the fruit of the palm tree Bactris guineensis highly sustainable. This study produced activated biochar chemically activated using ZnCl2 and utilized it as an effective adsorbent. The high micropollutant uptake is because of the high porosity and good specific surface area (SBET = 625 m2 g−1). Under basic conditions, propranolol adsorption was favored for an adsorbent dosage of 0.7 g/L. The adsorbent showed fast kinetics, with the equilibrium influenced by the concentration. Avrami's model showed a satisfactory fit having a t0.95 ranging from 47.8 to 179.3 min. Equilibrium data were best adjusted to the Liu isotherm model. The values of Qmax increased with the temperature, reaching up to 161.3 mg g−1 (45 °C). The thermodynamic data showed ΔG° < 0 for 298–328 K (adsorption process favorable) ΔH°= + 7.403 kJ mol−1 (endothermic; magnitude compatible with physical adsorption), and ΔS°= +115.2 J K−1 mol−1 (releases of water molecules of the adsorbate before it being adsorbed in the carbon surface). The biochar chemically activated with ZnCl2, produced from the leftover peels of Colombian palm fruits, is therefore inferred to be a promising option as an adsorbent for the treatment of effluents containing the medication propranolol hydrochloride.1 páginaapplication/pdfengLippincott Williams and Wilkins Ltd.United Stateshttps://www.sciencedirect.com/science/article/abs/pii/S0167732223004804Production of adsorbent for removal of propranolol hydrochloride: Use of residues from Bactris guineensis fruit palm with economically exploitable potential from the Colombian CaribbeanArtículo de revistahttp://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/drafthttp://purl.org/coar/version/c_b1a7d7d4d402bcceCaribbean RegionJournal of Head Trauma RehabilitationJ.C.V. Sposito et al. Emerging contaminants in Brazilian rivers: Occurrence and effects on gene expression in zebrafish (Danio rerio) embryos Chemosphere. (2018)J. Georgin et al. A review of the toxicology presence and removal of ketoprofen through adsorption technology J. Environ Chem. Eng. (2022)R. Ozola-Davidane et al. Bentonite-ionic liquid composites for Congo red removal from aqueous solutions J. Mol. Liq. (2021)B. Petrie et al. A review on emerging contaminants in wastewaters and the environment: Current knowledge, understudied areas and recommendations for future monitoring Water Res. (2015)N.H. Tran et al. Occurrence and the fate of emerging contaminants in municipal wastewater treatment plants from different geographical regions-a review Water Res. (2018)L. Sbardella et al. Advanced biological activated carbon filter for removing pharmaceutically active compounds from treated wastewater Sci. Total Environ. (2018)J. Menz et al. Transformation products in the water cycle and the unsolved problem of their proactive assessment: A combined in vitro/in silico approach Environ. Int. (2017)V. Arya et al. Adsorption of pharmaceuticals in water using Fe3O4 coated polymer clay composite Micropor. Mesopor. Mater. (2016)D. Ashton et al. Investigating the environmental transport of human pharmaceuticals to streams in the United Kingdom Sci. Total Environ. (2004)J. Maszkowska et al. Beta-blockers in the environment: Part II. Ecotoxicity study Sci. Total Environ. (2014)C. Peña-Guzmán et al. Emerging pollutants in the urban water cycle in Latin America: A review of the current literature J. Environ. Manage. (2019)M.C.V.M. Starling et al. Occurrence, control, and the fate of contaminants of emerging concern in environmental compartments in Brazil J. Hazard. Mater. (2019)H.T.B. Phan et al. Visible light-induced degradation of propranolol with peroxymonosulfate as an oxidant and a radical precursor Sep. Purif. Technol. (2022)A.H. Jawad et al. High surface area and mesoporous activated carbon from KOH-activated dragon fruit peels for methylene blue dye adsorption: Optimization and mechanism study, Chinese J Chem. Eng. (2021)Y. Ding et al. Lignin peroxidase-catalyzed direct oxidation of trace organic pollutants through a long-range electron transfer mechanism: Using propranolol as an example J. Hazard. Mater. (2022)A.B. Rakhym et al. Physicochemical evaluation of the effect of natural zeolite modification with didodecyl-dimethyl-ammonium bromide on the adsorption of Bisphenol-A and Propranolol Hydrochloride Micropor. Mesopor. Mater. (2021)D.S.P. Franco et al. Journal of Water Process Engineering Advances made in removing paraquat herbicide by adsorption technology : A review J. Water Process Eng. (2022)A. Bhatnagar et al. Utilization of agro-industrial and municipal waste materials as potential adsorbents for water treatment-A review Chem. Eng. J. (2010)A.H. Jawad et al. High surface area and mesoporous activated carbon from KOH-activated dragon fruit peels for methylene blue dye adsorption: Optimization and mechanism study, Chinese J Chem. Eng. (2021)N.F.G.M. Cimirro et al. Removal of diphenols using pine biochar. Kinetics, equilibrium, thermodynamics, and mechanism of uptake J. Mol. Liq. (2022)E. Brieva-Oviedo et al. Pollination of Bactris guineensis (Arecaceae), a potential economically exploitable fruit palm from the Colombian Caribbean Flora Morphol. Distrib. Funct. Ecol. Plants. (2020)C. Diaz-Uribe et al. TiO2 thin films sensitization with natural dyes extracted from Bactris guineensis for photocatalytic applications: Experimental and DFT study J. Saudi Chem. Soc. (2020)Y. Gao et al. Insight into activated carbon from different kinds of chemical activating agents: A review Sci. Total Environ. (2020)R. Leyva-Ramos et al. Model simulation and analysis of surface diffusion of liquids in porous solids Chem. Eng. Sci. (1985)E.C. Lima et al. Is one performing the treatment data of adsorption kinetics correctly? J. Environ. Chem. Eng. (2021)E.C. Lima et al. Response to “Some remarks on a critical review of the estimation of the thermodynamic parameters on adsorption equilibria. Wrong use of equilibrium constant in the van't Hoff equation for calculation of thermodynamic parameters of adsorption - Journal of J. Mol. Liq. (2019)E.C. Lima et al. A critical review of the estimation of the thermodynamic parameters on adsorption equilibria. Wrong use of equilibrium constant in the Van't Hoof equation for calculation of thermodynamic parameters of adsorption J. Mol. Liq. (2019)E.C. Lima et al. Comparison of the nonlinear and linear forms of the van't Hoff equation for calculation of adsorption thermodynamic parameters (ΔS° and ΔH°) J. Mol. Liq. (2020)H.N. Tran et al. Thermodynamic parameters of liquid–phase adsorption process calculated from different equilibrium constants related to adsorption isotherms: A comparison study J. Environ. Chem. Eng. (2021)O. Üner et al. The effect of carbonization temperature, carbonization time and impregnation ratio on the properties of activated carbon produced from Arundo donax Micropor. Mesopor. Mater. (2018)D.S.P. Franco et al. Preparation of activated carbons from fruit residues for the removal of naproxen (NPX): Analytical interpretation via statistical physical model J. Mol. Liq. (2022)J. Georgin et al. Effective adsorption of harmful herbicide diuron onto novel activated carbon from Hovenia dulcis Colloids Surfaces A Physicochem. Eng. Asp. (2022)E.M. Cuerda-Correa et al. On the use of carbon blacks as potential low-cost adsorbents for the removal of non-steroidal anti-inflammatory drugs from river water J. Hazard. Mater. (2010)M. Guo et al. Carbon nanotube-grafted chitosan and its adsorption capacity for phenol in aqueous solution Sci. Total Environ. (2019)H. Wu et al. Bifunctional porous polyethyleneimine-grafted lignin microspheres for efficient adsorption of 2,4-dichlorophenoxyacetic acid over a wide pH range and controlled release Chem. Eng. J. (2021)G. Cruz González et al. Degradation of 2,4-dichlorophenoxyacetic acid by photolysis and photo-Fenton oxidation J. Environ Chem. Eng. (2018)A.C. Lua et al. Effect of activation temperature on the textural and chemical properties of potassium hydroxide activated carbon prepared from the pistachio-nut shell J. Colloid Interface Sci. (2004)C. Bouchelta et al. Preparation and characterization of activated carbon from date stones by physical activation with steam J. Anal. Appl. Pyrolysis. (2008)X. Li et al. Inhibition of the corrosion of steel in HCl, H2SO4 solutions by bamboo leaf extract Corros. Sci. (2012)A.C. Lua et al. Effects of pyrolysis conditions on the properties of activated carbons prepared from pistachio-nut shells J. Anal. Appl. Pyrolysis. (2004)A.T. Mohd Din et al. 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(2022)380Propranolol hydrochlorideFruit palmColombian CaribbeanPublicationORIGINALProduction of adsorbent for removal of propranolol hydrochloride.pdfProduction of adsorbent for removal of propranolol hydrochloride.pdfArtículoapplication/pdf86005https://repositorio.cuc.edu.co/bitstreams/5b23f67d-1116-4e3f-9bfb-8ed7ce9bb09c/download29c521a6706af1f261638e71a88892f0MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.cuc.edu.co/bitstreams/01b872ea-f337-48af-8256-94ff04f34565/download2f9959eaf5b71fae44bbf9ec84150c7aMD52TEXTProduction of adsorbent for removal of propranolol hydrochloride.pdf.txtProduction of adsorbent for removal of propranolol hydrochloride.pdf.txtExtracted texttext/plain2078https://repositorio.cuc.edu.co/bitstreams/319f24f8-e05c-4b86-9d85-2557da2dc8a7/download42ffd8fd1eb85bb67c869a5593ff57efMD53THUMBNAILProduction of adsorbent for removal of propranolol hydrochloride.pdf.jpgProduction of adsorbent for removal of propranolol hydrochloride.pdf.jpgGenerated Thumbnailimage/jpeg13833https://repositorio.cuc.edu.co/bitstreams/e817b709-a180-4ecd-b701-32cb70307b79/download5570040f7093e4cd6442acc8af2c8cfcMD5411323/10475oai:repositorio.cuc.edu.co:11323/104752024-09-17 14:17:24.495https://creativecommons.org/licenses/by-nc-nd/4.0/open.accesshttps://repositorio.cuc.edu.coRepositorio de la Universidad de la Costa 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ada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.
 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