One step acid modification of the residual bark from Campomanesia guazumifolia using H2SO4 and application in the removal of 2,4-dichlorophenoxyacetic from aqueous solution
The residual bark of the tree species Campomanesia guazumifolia was successfully modified with H2SO4 and applied to remove the toxic herbicide 2.4-dichlorophenoxyacetic (2.4-D) from aqueous solutions. The characterization techniques made it possible to observe that the material maintained its amorph...
- Autores:
-
Bevilacqua, Raíssa C.
Preigschadt, Isadora A.
georgin, jordana
Franco, Dison
Mallmann, Evandro S.
Silva Oliveira, Luis Felipe
Pinto, Diana
Foletto, Edson
Dotto, Guilherme Luiz
Netto, Matias
Netto, Matias
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2021
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/9358
- Acceso en línea:
- https://hdl.handle.net/11323/9358
https://repositorio.cuc.edu.co/
- Palabra clave:
- Camponesia guazymifolia
Herbicide
2,4-D
Adsorption
Isotherm
- Rights
- embargoedAccess
- License
- © 2021 Taylor & Francis Group, LLC
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| dc.title.eng.fl_str_mv |
One step acid modification of the residual bark from Campomanesia guazumifolia using H2SO4 and application in the removal of 2,4-dichlorophenoxyacetic from aqueous solution |
| title |
One step acid modification of the residual bark from Campomanesia guazumifolia using H2SO4 and application in the removal of 2,4-dichlorophenoxyacetic from aqueous solution |
| spellingShingle |
One step acid modification of the residual bark from Campomanesia guazumifolia using H2SO4 and application in the removal of 2,4-dichlorophenoxyacetic from aqueous solution Camponesia guazymifolia Herbicide 2,4-D Adsorption Isotherm |
| title_short |
One step acid modification of the residual bark from Campomanesia guazumifolia using H2SO4 and application in the removal of 2,4-dichlorophenoxyacetic from aqueous solution |
| title_full |
One step acid modification of the residual bark from Campomanesia guazumifolia using H2SO4 and application in the removal of 2,4-dichlorophenoxyacetic from aqueous solution |
| title_fullStr |
One step acid modification of the residual bark from Campomanesia guazumifolia using H2SO4 and application in the removal of 2,4-dichlorophenoxyacetic from aqueous solution |
| title_full_unstemmed |
One step acid modification of the residual bark from Campomanesia guazumifolia using H2SO4 and application in the removal of 2,4-dichlorophenoxyacetic from aqueous solution |
| title_sort |
One step acid modification of the residual bark from Campomanesia guazumifolia using H2SO4 and application in the removal of 2,4-dichlorophenoxyacetic from aqueous solution |
| dc.creator.fl_str_mv |
Bevilacqua, Raíssa C. Preigschadt, Isadora A. georgin, jordana Franco, Dison Mallmann, Evandro S. Silva Oliveira, Luis Felipe Pinto, Diana Foletto, Edson Dotto, Guilherme Luiz Netto, Matias Netto, Matias |
| dc.contributor.author.spa.fl_str_mv |
Bevilacqua, Raíssa C. Preigschadt, Isadora A. georgin, jordana Franco, Dison Mallmann, Evandro S. Silva Oliveira, Luis Felipe Pinto, Diana Foletto, Edson Dotto, Guilherme Luiz |
| dc.contributor.author.none.fl_str_mv |
Netto, Matias Netto, Matias |
| dc.subject.proposal.eng.fl_str_mv |
Camponesia guazymifolia Herbicide 2,4-D Adsorption Isotherm |
| topic |
Camponesia guazymifolia Herbicide 2,4-D Adsorption Isotherm |
| description |
The residual bark of the tree species Campomanesia guazumifolia was successfully modified with H2SO4 and applied to remove the toxic herbicide 2.4-dichlorophenoxyacetic (2.4-D) from aqueous solutions. The characterization techniques made it possible to observe that the material maintained its amorphous structure; however, a new FTIR band emerged, indicating the interaction of the lignocellulosic matrix with sulfuric acid. Micrographs showed that the material maintained its irregular shape; however, new spaces and cavities appeared after the acidic modification. Regardless of the herbicide concentration, the system tended to equilibrium after 120 min. Using the best statistical coefficients, the Elovich model was the one that best fitted the kinetic data. The temperature increase in the system negatively influenced the adsorption of 2.4-D, reaching a maximum capacity of 312.81 mg g−1 at 298 K. The equilibrium curves showed a better fit to the Tóth model. Thermodynamic parameters confirmed the exothermic nature of the system (ΔH0 = −59.86 kJ mol−1). As a residue obtained from urban pruning, the bark of Campomanesia guazumifolia treated with sulfuric acid is a promising and highly efficient alternative for removing the widely used and toxic 2.4-D herbicide from aqueous solutions. |
| publishDate |
2021 |
| dc.date.issued.none.fl_str_mv |
2021 |
| dc.date.accessioned.none.fl_str_mv |
2022-07-11T16:38:06Z |
| dc.date.available.none.fl_str_mv |
2022 2022-07-11T16:38:06Z |
| dc.type.spa.fl_str_mv |
Artículo de revista |
| dc.type.coar.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.coarversion.fl_str_mv |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| dc.type.coar.spa.fl_str_mv |
http://purl.org/coar/resource_type/c_6501 |
| dc.type.content.spa.fl_str_mv |
Text |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/article |
| dc.type.redcol.spa.fl_str_mv |
http://purl.org/redcol/resource_type/ART |
| format |
http://purl.org/coar/resource_type/c_6501 |
| dc.identifier.citation.spa.fl_str_mv |
: Raíssa C. Bevilacqua, Isadora A. Preigschadt, Matias S. Netto, Jordana Georgin, Dison S. P. Franco, Evandro S. Mallmann, Luis F. O. Silva, Diana Pinto, Edson L. Foletto & Guilherme L. Dotto (2021) One step acid modification of the residual bark from Campomanesia guazumifolia using H2SO4 and application in the removal of 2,4-dichlorophenoxyacetic from aqueous solution, Journal of Environmental Science and Health, Part B, 56:12, 995-1006, DOI: 10.1080/03601234.2021.1997283 |
| dc.identifier.issn.spa.fl_str_mv |
0360-1234 |
| dc.identifier.uri.spa.fl_str_mv |
https://hdl.handle.net/11323/9358 |
| dc.identifier.doi.spa.fl_str_mv |
10.1080/03601234.2021.1997283 |
| dc.identifier.eissn.spa.fl_str_mv |
1532-4109 |
| dc.identifier.instname.spa.fl_str_mv |
Corporación Universidad de la Costa |
| dc.identifier.reponame.spa.fl_str_mv |
REDICUC - Repositorio CUC |
| dc.identifier.repourl.spa.fl_str_mv |
https://repositorio.cuc.edu.co/ |
| identifier_str_mv |
: Raíssa C. Bevilacqua, Isadora A. Preigschadt, Matias S. Netto, Jordana Georgin, Dison S. P. Franco, Evandro S. Mallmann, Luis F. O. Silva, Diana Pinto, Edson L. Foletto & Guilherme L. Dotto (2021) One step acid modification of the residual bark from Campomanesia guazumifolia using H2SO4 and application in the removal of 2,4-dichlorophenoxyacetic from aqueous solution, Journal of Environmental Science and Health, Part B, 56:12, 995-1006, DOI: 10.1080/03601234.2021.1997283 0360-1234 10.1080/03601234.2021.1997283 1532-4109 Corporación Universidad de la Costa REDICUC - Repositorio CUC |
| url |
https://hdl.handle.net/11323/9358 https://repositorio.cuc.edu.co/ |
| dc.language.iso.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.ispartofjournal.spa.fl_str_mv |
Journal of Environmental Science and Health - Part B Pesticides, Food Contaminants, and Agricultural Wastes |
| dc.relation.references.spa.fl_str_mv |
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Bevilacqua, Raíssa C.Preigschadt, Isadora A.georgin, jordanaFranco, DisonMallmann, Evandro S.Silva Oliveira, Luis FelipePinto, DianaFoletto, EdsonDotto, Guilherme LuizNetto, MatiasNetto, Matias2022-07-11T16:38:06Z20222022-07-11T16:38:06Z2021: Raíssa C. Bevilacqua, Isadora A. Preigschadt, Matias S. Netto, Jordana Georgin, Dison S. P. Franco, Evandro S. Mallmann, Luis F. O. Silva, Diana Pinto, Edson L. Foletto & Guilherme L. Dotto (2021) One step acid modification of the residual bark from Campomanesia guazumifolia using H2SO4 and application in the removal of 2,4-dichlorophenoxyacetic from aqueous solution, Journal of Environmental Science and Health, Part B, 56:12, 995-1006, DOI: 10.1080/03601234.2021.19972830360-1234https://hdl.handle.net/11323/935810.1080/03601234.2021.19972831532-4109Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/The residual bark of the tree species Campomanesia guazumifolia was successfully modified with H2SO4 and applied to remove the toxic herbicide 2.4-dichlorophenoxyacetic (2.4-D) from aqueous solutions. The characterization techniques made it possible to observe that the material maintained its amorphous structure; however, a new FTIR band emerged, indicating the interaction of the lignocellulosic matrix with sulfuric acid. Micrographs showed that the material maintained its irregular shape; however, new spaces and cavities appeared after the acidic modification. Regardless of the herbicide concentration, the system tended to equilibrium after 120 min. Using the best statistical coefficients, the Elovich model was the one that best fitted the kinetic data. The temperature increase in the system negatively influenced the adsorption of 2.4-D, reaching a maximum capacity of 312.81 mg g−1 at 298 K. The equilibrium curves showed a better fit to the Tóth model. Thermodynamic parameters confirmed the exothermic nature of the system (ΔH0 = −59.86 kJ mol−1). As a residue obtained from urban pruning, the bark of Campomanesia guazumifolia treated with sulfuric acid is a promising and highly efficient alternative for removing the widely used and toxic 2.4-D herbicide from aqueous solutions.12 páginasapplication/pdfengTaylor and Francis Ltd.United States© 2021 Taylor & Francis Group, LLCAtribución-NoComercial 4.0 Internacional (CC BY-NC 4.0)https://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/embargoedAccesshttp://purl.org/coar/access_right/c_f1cfOne step acid modification of the residual bark from Campomanesia guazumifolia using H2SO4 and application in the removal of 2,4-dichlorophenoxyacetic from aqueous solutionArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARThttp://purl.org/coar/version/c_970fb48d4fbd8a85https://www.tandfonline.com/doi/full/10.1080/03601234.2021.1997283Journal of Environmental Science and Health - Part B Pesticides, Food Contaminants, and Agricultural Wastes[1] Pavlovic, I.; Barriga, C.; Hermos ın, M. 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Principles of Adsorption and Adsorption Processes; John Wiley & Sons, New York, 1984; 62p10069951256Camponesia guazymifoliaHerbicide2,4-DAdsorptionIsothermPublicationORIGINALOne step acid modification of the residual bark from Campomanesia.pdfOne step acid modification of the residual bark from Campomanesia.pdfapplication/pdf2211822https://repositorio.cuc.edu.co/bitstreams/085b5105-1136-409e-8a76-958c8fce07fe/downloadccfb87af6b4bc68e334f0fd1a2115da6MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-83196https://repositorio.cuc.edu.co/bitstreams/58c9815f-899e-474f-94fd-c72840bfbeb4/downloade30e9215131d99561d40d6b0abbe9badMD52TEXTOne step acid modification of the residual bark from Campomanesia.pdf.txtOne step acid modification of the residual bark from Campomanesia.pdf.txttext/plain60064https://repositorio.cuc.edu.co/bitstreams/22726d90-a88a-4a6e-82b9-7208250261a5/downloadb88143234228b0221a2c2d193e68c207MD53THUMBNAILOne step acid modification of the residual bark from 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