Synthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption
A series of geopolymers were synthesized from fly and bottom ashes of a thermoelectrical power plant located in the Brazilian southern, aiming to add value for these wastes. The geopolymers were prepared in conventional and ultrasound-assisted ways and used to uptake Ag+, Co2+, Cu2+, and Ni2+ from a...
- Autores:
-
Chaves Peres, Enrique
Schadeck Netto, Matias
Mallmann, Evandro S.
Silva Oliveira, Luis Felipe
Foletto, Edson
Dotto, Guilherme Luiz
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2021
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/9138
- Acceso en línea:
- https://hdl.handle.net/11323/9138
https://repositorio.cuc.edu.co/
https://doi.org/10.1007/s11356-021-15882-3
- Palabra clave:
- Adsorption
Ash
Geopolymers
Heavy metals
Ultrasound
- Rights
- embargoedAccess
- License
- © 2022 Springer Nature Switzerland AG. Part of Springer Nature.
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Synthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption |
| title |
Synthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption |
| spellingShingle |
Synthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption Adsorption Ash Geopolymers Heavy metals Ultrasound |
| title_short |
Synthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption |
| title_full |
Synthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption |
| title_fullStr |
Synthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption |
| title_full_unstemmed |
Synthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption |
| title_sort |
Synthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption |
| dc.creator.fl_str_mv |
Chaves Peres, Enrique Schadeck Netto, Matias Mallmann, Evandro S. Silva Oliveira, Luis Felipe Foletto, Edson Dotto, Guilherme Luiz |
| dc.contributor.author.spa.fl_str_mv |
Chaves Peres, Enrique Schadeck Netto, Matias Mallmann, Evandro S. Silva Oliveira, Luis Felipe Foletto, Edson Dotto, Guilherme Luiz |
| dc.subject.proposal.eng.fl_str_mv |
Adsorption Ash Geopolymers Heavy metals Ultrasound |
| topic |
Adsorption Ash Geopolymers Heavy metals Ultrasound |
| description |
A series of geopolymers were synthesized from fly and bottom ashes of a thermoelectrical power plant located in the Brazilian southern, aiming to add value for these wastes. The geopolymers were prepared in conventional and ultrasound-assisted ways and used to uptake Ag+, Co2+, Cu2+, and Ni2+ from aqueous solutions. All materials were characterized by infrared spectroscopy (FT–IR), X-ray diffraction (XRD), and N2 adsorption isotherms (BET and BJH methods). The results revealed that the geopolymers obtained from the conventional method presented slightly higher values of surface area and total pore volume. However, in some cases, the adsorption potential was better for the ultrasound synthesized materials. The geopolymers prepared from both methods presented good adsorption performance concerning Ag+ and Cu2+, Co2+ and Ni2+. The removal percentages were higher than 90%. In addition, the adsorption capacities were within the literature range. These findings show that the ultrasound technique is not essential to improve the geopolymers production process compared to the conventional process, which generated material with better performance for heavy metals adsorption. Besides, it was possible to aggregate value for fly and bottom ashes, generating promising adsorbent materials. |
| publishDate |
2021 |
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2021 |
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2022-04-29T13:06:56Z |
| dc.date.available.none.fl_str_mv |
2022-04-29T13:06:56Z 2023 |
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Artículo de revista |
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Peres, E.C., Netto, M.S., Mallmann, E.S. et al. Synthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption. Environ Sci Pollut Res 29, 2699–2706 (2022). https://doi.org/10.1007/s11356-021-15882-3 |
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0944-1344 |
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https://hdl.handle.net/11323/9138 |
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10.1007/s11356-021-15882-3 |
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1614-7499 |
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Corporación Universidad de la Costa |
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REDICUC - Repositorio CUC |
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https://repositorio.cuc.edu.co/ |
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https://doi.org/10.1007/s11356-021-15882-3 |
| identifier_str_mv |
Peres, E.C., Netto, M.S., Mallmann, E.S. et al. Synthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption. Environ Sci Pollut Res 29, 2699–2706 (2022). https://doi.org/10.1007/s11356-021-15882-3 0944-1344 10.1007/s11356-021-15882-3 1614-7499 Corporación Universidad de la Costa REDICUC - Repositorio CUC |
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https://hdl.handle.net/11323/9138 https://repositorio.cuc.edu.co/ https://doi.org/10.1007/s11356-021-15882-3 |
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eng |
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eng |
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Environmental Science and Pollution Research |
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Al-Gheethi AAS, Lalung J, Noman EA, Bala JD, Norli I (2015) Removal of heavy metals and antibiotics from treated sewage effluent by bacteria. Clean Techn Environ Policy 17:2101–2123. https://doi.org/10.1007/s10098-015-0968-z Al-Othman ZA (2012) A review: fundamental aspects of silicate-mesoporous materials. Materials 5:2874–2902. https://doi.org/10.3390/ma5122874 Al-Othman ZA, Ali R, Naushad M (2012) Hexavalent chromium removal from aqueous medium by activated carbon prepared from peanut shell: adsorption kinetics, equilibrium and thermodynamic studies. Chem Eng J 184:238–247. https://doi.org/10.1016/j.cej.2012.01.048 Azevedo AGS et al (2017) Production of geopolymers from ashes using Na2O and Na2SiO3. Cerâmica 63:143–151. https://doi.org/10.1590/0366-69132017633662078 Barbosa TR, Foletto EL, Dotto GL, Jahn SL (2018) Preparation of mesoporous geopolymer using metakaolin and rice husk ash as synthesis precursors and its use as potential adsorbent to remove organic dye from aqueous solutions. Ceram Int 44:416–423. https://doi.org/10.1016/j.ceramint.2017.09.193 Chiang PC, Pan SY (2017) Carbon dioxide mineralization and utilization. Springer:1–452. https://doi.org/10.1007/978-981-10-3268-4 Demiral H, Gungor C (2016) Adsorption of copper(II) from aqueous solutions on activated carbon prepared from grape bagasse. J Clean Prod 124:103–113. https://doi.org/10.1016/j.jclepro.2016.02.084 Dotto GL, McKay G (2020) Current scenario and challenges in adsorption for water treatment. J Environ Chem Eng 8:103988. https://doi.org/10.1016/j.jece.2020.103988 Feng D, Tan H, Deventer (2004) Ultrasound enhanced geopolymerisation. J Mater Sci 9:571–580. https://doi.org/10.1023/B:JMSC.0000011513.87316.5c Gupta N, Kushwaha AK, Chattopadhyaya MC (2012) Adsorptive removal of Pb2+, Co2+ and Ni2+ by hydroxyapatite/chitosan composite from aqueous solution. J Taiwan Inst Chem Eng 43:125–131. https://doi.org/10.1016/j.jtice.2011.07.009 Jintakosol T, Nitaiyaphat W (2016) Adsorption of Silver (I) from Aqueous Solution Using Chitosan/Montmorillonite Composite Beads. Mater Res 19:1114–1121. https://doi.org/10.1590/1980-5373-MR-2015-0738 Ju T, Jiang J, Meng Y, Yan F, Xu Y, Gao Y, Aihemaiti A (2020) An investigation of the effect of ultrasonic waves on the efficiency of silicon extraction from coal fly ash. Ultrason Sonochem 60:1104765. https://doi.org/10.1016/j.ultsonch.2019.104765 Kara I, Yilmazer D, Akar ST (2017) Metakaolin based geopolymer as an effective adsorbent for adsorption of zinc(II) and nickel(II) ions from aqueous solutions. Appl Clay Sci 139:54–63. https://doi.org/10.1016/j.clay.2017.01.008 Ketsela G, Animen Z, Talema A (2020) Adsorption of Lead (II), Cobalt (II) and Iron (II) from aqueous solution by activated carbon prepared from white lupine (GIBITO) husk. J Thermo Catal 11:1–8. 203. https://doi.org/10.4172/2157-7544.20.11.2.203 Ihsanullah I, Abbas A, Al-Amer AM, Laoui T, Al-Marri MJ, Nasser MS, Khraisheh M, Atieh MA (2016) Heavy metal removal from aqueous solution by advanced carbon nanotubes: critical review of adsorption applications. Sep Purif Technol 157:141–161. https://doi.org/10.1-016/j.seppur.2015.11.039 Ihsanullah I, Al-Khaldi FA, Abusharkh B, Khaled M, Atieh MA, Nasser MS, Laoui T, Saleh T, Agarwal S, Tyagi I, Gupta VK (2015) Adsorptive removal of cadmium(II) ions from liquid phase using acid modified carbon-based adsorbents. J Mol Liq 2014:255–263. https://doi.org/10.1016/j.molliq.2015.01.033 Muthusaravanan S, Sivarajasekar N, Vivek JS, Paramasivan T, Naushad M, Prakashmaran J, Gayathri V, Al-Duaij OK (2018) Phytoremediation of heavy metals: mechanisms, methods and enhancements. Environ Chem Lett 16:1339–1359. https://doi.org/10.1007/s10311-018-0762-3 Nergis-Burduhos D et al (2018) Geopolymers and Their Uses : Review. IOP Conference Series: Mater Sci Eng 374:012019. https://doi.org/10.1088/1757-899X/374/1/012019 Peres EC, Slaviero JC, Cunha AM, Hosseini–Bandegharaei A, Dotto GL (2018) Microwave synthesis of silica nanoparticles and its application for methylene blue adsorption. J Environ Chem Eng 6:649–659. https://doi.org/10.1016/j.jece.2017.12.062 Rasaki SA, Bingxue Z, Guarecuco R, Thomas T, Minghui Y (2018) Geopolymer for use in heavy metals adsorption, and advanced oxidative processes: a critical review. J Clean Prod 213:42–58. https://doi.org/10.1016/j.jclepro.2018.12.145 Sodipo BK, Aziz AA (2018) One minute synthesis of amino-silane functionalized superparamagnetic iron oxide nanoparticles by sonochemical method. Ultrason Sonochem 40:837–840. https://doi.org/10.1016/j.ultsonch.2017.08.040 Vaz BS, Costa JAV, Morais MG (2016) Use of solid waste from thermoelectric plants for the cultivation of microalgae. Braz Arch Biol Technol 59:1–8. https://doi.org/10.1590/1678-4324-2016150452 Vieira Y, Netto MS, Lima EC, Anastopoulos I, Oliveira MLS, Dotto GL (2021) An overview of geological originated materials as a trend for adsorption in wastewater treatment. Geosci Front:101150. https://doi.org/10.1016/j.gsf.2021.101150 Zamzow MJ, Eichbaum BR, Sandgren KR, Shanks DE (1990) Removal of heavy metals and other cations from wastewater using zeolites. Sep Sci Technol 25:1555–1569. https://doi.org/10.1080/01496399008050409 Zhuang XY, Chen L, Komarneni S, Zhou CH, Tong DS, Yang HM, Yu WH, Wang H (2016) Fly ash-based geopolymer: clean production, properties and applications. J Clean Prod 125:253–267. https://doi.org/10.1016/j.jclepro.2016.03.019 |
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Chaves Peres, EnriqueSchadeck Netto, MatiasMallmann, Evandro S.Silva Oliveira, Luis FelipeFoletto, EdsonDotto, Guilherme Luiz2022-04-29T13:06:56Z20232022-04-29T13:06:56Z2021Peres, E.C., Netto, M.S., Mallmann, E.S. et al. Synthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption. Environ Sci Pollut Res 29, 2699–2706 (2022). https://doi.org/10.1007/s11356-021-15882-30944-1344https://hdl.handle.net/11323/913810.1007/s11356-021-15882-31614-7499Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/https://doi.org/10.1007/s11356-021-15882-3A series of geopolymers were synthesized from fly and bottom ashes of a thermoelectrical power plant located in the Brazilian southern, aiming to add value for these wastes. The geopolymers were prepared in conventional and ultrasound-assisted ways and used to uptake Ag+, Co2+, Cu2+, and Ni2+ from aqueous solutions. All materials were characterized by infrared spectroscopy (FT–IR), X-ray diffraction (XRD), and N2 adsorption isotherms (BET and BJH methods). The results revealed that the geopolymers obtained from the conventional method presented slightly higher values of surface area and total pore volume. However, in some cases, the adsorption potential was better for the ultrasound synthesized materials. The geopolymers prepared from both methods presented good adsorption performance concerning Ag+ and Cu2+, Co2+ and Ni2+. The removal percentages were higher than 90%. In addition, the adsorption capacities were within the literature range. These findings show that the ultrasound technique is not essential to improve the geopolymers production process compared to the conventional process, which generated material with better performance for heavy metals adsorption. Besides, it was possible to aggregate value for fly and bottom ashes, generating promising adsorbent materials.1 páginaapplication/pdfengSpringer Science + Business MediaGermany© 2022 Springer Nature Switzerland AG. Part of Springer Nature.Atribución-NoComercial-CompartirIgual 4.0 Internacional (CC BY-NC-SA 4.0)https://creativecommons.org/licenses/by-nc-sa/4.0/info:eu-repo/semantics/embargoedAccesshttp://purl.org/coar/access_right/c_f1cfSynthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorptionArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARThttp://purl.org/coar/version/c_b1a7d7d4d402bccehttps://link.springer.com/article/10.1007/s11356-021-15882-3Environmental Science and Pollution ResearchAl-Gheethi AAS, Lalung J, Noman EA, Bala JD, Norli I (2015) Removal of heavy metals and antibiotics from treated sewage effluent by bacteria. Clean Techn Environ Policy 17:2101–2123. https://doi.org/10.1007/s10098-015-0968-zAl-Othman ZA (2012) A review: fundamental aspects of silicate-mesoporous materials. Materials 5:2874–2902. https://doi.org/10.3390/ma5122874Al-Othman ZA, Ali R, Naushad M (2012) Hexavalent chromium removal from aqueous medium by activated carbon prepared from peanut shell: adsorption kinetics, equilibrium and thermodynamic studies. Chem Eng J 184:238–247. https://doi.org/10.1016/j.cej.2012.01.048Azevedo AGS et al (2017) Production of geopolymers from ashes using Na2O and Na2SiO3. Cerâmica 63:143–151. https://doi.org/10.1590/0366-69132017633662078Barbosa TR, Foletto EL, Dotto GL, Jahn SL (2018) Preparation of mesoporous geopolymer using metakaolin and rice husk ash as synthesis precursors and its use as potential adsorbent to remove organic dye from aqueous solutions. Ceram Int 44:416–423. https://doi.org/10.1016/j.ceramint.2017.09.193Chiang PC, Pan SY (2017) Carbon dioxide mineralization and utilization. Springer:1–452. https://doi.org/10.1007/978-981-10-3268-4Demiral H, Gungor C (2016) Adsorption of copper(II) from aqueous solutions on activated carbon prepared from grape bagasse. J Clean Prod 124:103–113. https://doi.org/10.1016/j.jclepro.2016.02.084Dotto GL, McKay G (2020) Current scenario and challenges in adsorption for water treatment. J Environ Chem Eng 8:103988. https://doi.org/10.1016/j.jece.2020.103988Feng D, Tan H, Deventer (2004) Ultrasound enhanced geopolymerisation. J Mater Sci 9:571–580. https://doi.org/10.1023/B:JMSC.0000011513.87316.5cGupta N, Kushwaha AK, Chattopadhyaya MC (2012) Adsorptive removal of Pb2+, Co2+ and Ni2+ by hydroxyapatite/chitosan composite from aqueous solution. J Taiwan Inst Chem Eng 43:125–131. https://doi.org/10.1016/j.jtice.2011.07.009Jintakosol T, Nitaiyaphat W (2016) Adsorption of Silver (I) from Aqueous Solution Using Chitosan/Montmorillonite Composite Beads. Mater Res 19:1114–1121. https://doi.org/10.1590/1980-5373-MR-2015-0738Ju T, Jiang J, Meng Y, Yan F, Xu Y, Gao Y, Aihemaiti A (2020) An investigation of the effect of ultrasonic waves on the efficiency of silicon extraction from coal fly ash. Ultrason Sonochem 60:1104765. https://doi.org/10.1016/j.ultsonch.2019.104765Kara I, Yilmazer D, Akar ST (2017) Metakaolin based geopolymer as an effective adsorbent for adsorption of zinc(II) and nickel(II) ions from aqueous solutions. Appl Clay Sci 139:54–63. https://doi.org/10.1016/j.clay.2017.01.008Ketsela G, Animen Z, Talema A (2020) Adsorption of Lead (II), Cobalt (II) and Iron (II) from aqueous solution by activated carbon prepared from white lupine (GIBITO) husk. J Thermo Catal 11:1–8. 203. https://doi.org/10.4172/2157-7544.20.11.2.203Ihsanullah I, Abbas A, Al-Amer AM, Laoui T, Al-Marri MJ, Nasser MS, Khraisheh M, Atieh MA (2016) Heavy metal removal from aqueous solution by advanced carbon nanotubes: critical review of adsorption applications. Sep Purif Technol 157:141–161. https://doi.org/10.1-016/j.seppur.2015.11.039Ihsanullah I, Al-Khaldi FA, Abusharkh B, Khaled M, Atieh MA, Nasser MS, Laoui T, Saleh T, Agarwal S, Tyagi I, Gupta VK (2015) Adsorptive removal of cadmium(II) ions from liquid phase using acid modified carbon-based adsorbents. J Mol Liq 2014:255–263. https://doi.org/10.1016/j.molliq.2015.01.033Muthusaravanan S, Sivarajasekar N, Vivek JS, Paramasivan T, Naushad M, Prakashmaran J, Gayathri V, Al-Duaij OK (2018) Phytoremediation of heavy metals: mechanisms, methods and enhancements. Environ Chem Lett 16:1339–1359. https://doi.org/10.1007/s10311-018-0762-3Nergis-Burduhos D et al (2018) Geopolymers and Their Uses : Review. IOP Conference Series: Mater Sci Eng 374:012019. https://doi.org/10.1088/1757-899X/374/1/012019Peres EC, Slaviero JC, Cunha AM, Hosseini–Bandegharaei A, Dotto GL (2018) Microwave synthesis of silica nanoparticles and its application for methylene blue adsorption. J Environ Chem Eng 6:649–659. https://doi.org/10.1016/j.jece.2017.12.062Rasaki SA, Bingxue Z, Guarecuco R, Thomas T, Minghui Y (2018) Geopolymer for use in heavy metals adsorption, and advanced oxidative processes: a critical review. J Clean Prod 213:42–58. https://doi.org/10.1016/j.jclepro.2018.12.145Sodipo BK, Aziz AA (2018) One minute synthesis of amino-silane functionalized superparamagnetic iron oxide nanoparticles by sonochemical method. Ultrason Sonochem 40:837–840. https://doi.org/10.1016/j.ultsonch.2017.08.040Vaz BS, Costa JAV, Morais MG (2016) Use of solid waste from thermoelectric plants for the cultivation of microalgae. Braz Arch Biol Technol 59:1–8. https://doi.org/10.1590/1678-4324-2016150452Vieira Y, Netto MS, Lima EC, Anastopoulos I, Oliveira MLS, Dotto GL (2021) An overview of geological originated materials as a trend for adsorption in wastewater treatment. Geosci Front:101150. https://doi.org/10.1016/j.gsf.2021.101150Zamzow MJ, Eichbaum BR, Sandgren KR, Shanks DE (1990) Removal of heavy metals and other cations from wastewater using zeolites. Sep Sci Technol 25:1555–1569. https://doi.org/10.1080/01496399008050409Zhuang XY, Chen L, Komarneni S, Zhou CH, Tong DS, Yang HM, Yu WH, Wang H (2016) Fly ash-based geopolymer: clean production, properties and applications. J Clean Prod 125:253–267. https://doi.org/10.1016/j.jclepro.2016.03.01911229AdsorptionAshGeopolymersHeavy metalsUltrasoundPublicationORIGINALSynthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption.pdfSynthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption.pdfapplication/pdf74326https://repositorio.cuc.edu.co/bitstreams/c4594309-b8fa-4315-b9af-2375042db7ff/download32807a7649099e416c55de4264f04048MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-83196https://repositorio.cuc.edu.co/bitstreams/cee38b83-0d99-405e-92b1-785cc5b3cc03/downloade30e9215131d99561d40d6b0abbe9badMD52TEXTSynthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption.pdf.txtSynthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption.pdf.txttext/plain1636https://repositorio.cuc.edu.co/bitstreams/199bdc67-997a-49bd-86fa-d5208776fe98/download1fd35a6bd9332735daef675f3c8ba275MD53THUMBNAILSynthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption.pdf.jpgSynthesis of geopolymers from fly and bottom ashes of a thermoelectrical power plant for metallic ions adsorption.pdf.jpgimage/jpeg13105https://repositorio.cuc.edu.co/bitstreams/e3413c27-cd0b-4d29-9bcc-d0deee918d89/download915e04375f19242d421f91133c375a70MD5411323/9138oai:repositorio.cuc.edu.co:11323/91382024-09-17 14:20:11.333https://creativecommons.org/licenses/by-nc-sa/4.0/© 2022 Springer Nature Switzerland AG. 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