Application of physical statistical modeling in the adsorption of the drug ketoprofen and the 2,4-d herbicide using the bark campomanesia guazumifolia forest species modified with H2SO4 as an adsorbent

Emerging pollutants are a widespread environmental concern, andadsorption represents one of the choices available for the removal of suchcompounds from polluted waters. However, the set-up of a new adsorption system requiresthe experimental determination of adsorption isotherms and their thoroughmod...

Full description

Autores:
Aouaini, Fatma
Dhaouadi, Fatma
georgin, jordana
Franco, Dison S. P.
Alyousef, Haifa
Erto, Alessandro
Ben Lamine, Abdelmottaleb
Tipo de recurso:
Article of investigation
Fecha de publicación:
2024
Institución:
Corporación Universidad de la Costa
Repositorio:
REDICUC - Repositorio CUC
Idioma:
eng
OAI Identifier:
oai:repositorio.cuc.edu.co:11323/13361
Acceso en línea:
https://hdl.handle.net/11323/13361
https://repositorio.cuc.edu.co/
Palabra clave:
2,4-dichlorophenoxyactic acid
Adsorption
Functionalized biomass
ketoprofen
Physical statistical modeling
Rights
closedAccess
License
Atribución-NoComercial 4.0 Internacional (CC BY-NC 4.0)
id RCUC2_c39728aae46895d6dc00ff306d5838c0
oai_identifier_str oai:repositorio.cuc.edu.co:11323/13361
network_acronym_str RCUC2
network_name_str REDICUC - Repositorio CUC
repository_id_str
dc.title.eng.fl_str_mv Application of physical statistical modeling in the adsorption of the drug ketoprofen and the 2,4-d herbicide using the bark campomanesia guazumifolia forest species modified with H2SO4 as an adsorbent
title Application of physical statistical modeling in the adsorption of the drug ketoprofen and the 2,4-d herbicide using the bark campomanesia guazumifolia forest species modified with H2SO4 as an adsorbent
spellingShingle Application of physical statistical modeling in the adsorption of the drug ketoprofen and the 2,4-d herbicide using the bark campomanesia guazumifolia forest species modified with H2SO4 as an adsorbent
2,4-dichlorophenoxyactic acid
Adsorption
Functionalized biomass
ketoprofen
Physical statistical modeling
title_short Application of physical statistical modeling in the adsorption of the drug ketoprofen and the 2,4-d herbicide using the bark campomanesia guazumifolia forest species modified with H2SO4 as an adsorbent
title_full Application of physical statistical modeling in the adsorption of the drug ketoprofen and the 2,4-d herbicide using the bark campomanesia guazumifolia forest species modified with H2SO4 as an adsorbent
title_fullStr Application of physical statistical modeling in the adsorption of the drug ketoprofen and the 2,4-d herbicide using the bark campomanesia guazumifolia forest species modified with H2SO4 as an adsorbent
title_full_unstemmed Application of physical statistical modeling in the adsorption of the drug ketoprofen and the 2,4-d herbicide using the bark campomanesia guazumifolia forest species modified with H2SO4 as an adsorbent
title_sort Application of physical statistical modeling in the adsorption of the drug ketoprofen and the 2,4-d herbicide using the bark campomanesia guazumifolia forest species modified with H2SO4 as an adsorbent
dc.creator.fl_str_mv Aouaini, Fatma
Dhaouadi, Fatma
georgin, jordana
Franco, Dison S. P.
Alyousef, Haifa
Erto, Alessandro
Ben Lamine, Abdelmottaleb
dc.contributor.author.none.fl_str_mv Aouaini, Fatma
Dhaouadi, Fatma
georgin, jordana
Franco, Dison S. P.
Alyousef, Haifa
Erto, Alessandro
Ben Lamine, Abdelmottaleb
dc.subject.proposal.eng.fl_str_mv 2,4-dichlorophenoxyactic acid
Adsorption
Functionalized biomass
ketoprofen
Physical statistical modeling
topic 2,4-dichlorophenoxyactic acid
Adsorption
Functionalized biomass
ketoprofen
Physical statistical modeling
description Emerging pollutants are a widespread environmental concern, andadsorption represents one of the choices available for the removal of suchcompounds from polluted waters. However, the set-up of a new adsorption system requiresthe experimental determination of adsorption isotherms and their thoroughmodelling, for the sake of a convenient optimization. In this work, the Campomanesia guazumifolia biomass is adopted as precursor for the synthesis of anew adsorbent and then tested for the adsorption of KTP and 2,4-D. Theadsorption performances of this biomass are significantly improved through atreatment with sulfuric acid, which allows obtaining higher removal efficiency ofthe target organic molecules. The experimental isotherms are measured at 298 – 328 K and pH 2. An ETAM model is employed for amodeling analysis of the experimental data, for the comprehension of theoccurring adsorption mechanism. Results demonstrated that adsorption of KTP isendothermic and occurs in multilayer with a multimolecular process, in whichthe molecular aggregation can be predicted. On the contrary, the adsorption of 2,4-D on this functionalized biomass is exothermic. The adsorption energiesresulted to be < 40 kJ mol−1, indicating that physical adsorption forces are involved inthe removal of these organic molecules.
publishDate 2024
dc.date.accessioned.none.fl_str_mv 2024-09-23T20:40:08Z
dc.date.available.none.fl_str_mv 2024-09-23T20:40:08Z
2025
dc.date.issued.none.fl_str_mv 2024
dc.type.spa.fl_str_mv Artículo de revista
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.content.spa.fl_str_mv Text
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/article
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/ART
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/draft
dc.type.coarversion.spa.fl_str_mv http://purl.org/coar/version/c_b1a7d7d4d402bcce
format http://purl.org/coar/resource_type/c_2df8fbb1
status_str draft
dc.identifier.citation.spa.fl_str_mv Aouaini, F. & Dhaouadi, Fatma & Georgin, Jordana & Franco, Dison & Alyousef, Haifa & Erto, Alessandro & Ben Lamine, Abdelmottaleb. (2024). Application of Physical Statistical Modeling in the Adsorption of the Drug Ketoprofen and the 2,4‐D Herbicide using the Bark Campomanesia Guazumifolia Forest Species Modified with H2SO4 as an Adsorbent. Advanced Theory and Simulations. 10.1002/adts.202400236.
dc.identifier.issn.spa.fl_str_mv 2513-0390
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/11323/13361
dc.identifier.doi.none.fl_str_mv 10.1002/adts.202400236
dc.identifier.instname.spa.fl_str_mv Corporación Universidad de la Costa
dc.identifier.reponame.spa.fl_str_mv REDICUC - Repositorio CUC
dc.identifier.repourl.spa.fl_str_mv https://repositorio.cuc.edu.co/
identifier_str_mv Aouaini, F. & Dhaouadi, Fatma & Georgin, Jordana & Franco, Dison & Alyousef, Haifa & Erto, Alessandro & Ben Lamine, Abdelmottaleb. (2024). Application of Physical Statistical Modeling in the Adsorption of the Drug Ketoprofen and the 2,4‐D Herbicide using the Bark Campomanesia Guazumifolia Forest Species Modified with H2SO4 as an Adsorbent. Advanced Theory and Simulations. 10.1002/adts.202400236.
2513-0390
10.1002/adts.202400236
Corporación Universidad de la Costa
REDICUC - Repositorio CUC
url https://hdl.handle.net/11323/13361
https://repositorio.cuc.edu.co/
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.ispartofjournal.spa.fl_str_mv Advanced theory and simulations
dc.relation.references.spa.fl_str_mv Erto, A., Bortone, I., Di Nardo, A., Di Natale, M., Musmarra, D. (2014) J. Environ. Manag., 140, p. 111.
Rainone, F., D'Agostino, O., Erto, A., Balsamo, M., Lancia, A. (2021) J. Environ. Chem. Eng., 9.
Di Natale, F., Erto, A., Lancia, A. (2013) J. Hazard. Mater., 260, p. 451.
Balsamo, M., Di Natale, F., Erto, A., Lancia, A., Montagnaro, F., Santoro, L. (2011) J. Hazard. Mater., 187, p. 371.
Sellaoui, L., Mendoza-Castillo, D.I., Reynel-Ávila, H.E., Bonilla-Petriciolet, A., Lamine, A.B., Erto, A. (2018) Chem. Eng. J., 343, p. 544.
Selim, A.Q., Sellaoui, L., Ahmed, S.A., Mobarak, M., Mohamed, E.A., Lamine, A.B., Erto, A., Seliem, M.K. (2019) J. Environ. Chem. Eng., 7.
Ali, I., Asim, M., Khan, T.A. (2012) J. Environ. Manag., 113, p. 170.
Kumar, J., Balomajumder, C., Mondal, P. (2011) CLEAN – Soil, Air, Water, 39, p. 641.
Franco, D.S.P., Georgin, J., Drumm, F.C., Netto, M.S., Allasia, D., Oliveira, M.L.S., Dotto, G.L. (2020) Environ. Sci. Pollut. Res., 27.
Li, C., Knierim, B., Manisseri, C., Arora, R., Scheller, H.V., Auer, M., Vogel, K.P., Singh, S. (2010) Bioresour. Technol., 101, p. 4900.
Carrier, M., Neomagus, H.W., Görgens, J., Knoetze, J.H. (2012) Energy Fuels, 26, p. 4497.
Asadieraghi, M., Daud, W.M.A.W. (2014) Energy Convers. Manage., 82, p. 71.
Catelan, T.B.S., Radai, J.A.S., Leitao, M.M., Branquinho, L.S., de Paula Vasconcelos, P.C., Heredia-Vieira, S.C., Kassuya, C.A.L., Cardoso, C.A.L. (2018) J. Ethnopharmacol., 226, p. 132.
Souza, M.T., Souza, M.T., Panobianco, M. (2018) J. Seed Sci., 40, p. 75.
Georgin, J., Franco, D.S.P., da Boit Martinello, K., Lima, E.C., Silva, L.F.O. (2022) J. Environ. Chem. Eng., 10.
Kerkhoff, C.M., da Boit Martinello, K., Franco, D.S.P., Netto, M.S., Georgin, J., Foletto, E.L., Piccilli, D.G.A., Dotto, G.L. (2021) J. Mol. Liq., 339.
Woźniak-Karczewska, M., Parus, A., Ciesielski, T., Trzebny, A., Szumski, R., Wilms, W., Homa, J., Chrzanowski, Ł. (2022) ACS Sustain. Chem. Eng., 10.
Legocka, I., Kuśmierek, K., Świątkowski, A., Wierzbicka, E. (2022) Materials, 15, p. 8433.
Bevilacqua, R.C., Preigschadt, I.A., Netto, M.S., Georgin, J., Franco, D.S.P., Mallmann, E.S., Silva, L.F.O., Dotto, G.L. (2021) J. Environ. Sci. Health, Part B, 56, p. 995.
Preigschadt, I.A., Bevilacqua, R.C., Netto, M.S., Georgin, J., Franco, D.S.P., Mallmann, E.S., Pinto, D., Dotto, G.L. (2021) Environ. Sci. Pollut. Res., p. 2122.
Aouaini, F., Dhaouadi, F., Sellaoui, L., Badawi, M., Bonilla-Petriciolet, A., Lamine, A.B. (2022) Environ. Sci. Pollut. Res., 29.
Dhaouadi, F., Aouaini, F., Al-Essa, L.A., Khemiri, N., Erto, A., Lamine, A.B. (2023) RSC Adv., 13.
Yanan, C., Ali, J., Sellaoui, L., Dhaouadi, F., Naeem, M., Franco, D.S.P., Georgin, J., Badawi, M. (2023) Chemosphere, 313.
Dhaouadi, F., Sellaoui, L., Taamalli, S., Louis, F., El Bakali, A., Badawi, M., Georgin, J., Rtimi, S. (2022) Chem. Eng. J., 445.
Njoku, C.B., Oseghe, E., Msagati, T.A.M. (2022) J. Mol. Liq., 346.
Ajibade, P.A., Nnadozie, E.C. (2022) Environ. Chem. Ecotoxicol., 4, p. 140.
Tavassoli, S., Cheraghi, S., Etemadifar, P., Mollahosseini, A., Joodaki, S., Sedighi, N. (2024) Sci. Rep., 14, p. 4398.
Vinayagam, R., Ganga, S., Murugesan, G., Rangasamy, G., Bhole, R., Goveas, L.C., Varadavenkatesan, T., Selvaraj, R. (2023) Chemosphere, 310.
Brito, G.M., Roldi, L.L., Schetino, M.Â., Jr., Checon Freitas, J.C., Cabral Coelho, E.R. (2020) J. Environ. Sci. Health, Part B, 55, p. 767.
Marsolla, L.D., Brito, G.M., Freitas, J.C.C., Coelho, E.R.C. (2022) J. Environ. Sci. Health, Part B, 57, p. 588.
Amiri, M.J., Roohi, R., Arshadi, M., Abbaspourrad, A. (2020) Environ. Sci. Pollut. Res., 27.
dc.relation.citationendpage.spa.fl_str_mv 2
dc.relation.citationstartpage.spa.fl_str_mv 1
dc.rights.eng.fl_str_mv © Copyright 2024 Elsevier B.V., All rights reserved.
dc.rights.license.spa.fl_str_mv Atribución-NoComercial 4.0 Internacional (CC BY-NC 4.0)
dc.rights.uri.spa.fl_str_mv https://creativecommons.org/licenses/by-nc/4.0/
dc.rights.accessrights.spa.fl_str_mv info:eu-repo/semantics/closedAccess
dc.rights.coar.spa.fl_str_mv http://purl.org/coar/access_right/c_14cb
rights_invalid_str_mv Atribución-NoComercial 4.0 Internacional (CC BY-NC 4.0)
© Copyright 2024 Elsevier B.V., All rights reserved.
https://creativecommons.org/licenses/by-nc/4.0/
http://purl.org/coar/access_right/c_14cb
eu_rights_str_mv closedAccess
dc.format.extent.spa.fl_str_mv 2 páginas
dc.format.mimetype.spa.fl_str_mv application/pdf
dc.publisher.spa.fl_str_mv Wiley-VCH Verlag
dc.publisher.place.spa.fl_str_mv Germany
dc.source.spa.fl_str_mv https://onlinelibrary.wiley.com/doi/epdf/10.1002/adts.202400236
institution Corporación Universidad de la Costa
bitstream.url.fl_str_mv https://repositorio.cuc.edu.co/bitstreams/5bf2936e-e554-4b8d-9dd8-d92652fae819/download
https://repositorio.cuc.edu.co/bitstreams/3248085b-9f20-4b6b-b84b-616465e2dbe4/download
https://repositorio.cuc.edu.co/bitstreams/0767edd5-9879-442a-9c2c-26b85250dc9a/download
https://repositorio.cuc.edu.co/bitstreams/af6fd6c1-fc85-42bd-96d5-c09c3fdc08c9/download
bitstream.checksum.fl_str_mv 732fedf8e178686dc5ee564b8a89f302
2f9959eaf5b71fae44bbf9ec84150c7a
c16ca0a52d01bbead7e445ef476a64b2
c69fd007b801102e773f15abb59cdb33
bitstream.checksumAlgorithm.fl_str_mv MD5
MD5
MD5
MD5
repository.name.fl_str_mv Repositorio de la Universidad de la Costa CUC
repository.mail.fl_str_mv repdigital@cuc.edu.co
_version_ 1811760849832902656
spelling Atribución-NoComercial 4.0 Internacional (CC BY-NC 4.0)© Copyright 2024 Elsevier B.V., All rights reserved.https://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/closedAccesshttp://purl.org/coar/access_right/c_14cbAouaini, FatmaDhaouadi, Fatmageorgin, jordanaFranco, Dison S. P.Alyousef, HaifaErto, AlessandroBen Lamine, Abdelmottaleb2024-09-23T20:40:08Z20252024-09-23T20:40:08Z2024Aouaini, F. & Dhaouadi, Fatma & Georgin, Jordana & Franco, Dison & Alyousef, Haifa & Erto, Alessandro & Ben Lamine, Abdelmottaleb. (2024). Application of Physical Statistical Modeling in the Adsorption of the Drug Ketoprofen and the 2,4‐D Herbicide using the Bark Campomanesia Guazumifolia Forest Species Modified with H2SO4 as an Adsorbent. Advanced Theory and Simulations. 10.1002/adts.202400236.2513-0390https://hdl.handle.net/11323/1336110.1002/adts.202400236Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/Emerging pollutants are a widespread environmental concern, andadsorption represents one of the choices available for the removal of suchcompounds from polluted waters. However, the set-up of a new adsorption system requiresthe experimental determination of adsorption isotherms and their thoroughmodelling, for the sake of a convenient optimization. In this work, the Campomanesia guazumifolia biomass is adopted as precursor for the synthesis of anew adsorbent and then tested for the adsorption of KTP and 2,4-D. Theadsorption performances of this biomass are significantly improved through atreatment with sulfuric acid, which allows obtaining higher removal efficiency ofthe target organic molecules. The experimental isotherms are measured at 298 – 328 K and pH 2. An ETAM model is employed for amodeling analysis of the experimental data, for the comprehension of theoccurring adsorption mechanism. Results demonstrated that adsorption of KTP isendothermic and occurs in multilayer with a multimolecular process, in whichthe molecular aggregation can be predicted. On the contrary, the adsorption of 2,4-D on this functionalized biomass is exothermic. The adsorption energiesresulted to be < 40 kJ mol−1, indicating that physical adsorption forces are involved inthe removal of these organic molecules.2 páginasapplication/pdfengWiley-VCH VerlagGermanyhttps://onlinelibrary.wiley.com/doi/epdf/10.1002/adts.202400236Application of physical statistical modeling in the adsorption of the drug ketoprofen and the 2,4-d herbicide using the bark campomanesia guazumifolia forest species modified with H2SO4 as an adsorbentArtículo de revistahttp://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/drafthttp://purl.org/coar/version/c_b1a7d7d4d402bcceAdvanced theory and simulationsErto, A., Bortone, I., Di Nardo, A., Di Natale, M., Musmarra, D. (2014) J. Environ. Manag., 140, p. 111.Rainone, F., D'Agostino, O., Erto, A., Balsamo, M., Lancia, A. (2021) J. Environ. Chem. Eng., 9.Di Natale, F., Erto, A., Lancia, A. (2013) J. Hazard. Mater., 260, p. 451.Balsamo, M., Di Natale, F., Erto, A., Lancia, A., Montagnaro, F., Santoro, L. (2011) J. Hazard. Mater., 187, p. 371.Sellaoui, L., Mendoza-Castillo, D.I., Reynel-Ávila, H.E., Bonilla-Petriciolet, A., Lamine, A.B., Erto, A. (2018) Chem. Eng. J., 343, p. 544.Selim, A.Q., Sellaoui, L., Ahmed, S.A., Mobarak, M., Mohamed, E.A., Lamine, A.B., Erto, A., Seliem, M.K. (2019) J. Environ. Chem. Eng., 7.Ali, I., Asim, M., Khan, T.A. (2012) J. Environ. Manag., 113, p. 170.Kumar, J., Balomajumder, C., Mondal, P. (2011) CLEAN – Soil, Air, Water, 39, p. 641.Franco, D.S.P., Georgin, J., Drumm, F.C., Netto, M.S., Allasia, D., Oliveira, M.L.S., Dotto, G.L. (2020) Environ. Sci. Pollut. Res., 27.Li, C., Knierim, B., Manisseri, C., Arora, R., Scheller, H.V., Auer, M., Vogel, K.P., Singh, S. (2010) Bioresour. Technol., 101, p. 4900.Carrier, M., Neomagus, H.W., Görgens, J., Knoetze, J.H. (2012) Energy Fuels, 26, p. 4497.Asadieraghi, M., Daud, W.M.A.W. (2014) Energy Convers. Manage., 82, p. 71.Catelan, T.B.S., Radai, J.A.S., Leitao, M.M., Branquinho, L.S., de Paula Vasconcelos, P.C., Heredia-Vieira, S.C., Kassuya, C.A.L., Cardoso, C.A.L. (2018) J. Ethnopharmacol., 226, p. 132.Souza, M.T., Souza, M.T., Panobianco, M. (2018) J. Seed Sci., 40, p. 75.Georgin, J., Franco, D.S.P., da Boit Martinello, K., Lima, E.C., Silva, L.F.O. (2022) J. Environ. Chem. Eng., 10.Kerkhoff, C.M., da Boit Martinello, K., Franco, D.S.P., Netto, M.S., Georgin, J., Foletto, E.L., Piccilli, D.G.A., Dotto, G.L. (2021) J. Mol. Liq., 339.Woźniak-Karczewska, M., Parus, A., Ciesielski, T., Trzebny, A., Szumski, R., Wilms, W., Homa, J., Chrzanowski, Ł. (2022) ACS Sustain. Chem. Eng., 10.Legocka, I., Kuśmierek, K., Świątkowski, A., Wierzbicka, E. (2022) Materials, 15, p. 8433.Bevilacqua, R.C., Preigschadt, I.A., Netto, M.S., Georgin, J., Franco, D.S.P., Mallmann, E.S., Silva, L.F.O., Dotto, G.L. (2021) J. Environ. Sci. Health, Part B, 56, p. 995.Preigschadt, I.A., Bevilacqua, R.C., Netto, M.S., Georgin, J., Franco, D.S.P., Mallmann, E.S., Pinto, D., Dotto, G.L. (2021) Environ. Sci. Pollut. Res., p. 2122.Aouaini, F., Dhaouadi, F., Sellaoui, L., Badawi, M., Bonilla-Petriciolet, A., Lamine, A.B. (2022) Environ. Sci. Pollut. Res., 29.Dhaouadi, F., Aouaini, F., Al-Essa, L.A., Khemiri, N., Erto, A., Lamine, A.B. (2023) RSC Adv., 13.Yanan, C., Ali, J., Sellaoui, L., Dhaouadi, F., Naeem, M., Franco, D.S.P., Georgin, J., Badawi, M. (2023) Chemosphere, 313.Dhaouadi, F., Sellaoui, L., Taamalli, S., Louis, F., El Bakali, A., Badawi, M., Georgin, J., Rtimi, S. (2022) Chem. Eng. J., 445.Njoku, C.B., Oseghe, E., Msagati, T.A.M. (2022) J. Mol. Liq., 346.Ajibade, P.A., Nnadozie, E.C. (2022) Environ. Chem. Ecotoxicol., 4, p. 140.Tavassoli, S., Cheraghi, S., Etemadifar, P., Mollahosseini, A., Joodaki, S., Sedighi, N. (2024) Sci. Rep., 14, p. 4398.Vinayagam, R., Ganga, S., Murugesan, G., Rangasamy, G., Bhole, R., Goveas, L.C., Varadavenkatesan, T., Selvaraj, R. (2023) Chemosphere, 310.Brito, G.M., Roldi, L.L., Schetino, M.Â., Jr., Checon Freitas, J.C., Cabral Coelho, E.R. (2020) J. Environ. Sci. Health, Part B, 55, p. 767.Marsolla, L.D., Brito, G.M., Freitas, J.C.C., Coelho, E.R.C. (2022) J. Environ. Sci. Health, Part B, 57, p. 588.Amiri, M.J., Roohi, R., Arshadi, M., Abbaspourrad, A. (2020) Environ. Sci. Pollut. Res., 27.212,4-dichlorophenoxyactic acidAdsorptionFunctionalized biomassketoprofenPhysical statistical modelingORIGINALApplication of physical statistical modeling in the adsorption of the drug ketoprofen and the 2,4-d herbicide using the bark campomanesia guazumifolia forest species modified with H2SO4 as an adsorbent.pdfApplication of physical statistical modeling in the adsorption of the drug ketoprofen and the 2,4-d herbicide using the bark campomanesia guazumifolia forest species modified with H2SO4 as an adsorbent.pdfArtículoapplication/pdf152566https://repositorio.cuc.edu.co/bitstreams/5bf2936e-e554-4b8d-9dd8-d92652fae819/download732fedf8e178686dc5ee564b8a89f302MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.cuc.edu.co/bitstreams/3248085b-9f20-4b6b-b84b-616465e2dbe4/download2f9959eaf5b71fae44bbf9ec84150c7aMD52TEXTApplication of physical statistical modeling in the adsorption of the drug ketoprofen and the 2,4-d herbicide using the bark campomanesia guazumifolia forest species modified with H2SO4 as an adsorbent.pdf.txtApplication of physical statistical modeling in the adsorption of the drug ketoprofen and the 2,4-d herbicide using the bark campomanesia guazumifolia forest species modified with H2SO4 as an adsorbent.pdf.txtExtracted texttext/plain6941https://repositorio.cuc.edu.co/bitstreams/0767edd5-9879-442a-9c2c-26b85250dc9a/downloadc16ca0a52d01bbead7e445ef476a64b2MD53THUMBNAILApplication of physical statistical modeling in the adsorption of the drug ketoprofen and the 2,4-d herbicide using the bark campomanesia guazumifolia forest species modified with H2SO4 as an adsorbent.pdf.jpgApplication of physical statistical modeling in the adsorption of the drug ketoprofen and the 2,4-d herbicide using the bark campomanesia guazumifolia forest species modified with H2SO4 as an adsorbent.pdf.jpgGenerated Thumbnailimage/jpeg15489https://repositorio.cuc.edu.co/bitstreams/af6fd6c1-fc85-42bd-96d5-c09c3fdc08c9/downloadc69fd007b801102e773f15abb59cdb33MD5411323/13361oai:repositorio.cuc.edu.co:11323/133612024-09-24 03:01:52.269https://creativecommons.org/licenses/by-nc/4.0/© Copyright 2024 Elsevier B.V., All rights reserved.open.accesshttps://repositorio.cuc.edu.coRepositorio de la Universidad de la Costa CUCrepdigital@cuc.edu.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