An Easy Method to Prepare D3 and C2-TATP Crystals

D3 and C2 TATP structures interconvert at room temperature. Herein, an easy method to isolate both conformers is shown that consists of multiple recrystallization steps using different solvent and heating to boiling. Spectroscopic and physical measurements, such as Raman spectroscopy, X-ray diffract...

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Autores:
Espinosa Fuentes, Eduardo Antonio
Colpas Castillo, Fredy
Meza Fuentes, Edgardo
Ropero, Jorge
Tipo de recurso:
Article of journal
Fecha de publicación:
2016
Institución:
Corporación Universidad de la Costa
Repositorio:
REDICUC - Repositorio CUC
Idioma:
eng
OAI Identifier:
oai:repositorio.cuc.edu.co:11323/864
Acceso en línea:
https://hdl.handle.net/11323/864
https://doi.org/10.1002/prep.201500245
https://repositorio.cuc.edu.co/
Palabra clave:
D3 and C2 TATP conformers
Raman
X-ray diffractogram
Rights
openAccess
License
Atribución – No comercial – Compartir igual
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dc.title.eng.fl_str_mv An Easy Method to Prepare D3 and C2-TATP Crystals
title An Easy Method to Prepare D3 and C2-TATP Crystals
spellingShingle An Easy Method to Prepare D3 and C2-TATP Crystals
D3 and C2 TATP conformers
Raman
X-ray diffractogram
title_short An Easy Method to Prepare D3 and C2-TATP Crystals
title_full An Easy Method to Prepare D3 and C2-TATP Crystals
title_fullStr An Easy Method to Prepare D3 and C2-TATP Crystals
title_full_unstemmed An Easy Method to Prepare D3 and C2-TATP Crystals
title_sort An Easy Method to Prepare D3 and C2-TATP Crystals
dc.creator.fl_str_mv Espinosa Fuentes, Eduardo Antonio
Colpas Castillo, Fredy
Meza Fuentes, Edgardo
Ropero, Jorge
dc.contributor.author.spa.fl_str_mv Espinosa Fuentes, Eduardo Antonio
Colpas Castillo, Fredy
Meza Fuentes, Edgardo
Ropero, Jorge
dc.subject.eng.fl_str_mv D3 and C2 TATP conformers
Raman
X-ray diffractogram
topic D3 and C2 TATP conformers
Raman
X-ray diffractogram
description D3 and C2 TATP structures interconvert at room temperature. Herein, an easy method to isolate both conformers is shown that consists of multiple recrystallization steps using different solvent and heating to boiling. Spectroscopic and physical measurements, such as Raman spectroscopy, X-ray diffraction, and melting point analysis, showed that clear and opaque crystals, respectively, represent different conformations of TATP. Additionally, the transition energy between both conformers was estimated using the Raman shifts.
publishDate 2016
dc.date.issued.none.fl_str_mv 2016
dc.date.accessioned.none.fl_str_mv 2018-11-10T20:06:40Z
dc.date.available.none.fl_str_mv 2018-11-10T20:06:40Z
dc.type.spa.fl_str_mv Artículo de revista
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dc.type.content.spa.fl_str_mv Text
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/article
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dc.type.version.spa.fl_str_mv info:eu-repo/semantics/acceptedVersion
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dc.identifier.issn.spa.fl_str_mv 07213115
dc.identifier.uri.spa.fl_str_mv https://hdl.handle.net/11323/864
dc.identifier.doi.spa.fl_str_mv https://doi.org/10.1002/prep.201500245
dc.identifier.instname.spa.fl_str_mv Corporación Universidad de la Costa
dc.identifier.reponame.spa.fl_str_mv REDICUC - Repositorio CUC
dc.identifier.repourl.spa.fl_str_mv https://repositorio.cuc.edu.co/
identifier_str_mv 07213115
Corporación Universidad de la Costa
REDICUC - Repositorio CUC
url https://hdl.handle.net/11323/864
https://doi.org/10.1002/prep.201500245
https://repositorio.cuc.edu.co/
dc.language.iso.none.fl_str_mv eng
language eng
dc.rights.spa.fl_str_mv Atribución – No comercial – Compartir igual
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rights_invalid_str_mv Atribución – No comercial – Compartir igual
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.publisher.spa.fl_str_mv Propellants, Explosives, Pyrotechnics
institution Corporación Universidad de la Costa
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spelling Espinosa Fuentes, Eduardo AntonioColpas Castillo, FredyMeza Fuentes, EdgardoRopero, Jorge2018-11-10T20:06:40Z2018-11-10T20:06:40Z201607213115https://hdl.handle.net/11323/864https://doi.org/10.1002/prep.201500245Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/D3 and C2 TATP structures interconvert at room temperature. Herein, an easy method to isolate both conformers is shown that consists of multiple recrystallization steps using different solvent and heating to boiling. Spectroscopic and physical measurements, such as Raman spectroscopy, X-ray diffraction, and melting point analysis, showed that clear and opaque crystals, respectively, represent different conformations of TATP. Additionally, the transition energy between both conformers was estimated using the Raman shifts.Espinosa Fuentes, Eduardo Antonio-4a2aee36-a6fd-4d38-92d3-66e15483bf70-0Colpas Castillo, Fredy-a58dfeef-b7d3-4dd6-b70d-f3ac2c117bf8-0Meza Fuentes, Edgardo-48e4de07-6e97-4229-9267-6ccec7edc159-0Ropero, Jorge-6f3ff826-2f63-4c62-a4a3-f49661251c1e-0engPropellants, Explosives, PyrotechnicsAtribución – No comercial – Compartir igualinfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2D3 and C2 TATP conformersRamanX-ray diffractogramAn Easy Method to Prepare D3 and C2-TATP CrystalsArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/acceptedVersionPublicationORIGINALAn Easy Method to Prepare D3.pdfAn Easy Method to Prepare D3.pdfapplication/pdf179060https://repositorio.cuc.edu.co/bitstreams/8ea425ba-8792-48f9-98b9-7d99028c925b/download3063bd3aa4b8d83e5416f14161631448MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://repositorio.cuc.edu.co/bitstreams/9276947d-2aac-4019-83a2-4cc14b4a6297/download8a4605be74aa9ea9d79846c1fba20a33MD52THUMBNAILAn Easy Method to Prepare D3.pdf.jpgAn Easy Method to Prepare D3.pdf.jpgimage/jpeg30559https://repositorio.cuc.edu.co/bitstreams/14556016-966e-416b-8f86-767113f737c4/download665165b319b6bf6db8474864622fbb2dMD54TEXTAn Easy Method to Prepare D3.pdf.txtAn Easy Method to Prepare D3.pdf.txttext/plain763https://repositorio.cuc.edu.co/bitstreams/0c7053e1-33e6-451a-bea7-6e3b096164bb/downloadc6a0d0bc59afab41eb60aa2408add469MD5511323/864oai:repositorio.cuc.edu.co:11323/8642024-09-17 11:00:08.612open.accesshttps://repositorio.cuc.edu.coRepositorio de la Universidad de la Costa CUCrepdigital@cuc.edu.coTk9URTogUExBQ0UgWU9VUiBPV04gTElDRU5TRSBIRVJFClRoaXMgc2FtcGxlIGxpY2Vuc2UgaXMgcHJvdmlkZWQgZm9yIGluZm9ybWF0aW9uYWwgcHVycG9zZXMgb25seS4KCk5PTi1FWENMVVNJVkUgRElTVFJJQlVUSU9OIExJQ0VOU0UKCkJ5IHNpZ25pbmcgYW5kIHN1Ym1pdHRpbmcgdGhpcyBsaWNlbnNlLCB5b3UgKHRoZSBhdXRob3Iocykgb3IgY29weXJpZ2h0Cm93bmVyKSBncmFudHMgdG8gRFNwYWNlIFVuaXZlcnNpdHkgKERTVSkgdGhlIG5vbi1leGNsdXNpdmUgcmlnaHQgdG8gcmVwcm9kdWNlLAp0cmFuc2xhdGUgKGFzIGRlZmluZWQgYmVsb3cpLCBhbmQvb3IgZGlzdHJpYnV0ZSB5b3VyIHN1Ym1pc3Npb24gKGluY2x1ZGluZwp0aGUgYWJzdHJhY3QpIHdvcmxkd2lkZSBpbiBwcmludCBhbmQgZWxlY3Ryb25pYyBmb3JtYXQgYW5kIGluIGFueSBtZWRpdW0sCmluY2x1ZGluZyBidXQgbm90IGxpbWl0ZWQgdG8gYXVkaW8gb3IgdmlkZW8uCgpZb3UgYWdyZWUgdGhhdCBEU1UgbWF5LCB3aXRob3V0IGNoYW5naW5nIHRoZSBjb250ZW50LCB0cmFuc2xhdGUgdGhlCnN1Ym1pc3Npb24gdG8gYW55IG1lZGl1bSBvciBmb3JtYXQgZm9yIHRoZSBwdXJwb3NlIG9mIHByZXNlcnZhdGlvbi4KCllvdSBhbHNvIGFncmVlIHRoYXQgRFNVIG1heSBrZWVwIG1vcmUgdGhhbiBvbmUgY29weSBvZiB0aGlzIHN1Ym1pc3Npb24gZm9yCnB1cnBvc2VzIG9mIHNlY3VyaXR5LCBiYWNrLXVwIGFuZCBwcmVzZXJ2YXRpb24uCgpZb3UgcmVwcmVzZW50IHRoYXQgdGhlIHN1Ym1pc3Npb24gaXMgeW91ciBvcmlnaW5hbCB3b3JrLCBhbmQgdGhhdCB5b3UgaGF2ZQp0aGUgcmlnaHQgdG8gZ3JhbnQgdGhlIHJpZ2h0cyBjb250YWluZWQgaW4gdGhpcyBsaWNlbnNlLiBZb3UgYWxzbyByZXByZXNlbnQKdGhhdCB5b3VyIHN1Ym1pc3Npb24gZG9lcyBub3QsIHRvIHRoZSBiZXN0IG9mIHlvdXIga25vd2xlZGdlLCBpbmZyaW5nZSB1cG9uCmFueW9uZSdzIGNvcHlyaWdodC4KCklmIHRoZSBzdWJtaXNzaW9uIGNvbnRhaW5zIG1hdGVyaWFsIGZvciB3aGljaCB5b3UgZG8gbm90IGhvbGQgY29weXJpZ2h0LAp5b3UgcmVwcmVzZW50IHRoYXQgeW91IGhhdmUgb2J0YWluZWQgdGhlIHVucmVzdHJpY3RlZCBwZXJtaXNzaW9uIG9mIHRoZQpjb3B5cmlnaHQgb3duZXIgdG8gZ3JhbnQgRFNVIHRoZSByaWdodHMgcmVxdWlyZWQgYnkgdGhpcyBsaWNlbnNlLCBhbmQgdGhhdApzdWNoIHRoaXJkLXBhcnR5IG93bmVkIG1hdGVyaWFsIGlzIGNsZWFybHkgaWRlbnRpZmllZCBhbmQgYWNrbm93bGVkZ2VkCndpdGhpbiB0aGUgdGV4dCBvciBjb250ZW50IG9mIHRoZSBzdWJtaXNzaW9uLgoKSUYgVEhFIFNVQk1JU1NJT04gSVMgQkFTRUQgVVBPTiBXT1JLIFRIQVQgSEFTIEJFRU4gU1BPTlNPUkVEIE9SIFNVUFBPUlRFRApCWSBBTiBBR0VOQ1kgT1IgT1JHQU5JWkFUSU9OIE9USEVSIFRIQU4gRFNVLCBZT1UgUkVQUkVTRU5UIFRIQVQgWU9VIEhBVkUKRlVMRklMTEVEIEFOWSBSSUdIVCBPRiBSRVZJRVcgT1IgT1RIRVIgT0JMSUdBVElPTlMgUkVRVUlSRUQgQlkgU1VDSApDT05UUkFDVCBPUiBBR1JFRU1FTlQuCgpEU1Ugd2lsbCBjbGVhcmx5IGlkZW50aWZ5IHlvdXIgbmFtZShzKSBhcyB0aGUgYXV0aG9yKHMpIG9yIG93bmVyKHMpIG9mIHRoZQpzdWJtaXNzaW9uLCBhbmQgd2lsbCBub3QgbWFrZSBhbnkgYWx0ZXJhdGlvbiwgb3RoZXIgdGhhbiBhcyBhbGxvd2VkIGJ5IHRoaXMKbGljZW5zZSwgdG8geW91ciBzdWJtaXNzaW9uLgo=