Investigation of biochar from Cedrella fissilis applied to the adsorption of atrazine herbicide from an aqueous medium
Biochar was produced from the sawdust of the wood forest species Cedrella fissilis and later used as an adsorbent to remove atrazine herbicide from aqueous media. Biochar showed high thermal stability, an amorphous structure, and a highly irregular surface, mainly composed of carbon-containing bonds...
- Autores:
-
Hernandes, Paola T.
Dison S.P., Franco
georgin, jordana
P. G. Salau, Nina
Dotto, Guilherme Luiz
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2022
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/9184
- Acceso en línea:
- https://hdl.handle.net/11323/9184
https://doi.org/10.1016/j.jece.2022.107408
https://repositorio.cuc.edu.co/
- Palabra clave:
- Adsorption
Atrazine
Biochar
Pesticides
River water
- Rights
- embargoedAccess
- License
- Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)
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| dc.title.eng.fl_str_mv |
Investigation of biochar from Cedrella fissilis applied to the adsorption of atrazine herbicide from an aqueous medium |
| title |
Investigation of biochar from Cedrella fissilis applied to the adsorption of atrazine herbicide from an aqueous medium |
| spellingShingle |
Investigation of biochar from Cedrella fissilis applied to the adsorption of atrazine herbicide from an aqueous medium Adsorption Atrazine Biochar Pesticides River water |
| title_short |
Investigation of biochar from Cedrella fissilis applied to the adsorption of atrazine herbicide from an aqueous medium |
| title_full |
Investigation of biochar from Cedrella fissilis applied to the adsorption of atrazine herbicide from an aqueous medium |
| title_fullStr |
Investigation of biochar from Cedrella fissilis applied to the adsorption of atrazine herbicide from an aqueous medium |
| title_full_unstemmed |
Investigation of biochar from Cedrella fissilis applied to the adsorption of atrazine herbicide from an aqueous medium |
| title_sort |
Investigation of biochar from Cedrella fissilis applied to the adsorption of atrazine herbicide from an aqueous medium |
| dc.creator.fl_str_mv |
Hernandes, Paola T. Dison S.P., Franco georgin, jordana P. G. Salau, Nina Dotto, Guilherme Luiz |
| dc.contributor.author.spa.fl_str_mv |
Hernandes, Paola T. Dison S.P., Franco georgin, jordana P. G. Salau, Nina Dotto, Guilherme Luiz |
| dc.subject.proposal.eng.fl_str_mv |
Adsorption Atrazine Biochar Pesticides River water |
| topic |
Adsorption Atrazine Biochar Pesticides River water |
| description |
Biochar was produced from the sawdust of the wood forest species Cedrella fissilis and later used as an adsorbent to remove atrazine herbicide from aqueous media. Biochar showed high thermal stability, an amorphous structure, and a highly irregular surface, mainly composed of carbon-containing bonds. The isothermal curves confirmed that the increase in temperature favored the adsorption of the herbicide. The Langmuir model best suited the experimental equilibrium data, with the maximum adsorption capacity of 7.68 mg g-1 at 328 K. The thermodynamic parameters confirmed a spontaneous process of an endothermic nature governed by physical interactions (interactions of van der Waals and hydrogen bonds). Kinetic studies showed that equilibrium was reached within 180 min. The linear driving force model (LDF) showed good statistical adjustment to the experimental data, where it was observed that the diffusion coefficient increased with the concentration of adsorbate. Biochar can be reused in up to three cycles. Finally, the adsorbent showed good efficiency in real water samples from rivers contaminated with atrazine, with 76.58% and 71.29% removal. |
| publishDate |
2022 |
| dc.date.accessioned.none.fl_str_mv |
2022-05-23T12:55:14Z |
| dc.date.available.none.fl_str_mv |
2022-05-23T12:55:14Z 2024 |
| dc.date.issued.none.fl_str_mv |
2022 |
| dc.type.spa.fl_str_mv |
Artículo de revista |
| dc.type.coar.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.coar.spa.fl_str_mv |
http://purl.org/coar/resource_type/c_6501 |
| dc.type.content.spa.fl_str_mv |
Text |
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info:eu-repo/semantics/article |
| dc.type.redcol.spa.fl_str_mv |
http://purl.org/redcol/resource_type/ART |
| dc.type.version.spa.fl_str_mv |
info:eu-repo/semantics/acceptedVersion |
| format |
http://purl.org/coar/resource_type/c_6501 |
| status_str |
acceptedVersion |
| dc.identifier.issn.spa.fl_str_mv |
2213-3437 |
| dc.identifier.uri.spa.fl_str_mv |
https://hdl.handle.net/11323/9184 |
| dc.identifier.url.spa.fl_str_mv |
https://doi.org/10.1016/j.jece.2022.107408 |
| dc.identifier.doi.spa.fl_str_mv |
10.1016/j.jece.2022.107408 |
| dc.identifier.instname.spa.fl_str_mv |
Corporación Universidad de la Costa |
| dc.identifier.reponame.spa.fl_str_mv |
REDICUC - Repositorio CUC |
| dc.identifier.repourl.spa.fl_str_mv |
https://repositorio.cuc.edu.co/ |
| identifier_str_mv |
2213-3437 10.1016/j.jece.2022.107408 Corporación Universidad de la Costa REDICUC - Repositorio CUC |
| url |
https://hdl.handle.net/11323/9184 https://doi.org/10.1016/j.jece.2022.107408 https://repositorio.cuc.edu.co/ |
| dc.language.iso.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.ispartofjournal.spa.fl_str_mv |
Journal of Environmental Chemical Engineering |
| dc.relation.references.spa.fl_str_mv |
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Hernandes, Paola T.Dison S.P., Francogeorgin, jordanaP. G. Salau, NinaDotto, Guilherme Luiz2022-05-23T12:55:14Z20242022-05-23T12:55:14Z20222213-3437https://hdl.handle.net/11323/9184https://doi.org/10.1016/j.jece.2022.10740810.1016/j.jece.2022.107408Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/Biochar was produced from the sawdust of the wood forest species Cedrella fissilis and later used as an adsorbent to remove atrazine herbicide from aqueous media. Biochar showed high thermal stability, an amorphous structure, and a highly irregular surface, mainly composed of carbon-containing bonds. The isothermal curves confirmed that the increase in temperature favored the adsorption of the herbicide. The Langmuir model best suited the experimental equilibrium data, with the maximum adsorption capacity of 7.68 mg g-1 at 328 K. The thermodynamic parameters confirmed a spontaneous process of an endothermic nature governed by physical interactions (interactions of van der Waals and hydrogen bonds). Kinetic studies showed that equilibrium was reached within 180 min. The linear driving force model (LDF) showed good statistical adjustment to the experimental data, where it was observed that the diffusion coefficient increased with the concentration of adsorbate. Biochar can be reused in up to three cycles. Finally, the adsorbent showed good efficiency in real water samples from rivers contaminated with atrazine, with 76.58% and 71.29% removal.10 páginasapplication/pdfengElsevier BVUnited KingdomAtribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)© 2022 Elsevier Ltd. All rights reserved.https://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/embargoedAccesshttp://purl.org/coar/access_right/c_f1cfInvestigation of biochar from Cedrella fissilis applied to the adsorption of atrazine herbicide from an aqueous mediumArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/acceptedVersionhttps://www.sciencedirect.com/science/article/pii/S2213343722002810Journal of Environmental Chemical Engineering[1] T.B. Hayes, A. Collins, M. Lee, M. Mendoza, N. Noriega, A.A. Stuart, A. Vonk, Hermaphroditic, demasculinized frogs after exposure to the herbicide atrazine at low ecologically relevant doses, Proc. Natl. Acad. Sci. U.S.A. 99 (2002) 5476–5480, https://doi.org/10.1073/pnas.082121499.[2] J.P. Lasserre, F. Fack, D. Revets, S. Planchon, J. Renaut, L. Hoffmann, A.C. Gutleb, C.P. Muller, T. 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Ed. 55 (2016) 12596–12624, https://doi.org/10.1002/anie.201600547.101310AdsorptionAtrazineBiocharPesticidesRiver waterPublicationORIGINALInvestigation of biochar from Cedrella fissilis applied to the adsorption of atrazine herbicide from an aqueous medium.pdfInvestigation of biochar from Cedrella fissilis applied to the adsorption of atrazine herbicide from an aqueous medium.pdfapplication/pdf2943607https://repositorio.cuc.edu.co/bitstreams/57bd167a-ddb4-4249-9fc2-a4c590f29903/downloadd163d2f01c3ac6286d3939bd2e465032MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-83196https://repositorio.cuc.edu.co/bitstreams/96c39d4a-1e8e-429b-bc4f-973985a24bb6/downloade30e9215131d99561d40d6b0abbe9badMD52TEXTInvestigation of biochar from Cedrella fissilis applied to the adsorption of atrazine herbicide from an aqueous medium.pdf.txtInvestigation of biochar from Cedrella fissilis applied to the adsorption of atrazine herbicide from an aqueous 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