Adsorption and photocatalytic degradation of pesticides into nanocomposites: a review

The extensive use of pesticides in agriculture has significantly impacted the environment and human health, as these pollutants are inadequately disposed of into water bodies. In addition, pesticides can cause adverse effects on humans and aquatic animals due to their incomplete removal from the aqu...

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Autores:
Bruckmann, Franciele
Schnorr, Carlos Eduardo
Oviedo, Leandro R.
Knani, Salah
Silva Oliveira, Luis Felipe
Silva, William L.
Dotto, Guilherme Luiz
Bohn Rhoden, Cristiano R.
Tipo de recurso:
Article of investigation
Fecha de publicación:
2022
Institución:
Corporación Universidad de la Costa
Repositorio:
REDICUC - Repositorio CUC
Idioma:
eng
OAI Identifier:
oai:repositorio.cuc.edu.co:11323/10798
Acceso en línea:
https://hdl.handle.net/11323/10798
https://repositorio.cuc.edu.co/
Palabra clave:
Emerging pollutants
Nanotechnology
Sustainability
Rights
openAccess
License
Atribución 4.0 Internacional (CC BY 4.0)
id RCUC2_9526e4e5bcefd8eedbb7624480ba8b62
oai_identifier_str oai:repositorio.cuc.edu.co:11323/10798
network_acronym_str RCUC2
network_name_str REDICUC - Repositorio CUC
repository_id_str
dc.title.eng.fl_str_mv Adsorption and photocatalytic degradation of pesticides into nanocomposites: a review
title Adsorption and photocatalytic degradation of pesticides into nanocomposites: a review
spellingShingle Adsorption and photocatalytic degradation of pesticides into nanocomposites: a review
Emerging pollutants
Nanotechnology
Sustainability
title_short Adsorption and photocatalytic degradation of pesticides into nanocomposites: a review
title_full Adsorption and photocatalytic degradation of pesticides into nanocomposites: a review
title_fullStr Adsorption and photocatalytic degradation of pesticides into nanocomposites: a review
title_full_unstemmed Adsorption and photocatalytic degradation of pesticides into nanocomposites: a review
title_sort Adsorption and photocatalytic degradation of pesticides into nanocomposites: a review
dc.creator.fl_str_mv Bruckmann, Franciele
Schnorr, Carlos Eduardo
Oviedo, Leandro R.
Knani, Salah
Silva Oliveira, Luis Felipe
Silva, William L.
Dotto, Guilherme Luiz
Bohn Rhoden, Cristiano R.
dc.contributor.author.none.fl_str_mv Bruckmann, Franciele
Schnorr, Carlos Eduardo
Oviedo, Leandro R.
Knani, Salah
Silva Oliveira, Luis Felipe
Silva, William L.
Dotto, Guilherme Luiz
Bohn Rhoden, Cristiano R.
dc.subject.proposal.eng.fl_str_mv Emerging pollutants
Nanotechnology
Sustainability
topic Emerging pollutants
Nanotechnology
Sustainability
description The extensive use of pesticides in agriculture has significantly impacted the environment and human health, as these pollutants are inadequately disposed of into water bodies. In addition, pesticides can cause adverse effects on humans and aquatic animals due to their incomplete removal from the aqueous medium by conventional wastewater treatments. Therefore, processes such as heterogeneous photocatalysis and adsorption by nanocomposites have received special attention in the scientific community due to their unique properties and ability to degrade and remove several organic pollutants, including pesticides. This report reviews the use of nanocomposites in pesticide adsorption and photocatalytic degradation from aqueous solutions. A bibliographic search was performed using the ScienceDirect, American Chemical Society (ACS), and Royal Society of Chemistry (RSC) indexes, using Boolean logic and the following descriptors: “pesticide degradation” AND “photocatalysis” AND “nanocomposites”; “nanocomposites” AND “pesticides” AND “adsorption”. The search was limited to research article documents in the last ten years (from January 2012 to June 2022). The results made it possible to verify that the most dangerous pesticides are not the most commonly degraded/removed from wastewater. At the same time, the potential of the supported nanocatalysts and nanoadsorbents in the decontamination of wastewater-containing pesticides is confirmed once they present reduced bandgap energy, which occurs over a wide range of wavelengths. Moreover, due to the great affinity of the supported nanocatalysts with pesticides, better charge separation, high removal, and degradation values are reported for these organic compounds. Thus, the class of the nanocomposites investigated in this work, magnetic or not, can be characterized as suitable nanomaterials with potential and unique properties useful in heterogeneous photocatalysts and the adsorption of pesticides.
publishDate 2022
dc.date.issued.none.fl_str_mv 2022-09-23
dc.date.accessioned.none.fl_str_mv 2024-02-28T13:35:56Z
dc.date.available.none.fl_str_mv 2024-02-28T13:35:56Z
dc.type.spa.fl_str_mv Artículo de revista
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.content.spa.fl_str_mv Text
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/article
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/ART
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.coarversion.spa.fl_str_mv http://purl.org/coar/version/c_970fb48d4fbd8a85
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dc.identifier.citation.spa.fl_str_mv Bruckmann, F.S.; Schnorr, C.; Oviedo, L.R.; Knani, S.; Silva, L.F.O.; Silva, W.L.; Dotto, G.L.; Bohn Rhoden, C.R. Adsorption and Photocatalytic Degradation of Pesticides into Nanocomposites: A Review. Molecules 2022, 27, 6261. https://doi.org/10.3390/molecules27196261
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/11323/10798
dc.identifier.doi.none.fl_str_mv 10.3390/molecules27196261
dc.identifier.eissn.spa.fl_str_mv 1420-3049
dc.identifier.instname.spa.fl_str_mv Corporación Universidad de la Costa
dc.identifier.reponame.spa.fl_str_mv REDICUC – Repositorio CUC
dc.identifier.repourl.spa.fl_str_mv https://repositorio.cuc.edu.co/
identifier_str_mv Bruckmann, F.S.; Schnorr, C.; Oviedo, L.R.; Knani, S.; Silva, L.F.O.; Silva, W.L.; Dotto, G.L.; Bohn Rhoden, C.R. Adsorption and Photocatalytic Degradation of Pesticides into Nanocomposites: A Review. Molecules 2022, 27, 6261. https://doi.org/10.3390/molecules27196261
10.3390/molecules27196261
1420-3049
Corporación Universidad de la Costa
REDICUC – Repositorio CUC
url https://hdl.handle.net/11323/10798
https://repositorio.cuc.edu.co/
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.ispartofjournal.spa.fl_str_mv Molecules
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spelling Atribución 4.0 Internacional (CC BY 4.0)© 2022 by the authors. Licensee MDPI, Basel, Switzerlandinfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Bruckmann, Franciele Schnorr, Carlos EduardoOviedo, Leandro R.Knani, SalahSilva Oliveira, Luis FelipeSilva, William L.Dotto, Guilherme LuizBohn Rhoden, Cristiano R.2024-02-28T13:35:56Z2024-02-28T13:35:56Z2022-09-23Bruckmann, F.S.; Schnorr, C.; Oviedo, L.R.; Knani, S.; Silva, L.F.O.; Silva, W.L.; Dotto, G.L.; Bohn Rhoden, C.R. Adsorption and Photocatalytic Degradation of Pesticides into Nanocomposites: A Review. Molecules 2022, 27, 6261. https://doi.org/10.3390/molecules27196261https://hdl.handle.net/11323/1079810.3390/molecules271962611420-3049Corporación Universidad de la CostaREDICUC – Repositorio CUChttps://repositorio.cuc.edu.co/The extensive use of pesticides in agriculture has significantly impacted the environment and human health, as these pollutants are inadequately disposed of into water bodies. In addition, pesticides can cause adverse effects on humans and aquatic animals due to their incomplete removal from the aqueous medium by conventional wastewater treatments. Therefore, processes such as heterogeneous photocatalysis and adsorption by nanocomposites have received special attention in the scientific community due to their unique properties and ability to degrade and remove several organic pollutants, including pesticides. This report reviews the use of nanocomposites in pesticide adsorption and photocatalytic degradation from aqueous solutions. A bibliographic search was performed using the ScienceDirect, American Chemical Society (ACS), and Royal Society of Chemistry (RSC) indexes, using Boolean logic and the following descriptors: “pesticide degradation” AND “photocatalysis” AND “nanocomposites”; “nanocomposites” AND “pesticides” AND “adsorption”. The search was limited to research article documents in the last ten years (from January 2012 to June 2022). The results made it possible to verify that the most dangerous pesticides are not the most commonly degraded/removed from wastewater. At the same time, the potential of the supported nanocatalysts and nanoadsorbents in the decontamination of wastewater-containing pesticides is confirmed once they present reduced bandgap energy, which occurs over a wide range of wavelengths. Moreover, due to the great affinity of the supported nanocatalysts with pesticides, better charge separation, high removal, and degradation values are reported for these organic compounds. Thus, the class of the nanocomposites investigated in this work, magnetic or not, can be characterized as suitable nanomaterials with potential and unique properties useful in heterogeneous photocatalysts and the adsorption of pesticides.27 páginasapplication/pdfengMultidisciplinary Digital Publishing Institute (MDPI)Switzerlandhttps://www.mdpi.com/1420-3049/27/19/6261Adsorption and photocatalytic degradation of pesticides into nanocomposites: a reviewArtículo de revistahttp://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Molecules1. Rout, P.R.; Zhang, T.C.; Bhunia, P.; Surampalli, R.Y. Treatment technologies for emerging contaminants in wastewater treatment plants: A review. Sci. Total Environ. 2021, 753, 141990. [CrossRef] [PubMed]2. Song, B.; Xu, P.; Chen, M.; Tang, W.; Zeng, G.; Gong, J.; Zhang, P.; Ye, S. 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[CrossRef]2711927Emerging pollutantsNanotechnologySustainabilityPublicationORIGINALAdsorption and Photocatalytic Degradation of Pesticides into Nanocomposites.pdfAdsorption and Photocatalytic Degradation of Pesticides into Nanocomposites.pdfArtículoapplication/pdf6063985https://repositorio.cuc.edu.co/bitstreams/682c9b0d-2d15-4308-9b41-d58949a72fa3/downloadcfaca9f4d12d617db9e3b45d5afc831aMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-814828https://repositorio.cuc.edu.co/bitstreams/190ff29f-dfe6-4228-888f-d8019c921b8a/download2f9959eaf5b71fae44bbf9ec84150c7aMD52TEXTAdsorption and Photocatalytic Degradation of Pesticides into Nanocomposites.pdf.txtAdsorption and Photocatalytic Degradation of Pesticides into Nanocomposites.pdf.txtExtracted texttext/plain143907https://repositorio.cuc.edu.co/bitstreams/56521655-3623-4fd1-a657-7a3398c52608/download7fcf35ab8d0cdade60f5978b351afe4aMD53THUMBNAILAdsorption and Photocatalytic Degradation of Pesticides into Nanocomposites.pdf.jpgAdsorption and Photocatalytic Degradation of Pesticides into Nanocomposites.pdf.jpgGenerated Thumbnailimage/jpeg15769https://repositorio.cuc.edu.co/bitstreams/a82f8eda-d235-4e7b-a4c4-5ab1a658c54a/download629926d4d9eb427f53ab9cb0283c7f67MD5411323/10798oai:repositorio.cuc.edu.co:11323/107982024-09-17 14:11:34.607open.accesshttps://repositorio.cuc.edu.coRepositorio de la Universidad de la Costa 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ada en las Obras Colectivas.

b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.

c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).

4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:

a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).

b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.

c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.

d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:

i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.

ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.

e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.

5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.

7. Término.

a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.

b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.

8. Varios.

a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.

b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.

c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.

d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.


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